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By Antrekowitsch Jürgen

The recycling of residues from metal producing by-products has become a main field of interest in metallurgical investigations. Forced by a stricter environmental legislation and the resulting increase of landfilling costs, combined with the aim to recover as many valuable metals as possible, a lot of different processes have been developed in the last two decades. Because of the high yearly tonnage residues from the iron and steel industry like slags, dusts and sludges have moved in the center of interest. Dusts from the steel mill, containing heavy metal oxides and halides did not play a considerable role as secondary raw materials for a long time. They even contain a huge amount of leachable elements and compounds which cause noticeable problems in case of a dumping. Nevertheless, the implementation of a new landfilling regulation, including a prohibition of aboveground dumping without inertisation, caused a rising interest concerning recycling technologies for such residues. In addition, the zinc content of these dusts became higher and higher and began to play the most important role for the economy of dust recycling.

Jan 1, 2006

By Renato G. Bautista

The solvent extraction separation of nickel, cobalt and their associated metals have been considered for industrial application since the early 1960's. This review of the solvent extraction processes is limited to the industrial applications, pilot plant and the more extensive bench scale studies reported in the literature. The processes with their significant chemical and technological contributions are discussed in detail whenever the information are available. The application of solvent extraction to the nickel-cobalt processing has so far been limited to the secondary separation of nickel-cobalt containing feedstocks derived from other primary nickel-cobalt separation methods.

Jan 1, 1993

By J. T. I. Poijärvi

Outokumpu Harjavalta Metals Oy operates copper and nickel smelters, three sulphuric acid plants and nickel refinery at Harjavalta and copper refinery and precious metal plant at Pori. The by-products of these plants are presented in this paper. The by-products of the smelters include products from slag cleaning of flash smelting furnaces and converters, flue dusts and smelter off-gases. Weak acid and sludges from cleaning of smelter off-gases and acids are the by-products of the acid plants. The by-products out of the copper refinery are crystallized metal sulphates and sludges from electrolyte purification, on which a co-production process of the copper tankhouse is based. The main by-products of the precious metals plant are products from anode slime treatment and platinum metal group concentrates in the recovery of precious metals. Sludges from nickel matte leaching and precipitates from solution purification are the by-products of the nickel refinery. The formation, treatment and processing as well as the research work done for the utilization instead of dumping of the by-products in the production of copper and nickel will also be discussed in this paper.

Jan 1, 1995

By J. Rastas

The recovery of lead, silver and gold from existing and potential zinc process residues using a sulfidization-flotation method was investigated on a laboratory scale. The following residues were tested: neutral leach residue, high acid leach residue, and hematite residues. The sulfidization of lead and silver is carried out at low pH by the addition of a stoichiometric amount of sulfide at a controlled rate. To increase the particle size of the sulfides, seeding with synthetic lead and silver sulfides -is employed. The flotation is carried out at pH 2-4 using low pH-collectors such as dithiophosphates and dithiophosphinates. Special attention must be paid to the role of oxygen in the conditioning stage. The effect of different parameters on both the sulfidization and the flotation has been evaluated. Recoveries of 85-90, 90-95 and about 80 % were obtained for lead, silver and gold, respectively. Typically, concentrates containing 50-60 % lead, 3-5 kg/t silver and 10-15 git gold were produced.

Jan 1, 1990

By Nobuhiro Oguma, Yuji Mizuta, Hideya Sato, Shigehiko Iwahori

"Recyclable materials containing copper and precious metals have been treated at the Mitsubishi Process in Naoshima. In 2003, a new incinerating and melting plant (pre-treatment plant) for waste materials, such as shredder residue of automobile and scrapped appliance, was constructed. All of produced slag/metal mixture is treated at the Mitsubishi Process, and which results in the significant increase of recyclable materials treatment. The combination of two processes has realized a highly efficient and environmentally friendly system for recycling valuable metals in the waste which used to be sent to a landfill. Naoshima continues to make efforts to achieve the highly efficient operations of the two processes, and plans to increase the treatment of recyclable materials further. This paper summarizes the recent operations and the various improvements implemented in the pre-treatment plant.IntroductionRecyclable materials containing valuable metals such as copper and precious metals have been treated at the Mitsubishi Continuous Copper Smelting and Converting Process (Mitsubishi Process) since the start-up in 1991. In the early stages, recyclable materials consisting mainly of metal scrap were charged into the process and the treatment had been increased steadily. In order to promote the recycling business, treatment of various kinds of materials including printed circuit boards was started. However, the treatment hit the ceiling due to a limitation of furnace boiler capacity, since they contained large amounts of combustible materials. In addition, severe corrosion of boiler tubes was caused by halogen contained in recyclable materials."

Jan 1, 2012

By Francis Vanbellen

Umicore Precious Metals Refining operates an integrated precious metals smelting and refining plant in Hoboken, Belgium. Once a smelter and refiner of complex concentrates, the plant today?s feed consists exclusively of industrial and consumer recycled products, making it the world?s largest recycling facility for precious metals. Unlike the fairy tale of the Frog Prince, it took much more than a princess? kiss to successfully realize this makeover. A completely renewed plant has been built over the past decade. The most visible technological innovation was the commissioning of the Pb-Cu smelter. Its flexibility towards very different types of feed makes it perfectly suited as main entry to the Hoboken flow sheet. A new Cu-leaching & electro winning plant and precious metals refinery make up the Precious Metals Operations (PMO) whose targets are fast throughput and maximized yields for gold, silver and the platinum group metals. The Base Metals Operations (BMO), flexibly process the by-products from the PMO, valorizing ?impurities? like indium, tellurium, selenium and others. Off gas and waste water treatments ensure compliance with strict environmental standards. Precious metals recycling is an art that goes beyond mastering a unique flow sheet. Umicore Precious Metals Refining offers a complete recycling service, taking care of sampling and assaying, metals management and logistics. The quality of this integral service is recognized through the attribution of ISO certifications for our operational activities, sampling and the environmental care. And it?s an art that follows Michelangelo?s experience: ?Art is 5% of inspiration and 95% of transpiration.?

Jan 1, 2006

By R. A. Spitz, R. Leiby, M. Bricker

Electrochemistry plays a significant role in minimizing wastes at East Penn's secondary lead smelter. East Penn has been recovering spent battery acid for reuse in new batteries since 1992. East Penn also produces a fertilizer feedstock from sulfur dioxide in the smelter stack gases. The success of these processes is, in large part, due to the installation of electrochemical cells. The cells in the acid recovery plant allow the waste from this process to be concentrated into less that 10% of the original spent acid. The cells in the fertilizer plant treat the solution to remove dissolved metals prior to sale to fertilizer manufacturers.

Jan 1, 2000

By K. R. Robilliard

Ausmelt Technology has been developed to process copper concentrates containing significant levels of lead, arsenic and antimony. A process was developed aimed at smelting these concentrate materials to remove the contaminants to fume and produce a clean copper product. The production of clean copper and the potential economic benefits of this process step over the sale of impure concentrates is discussed.

Jan 1, 1995

By Vladimiros G. Papangelakis

During the past five years, chemical modelling work at the University of Toronto has elucidated the role of soluble magnesium on the autoclave acidity and has demonstrated why feeds rich in magnesium, and other divalent metals, require more than the stoichiometric requirements in acid to produce a leaching performance comparable to that of low magnesium feeds. This understanding has allowed the calculation of acid additions to the pressure acid leach (PAL) on a less empirical basis. Optimizing acid additions to the PAL confers savings in neutralization costs, ensures high productivity and minimises corrosion problems. Hence, our picture of the solution chemistry inside the autoclave during the PAL process has been substantially improved and is reviewed here. Experimental techniques based on solubility and direct acidity measurements that support the theoretical predictions are presented. Concepts of chemical modelling of electrolyte systems at high temperature and software issues are also discussed. Finally, a better understanding of the solution chemistry at temperature has led to better kinetics models because all metal dissolution and precipitation reactions are acid driven and controlled. . Therefore, reactor modelling efforts by our group are also presented and a reactor model with very good performance, as compared to pilot-plant data, is also made here. Finally, in spite of the above success in PAL solution chemistry and reactor modelling, significant challenges lie ahead in theoretical data gaps and instrumentation; these are also discussed in this paper. Keywords: Laterites, process modelling, pressure acid leach, solution chemistry, chemical modelling, reactor simulation

Jan 1, 2004

By Z. M. Zheng

Cyclic voltammetry, potential step, and ac impedance techniques were applied to study the electrochemical reaction of arsenopyrite in chloride solutions. The relationship between anodic current density and time in potential step measurements indicates that the oxidation of arsenopyrite is irreversible. The results of the constant potential coulometry show that the stoichiometric factor of the total electron involved in the overall reaction is 14. It is proposed that the dissolution of arsenopyrite is retarded by coverage of sulfur produced in the reaction as an intermediate product. The measured results of ac impedance strongly support the proposition. The proposed reaction mechanism also explains satisfactorily the charging current density and Tafel slopes measured in potential step measurements.

Jan 1, 1995

"Depletion of known ore reserves and increased demand for precious metals have caused a revolution in biohydrometallurgical processing technology for gold recovery. Known ore deposits and future discoveries are most likely to be lower grade sulfide ores that can be difficult to recover with current leaching technology. Future metal recovery operations will increasingly use bio-oxidation techniques.Bacteria are an integral part of mineral cycling and mineral transformation in nature. Although biological processes are recognized as part of the mineralization and oxidation reactions in some ore deposits, they have only recently been applied to enhancing metal recovery in hydrometallurgical procedures. This paper explores the traditional metallurgical application of biological leaching and oxidation reactions and reviews the complete range of bacteria available for metal recovery systems. Pre-treatment of ores with bacteria improves metal recoveries in tank leaching systems and shows promise for heap leaching methods.IntroductionThere is no longer any question that bacteria playa natural role in the on-going transformation of some ore deposits (1,2). As applied to sulfide ores, a few strains have been specifically identified that exhibit a natural leaching potential (3). These bacteria can be isolated from waters and soils in old mining districts where they contribute to continuing leaching and pollution problems in acid drainage and heavy metal solubilization. Sulfur and iron bacteria as well as many heterotrophic strains have also been found in ore deposits and sedimentary rocks at depths up to 2000 meters (4). Their presence in both ore deposits and processed ores shows the microbial association with natural leaching and the potential role that bacteria can play in the development of new leaching technology."

Jan 1, 1988

By A. Hasko

Phytoremediation is a new low cost alternative technique for remediation of contaminated soils from heavy metals that are emitted by ferrous and nonferrous mining and extracting processes. It is based on the possibility to use several plants that accumulate high level of metals in order to remove metallic pollutants from soils and render them harmless. Phytoextraction is an adjacent new technique that uses these hyper-accumulator plants in order to extract the metals from them using even the conventional smelting or refming processes. In our previous work, an extensive investigation of about 150 plants have been carried and several species were identified that could be used for nickel phytoremediation and phytoextraction because of their high accumulation of nickel. It has been found that five taxa from Alyssum genus specie had the highest ability to accumulate nickel with concentrations more than 10000 ug/g (dry weight) or 1%. The taxa showing the highest accumulation of this metal is Alyssum murale var. chlorocarpum with 28 600 ug/g or 2.86%, a good candidate for Phytoextraction. In this work, in order to optimize the phytoremediation and phytoextraction processes further Absorption Spectrometry measurements and biological studies were carried out to determine the parts of the plants that accumulate the highest amount of nickel and the best biological cycle during which they accumulate the highest amount. The results show that the greatest accumulation of nickel occurred in the leaf material (2.86%) and the least in the roots (0.43%). The investigation of the biological cycle of the genus Alyssum showed that: (1) the seeds germinated between 50 C to 30 0 C and more in 25 0 C; (2) 62.9 % of seeds germinated at A.m. var. chlorocarpum; (3) the emergence is almost continue from March to April; (4) the anthesis occurs from May to July; (5) the ripening of the fruit takes place 30 days after flowering; (6) the dissemination of fruits occurs from September to October. Due to these special characteristics it is reaffirmed that Alyssum murale var. chlorocarpum, as a nickel hyperaccumulator, is the most promising plant to be used for feasible phytoremedation and phytoextraction purposes. Keywords: Key words: Phytoextraction, PhytoRemediation, Nickel accumulators, Alyssum sp., Biological cycle

Jan 1, 2003

By B. R. Davis, Neale R. Neelameggham, R. E. Brown

The element Calcium element has a unique place in the production of etals, intermetallics and other compounds. The unusualness arises from the fact that we have several possible reductants – metallic calcium, calcium carbide, calcium cyanamide and calcium hydride. A review of how metallic calcium is manufactured and utilized is presented. The difficulties involved in producing the metal in large quantities and price implications are noted. . Fundamental thermodynamics of how these act as reductants are shown, along with the historic application of these in metal production during the past century and a half. Alternate applications as to how to control the cost of the reductant is indicated, such as the numerous attempts in making low cost titanium utilizing direct or indirect calcium reductant.

Jan 1, 2014

By Houyuan Liu

A new process was developed to recover nickel and cobalt by leaching laterite ore at atmospheric pressure and.95"-105" C. The nickel-containing goethite in limonite was first leached with sulphuric acid to liberate over 90% of nickel, cobalt and iron. The dissolved iron was then precipitated as Ni-free goethite by the additioil of saprolite. The acid released during iron precipitation as goethite was simultaneously used as lixiviant to leach saprolite to recover more nickel. With this process the limonite and saprolite were essentially converted into goethite-, gypsum- and silica- containing tailings. Twenty bench scale tests and two campaigns of pilot plant operation were carried out at BHP Billiton's Newcastle Technology Centre (NTC) from January to August 2002. The overall nickel and cobalt extractions were 81 to 90% and 91 to 100% respectively. The average plant availability was 99%. The advantages of this process over existing processes include high plant availability, high consistency, robustness and simplicity of the operation.

Jan 1, 2004

By S. N. Monteiro, C. M. F. Vieira, A. P. N. M. de Sa, J. P. D. Vitorino

"This work has as its objective to characterize an ash waste and to evaluate its incorporation into a clay to produce bricks and roofing tiles. The waste is a type of fly-ash resulting from the incineration of a selected part of urban garbage, which is basically constituted of organic matter and plastics. The waste was submitted to mineralogical and chemical characterization. Compositions were prepared with incorporation of the waste in amounts of up to 20wt.% into athe clay. Rectangular specimens were prepared by extrusion and fired in a laboratory furnace at 900°C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The results showed that the waste is predominantly composed of quartz and calcium compounds. The incorporation of the ash was deleterious to the evaluated properties of the clay. It is suggested that the incorporation should be made in amounts below 5wt. % to avoid deleterious effect in the mechanical strength and water absorption of the clayey ceramic.IntroductionThe world attention has turned to a subject of great concern today, the production and disposal of large amounts of industrial wastes as well as wastes of various sources. When deposed in an unsuitable place, these wastes can cause considerable harm to human health and to the environment. Our planet suffers with air pollution, groundwater and soil contamination as well as silting of rivers and lakes with the growing amounts of our society wastes.The recycling of waste materials is of great interest to the industries, mainly due to the environmental agencies legislation. One of the practices for correct disposal of these wastes being investigated is to incorporate into red ceramics, such as bricks and roofing tiles. The natural variability of the characteristics of the clays associated with the relatively simple processing techniques and also the low performance required for the products allow the presence of relatively high levels of impurities in clayey ceramics."

Jan 1, 2011

Four slag types covering the range of Fe-Ca-Si-O compositions and two iron blast furnace slags were melted at 1300 °C and doped with 1% of arsenic, antimony, cadmium, zinc and chromium. The melts were either slow cooled or quenched and the solidified slags were leached according to TCLP procedures. The morphology of the solidified slags was characterised using XRD, optical and electron microprobe techniques. Theoretical considerations showed that the capacity of the molten slag to hold the above toxic elements depended upon slag basicity and this was confirmed in practice. The experiments showed that the leaching of the toxic elements was a function of surface area and the phases present, both of which were affected by the mode of cooling. Iron silicate slags produced in nonferrous smelting operations and blast furnace slag from ferrous smelting operations both show promise of being suitable media for immobilising low levels of toxic elements and complying with current regulatory requirements.

Jan 1, 1994

By Basant L. Tiwari

An electrolytic process, based on a three-layer concentration cell, to extract magnesium from commercial aluminum alloy scrap has been examined. The process was repeatedly tested at 1025 K with two cells of d1fferent sizes, 0.6 kg and 5 kg feed aluminum, to have a better understanding of the opera ting parameters and evaluate the scale-up potential. In both cells, the magnesium content of the scrap was selectively reduced ?from 1. 1 to less than 0.1 wt.% at anodic current dens-Hy as high as 1. 1 A/cm2 with current efficiency exceeding 85%. Magnesium was recovered in the form of salt coated globules. Comparison of performances for the two cells suggests that the process can be scaled up. With further development, this process could become a viable alternative for demagging secondary aluminum.

Jan 1, 1985

By Thomas E. P. Wechsler

The limiting factor for most pyro-metallurgical processes in secondary cop- per melting is the time required to heat and melt the product. American Combustion's proprietary PYRETRON variable £uel/air/oxygen combustion system improves the throughput of existing scrap melting and heating furnaces for copper and copper alloy production by increasing the rate of heat transfer from the flame to the product. The increased productivity and energy savings obtained from this technology can result in sizable reductions in operating costs for smelting operations.

Jan 1, 1991

By I. C. Howard, E. J. Palmiere

"Heat transfer and friction in hot flat rolling have traditionally been characterised by an average heat transfer coefficient (h) and an average friction coefficient (p.). However, the presence of oxide scales and asperities at the interface question the use of such averages. The apparent irregularity and lack of pattern of interactions at the interface has prompted this present investigation to move away from averaged h and 11 values, and to study their local evolution based on probabilistic rules. The approach is based on the probability of finding the workpiece surface in a specific configuration at a particular instance of time in the roll gap. These rules are based on observations of surface phenomena such as scale behaviour during hot rolling. The model is implemented using user-subroutines integrated with the commercially available finite element program ABAQUS™. The results show the strong dependence of h and u on the local scale interactions. In particular, the effect of scale thickness, material behaviour and processing conditions on the evolution of hand 11 are discussed. Finally, the development of a Cellular Automata based Finite Element (CAFE) model is proposed to model the combined interfacial phenomenon of friction and heat transfer at the tool-work piece interface.IntroductionIntricate interactions between process variables in hot rolling of steels make it a challenge to the modelling community. For a given material and geometry combination, reducing interfacial power losses can increase the efficiency of the rolling process. The roll-strip interface, therefore, forms the critical zone and is currently the domain of intense investigation, especially to characterize interfacial frictionl • 2 and heat transfer3 • 4 . These interfacial phenomena are inter-related and cannot be studied in isolation. However, very few mathematical models4 • 5 combine an analysis of friction and heat transfer and deformation of the strip-roll interface taking into account the role of asperities and oxide scales."

Jan 1, 2001

By B. A. Paponetti

The following report discusses the bioleaching of chalcopyrite of italian origin catalyzed by Thiobacillus ferrooxidans. The developments vcr.ius time of the main .biochemical and chemical reactions involved in the production of soiuble and insoluble species were investigated focusing on the times at which they begin and bow long they last. The precipitates were characterized both in quantity and in quality relating the rate of the process to the precipitates fonnatiom. A material. balance has been made to verify the proposed mechanism.

Jan 1, 1991