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By S. K. Kawatra, S. Valluri

With increased CO2 emissions from steel and coal industry, there is great opportunity to capture CO2 and utilize the captured CO2 for economic advantage. The primary goal is to develop energy-efficient processes that reductively couple CO2, an abundant and renewable carbon source, for the production of value-added chemicals such as methanol, ethanol, and oxalic acid. These chemicals can be used elsewhere in the refining process or sold as valuable by-products. Geological sequestration, in comparison, has no economic return. Current CO2 utilization research at Michigan Technological University focuses on electrochemical reduction of CO2. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. This paper will present different ideas and their viability to utilize CO2 as a feedstock to produce several value-added compounds. INTRODUCTION Carbon dioxide (CO2) emissions into the atmosphere will need to be drastically reduced to curb the various undesirable effects of climate change. The large contribution in total CO2 emission originates from coal or natural gas power plants, and a considerable amount from steel plants. Average CO2 emissions in the US from steel industry is 2.9t CO2/t steel (Global CCS Institute 2013). Capturing the available CO2 from the steel and coal industries for economic advantage is a win-win situation for the industry. This technology is not only important scientifically but is also vital for a sustainable future. The various ongoing investigations can be categorized as biochemical, thermochemical, photochemical, and electrochemical approaches. Among these, the electrochemical method shows the most promise as an efficient form of CO2 conversion technology, because of its many advantages like high reactivity under ambient conditions and good extensibility from small- to large-scale processes1 BACKGROUND Extensive research has been done on the chemistry of transforming carbon dioxide into more useful products. Methods are known to convert carbon dioxide into a wide variety of substances, including methanol, isobutanol, carbohydrates, methane, carbonates, urea, formic acid, oxalic acid, carbon monoxide, epoxides, formaldehyde, and so on. Several of these (carbohydrates, formaldehyde, isobutanol etc.) are primarily results from biological processes. The rest are results of strong reduction reactions or electrolytic reduction. In short, electrolytic reduction can be used to form methane, methanol, formic acid, oxalic acid, carbon monoxide from carbon dioxide2. CO2 reduces at the cathode in an electrolysis cell. These processes have the general form of generating the carbon dioxide anion radical (2⋅−) and allowing it to react with itself or the electrolyte3. Catalysts can be added to influence the formation of the anion radical or to suppress side reactions3. The electrolyte, catalyst, voltage, electrode material and CO2 content are all known to effect the reaction pathway. Table 1 shows the overall reactions and energy requirements for electrochemical conversion of CO2 to chemicals

Jan 1, 2019

By Edwin H. Bentzen

Talc, as a mineral, is rather widespread, but as an ore sultable for mining, it is rather limited. Materials sold as "talc" range from the impeccable white material from Italy to a gray-green-bluish material from Virginia. Some uses of the material called "talc" seem to be determined by the color of the material, some by the chemistry of the material, and some by the particle size of the ground material. But, there seems to be some overlapping of criteria used to judge the acceptability of a raw material. So then, any producer of talc material that is not a consumer of this raw material is faced with the age-old problems: "what do I call the stuff, and to whom should I try to sell it?" The answer to the first part is easy: if you want a high price, call it "talc"; if you want a low price, call it "soapstone". This may seem like a very simplified answer, but it is apparent that some of the products sold as "talc" have more than a minor amount of impurities in them; whereas, if they were called "soapstone", these same products would probably get a lower price.

Jan 1, 1973

By William J. Miles, Raymond E. Blair

The oil and gas drilling industry is the largest user of "functional" industrial minerals for well drilling and completion. (Functional industrial minerals can be defined as those used for performance characteristics rather than composition.) This industry's use of industrial minerals involves complex mining, processing, and distribution of products. The cost of these products at the well site reflects the complexity of distribution to typically remote locations and the cost of service. Table 1 illustrates the use of functional industrial minerals by the drilling industry. The total tonnage shown is almost 2 1/2 times larger than the 3.3 Mt (3.6 million st) of kaolin used by the paper industry for filling and coating, another major use for functional industrial minerals. Drilling fluids are an indispensible part of a drilling operation. These fluids perform several functions simultaneously. They cool and lubricate the drill bit, remove formation cuttings, increase the specific gravity of the fluid to counteract formation fluid pressures, provide a filter cake on the wall of the drill hole to prevent drilling fluid loss to the formation, protect the porosity of producing zones, and prevent reaction of the formation or formation fluids with the drilling mud. When porosity of a formation exceeds the ability of the drilling fluid to form a wall cake, it is referred to as lost circulation. Because these fluids are being constantly formulated for changing formation conditions, they require a skilled technician or drilling mud engineer on the site at all times. Drilling fluids are composed of oil or water as the liquid phase, and industrial mineral products and chemicals to control chemical and physical properties. The basic function of viscosity and suspension result from the use of gelling clays and chemical and mineral dispersants; specific gravity of the mud is adjusted with mineral weighting agents; filtration control is maintained by clays and various natural and synthetic polymers; platey minerals and scrap products are used for controlling lost circulation in porous or fractured zones; salts are added to the mud to inhibit shale and clay swelling; chemicals are added for pH adjustment, prevention of corrosion, and as scavengers for formation fluid components. Because of the clay component, drilling muds have rheological properties different from conventional fluids, behaving as Bingham plastic fluids as opposed to the Newtonian behavior of water and oil. Newtonian fluids will begin to flow with the application of any force, however small. Bingham plastic fluids require a finite force or shear stress (yield value) before flow begins. Thixotropy is another property of clay-based drilling fluids. At rest they form a gel structure that suspends the weighting agents and rock cuttings. These gels break down when a finite force is applied and circulation is restored. At the bit where shear rates are the greatest, the viscosity or resistance to flow decreases, so hydraulic pressures and pumping costs are minimized. A drilling rig provides a means of rotating a hollow pipe attached to a cutting bit. A mud pit or tank is used for mixing the drilling mud and its components. A centrifugal pump delivers this fluid to the drill ripe and down to the bit

Jan 10, 1983

By Wilfred M. Kenan

The relationship of various genetic classifications of graphite, their properties and general applications are reviewed. The classifications being amorphous, flake, high crystalline (vein) primary synthetic graphite and secondary graphite. The properties discussed are size, carbon, sulfur, ash content, general chemical analysis and degree of graphitization of each type. The major sources for natural and synthetic graphite powders are discussed in addition to factors which govern the cost as well as the supply. The economics of graphite are basically determined by the consumer and the end application. Graphite is a strategic mineral and is on the government stockpile list.

Jan 1, 1984

By C. K. Jankousky

The midwestern area referred to is the Illinois basin. The coals presently worked are mainly the No. 5 and No. 6 coal seams which vary in thickness from five to eleven feet. Present average of the more important No. 6 id about nine feet. The coal can vary considerably in toughness within the same mine with some coal perhaps rashing very easily and other coal being extremely difficult to cut. Top is generally well laminated shales with some fortunate areas having limestone roof. There are local areas with troublesome top of poorly laminated shales, shale with slickensides and shale intermingled with small partings and traces of coal. The bottoms are generally one to three feet of clay which softens readily on exposure to moisture. The mines are dry although some water is released and collects from rapid penetration of the seam by continuous miners. However, there are locally wet areas. Most of this material refers to mines of the Freeman Coal Mining Corporation. The mining operations written about are underground mines in southern and central Illinois.

Jan 1, 1962

By Glenn A. Squibb

An example of market development is described. The market in rail-lake movement of coal is vital to a rail carrier because of its location. This market is threatened by nuclear and other competing fuel sources and by depressed all-rail unit train rates, The first step to develop the rail-lake transportation market consists of rate adjustments and tariff changes to force tighter scheduling of mines, railroad, port and boats, and thus reduce cost. The second step provides a surge pile at the port to eliminate most of the seasonal disadvantage of rail-lake movement and reduce car detention at the port to almost zero.

Jan 1, 1966

By DEBASHISH MISHRA, SOMU MANDAL, ASFAR MOBIN KHAN, JAI KRISHNA PANDEY, NIROJ KUMAR MOHALIK, SANTOSH KUMAR RAY

Coal is a low-cost fuel with high calorific value. Statistically, the global coal mining industry suffered 12,489 fatalities in 104 reported mining accidents from coal dust explosions during 1900 to 2020. This review article discusses the occurrence, mechanism and explosibility parameters of coal dust explosions and presents a literature survey of the laboratory and computational fluid dynamics (CFD) simulation methods of studying them, as well as a comparison of the two methods.

Feb 1, 2023

By D. Nebbia, R. Aliberti, F. Solesin

The launch of a Tunnel Boring Machine (TBM) is one of the most challenging activity parts of the construction of a tunnel. Challenges are coming from limited space available, learning curve, concurrence of other activities and in some cases from the geological conditions. Launching a TBM is an extraordinary and complicated operation requiring a great level of planning. The Earth Pressure Balance (EPB) TBM named “Chris” was successfully launched for the Northeast Boundary Tunnel, the largest component of the Clean Rivers Project in Washington, DC. Due to space and time constraints, the 8-meter diameter TBM was launched from a single 20-meter diameter shaft, with a 30-meter-long tail tunnel by means of umbilical connections. This paper presents the steps followed during the TBM assembly and launching to complete the excavation of the initial drive of the tunnel maintaining high level of efficiency and quality despite the space constraints. Specifically, it focuses on the methods and phases used to extract the excavated material (muck) from the TBM and from the tunnel, to supply consumables, precast rings and backfill grout. The paper presents results in terms of productivity, lesson learned and possible alternatives to be considered in similar conditions.

Jun 13, 2021

Newmont Mining Corp. has been producing gold from the Carlin Trend for more than 45 years. Naturally, the focus, scale and complexity of the operations have changed considerably during this time. Newmont discovered and developed the Carlin Main orebody that is located about 32 km (20 miles) north of Carlin, NV. The property was developed as a one-mine, one-gold mill treatment plant operation, which produced about 6.2 t/a (200,000 oz/year) of doré gold bars. The initial mine, mill and gold refining facilities were relatively small in comparison to today?s standards. The milling circuit used the Merrill-Crowe zinc precipitation process to recover dissolved gold and prepare a concentrated precious metal ?precipitate? to be melted into a doré bar for sale.

Jan 1, 2012

By M. B. Daza, B. Lattimer

"Even with modern detection and firefighting techniques, mine fires continue to be a safety concern. However, some underground mine fires can be addressed with the remote application of high expansion foam, reducing firefighter exposure to hazards. The flow of this foam can be numerically or computationally simulated in order to gain a better understanding of its behavior, but rheology parameters are needed as inputs to produce accurate simulations. For this reason, this work studies the rheology of firefighting high expansion foam using a foam generator and Poiseuille –Flow Rheometer. Rheological parameters for foams with expansion ratios between 250-1280 are represented by the consistency index (k) and the power law index (n) due to the results show a strong agreement with the Power Law model for non-Newtonian fluid viscosity. Furthermore, experimental results show that high expansion foam behaves as a shear thinning fluid with a power law index around 0.4 and viscosities in the range of s 0.1 Pa-s and 0.042 Pa-s under shear rates between 44 ??-1 and 187.3 ??-1. INTRODUCTION High expansion foams are called to foams with expansion ratio greater than 200. Expansion ratio (??) is defined as the ratio between the volume of foam produced (i.e. volume of foam solution and volume of gas) and the volume of foam solution used (NFPA 2014). Because of its high expansion ratio, one of the most important application of high expansion foams is to fill or flood large spaces such as hangars, storage facilities and underground mines for fire suppression. The foam can fill large structures using small quantities of foam solution within a short time (Sthamer 2012) (Martin 2012). Although the specific high expansion fire suppression mechanism has not been understood on a quantitative basis, a possible mechanism is fuel isolation when the foam act as a physical barrier between oxygen and the flame. Furthermore, as a consequence of this contact water is evaporated, causing cooling of fuel and surrounding air. Besides, water vapor as product of water evaporation causes a dilution of oxygen concentration available to the fire (Fleming and Sheinson 2012). High expansion foam can be applied remotely by means of conduit pipes or in situ close to the fire. In most of the underground mines scenarios, fires have to be addressed remotely to reduce miner and firefighter exposure to the hazards (Smith et al. 2005). Although high expansion foams should not be blasted and must be deposited directly on the area of application because of their low density (Harding et al. 2016) sometimes it is complicated to apply it directly to the fire due to complex access areas at underground mines. In these cases, foam has to be applied far away from the fire. Despite of this fact there is a lack of knowledge in terms of rheological behavior of high expansion foam under high shear rates (Gardiner, Dlugogorski, and Jameson 1998). Furthermore, there are a few attempts to simulate numerically the high expansion foam flow due to the ignorance of its rheological parameters and its complex behavior. (Weaire 2008)."

Jan 1, 2018

By Qinghua Tian, Zhipeng Xu, Dong Li, Xueyi Guo, Liu Zhu

Tellurium (Te) is an important scattered metal. Known as the vitamin of modern industry, national defense and cutting-edge technology, it is the supporting material for new high-technology materials. Currently, its separation and extraction from Te-bearing materials face problems such as long flowsheets and high reagent consumption, giving rise to an urgent need to develop new methods for its recovery.

By Jerry Wang, Greg Bold, Mahmood Khwaja, Rebecca Caldon, William Simcoe

Phase III and Phase IV of the Beaver Creek Clean River Project, Albany, NY, includes microtunnel construction of 2,320 feet of 48-inch/36-inch internal diameter (ID) conveyance pipe and a 525 foot long 9.5-ft horseshoe shape roadheader excavated tunnel. Notable challenges were encountered during the construction including mixed face tunnel conditions, undocumented existing fill ground conditions that resulted in settlement during shaft construction, and unstable tunnel face conditions. This paper discusses several of the key challenges encountered during construction and selected solutions to construction sequencing and methodology to successfully complete Phase III and Phase IV of the Beaver Creek Clean River Project.

Dec 1, 2022

By H. Bradley Johnson

A number of Federal laws affecting safety and health in the mining industry has been enacted and revised over a period of many years. We have tended to classify these laws and their applicability into three categories: 1) coal mines, 2) metal and nonmetallic mines, and 3) mines with Federal supply contracts. With the growing attention which is being given to mine safety by the Federal government, the entire mining industry should keep aware of all developments in the administration of each of these laws.

Jan 1, 1970

By A. L. Wilder, S. N. Dixon

Introduction Coeur d'Alene Mines Corp.'s largest precious metals property is located in the historic Rochester Mining District 40 km (25 miles) northeast of Lovelock, NV. The property encountered cold weather operational problems soon after its fall start-up in 1986 due to its elevation of over 1830 m (6000 ft). The problem of ice buildup on the heaps because of sprayed solution application was faced immediately. It was felt that allowing ice to build up all winter long until a spring thaw was impractical due to the large area under leach. Further, the operating cost and delivery schedule for a solution heating system was unacceptable. The development and installation of a leach solution distribution system using drip emitters made efficient, cost-effective winter operation possible. Other benefits of this system have also been observed and are discussed here. General process description 15,422 kt/day (17,000 stpd) of - 1.27-cm (-1 /2-in) crushed ore from the three-stage crushing plant are delivered to the leach pad using 77.1 t (85 st) rear dump haul trucks. The ore is drifted into place with a D-9 bulldozer. Leach panels are contiguous and are approximately 8861 m'(90,000 square ft) in area built in 6-m (20-ft) lifts. New panels are built on top of older areas to a final height of 61 m (200 ft). Each panel is ripped and cross-ripped prior to leaching. Barren solution is distributed to the heap using drip emitters at rates of 0.02 to 0.41 L/min/m2 (0.0005 to 0.01 gpm per sq ft), depending on the age of the panels. The pH of the leach solution is 10.7 with a cyanide concentration of 0.75 kg/t (1.5 lb per st). Approximately 50% of the silver and 80% of the gold are finally recovered. Pregnant solution percolates though the heap and flows by gravity into one of two 9.46 ML (2.5 million gal) pregnant solution ponds. The solution is then pumped to a conventional Merrill-Crowe process plant. Clarification takes place in three 9464 L/min (2,500 gpm) capacity filters. The solution is then pumped to a packed vacuum deareation tower for the removal of dissolved oxygen. Typical deareated solution contains 0.7 parts per million dissolved oxygen. Precipitation of gold and silver is accomplished by adding a zinc dust slurry to the deareated solution at the suction of the filter press feed pump. Precipitated gold and silver are recovered in three recessed plate and frame filter presses. Barren solution is discharged into a 11.7 ML (3.1 million gal) pond where cyanide makeup occurs. This solution is pumped back to the heap for further leaching. The precipitate filter cake, containing approximately 75% dore (Ag + Au), is then fluxed with anhydrous borax, soda ash, sodium nitrate and fluorspar to yield a neutral, bisilicate slag. The fluxed precipitate is then charged into a propane-fired melting furnace and heated to 1150° C (2100° F) for 3 1/2 hours. Slag and dore bullion are poured into conical cast iron pots yielding buttons of 800 to 1000 troy oz. The dore typically contains 98.5% silver and 1 % gold. Slag is crushed and tabled to recover the trapped dore blebs and beads. Concentrate from the table is returned to the furnace. Table tails are sent to the crushing circuit and out to the leach pad. Solution application The area kept under leach at Rochester is approximately 130 000 m2 (1.4 million sq ft). Barren solution is delivered to the pad at 21.2 kL/min (5600 gpm) for a resultant application rate of 0.16 L/min/m2 (0.004 gpm per sq ft). A traditional solution sprinkling system using No. 12 Senninger Wobblers with individual pressure regulators was installed at the onset of leaching activities. The Wobblers were placed at 9.1-m (30¬ft) staggered centers and were fed off of a gridwork of Yellowmine plastic piping. Solution flow rates were moni¬tored to each panel. The onset of cold weather with an average nighttime temperature of -12° C (10° F) made it apparent that continual operation would not be possible with the sprinklers. A significant amount of ice was built up on top of the heap, making maintenance and pipe removal dangerous, if not impossible. Leach solution application was restricted to daylight hours to inhibit ice formation. Process plant flow rates were reduced to maintain steady-state operating conditions. However, as daylight temperatures dropped below freezing, ice continued to accumulate due to the sprays. Besides the obvious operating hazards brought on by the growing icefield, there was also the potential environmental hazard associated with an early thaw melting the ice too rapidly for the solution containment facilities. One other option for preventing ice formation was heating of the barren solution prior to spraying. Initial plant design allowed for expansion of the propane storage and distribution system as well as modification of the barren piping for a solution heater. This option was not exercised because the operating costs for an adequate system would have been prohibitive, and timely delivery of a system was not available. An investigation was conducted on the various drip irriga¬tion products available, since subsurface solution applicators would eliminate ice formation altogether. Systems utilizing external flow emitters were ruled out because of their ten¬dency to clog when buried. Emitter systems using perforated tubing were also eliminated from consideration due to their inability to adequately control flow over required lengths of tubing. An in-line emitter system was finally selected which demonstrated clog resistance and adequate flow control, enabling direct burial.

Jan 1, 1990

By J. Noll, E. Cauda, T. Barone, S. Vanderslice

Measuring diesel particulate matter (DPM) for underground metal/nonmetal mine compliance samples is done by collecting DPM onto quartz fiber filters and analyzing the samples via NIOSH method 5040 for elemental carbon (EC) and total carbon (TC). As part of the sampling train, two quartz fiber filters in tandem are housed inside an SKC DPM cassette that includes an impactor. The impactor segregates DPM and mine dust, and the second filter is used to correct for adsorption of vapor phase organic carbon (OC). Since the value of the second filter is subtracted from the first, the pre-existing carbon on the filter media for both filters needs to be comparable. In addition, the pre-existing carbon on the media should be low for accurate and sensitive results. However, there have been some reports of elevated OC on the filter media of the SKC DPM cassettes, which would cause the limit of detection (LOD) to be higher than reported at times. In this study, blank SKC DPM cassettes from different batches and with different expiration dates were analyzed to quantify the amount of carbon on the filter media and to determine the LOD and limit of quantification (LOQ) associated with these samplers. It was found that the organic carbon and total carbon on the media was about five times higher than quartz media used in samplers from other studies. The average TC on the blanks was 2.57 μg/cm2 with a standard deviation of 0.70, resulting in a LOD of 21 μg/m3 TC, 8-hr Time Weighted Average (TWA), and LOQ of 69 μg/m3 TC, 8-hr TWA, when using these samplers for collecting DPM. The LOD and LOQ may be improved through some sample preparation techniques. INTRODUCTION Exposure to diesel exhaust (DE) is associated with an increased risk for lung cancer and other adverse health effects (Attfield et al. 2012, Silverman et al. 2012, Ping and Guang 2017, IARC 2012). Pronk et al. 2009 reported that the highest exposed groups to elemental carbon (EC) from DE worked in underground sites in mining and construction and they were exposed to concentrations between 27–658 μg/m3. At concentrations (1–25 μg/m3 EC) well below those observed in mining, diesel particulate matter (DPM) exposures were estimated to increase the risk of cancer by levels exceeding those typically acceptable for occupational risk in the United States and Europe (Vermeulen et al. 2014). This suggests that underground miners are especially at risk because of their more substantial exposures in confined working spaces. As a protective measure, in 2001, the Mine Safety and Health Administration (MSHA) promulgated a rule to limit exposures of metal/nonmetal underground miners to DPM to an 8-hr time-weighted average (TWA) of 160 μg/m3 total carbon (TC) (MSHA 2001, 2006).

Jan 1, 2019

By Jake Coibion, Elmira Riahi, Dominic Reda, Walter Klary, Vojtech Gall

Progressive Design-Build is becoming a more common delivery method in the tunneling industry. This approach allows the Owner to select a design-builder primarily based on qualification instead of lowest price. The delivery method promotes flexibility and collaboration at all levels from the initial design stage through construction. Using the example of the Atlanta Airport Plane Train Tunnel West Extension, value-added risk management was added during the initial design phase with an independent reviewer. This paper presents the independent reviewer transitioning from constructability review in the very early stages of design to independent design verification to on-site supervision during construction.

Jun 13, 2023

By Lorraine B. Burgin

The extensive lead time to develop most Arizona copper deposits commenced with initial production efforts before the turn of the century, when the first attempts were made to recover gold and silver and later copper from the high-grade vein deposits of the territory. Each of these discoveries, prospects, and early operations had its own lead time and life cycle as economic production was attempted. Because prices of the metals fluctuated and the higher grade material was depleted, economics forced operations to close and companies to fail. Renewed interest in the property because of improved conditions, different interpretation of the geologic structure, or new promotional ability frequently resulted in the formation of yet another company to finance the exploration and, hopefully, the development of the property. This cycle of renewed activity and subsequent abandonment was and is common, accounting for many lead times and for the long period of time from the initial location of claims to large-scale production. In order to gain a perspective on the lead-time interval necessary to achieve development of a large-scale operation, the histories of several major Arizona mines were examined, rather than a simple listing of discovery and production dates of many mines to arrive at a statistical average. The Miami, Castle Dome, Copper Cities, San Manuel, and Twin Buttes properties were studied, and as much data as possible obtained on the Pinto Valley, Esperanza, Sierrita, Pima, and Mineral Park-Ithaca Peak properties.

Jan 1, 1974

By Ron Drake

The Anderson Dam Tunnel Project is a high-priority, urgent project under construction by the Santa Clara Valley Water District in California. The project will provide a new low-level outlet for the Anderson Reservoir enabling the seismic retrofit of the Anderson Dam as mandated by the Federal Energy Regulatory Commission. This paper describes planning for construction of the tunnel through the dam’s right abutment crossing several faults in challenging and variable soft and hard ground conditions. The construction methods include SEM, hard rock drill and blast techniques, and a mechanized 8-foot (2.5 m) diameter microtunneled lake tap.

Dec 1, 2022

By Shangyong Lin, Wei Sun, Weiping Liu, Muhammad Azam, Junfeng Cheng, Yujie Zhao, David Asubonteng, Michael Ngoie

Copper concentrates have wide application in global smelting operations, comprising primarily of chalcopyrite (CuFeS2) as the principal mineral, accompanied by chalcocite (Cu2S) and bornite (Cu5FeS4) as secondary copper-bearing minerals. However, these concentrates frequently harbor detrimental impurities, notably fluorine ions, which can cause various complications during the smelting process. Moreover, an elevated fluorine content in copper concentrates may entail financial penalties and sales constraints. This review conducts a comprehensive analysis of existing methods for the removal of fluorine, presenting a nuanced assessment of their merits and demerits. It also provides valuable insights into the current landscape of fluorine elimination from copper concentrates and pinpoints pivotal areas warranting future investigation. This review endeavors to serve as a pragmatic resource for researchers and industry professionals operating within this domain.

Jan 1, 2024

By B. J. Scheiner

The Bureau of Mines has developed a system for dewatering waste slurries by flocculating mineral particles with polyethylene oxide (PEO) and dewatering the resulting flocs on static and/or rotary screens. This paper discusses data obtained from dewatering, rheology, and ion-exchange experiments. A possible mechanism is postulated for the attachment of PEO to claylike particles through a water bridge with the intershell waters of the exchanged ion and the polymer.

Jan 1, 1986