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By W. A. McKinney

The U.S. Bureau of Mines, Kennecott Copper Corp., and New Mexico Institute of Mining and Technology are cooperating on a research project to improve extraction of copper from previously leached waste dumps that are in part compacted and impervious to leach solutions. The field work is being done at the "J" leach dump, Chino Mines Division, Kennecott Copper Corp., Santa Rita, N. Mex. The laboratory percolation leaching tests were made at the U.S. Bureau of Mines Salt Lake City Metallurgy Research Center on drill core samples from the "J" dump to determine how much copper might be leached if permeability could be restored by explosive heaving or other means. The core samples from nine drill holes on "J" dump contained from 0.06 to 0.14 percent copper. Copper extractions ranging from 15 to 3 percent were obtained in 75 days by percolation leaching of minus-1-inch material with dilute sulfuric acid. The tests results indicate that about 2'7 percent of the copper remaining in the "J" dump could be extracted under ideal leaching conditions.

Jan 1, 1970

By F. A. Schinner

The present study has investigated the leachability of cadmium sulfide minerals by Thiobacillus ferrooxidans and the electrochemical reactions involved in the process. Using a cyclic voltammetric technic and carbon-paste-CdS electrodes, it was found that the bio-oxidation of semiconductor cadmium sulfide minerals consisted of a number of intermediate electrochemical reactions. The overall reaction was found to be controlled by solid state diffusion as suggested by the chrono-amperometric and chrono-potentiometric measurements. The activation energy of solid state diffusion was determined by the Sand's method to be AE=24.3 kJ. A generalized mechanism was proposed for the bacterial oxidation of cadmium sulfide by T. ferrooxidan and an explanation given for the importance of high redox potential of leach solution versus the decomposition potential of the sulfide mineral. Furthermore, the effects of n-type or p-type character of CdS substrates relative to their bioleachability was discussed.

Jan 1, 1993

By R. N. Browne

As man searches unexplored horizons for new and economic industry, he must be constantly and acutely aware of the presence or absence of that precious commodity without which Industry, indeed Man himself, could not survive --W ATE R. The water requirements of the world today are magnanimous, considering that in 1960 the estimated consumption in the united States was over 300 billion GPD (1) or more than 1,700 GPD per person (5). The magnitude of the problem can be visualized as one considers that three times this quantity of water will be required in the united States by the year 2 000, when the dependable supplies of water are estimated to be only two-thirds of that required(2). How, then, can we continue to wreak such havoc on that life-sustaining substance -W ATE R? It is necessary, indeed mandatory, that those engaged in the Engineering profession consider it their moral obligation, not only to conserve the quantity of water which their conceived projects may require, but also to treat the effluent in order that the eutro-phication of natural water courses not be abnormally accelerated. The International Nickel Company of Canada Limited consumes some 33-1/2 millions of gallons of fresh water daily at its nine town-sites, fourteen mines and eight plants throughout the Sudbury district of Ontario. The present daily reuse of water exceeds 100 millions of gallons in the same area. It is noteworthy to mention that the milling rate has increased from 46,000 to 70,000 tons per day during the past five years, with no increase in water consumption. In fact, there has been a reduction in fresh water requirements.

Jan 1, 1971

By M. G. Vieira

This investigation addressed the possibility of producing pellet feed at a silica content of = 1.0% using a representative sample of Samarco´s mechanical flotation tailings. This sample contained 11.0% Fe and presented an F80 = 116 µm and a d50 = 63 µm. The higher silica content was verified in the coarser fractions and the higher iron content in the fraction -37 µm. Specular hematite is the most abundant mineralogical phase in the fraction -37 µm. The technological tests used one of four methods: magnetic concentration using a wet high-intensity magnetic separator, magnetic concentration using a SLon high-gradient magnetic separator, reverse flotation or direct flotation. The methods using the magnetic concentrator SLon, reverse flotation and direct flotation did not present results meeting the target of the study: iron content in the concentrate (rougher stage) greater than 34% or iron recovery greater than 80%. Cleaner stages were not achievable with the resulting concentrates. In contrast, the most successful method consisted of using wet high-intensity magnetic separators (WHIMS) as a rougher stage and reverse flotation as a cleaner stage. Using this route, it was possible to produce a pellet feed with a silica grade of 1.0% and high specular hematite content.

Jan 1, 2010

By Ivan C. Machado

In full autogenous grinding (FAG Mills) the ore itself determines almost exclusively the product size that will be produced, as opposed to conventional steel-media grinding where the product size can be "engineered" by changing media size, feed size, feed rate, classifier cutpoint size, etc. SAG Mills are in the middle of the way, since they offer some room to engineer their product size by properly defining some critical process variables, such as feed size, ball charge and size, mill charge and speed. SAG Mill product P80 values are typically in the range of 500 µm (35 US mesh) to 2000 µm (10 US mesh.) Whenever it is possible to determine an optimum value for the SAG Mill product P80 value (which will be the Ball Mill fresh feed F80 value), the Engineer should define the process variables that will yield a SAG product size as close as possible to the optimum calculated P80 value. In general, a coarser SAG product will draw less power from the SAG Mill and more power from the Ball Mill, and conversely, a finer SAG product will draw more power from the SAG Mill and less power from the Ball Mill. Metal consumption analyses also have to be taken into consideration, for they typically account for 30% to 45% of the total grinding cost. This presentation addresses the issue of defining an optimum SAG Mill product size (X=P80), during the design phase of the SAG and Ball milling circuits, from a general perspective, i.e., the SAG product size that will lead to an overall SAG Mill - Ball Mill optimum performance. Bond's Third Law approach is used, as well as the SPI (SAG Power Index), and also the generally accepted equations and Engineering Practice currently utilized to design SAG Mill

Jan 1, 1999

By Fiona M. Doyle, Christopher R. Lubeck, Michael C. Chin

The fundamentals behind a novel approach for creating inorganic/polymer hybrids are described. The binding of +2 charged ions, specifically Cue-and Cat+, to ionic functional groups is explored through UV-Vis spectroscopy and zeta potential measurements. The novel approach uses an electric field to drive ions into a functionalized polymeric matrix, thereby inducing the precipitation of calcium phosphate species. Scanning electron microscopy images of the resulting composite illustrate the results of these precipitations with two distinct morphologies observed.

Jan 1, 2003

By Peter N. Yanker

The two types of dryers used in the drying of copper concentrates are the rotary dryer and the spray dryer. The rotary dryer has until recent history been the traditional drying method used, Although spray dryers have been used in the chemical field for many years it is only recently that they have been accepted for drying of copper concentrates. The comparison made here will apply in a narrower sense to the drying of copper concentrates as fed into the reverbatory furnaces of the Smelter. To compare a rotary dryer and a spray dryer, which are two totally different methods and pieces of equipment, it is best to view them as systems each made up of certain elements

Jan 1, 1976

By Jun Yuan

Kaolin clays from five different commercial deposits in Georgia were studied to understand the variations of zeta potential and related fundamental properties. The results suggest that higher negative zeta potential is related to exchangeable or soluble calcium ions in the clays.

Jan 1, 1997

By Bryson D. Trexler

Man's activity in developing, operating, and abandoning a mine often affects the quality of the ground water and surface water. Acid water drainage from mines is an example of an impact from mining that results in degradation of ground and surface water. New flow systems are created by the mining activity. The mining made possible complex chemical reactions that, with water movement, create a discharge of low pH, poor quality water. Remedies for these problems fall into two general solutions: 1) treatment of the end product and 2) reversal of some aspect of man's disturbance of the natural system. The relative reversibility of various aspects of man's impact from mining activities ranges from relatively easy to very difficult, from economically feasible to economically infeasible, and from technically possible to essentially impossible with present knowledge. The relative reversibility of a mine-related problem cannot be assessed without first understanding the detailed physical interactions that combine to form the problem. Acid water drainage is a combination of the availability of several chemical factors with the availability of water for a transport mechanism.

Jan 1, 1982

By P. K. Ackerman, F. F. Aplan, G. H. Harris, R. R. Klimpel

Fourteen reagents that are potentially capable of chelating with a metal ion on the surface of the major copper sulfide minerals and pyrite were evaluated for their effectiveness in floating these sulfides. The reagents studied fall into the classes of mercaptobenzole mutations, thiouronium, thionocarbamates, thiourea, imidazole mutations, oximes, hydroxyquinoline and xanthogen formate. The best overall copper sulfide collector was an imidazoline (1-Hydoxyethyl - 2-Heptadecenyl), but it also proved to be an excellent collector for pyrite. Its potency as a pyrite collector can be reduced by structural alteration, but at some loss in its collecting power for the copper sulfides. The effectiveness of many of these potential collectors can be changed by minor alterations to the collector molecule and, to a lesser extent, by pH adjustment. The general order of mineral floatability with these reagents is chalcopyrite = chalcocite > covellite =bornite >> pyrite. The flotation of malachite is generally similar to that of the copper sulfides, indicating the special effectiveness of copper in the crystal lattice for collector attachment.

Jan 1, 2000

By S. Triantafyllidis

The tailings produced from the Kirki (Agios Filippos) high sulfidation epithermal deposit processing plant are laminated, weakly cemented and their particle size ranges from fine sand to fine silt. They are mainly composed of milling residues of gangue (quartz, dickite/kaolinite, pyrophyllite, illite); sulfides and secondary minerals (jarosite group minerals, butlerite, anglesite, beudantite and gypsum) are present to a lesser extent. They have high Pb and Zn (average 0.75 % and 0.57 % respectively) and low S (1.04 to 2.92 %), Cu, As, Cd, Ni and Sb content (average 248, 163, 59, 27, 20 g/t respectively). Stagnant waters forming small ponds on the surface of the impoundments exhibit low pH and high heavy metal and sulfate concentrations. Negative Net Neutralization Potential (NNP) characterizes the tailings, indicating moderate to high potential for acid generation. Application of the TCLP test revealed that the tailings are characterized as toxic because of the increased solubility of Pb and Cd. On the other hand, As TCLP solubility is very low.

Jan 1, 2006

By J. C. Squire, E. W. Baker, G. A. Sullivan, G. W. Flathers

A mine collapse severs communication with trapped miners. Landlines are crushed and commercially available radios cannot penetrate hundreds of feet of dense, conductive earth without the use of regenerative repeaters that may also be crushed. This paper describes a proof-of-concept device that uses seismic P-waves, instead of radio waves, to allow communication of a code that represents prearranged messages, including the safe haven location identifier, number of people and air quality, from trapped miners to aboveground rescue units. The transmitter designed is about 0.03 m3 (1 ft3) in size and can broadcast for four hours from its 27-kg (60-lb) battery pack. The receiver consists of a geophone and a 2.5-kg (5.5- lb) signal conditioning unit attached to a laptop computer, which displays the communication signal in real time. Testing in a bituminous coal mine with an MSHA representative revealed the device was able to transmit through 271 m (890 ft) of overburden, at 0° and 12° from vertical, using 500 W of power.

Jan 1, 2009

By Seokwon Jeon, Ho-Young Jeong

"Various numerical methods have been tried to estimate the cutting forces of a TBM disc cutter. In this study, SPH/FEM coupled method was newly employed to improve the traditional FEM analysis. The disc cutter and rock were modeled by Lagrange and SPH codes, respectively. The numerical cutting test was carried out for representative Korean rocks with different cutting conditions. The results show that the cutting forces obtained from numerical simulation had a good agreement with those from LCM tests, and that applying SPH method to rock cutting model has advantages and improvement compared to traditional FEM method. Erosion criterion and erosion limit were not required to simulate the rock fragmentation process, and the cutting forces from the numerical simulation was more stable and accurate. The results indicate that the numerical simulation can be successfully used to estimate cutting performance of a TBM. 1. INTRODUCTION Various numerical studies have been carried out to accurately simulate the limitations of linear cutting machine (LCM) tests. Numerical modelling methods have advantages comparing with full scale tests in terms of cost and time involved. Many numerical methods have been used to simulate rock cutting process by different cutting tools and the studies are summarized in Table 1.In 2D simulations listed in Table 1, because they do not take account of rolling force and horizontal rolling mechanism of a disc cutter, indenter was selected as cutting tool in their modelling. For these reason, 2D modelling is not suitable for rock cutting modelling using a disc cutter. In contrast, 3D numerical models can take account of the indentation process by thrust force and penetration processes controlled by rolling force."

Jan 1, 2016

By J. K. Mohanty, D. Panda, P. K. Sahoo, R. K. Paramguru, K. C. Nathsarma

Ferromanganese slag, a product of the manganese industry, was characterized mineralogically. The slag, which contains high Mn values, was characterized using optical microscopy, XRD analysis and electron microscopy. No separate Mn-bearing oxide mineral phase was found. The slag is amorphous, and no crystalline phase was identified in the hulk sample by XRD, However, in. fine fractions, quartz was identified. Scanning electron microscopy (SEM) revealed the presence of Mn, Si, Al and Ca in the matrix without the development of a mineral phase. Leaching experiments using H2SO4 were carried out to determine if Mn could be extracted from the slag. At room temperature, almost 100% of the manganese could be dissolved at a solid-liquid ratio o f 1:10 by leaching with dilute sulfuric acid. The impurities could be precipitated by pH adjustment to produce a manganese sulfate solution suitable for the production of MnO2 or electrolytic Mn metal. Based on the laboratory-scale experiments, a suitable process is proposed to recover manganese values from the, ferromanganese slag.

Jan 1, 1999

By H. Soto, J. Jara, F. Nava, J. B. Hiskey, B. J. Scheiner

Laboratory tests showed that ozone can destroy free cyanide and weakly complexed cyanide (copper and zinc cyanides). The iron cyanide complexes were resilient to ozonation but they were effectively eliminated by precipitation with Fe (II) ions under controlled pH conditions. Tests carried out with effluents from a number of gold mills confirmed the results obtained previously in the laboratory. The industrial samples contained cyanide in the form of free cyanide and also complex copper, zinc and iron cyanides. Solutions that contained up to 184 mg/L total cyanide, after the ozone treatment analyzed only 2-3 mg/L dissociable cyanide and 50-90 mg/L CN(t) (accounted for by iron complexes). After precipitation with ferrous ions total cyanide was reduced below 1.5 mg/L. For most solutions ozone consumption ranges from 3 to 6 g per g of cyanide destroyed. However, certain impurities (such as SCN and S203 ), present in some effluents, increase ozone consumption and make it more difficult to reduce copper concentration to satisfactory levels.

Jan 1, 1993

By D. V. Professor Keller

The production of premium coal-based fuels (<3% ash) and ultra clean coals (<1% ash) using the process of selective agglomeration requires proper selection of raw coal, rough preparation procedures, milling equipment, product coal size distribution, water purity, agglomerants, agglomeration equipment and operational procedures. Each of the variables can contribute a small fraction to the impurity load in the product coal or limit the ability of the process to separate mineral matter-free coal. Each of the variables and their importance will be examined from data produced at the bench by batch and continuous agglomeratons as well as the results from pilot plant and tonnage production units. The results are discussed which have indicated that some standard commercial coals can be produced with ash contents as low as 0.2 % ash (batch/bench) and several tonnage lots of 0.6% ash in as 200 lb/hr pilot plant. In most cases iron pyrite released from the coal matrix and with proper pH control is rejected from the product coal agglomerates.

Jan 1, 1995

By F. Calizaya, I. Duckworth

An ore-pass is an underground conduit used to transfer ore from one level of a mine to another. This method of transportation depends on the elevation energy only; therefore, it has very low operating cost. However, two inherent problems may hamper this process: (1) hang-ups of interlocked pieces and (2) a sudden release of trapped air from the ore-pass (belching). These events can create unsafe conditions with the potential for catastrophic consequences. This paper presents a summary of CFD modeling studies that were formulated to investigate the pressure build-up and belching of dust and rock particles from long ore-passes. The models were calibrated against field data collected from an actual ore-pass system and used to predict the airflow-pressure distributions in the mine for various ore feed rates and ore-pass geometries. P.T. Freeport Indonesia’s Grasberg ore-pass system (240,000 tpd capacity) was used for this purpose. This system comprises of four active ore-passes, with each being more than 600 m in vertical length.

Jan 1, 2004

By Alan Fricker, Bill Owers

Cyprus Gold NZ Ltd will be recovering residual cyanide from their CIT, operation in New Zealand. The process will use air to strip the cyanide from the acidified barren pulp. DSffi. Industrial Development, who were involved in the bench and pilot studies for Cyprus, have extended the concept to pregnant pulp. The stripping of pregnant pulp eliminates the substantial loss of cyanide through carbon catalysed oxidation during the adsorption stage. A 50% increase in cyanide recovery was obtained from an extensive laboratory investigation. The presence of a cyanide recovery circuit enables leaching to be conducted, without detriment, at pHs at least as low as 9, with consequential 50% reductions in the consumption of lime and sulphuric acid. There should be a small reduction in carbon consumption, and a significant improvement in the quality of the final effiuent, at least in terms of cyanide, cyanates, copper, zinc and sulphur. A small but significant increase in gold recovery can be expected too. There is a net economic advantage of NZ$1.20/tonne of ore by stripping pregnant rather than barren pulp.

Jan 1, 1990

By W. D. Gould, . W. Koren, P. Bedard, P .. B. Marchant

Ammonia and nitrate in metallurgical operations arise from several sources: (1) the use of ammonium nitrate based explosives, e.g. ANFO; (2) the use of cyanide for gold extraction which is degraded to ammonia by most cyanide destruction techniques; and (3) the use of nitrogenous reagents in the mill for neutralisation, flotation and extraction. The concentrations of ammonia and nitrate in effluents vary from 10-50 ppm and 25-300 ppm respectjvely. A number of environmental problems are associated with both ammonia and nitrate. Both of these forms of nitrogen can contribute to the eutrophication of receiving waters. Ammonia and organic nitrogen can also cause high dissolved oxygen demands in receiving waters. Ammonia is also toxic to fish, particularly at elevated pH values. Several methods are in use for the removal of ammonia and nitrate from municipal wastewater, industrial effluents and agricultural runoff. To date, no treatment systems have been developed specifically for the removal of nitrogen from mine and mill effluents. This paper will report on some removal techniques that have been tested using actual and synthetic mine effluents.

Jan 1, 1993

By Vincent J. Murphy

INTRODUCTION Geophysical applications to engineering projects are usually considered for reconnaissance exploration, and for some preliminary design phases. Recent experience indicates a growing need and a greater number of requests for measurements during construction. This is particularly true where seismic velocity values are related to strength properties of rock. Typical project objectives during construction are: dike and tunnel realignments required by surprise conditions encountered during foundation preparation; checks on grouting effectiveness which require velocity measurements before and after grouting; and dynamic moduli measurements along the walls of tunnels and deep excavations. This paper considers one of the on-site seismic applications that is rather simple and straightforward, and yet has few references in the literature. The specific objective is the measurement of seismic velocities (both "P" waves and "S" waves) for determining the thicknesses and dynamic moduli values of loosened zones of tunnel wall rock. PRE-EXCAVATION SEISMIC METHODS The seismic methods suitable for engineering project studies are well known and especially suited for routine site reconnaissance; these are illustrated in Fig. 1. The seismic refraction profile with a

Jan 1, 1997