Search Documents

By J. Hanna, R. Kalathur

Over the years, Alabama's coal industry has generated, during mining and cleaning operations, about 150 million st of fine waste coal, with this total increasing at a rate of 2 million stpy. Reclamation of the fine-size wastes (containing 20% - 60% clean coal by weight) provides, free of charge, mined and crushed feed stocks for coal recovery. Also, the removal or recovery of pyrite from the tailings should eliminate a major source of acid-water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the +100-mesh material produced commercial-grade coal averaging 7.6% ash, 0.8% sulfur and 13,471 Btu/lb. However, the coal yield, at about 31 % - 56%, was relatively low. Froth flotation, using mechanical and froth column methods, gave similar coal products at much higher coal recovery rates of 87% - 93%. This coal analyzed 10% ash and 1.1% sulfur.

Jan 1, 1993

By Fred H. Seymour

In spite of the progress made by geostatistical theory over the years, evaluation of low grade open pit gold deposits continues to be challenging. Many Carlin type deposits are modelled from exploration drilling spaced on 10C foot centers. From these drill holes, 50 by 50 by 20 foot blocks containing about 4000 tons of material are estimated. The block size is a compromise between being large enough for a good geostatistical estimation and being small enough for practical pit limit analysis and mine planning. Most of these gold deposits are highly variable and include ore and waste zones that are too small to be properly defined from exploration drilling information. Because of this, selective mining is controlled by sampling closely spaced blast holes where the density can be as high as 50 blast holes per exploration drill hole intercept. Figure 1 illustrates an example of the ore/waste contact definition before and after blast hole sampling. With exploration information only, a tentative ore/waste contact can be drawn between the exploration blocks.

Jan 1, 1989

By Michael J. Pratko

The bulk handling industries have long been plagued with problems in their attempt to obtain one of their major goals - the maximum efficiency for which a bulk handling flow system was designed. Mentor Dynamics Ltd. is an international firm with offices in Canada, Japan, and the United States. Mentor Dynamics Ltd. is in the business of solving the "why not" of a system and engineers the solution for the problem. Studies of the varied difficulties encountered with bulk flow systems indicate that 90% of all flow problems fall into one or more of the following categories: abrasion, impact, sticking, and/or inadequate design. These problems can occur with a myriad of bulk solids: coal, gypsum, aragonite, phosphate, fly ash, ore. Solutions to the problems are as varied as the problems. The proper lining material, ceramic, urethane, rubber, and/ or ultra high molecular weight polyethylene, must be coupled with the correct fastening system, annular ring and 'F' cap, weld washer, button head fastener, weld studs and/or nuts and bolts.

Jan 1, 1982

By K. L. Bickel

Catalyzed diesel particulate filters (CDPFs) are used for reducing diesel particulate matter (DPM) concentrations in underground mines. The U.S. Bureau of Mines is conducting research on how catalyzed diesel particulate filters perform. Two CDPFs, with two different catalysts, are used on vehicles in two mines. The CDPFs are periodically removed from service and evaluated in the laboratory to determine their DPM collection efficiency, regeneration temperature, and effects on gaseous hydrocarbon (HC) and carbon monoxide (CO) emissions. This report summarizes the results of the laboratory evaluation, and the mines' experience with the CDPFs. Both CDPFs have operated over 2,000 h. One was evaluated after 1,646 h; its collection efficiency at one operating condition was 87.3 pct. After 2,135 h of operation it was removed from service because it was damaged. The second CDPF continues to be used after 2,328 h of service. The laboratory evaluation indicated its collection efficiency decreased after 1,584 h of use and its regeneration temperature increased from 405' C to 420' C. The mines' experiences with the two CDPFs varied. While being used on mine vehicles, both CDPFs became plugged with DPM on a number of occasions because of insufficient regeneration. CDPFs are capable of lowering DPM concentrations in diesel exhaust. They can also lower emissions of CO and HC, depending on the type of catalyst used. In this study, the performance of the CDPFs changed with use. Recommendations are given in this report for proper use of CDPFs in mines.

Jan 1, 1994

By Karl C. Dean

The current emphasis on environmental problems has focused attention on the massive nationwide accumulations of mine, mill, and smelter wastes that represent potential air and water pollution hazards. The pollution hazards can be reduced or eliminated by utilization or stabilization of these wastes. The U.S. Bureau of Mines, since the inception of the Solid Waste Disposal Act of 1965, has been conducting research to determine the practicality of various utilization and stabilization procedures. Investigations include partial extractions of desirable waste components and full utilization of the wastes as simulated soils or in ceramic or other structural products. Chemical, vegetative, and combined chemical-vegetative methods of stabilization have been actively studied. This report updates information previously developed by the Salt Lake City Metallurgy Research Center and presents the current status of antipollution solid waste work 1/,2/.

Jan 1, 1970

By Kenneth A. Gutschick, Harry L. Francis

A large number of minerals and chemicals (Table 1), some mineral-derived, are used in the treatment of both potable water and domestic sewage waste water and solids (Anon., 1990). In water treatment there are ten principal process uses as shown in Table 2 (Anon., 1990), which also lists the major chemicals in each process. Since lime (calcium oxide, calcium hydroxide, and dolomitic lime) is the largest chemical (by tonnage) used in water treatment, this chapter will deal primarily with this product. Note that it is included in five of the process uses shown in Table 2, and that indirectly it is also used in at least one other category (taste and odor control, where lime is used with potassium permanganate to provide optimum pH condition). POTABLE WATER TREATMENT Water Softening The biggest use for lime in water treatment involves water softening, where it serves to reduce carbonate hardness caused by dissolved bicarbonate and carbonate compounds. Currently there are more than 1000 domestic water softening plants (Table 3) located in most sections of the country, but particularly in Ohio, other midwestern states, Florida, and Texas, where limestone bedrock abounds (Anon., 1990). Among the other uses for lime in water treatment are coagulation, disinfection, and removal of heavy metals due to high pH softening, removal of certain radioactive and organic compounds and fluorides, neutralization of acidic water, removal of silica, particularly with dolomitic lime, and removal of color. Most of the above advantages accompany water softening, although at some plants lime is used specifically for one purpose, such as silica removal with dolomitic lime, minimizing pipeline corrosion by addition of lime to correct an aggressive water, and others. Hardness in water comprises two types - carbonate hardness, caused by dissolved calcium and magnesium carbonates and bi- carbonates, and non-carbonate hardness caused by dissolved non- carbonate salts, particularly calcium sulfate, calcium chloride, magnesium sulfate, and magnesium chloride. Total hardness is the sum of the carbonate hardness and non-carbonate hardness. Waters are classified as soft (0 to 75 mg/L as CaCO,), moderate (75 to 150 mg/L), hard (150 to 300 mg/L), and very hard (above 300 mg/L). Most water plants strive to reduce total hardness to about 100 mg/L, although in recent years the tendency in some cities has been to allow a little higher value in order to reduce both chemical costs and the amount of water softening sludges produced. There are four basic types of softening plants: lime softening, primarily to reduce carbonate hardness; lime-soda softening, for reduction of both types of hardness (in some plants caustic soda is used in place of soda ash, but it is more costly); split lime-zeolite, where a base exchange mineral is employed in place of soda ash (this system also requires salt [sodium chloride] to regenerate the zeolite mineral); and finally zeolite softening, which is generally used in small systems for private houses and small municipalities. Principal disadvantages of the latter system are its relatively high cost and the salt requirement, which introduces considerable quantities of soluble salts into the waste water discharge system.

Jan 1, 1994

By Phillip J. Maddex

During the last 10 years there have been many new developments in transport and handling equipment. Important technical and economic developments that can be used to reduce costs are; new terminal and materials handling concepts large river tows - 40,000 tons and 9000 hp towboats slurry loading and unloading of ocean vessels long distance pipelining of solids development of the shuttle train (unit train) large ocean barges ? 25,000+ tons ? pushed & towed 150,000 ton self-unloading super tankers - 300,000+ tons container shipping Some of these developments have been discussed at SME meetings in papers describing the transportation of minerals from new mines. But, only a few papers described improved transportation from older operations. Since transportation is a major part of the delivered cost for minerals, the economic benefits to be gained by putting new transportation developments to work are very substantial. Frequently good transportation planning and management makes the difference between a marginal ore body and a very profitable one.

Jan 1, 1972

By David L. Durler

In-situ uranium mining is a relatively new and innovative method utilized for the commercial extraction of uranium. As with any mining method, however, significant environmental concerns will be evident and must be addressed in a rational and far-sighted manner. Experience has shown that radiological and non-radiological environmental problems may not manifest themselves until after the in-situ methodology has become established and matured to some degree. It is important, therefore, to recognize potential environmental concerns and incorporate them into an environmental program that spans the premining, mining, and post-mining phases of an in-situ operation.

Jan 1, 1982

By M. Misra

The interaction of xanthate with SO2 in the flotation of sphalerite and chalcopy.ite is discussed. 'The SO depression of sphaledte is due to the decomposition reaction of xanthate by SO2 The decomposition reaction is dependent on the cole ratios of xanthate/SO2, oxygen concentration and pH. Xanthate adsorbs at a faster rate by chalcopyrite than sphalerite. The faster rate of xanthate adsorption by chalcopyrite and the specific action of S02 on the surface of chalcopy.ite facilitate the selective separation of chalcopyrite from sphaledte.

Jan 1, 1989

By S. Chander

The effect of pretreatment potential on the response of a gold electrode for Eh measurements in sulfide solutions was examined in terms of measured Eh values and electrode response time. The electrode response time is defined as the time required for the electrode to reach a steady-state value. The relationship between measured Eh values and the hydrosulfide ion concentration is established. The effect of pH, the reversibility of the gold electrode in the sulfide solutions, and the reproducibility of measurements are also investigated. A mixed potential theory is proposed to explain the observations.

Jan 1, 1989

By Pradip

Chelatang agents, because of their metal specificity, can function as effective mineral processing reagents. A brief review of the work carried out in this area is presented. Some of the salient features of mineral flotation and flocculation with chehting-type reagents, such as bulk us. surface chelation, the role of pH, mineral solubility, solution chemistry of reagents, and temperature, are illustrated with appropriate examples. The problems associated with the commercialization of chelating reagents for ore beneficiation and the research efforts required in this area are also discussed.

Jan 1, 1987

By James P. Sabogal

A control and monitoring system is being developed by Betz Laboratories for the heap leach process in gold recovery. Called Betz 14000GL, the system is designed to improve gold leaching and provide savings in chemical consumption by controlling and monitoring key parameters in the heap leach gold recovery circuit. The system uses information from on-line sensors to control antiscalant chemical addition, pH and cyanide levels. The proprietary graphics and report features of the computer system allows the user to monitor and critically evaluate the performance of the process.

Jan 1, 1998

By G. X. Wang, J. O. Marsden, M. C. Fuerstenau

Zinc cementation of high-temperature carbon eluates is now used extensively in gold processing to replace electrowinning. Under these conditions, zinc consumption is high. In this paper, zinc solubility is press rated us functions of temperature, cyanide concentration and pH in the presence of gold, silver and mercury cyanides (both individually and in combined solutions). Based on the experimental results, cementation of these metals is characterized and discussed. The importance of cyanide concentration in cementation efficiency and the effect of mercury and its co-precipitation onto zinc are also discussed.

Jan 1, 1997

By R. Sharma, S. Svoronos, S. Gupta, N. A. Abdel-Khalek

This paper presents the results of a column flotation study on a fine feed sample of Florida phosphate. A central composite design was used to study the main and interaction effects of parameters affecting column efficiency. The statistical design is also used to determine the optimum conditions. The results indicate that, depending on the experimental conditions, it is possible to produce a high-grade concentrate with a high recovery. A 15ppm concentration of nonionic frother was found sufficient to maximize the recovery at pH of 9.5.

Jan 1, 2002

By Ross W. Smith, Xiapeng Zheng, Merrill P. Allen

The results of flotation of a primary desliming hydrosizer overflow material containing 14.6 wt.% P20, and 3.6 wt.% MgO are presented. The phosphate minerals were collophane and francolite and all minerals appeared to be liberated. The material had not been previously treated with flotation reagents. In the experimentation, various collectors were evaluated for effectiveness. The relative effectiveness of flotation in different flotation devices was determined. Finally a two-stage flotation scheme is proposed using column flotation of dolomite in the first stage and Denver cell flotation in the second.

Jan 1, 2002

By Howard V. Sears

Prospecting in its modern context means simply the gathering of information on which, to base plans for the utilization of our mineral resources. One prospecting system familiar to T. V. viewers is the pan of the old gold prospector which, while he prospected, could produce the wealth which financed him in his search. Present day geophysical "prospecting" systems, which are based on the real or supposed responses of an ore specimen, to various stimuli finder controlled laboratory conditions, are promoted as means of reducing the cost of prospecting. The universal drawback to all geophysical systems is that they yield "soft" data which are only presumed to be analogous to ore mineralization until they can be calibrated, by conventional prospecting systems, to each actual mineral environment being tested. By this time the system usually is no longer cheap. Since the raw data are too esoteric to be used until interpreted by geophysicists, usually in the light of their own personal theories and experience, the certainty of multiple interpretation is introduced. The concept of prospecting, at St. Joe Minerals Corporation's Viburnum, Fletcher and Brushy Creek mines in the new Missouri Lead Belt, encompasses surface diamond drilling for preliminary exploration, the sub¬sequent development of ore body tonnages and grades and the establishment of mining parameters. The predominantly flat-lying mineralized formation is mined by room and pillar stoping. In an operating mine, jackhammer holer are drilled in backs and bottoms of stopes, and chip samples are taken for assay, concurrent with mining. Thus irregularities in ore bodies or nearby discontinuities are not overlooked which are above or below the general mine

Jan 1, 1971

By S. L. Zhu, Brij M. Moudgil, J. L. Pinault

Prompt neutron activation probe (PNAP) was evaluated to determine chemical composition of phosphate rock slurry in-situ. The technique was able to precisely analyze Ca, Si and H using a 252Cf source. Direct measurement of P and Mg was not accurate due to interference by the rare earth elements associated with the Florida Phosphate Rock. The solids loading, particle size distribution and flotation reagents present in the slurry had no significant effect on the accuracy of the measurements. The technique was found to be reliable also under industrial conditions.

Jan 1, 1993

By Zhengbin Cheng, Wenguang Lu, Baoqi Sun, Jiaying Tang

This paper studied the flotation separation of feldspar, zircon and kyanite from quartz with a mixture of cationic and anionic collectors. Tests show that collector mixture has specially good effect, using it, the separation of these three silicate minerals from quartz can be successfully achieved at the natural pH value of tap water in the absence of any acid, fluoride and other inorganic reagents. The properties and characteristics of collector mixture were analysed. By means of IR-spectra, ESCA and AES, the action mechanism between collector mixture and minerals was throughoutly studied.

Jan 1, 1995

By Jacques Monette

Gold and silver cyanide complexes are presently desorbed from activated carbon by means of hot caustic elutions. These solutions may or may not contain additional sodium cyanide. There are several parameters which affect the rate of stripping. Some of these include pH, ionic strength, and tempera­ture. Stripping is conducted in recirculating (ZADRA) or once through (AARL) circuits. This paper describes the development of a new chemical eluant which increases the rate of stripping of both gold and silver cyanide complexes from carbon. Two case history applications are described.

Jan 1, 1995

By S. Behl, S. Mathur

The viability of physico-chemical purification methods such as selective, flocculation for the separation of two components having similar chemical compositions and the same crystal structure but different surface properties is demonstrated. A loss of selectivity was observed in a dolomite-dolomite mixture when polyethylene oxide (PEO) (five million molecular weight) was used us the flocculant. Heteroflocculation was minimized using a low molecular weight PEO (MW =105) as a site blocking agent (SBA). Near complete separation was achieved at pH 10.5 at the 100% recovery level

Jan 1, 1996