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By V. Saltas

The present work investigates whether dielectric spectroscopy can be used to detect contamination, which may appear in a natural porous material, due to the spreading of pollution. For this purpose, dielectric and conductivity measurements, in the frequency range of 10mHz to 1MHz, were carried out in sandstone samples, partially filled or saturated with solutions of leachates, at different concentrations. The experimental results suggest that although the role of water is dominant to the measured electrical conductivity, variations of two orders of magnitude are observed due to the different concentrations of leachates, in partially filled sandstone samples. Experimental data are well fitted with a Havriliak?Negami dielectric relaxation function, superimposed with a conductivity term. The parameters of the fitting function have been correlated to the concentration of leachate in the sandstone samples and considerable changes have been observed at low leachate?s concentration.

Jan 1, 2005

By R. Vergunst, E. A. Devuyst, G. Robbins

By the middle of 1989 Inco will have applied its patented cyanide removal technology to seventeen commercial operations. Removal of cyanide from CIL slurry tailings is applied at Equity Silver and Inco's new 1.200 mtpd mill at Inco/Golden Knight. Detoxification of CIP tailings is carried out by Colosseum California (3.600 mtpd), Canamax's Ketza River (360 mtpd) and Westmin's Silbak Premier (2000 tpd) operations. Repulped tailings from Merrill-Crowe flowsheets are treated at Total Erikson's Mount Skukum (300 mtpd) and Skyline's Johnny Mountain (200 mtpd) mills and barren bleed at Inco/Queenston's McBean mill (500 mtpd). Lynngold's MacLellan mill (1800 mtpd) and ERG (40.000 mtpd) treat pond supernatant water. Plating shop cyanide effluents are decyanized at Kuntz Electroplating and two other plating shops in Ontario. Details regarding some of the above operations are given. Operating and capital cost estimates for various treatment options are discussed.

Jan 1, 1989

By Fathi Habashi

At the Duisburger Kupferhütte plant in Germany, pyrite cinder is collected from the sulfuric acid manufacturers in that country and processed to recover the nonferrous metals contained in the cinder, before charging it to the blast furnace for iron recovery. A typical analysis of the cinder is given in Table 9-1. The pyrite cinder is mixed with NaCl and treated continuously in a multiple hearth furnace. The evolved gases are scrubbed with water to form a weak acid which is used for the leaching process. Each batch requires about 2 days for leaching. The concentrated leaching solution obtained in the first 15 to 20 hr is sent for copper recovery, while that subsequently obtained, being poor ill metal content, is recycled. The residue, called purple ore, now a high-grade iron ore (61-63 % Fe); is sintered and delivered to the blast furnace.

Jan 1, 1970

By Shahzad Moosa, John M. Pitt

Statistical variability in rock strength can be evaluated by rapid, inexpensive ultrasonic pulse velocity measurements, an important consideration since rational probabilistic design in rock is often hampered by the cost of obtaining sufficient strength data. Experimental ultrasonic pulse velocity measurements on a set of 96 limestone specimens showed two distinct statistical populations. Both populations followed Weibull distributions, with flexural strength distributions paralleling pulse velocity distributions. Thus, experimental results suggest that strength variability may be predicted from a few rationally selected strength measurements and several ultrasonic tests. The correspondence between strength and velocity may then be used to develop an experimental transformation function, allowing the development of a statistical distribution function for strength based on the known statistics of velocity. Comparison of experimental groups with full sets of corresponding strength1 velocity data showed the technique offers a fairly accurate description of the statistics of strength.

Jan 1, 1986

A form of column flotation cell is described in which the contact between the feed and the air stream is made in a mixing device at the top of a vertical downcomer. The air-liquid mixture flows downward to discharge into a shallow pool of pulp in the bottom of a short cylindrical column. The bubbles disengage and rise to the top of the column to overflow into a concentrate launder, while the tails are discharged from the bottom of the vessel. The main advantages of the device described are that the overall height of the column is reduced to about 1 m (3 ft), and the column can be self-inducing with respect to the air supply. Experimental results are given from tests on a feed stream to a conventional zinc cleaner circuit. Using wash water to reduce gangue entrainment, the column gave high concentrate grades and high recoveries.

Jan 1, 1987

By S. Veeramasuneni, Qingxia Liu, Susan Dichter

Gypsum (CaSO4-2H2O) is an abundant and naturally occurring mineral. Under elevated temperatures (250 to 300°F) gypsum loses its crystalline water and is converted to hemihydrate (CaSO4 -0.5H2O). The hemihydrate form is also called plaster that is widely used in wall- board, joint compound, and many other industrial applications. At temperatures higher than 450°F (up to 1,200°F), gypsum loses all crystalline water and is converted to anhydrite form (CaSO4). The loss of crystalline water at elevated temperatures is an endothermic reaction. This property makes gypsum an attractive filler and fire retardant in certain thermosetting plastics. The applications of gypsum in plastics, food, pharmaceutical, and paper coatings will be reviewed in this paper. The future of synthetic gypsum, a by product of various industrial processes, will also be discussed.

Jan 1, 2003

By Yves Picot

Construction of new installations was recently completed in the Port of Tubarao, Brazil, With this expansion the port, operated by Companhia Vale do Rio Doce (CVRD), has become the largest iron ore port in the world, with an annual throughput capacity of 60 million long tons. GROWTH OR IRON ORE EXPORTS Since its formation CVRD has steadily increased the shipment of iron ore to overseas markets. Starting with less than 100,000 tons in 1942, the yearly export volume grew to 1,500,000 tons in 1951, 5,000,000 tons in 1961 and 25,000,000 tons in 1971. The number of different grades of ore also increased during this period. Production of high grade pellets, starting in 1970, further increased the number of ore products to be shipped. In the same period the size of ore carriers increased twenty-fold to over 250,000 DWT.

Jan 1, 1974

By Gill G. Geesey, Michael R. Hankins, Paul L. Wichlacz, Anita Gianotto, John G. Jolley, Randy B. Wright

Thin films of copper [2.0 nm on germanium internal reflection elements (IREs) and 3.4 nm on germanium discs] were exposed to 10% gum arabic (aqueous solution) , 2% alginic acid (aqueous solution), 1% bacterial culture supernatant (BCS, simulated seawater solution) and 0.5% Pseudomonas atlantica exopolymer (simulated seawater solution). The IRES were monitored in situ, in real time using fourier transform infrared/cylindrical internal reflection/attenuated total reflection spectroscopy as a function of time at ambient conditions. The discs were characterized (pre- and post-exposure) by X-ray photoelectron and Auger electron spectroscopies. Ancillary graphite furnace atomic absorption spectroscopy was used to monitor the removal process of the copper thin film from the germanium substrates. Results indicate that Cu was oxidized by gum arabic, alginic acid and BCS. Furthermore, Cu was removed from the Cu/Ge interface by all four polymers. The Cu was found associated with the polymer solutions.

Jan 1, 1989

By Gary N. Greenfield

This morning, gentlemen, I should like to discuss resin anchors of a type introduced to North America approximately 2-1/2 years ago. We shall also briefly review the basics of mechanically anchored rockbolts so that a general comparison may be made. Previous efforts with synthetic resins were aimed at aiding a mechanical Or "point" anchor, obtain a better purchase in the rock mass. Resin cartridges of the type to be described in this paper are capable of achieving point anchorage or full encapsulation of mine roof or rockbolts. Of significance, therefore, is that unlike a mechanical bolt, placed and tensioned, celtite rockbolts may be fully grouted and tensioned or left untensioned in the installation sequence. Our principle effort has been to offer this system to mining and civil engineers who have encountered difficult rock conditions and wish to reinforce strata to achieve a greater degree of permanence and safety.

Jan 1, 1972

By Liuming Wu, Willis Forsling

The complexation of Alizarin Red S (ARS) at the surface of hydrous fluorapatite particles has been investigated at 25.0 C by means of potentiometric titrations, adsorption experiments in 0.1 M NaCI ionic medium, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT) studies. A chemical model describing the reaction at the aqueous mineral surface has been established under equilibrium conditions according to the reaction [== -CaOH2 + HA2 - « _ =PO CaA2 - z + H30&apos;; to (int.) = -5.61 ± 0.02 3 a =PO- logBs-1110(int.) ( ) within the range 8.40 <_ -log[H ] <_ 9.80.] Experimental data were evaluated using the computer program FITEQL on the basis of a constant capacitance model for the electric double layer. The surface complex structure, has been proposed to involve the quinoid and alpha phenolic oxygens of ARS coordinated to the calcium sites on the fluorapatite surface.

Jan 1, 1993

By John E. Auten

The computer program "Spike" is an "expert-rule based system" designed to fulfill two requirements. 1) acquaint unfamiliar personnel with big hole drilling techniques and 2) to stimulate the "old hands" in solving drilling problems. "Spike" will not make anyone a drilling expert The best way to understand a computer program is by example, but first some explanation of an? "expert-rule based system", As the name implies, the program tries to imitate a human expert. Unlike a normal computer program which uses a list of instructions to follow in a set order, a rule-base program has a collection of independent rules without an explicit list of things to do, one after the other. This type of program was mandatory to accommodate the ever changing situations and corrective actions that more accurately duplicate actual drilling operations and the advise of an experienced drilling expert.

Jan 1, 1988

By J. R. England, W. J. Taylor

The Sudbury Basin is the scene of the mining operations of the Ontario Division of the International Nickel Company of Canada, Limited. Around the rim of the geological formation and within thirty miles of the City of Sudbury are located twelve operating mines and one open pit operated by the Company. The City, with a metropolitan population of some 100,000 lies 240 miles Northwest of Toronto. In addition, there is one mine in Northwestern Ontario, at Shebandowan, 700 miles Northwest of Sudbury. In 1973 these mines produced 16.5 million short tons of ore of which 14.9 million tons were from underground and the balance from open pit operations. Mining methods include blasthole, sublevel caving, induced caving, shrinkage, cut-and-fill and undercut-and-fill. Raise boring commenced at Inco in 1964 and is now applied at all mines in the Sudbury District (Figure 1). [ ]

Jan 1, 1974

By Catherine T. Aimone

A computerized cost model has been developed to simulate the technical and economic effects of strip mine blasting in the vicinity of structures. Current surface mining regulations restrict the allowable level of production blasting as a function of this distance. Blast design modifications,&apos; therefore must be employed when blasting in the vicinity of homes to ensure compliance with federal and state regulations specifying limits to the seismic effects generated from a blast. The blasting level allowed. is computed by the charge weight of explosives per delay from the following scaled distance formula: [ ] where W is the charge weight per delay, in kilograms (pounds), D is the distance factor corresponding to the regulatory limit of peak particle velocity to which a structure may be subjected to. Current regulations specify 2.54 cm (1.0 in.) per second corresponding to a SD factor of 27 (60) (Federal Register, 1977).

Jan 1, 1982

By Vas Choudhry, Randhir Sehgal

Conventional clean coal technologies which consist of coarse coal cleaning by gravity methods and treatment of natural fines by flotation can only remove a portion of the pyritic sulfur and ash in the coal. Higher (+90%) pyritic sulfur rejection is attainable when coals are ground to ultrafine sizes to enhance liberation of the mineral matter and then cleaned. However, cleaning of coal at very fine sizes poses a number of unsolved problems, the chief one being the loss of cleaning efficiency. This, of course, means that liberation of pyrites does not always equal its rejection. In addition, the dewatering of fine- cleaned coal, and its handling, transportation, and acceptability to the utility industry a1 so pose considerable technical and economic problems, especially when compared to the FGD alternative. This paper addresses some of the critical issues involved in the cleaning of ultrafine coal s.

Jan 1, 1989

By Heribert F. Broicher

As of 1998 German companies have been engaged in research and development of LIF analyzers for rock identification, i.e. for the fingerprinting of rock by the analysis of laser-induced fluorescence (LIF). Test work in Germany, Sweden and South Africa showed the potential of this new technique, which operates online and in realtime (1). In 2003 the Finnish company IMA Engineering Ltd Oy commenced building and marketing LIF analyzers under the trade name OreSpex. Today, one OreSpex analyzer has been installed in the Kiruna Mine, Sweden to check the phosphorus content of train loads. In 2004 a second OreSpex analyzer was built for dilution control in the Argyle Diamond mine, Australia. In 2005 another LIF analyzer will be used for test work in various mines in the US. The principles of the technology and status of ongoing work are presented.

Jan 1, 2005

By Eugene R. Palowitch

From the late 1880s to the present, the Appalachian region continues to be a dominant supplier of premium-quality coals. The region contains an estimated 93.4 Gt (102.7 billion st) of demonstrated reserves in Alabama, eastern Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Virginia and West Virginia. Therefore, Appalachia will remain a source of quality coals for the metallurgical, export and utility markets. Figure 1 shows the annual production of coal in Appalachia and nationally from 1970 through 1993 (Energy Information Administration, 1994). During that 23-year period, annual domestic coal production almost doubled. Coal production from Appalachia increased at an average annual rate of only 0.7%. Coal production remained essentially constant at about 409 Mt/a (450 million stpy). Thus, Appalachia&apos;s market share decreased from 69.8% in 1970 to 47.2% in 1993 - a drop of almost one-third (Energy Information Administration, 1994).

Jan 1, 1995

By Donald P. Richards, David W. Campo, Michel Coudry

This paper presents a review of the grouting works of Line 2 of the Greater Cairo MetroSystem. The Nile River alluvial deposits underlying this ancient city provided for a challenging and sometimes difficult grouting project. Permeation grouting using state-of-the-art computerized grouting techniques, as well as extensive ground treatment by jet grout, was per-formed for soil consolidation and/or groundwater control. During the project, over 425,000m3 of ground was treated, requiring 1.4 million linear meters of drilling and PVC injection pipe, 54,000 m3 of bentonite cement and 230,000 m3 of chemical and mineral grout. In addition, over 70,000 m3 of ground was treated using the jet grout method. Relative to major international transportation projects, the grouting works for Line 2 of the Cairo Metro represent one of the largest worldwide grouting endeavors to date.

Jan 1, 1997

By Timothy N. Dunne, Joseph M. Gonzalez

This paper presents the case history of a comprehensive geotechnical investigation for the Crosstown Transport Facility, a 10,880 m long, 3.2 m diameter pressure tunnel proposed for construction in San Francisco, California. The proposed tunnel would be part of the City and County of San Francisco&apos;s Clean Water Program, and its purpose would be to convey stormwater and sewage from the east side of the City to the Pacific Ocean. Tunneling conditions were defined by surface geologic mapping, 94 exploratory borings, surface and borehole geophysics, aquifer testing, Goodman Jack testing, pressuremeter testing, and laboratory testing. Through the use of advanced coring techniques and a strictly controlled drilling fluid system, core recovery averaged 90 percent in the sheared and fractured rock of the Franciscan Formation. As a result, over 1,400 linear meters of rock core was recovered and is available for examination.

Jan 1, 1983

By James E. Brewer

Procedure for approval by the U. S. Army Corps of Engineers of a new source of aggregate is in three phases. Phase 1 consists of an investigation of a quarry or proposed quarry by district geologist and laboratory geologist and/or petrographer. The quarry face or suitable outcrop is logged in detail or, if exposures are poor, cores may be taken to determine whether further investigations are warranted. Phase 2 consists of thorough laboratory testing. Cores and crushed material are subjected to a number of acceptance and quality tests for soundness, absorption, abrasion, reactivity, and other properties. Petrographic analysis is also made. Phase 3 is a physical and economic study of the site and involves determining quantity of stone avail- available, amount-and character of overburden, condition of haul roads and distance to rail shipping point, plant flow sheets and capacity, aggregate sizes produced, and approximate price of material at plant.

Jan 1, 1966

By S. K. Kawatra, S. J. Ripke

During 1998, 62 million tons of iron ore pellets valued at $1.7 billion were shipped from U.S. mines. These pellets are the primary source for domestic iron and steel production. During pelletization, binders are required to improve the green strength of the pellets. Each year, bentonite binder costs a typical plant from $3 million to $5 million. Reducing the bentonite dosage has the advantages of significant cost savings while producing higher quality, lower silica pellets. The authors have recently identified a new and important bentonite binding mechanism, the fiber theory. During this study, procedures were developed that took advantage of the ability of bentonite to form fibers, and resulted in a dramatic decrease in the necessary bentonite dosage. Acceptable quality pellets were produced with the bentonite dosages reduced in half from 14 lb/lt (0.66%) to 7 lb/lt (0.33%).

Jan 1, 2001