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By M. Sengupta, A. A. de Gast

"With rapid deterioration in the urban environment caused by air pollution, the possibility of chemical reaction between dimension stone and the industrial waste gases present in the ambient atmosphere remains. The chemical reaction can cause expensive damage to building stone; it is essential that a stone evaluation for use in construction should assess the possibility of this type of decay. This paper endeavours to develop testing procedures for evaluating stone decay in polluted environments. Such tests can accompany other standard tests used in dimension- stone evaluation."

Jan 1, 1972

By D. D. Hogarth

"IntroductionThe Hull iron range, comprising the Forsyth, Scott , Baldwin and Lawless properties (Fig. I), is in Gatineau Park, on the outskirt s o f the city of Hull , and about 6 miles (10 kilometres) northwest of the Federal Parliament Buildings.The deposits have been known many years and described numerous times, although the history has been treated lightly in former publications. Total ore shipments have been calculated at 122,700 long tons, of which over 80% were mined before 1900 and 74% in two brief periods: 1870-74 and 1880-82. It is surprising that the period 1870-74 has been overlooked by most authors and 1880-82 ignored altogether. More surprising, the essential data for these two periods are contained in manuscripts of the Robert Bell collection, which must have been available to officers of the Geological Survey o f Canada.The period 1801-1874 ha s already been covered by the writer in ""Pioneer mines”, but much information has come to light since publication. The present paper is therefore based o n new data and a fresh appraisal. However, little additional data were found for the early history (1801-1854) or for the legal cases involving A.H. Baldwin, and these parts were mainly summarized from the relevant sections of the above-mentioned publication.GeologyThe ore deposits are all situated somewhat below the middle of a graphitic, calcitic marble horizon, here folded into a northeast-plunging synform. The Forsyth, Scott and Baldwin deposits are on the south limb of the synform; the Lawless is on the north limb. The marble is underlain by three non-carbonate groups: biotite gneiss with interlayered quartzite (top), granite gneiss and skarn (middle), and biotite-garnet gneiss (bottom). Below these groups is a lower horizon of graphitic, calcitic marble. The whole sequence is Precambrian and has been subjected to high-grade (Grenvillian) metamorphism, but, in the north, is cut by an unmetamorphosed Cambro-Ordovician diabase dyke. For further information, the reader is referred to the summary by Baird."

Jan 1, 1983

By Alan E. Cameron

WE assemble again today in this comfortable, hospitable Inn to begin this, the 58th, Meeting of our Society. It is just a year ago when last we met but that year was, probably, the most portentious year in the whole history of mankind. In that year, the German 'Atlantic Wall' was broached, the Rhine was crossed, and Germany, as a Nation, has ceased to be. The agony of Europe is over; convalescence may be, probably will be, slow. But blood no longer flows in Europe. Time will heal the sores, cover the scars, regenerate the industries, rebuild the cities, and re-establish the people. True, the war of all wars is not yet over. True, a bloody conflict remains . But, the power of the United Nations now converges on one target. The rain of blood will be heavy. We can hope the storm will be short. The sun is on the horizon. The light of peace 1s in the sky. What of that Peace? Are we ready for it? Have we a 'sure foundation ' for our future world? Are the footings under that foundation broad and substantial? Can we look forward with confidence to a lasting peace and a fruitful life? The United Nations, even as this is being written, are in conference in San Francisco, placing the footings, rearing the foundations for a world edifice. There are bickerings; there are jealousies. The world is tired, and a tired family always squabbles. We can, we must, believe that the decisions they make, the edifices they rear, will be better than anything we each could effect separately. It will be a compromise, probably; it will carry things that will hurt us, just as it will carry things that will hurt others. We can, we must, believe that the good of the whole is a greater good than the good of the part. Each Nation within the United Nations must sacrifice something, each part of each Nation must sacrifice something, each individual within each part of each nation must contribute something, if the whole is to be wholesome. Sacrifice and contribution must be the order of the day if the New World we are about to build is to be worth while. What of Nova Scotia? The world has travelled far in the last year; how far has Nova Scotia gone? Canada has preparations for the Peace under way; what has Nova Scotia done? Is Nova Scotia preparing counter measures for the sacrifices it must make? Is each of us ready to contribute his share?

Jan 1, 1945

By Ning Zhang, Yan Chen, Qikang Yi, Linjian Ma, Guoan Wang

Laboratory tests were performed to explore the effects of frequency on the deformation property of rock salt subjected to cyclic loading under confining stress condition. A two-stage (transient and steady) evolution law of axial cumulative strain was obtained through cyclic stress-strain curves complied from the loci of minimum load of each cycle. The unloading modulus decreases with loading cycles/time as a negative exponential function. The damage of rock salt under cyclic loading is reflected by the degradation of elastic modulus. A unified damage evolution equation considering the effects of frequency and time was established based on the experimental results. A new creep damage model for rock salt was proposed by introducing the non-stationary modular components in Burgers creep equation according to the Lemaitre equivalent strain theory. Comparative study indicates that the new model can accurately describe the creep deformation and damage evolution of rock salt under different loading frequencies. This paper provides a more reasonable model and relevant mechanical parameters for the stability analysis of compressed-air storage cavern in the injection and withdrawal durations.

Jan 1, 2015

By P. Rocque, S. Talebi

Although the measurement of blast vibration close to the blasthole is critical to the understanding of rock fragmentation mechanisms and blast damage in the rock masses, limited experience for such monitoring exists. Because much higher vibration amplitude and frequency ranges are expected in rock masses close to an explosive charge as compared to far field vibrations, different problems from those for the far field monitoring must be considered for near field blast vibration monitoring. Currently, guidelines for design of the near field blast monitoring systems do not exist. This paper describes the development of an integrated technique for vibration monitoring close to a blast hole, including selection and installation of transducers, design of a monitoring system and signal recording. A densified cement was designed for grouting accelerometers in order to match p-wave impedance between the rock and grout. The monitoring technique described has proven suitable for blast vibration monitoring within 2 m to 15 m of a blast hole having loading conditions similar to production blasts.

Jan 1, 1993

By Euler De Souza

"The uninterrupted operation of a ventilation system is critical to ensure the mine meets its scheduled production and, as important, is vital to the health and safety of all personnel working underground. Those operating the mine ventilation system must have fundamental engineering training in the art of fluid dynamics and have a good comprehension and control of the mine ventilation network. Ventilation management by untrained and inexperienced personnel may result in serious consequences when the system becomes ineffective. This paper shares observations and experiences pertinent to the occurrence of upset conditions as a result of the improper design and operation of mine ventilation systems. A series of real life case studies are presented to describe disruptions to mine ventilation systems and the gradual deterioration of system operational efficiencies leading to eventual failure. Special focus is given to mistakes made and on the resulting serious consequences. The case studies also demonstrate how each upset condition was resolved, permitting the mines to safely resume production activities.INTRODUCTIONThe ventilation of operating mines is a continuously changing and evolving system; upset conditions will occasionally occur, but should be promptly resolved in order for the system to function properly, according to design, and in compliance.Those designing, managing or operating the mine ventilation system must have pertinent training and have a good understanding of fundamental ventilation concepts to be able to devise and implement engineering solutions to day-to-day challenges. Realistically, the operator must also have extensive practical experience and be able to effectively apply operating procedures, design criteria and ‘best practices’. They must be able to, on a daily basis, evaluate the mine ventilation system, determine and locate any problems, understand the causes of each problem, find a solution, and promptly and efficiently correct those problems.Ten case studies are presented to demonstrate how fundamental design or operational mistakes can lead to adverse conditions or to catastrophic consequences, how detailed on-site engineering assessments can be employed and how simple, low cost, engineering solutions can be implemented to successfully resolve the issues and return the ventilation system to compliance, permitting the mines to safely resume production activities."

Jan 1, 2019

By J. J. Emery

There is an increasing awareness on an international level of the potential for utilizing many wastes and by-products as construction materials. This has resulted in recent major reviews by OECD and RILEM to supplement national activities by agencies such as CANMET, USBM, BRE and LCPC. Much of this international and national work was reported during an International Conference on the use of by-products and wastes in civil engineering held in November 1978 in Paris. Based on participation in the OECD and RILEM reviews, and the Paris conference, developments in waste and byproduct utilization of particular concern to Canada are described. The major technical and economic constraints involved are also reviewed, so that the over-all evaluation reflects important factors such as inherent variability and transport logistics. Areas requiring further research and development are also identified. Particular emphasis is placed on slags, salvaged asphaltic concrete and surplus sulphur. "Due to the rapid development of China's industry, more than a hundred million tons of industrial wastes are generated annually, which occupy lots of land for storing, bring about environmental pollution, obstruct industrial and agricultural production and cause harm to people 's living. Therefore we must utilize them effectively to create wealth for our country. "

Jan 1, 1979

By H. Lorenzen, D. Buyze

"Magnesium-bearing salts occur in the Zechstein Basin in the north eastern part of the Netherlands at a depth of 1500m to 2500 m.Exploration results justified the exploitation of these salts by means of solution mining for the production of refractory grade magnesium- oxide. This paper discusses design criteria, operation parameters, and methods used for magnesium chloride solution mining by Noordelijke Zoutwinning B. V. (NOZO), an operating company of Billiton International Metals B. V.A unique variation of widely used solution mining techniques has been developed for mining the complex Veendam salt deposit. NOZO extracts salt through deviated wells with a set of parallel, suspended tubings. Cavern fluid pressure is maintained close to that of overburden rock. These special design features provide an answer for the complex characteristics of the minerals, halite, carnallite, bischofite and kieserite, from which a solution rich in magnesium is generated. Dissolution chemistry and rock mechanical behaviour of these salts are unlike those of rock salt. Throughout a few years, NOZO demonstrated adequate process control while they continue improving the operation.IntroductionBilliton, a wholly owned company of the Royal Dutch /Shell Group of Companies, is active in metal exploration, mining, processing, and trading, mainly in the non-ferrous sector.Since 1972 Billiton has been active with solution mining magnesium salts in the northeastern part of the Netherlands, in the Province of Groningen, near the city of Veendam . Solution mining techniques were developed in conjunction with the ""Koninklijke/Shell Laboratorium Amsterdam"" (KSLA) and the ""Koninklijke/Shell Exploration and Production Laboratorium"" (KSEPL), Rijswijk. The company's objective is to produce magnesia sinter (MgO) from magnesium-chloride brine (MgClz) and de-carbonated dolomite (CaO.MgO). The magnesia produced serves as base material for the manufacturing of refractory bricks, used for furnace linings in the steel industry."

Jan 1, 1986

By Hoeve. J.

"In the unconformity-type uranium deposit at Midwest Lake, mineralization is associated with extensive host rock alteration, which affects the metamorphic basement as well as the overlying Athabasca Group sandstones. Host rock alteration is manifested by (I) transformation of clay minerals [kaolinite into illite and chlorite (sudoile)]; (2) bleaching due to removal of hematite from the lateritic paleoweathering profile and the overlying red bed, Athabasca Group sandstones; (3) loss of coherence of the sandstone resulting from corrosion of quartz cement; and (4) in the immediate vicinity of high-grade ore, development of a clay envelope due to residual enrichment of clay minerals caused by massive dissolution of quartz. Clay mineral transformation and bleaching are the most prominent and the most widespread alteration effects, forming haloes that extend for several kilometres along the strike of the mineralized structure and also constitute distinct alteration pipes that rise f or several hundred metres above the unconformity to be truncated at the present top of the bedrock.Although the two haloes are largely congruent features, cross-culling relationship s indicate that clay mineral alteration represents an earlier phase in the history of the deposit than the large-scale bleaching that gave rise to the superimposed bleaching halo.Because clay mineral alteration and bleaching are intimately tied to the mineralization and extend well beyond the limits of the actual orebodies, host rock alteration may be used as an ore guide in exploration and drill-hole evaluation. In this application a third hydrothermal discharge centre was identified, as yet untested for are, which is located between the hydrothermal centres associated with the two known orebodies of the deposit.It is estimated that host rock alteration may enlarge a potential drill-target by a factor 10 - 20X. Information on the configuration of bleaching haloes can be obtained from systematic core logging, whereas diagnostic clay mineral alteration is readily identified by means of automated, quantitative XRD techniques."

Jan 1, 1984

By George F. Bassett

"More will be expected from the mine or metallurgical plant electrical system in the late 70's and 80's in terms of energy conservation, reliability and fire prevention. Increased electrical loads 1•equired by larger arc furnaces, higher-horsepower motors for mine hoists and pollution control fans, and greater use of electrical heating will have to be supplied. Computers and sophisticated instruments will be used more extensively and have less tolerance for electrical fluctuations. More extensive control and monitoring systems will be required to increase production and minimize operating and maintenance costs. Changing energy costs will prompt design engineers to investigate in-plant generation, particularly where sites are remote from existing utilities lines or steam from turbines may be used in the process. Some utilities are requiring industries to increase their power factor to above 90% ; others are requiring stricter control of voltage flicker from arc furnaces and harmonics from rectifiers. There is a trend to AC with solid-state cont1•ols instead of DC for large cranes."

Jan 1, 1976

By T. Feldmann, G. P. Demopoulos

The feasibility of chloride leaching processes depends on interfacing them with cost-effective HCl regeneration technologies. This paper summarizes the most important findings of research conducted in the past 3 years concerned with a novel process to regenerate high-strength HCl from concentrated CaCl2 solutions at temperatures below 100°C, via reaction of CaCl2 with H2SO4 resulting in the formation of calcium sulfate phases (gypsum, a-hemihydrate or anhydrite). From constant supersaturation semi-batch experiments in pure solution it was found that the crystal growth rate of hemihydrate, and hence the particle size, was influenced by the rate of reagent (Ca2+, SO4 2-) supply to the reactor. Additionally, growth studies of DH in presence of impurities (K+, Mg2+, Sr2+, Ba2+, Fe2+/3+, Al3+, La3+, Y3+, F- and PO4 3-) showed that specifically Sr2+ and PO4 3- are taken up during crystal growth. Furthermore, it was found that decreasing water activity (via different HCl/CaCl2 concentrations) and increasing temperature reduce the metastable life-time of DH and HH by increasing the phase transformation speed. The DH/HH transformation was identified to be dissolution-precipitation based, while HH to AH is a topochemical process. Finally, continuous experiments on bench scale are underway to confirm the feasibility of the process to obtain super-azeotropic strength HCl with up to 9 mol/L (~30wt.%) from 5 mol/L CaCl2 (~40wt.%) solution.

Jan 1, 2014

By Dharmendr Kumar, Pradip, Sivakumar Subramanian, Beena Rai, Venugopal Tammishetti

The separation efficiency in a mineral processing plant is generally assessed and reported in terms of elemental assays constituting the minerals of interest. However, different minerals comprising of same elements behave differently under similar process conditions. Thus, it is imperative to track the mineral composition thank elemental composition of different streams in a processing plant. The availability of automated mineral analyzers such as QEMSCAN and TESCAN in recent times has made it possible. However, due to the high cost and expertise required, their adaptation in day to day monitoring of operations is not yet a common place. X-ray diffraction (XRD) profile fitting (Rietveld Refinement) is another technique which can provide estimates of mineral proportions in a sample. The results of Rietveld Refinement however are affected by coating of fines on coarse particles, method of sample preparation, particle size distribution of sample, elemental substitution in mineral crystal lattice. In the present work, we propose a simple and efficient method for quantitative estimation of minerals in iron ores using elemental assays and thermo-gravimetry analysis data. The minerals (hematite, goethite, gibbsite, kaolin and quartz) are identified using powder XRD analysis. It is also observed that goethite contains Al substitution in the crystal lattice. The samples were analyzed for %Fe, %Al2O3 and %Silica using chemical analysis. The measured Loss on Ignition (LOI) in the sample is contributed from goethite, gibbsite and kaolinite phases. LOI from gibbsite and goethite occur in temperature range 250–350°C and LOI from kaolinite occur in temperature range 400–700°C. According, LOI are determined in two different temperature ranges that are 100–400°C and 400–850°C. We have used the data to successfully determine the mineral compositions of iron ore samples. We have also employed a data reconciliation algorithm on the calculated data for further improvement and consistency of our results. Our method is very convenient for quick estimation of mineral proportions in a sample. The proposed method can also be used for quantitative phase estimation in bauxite ores and red muds.

Jan 1, 2016

By Brad Gunn

Our program has been dictated by the necessity of broadening our markets through converting potash chemicals to fertilizers more in demand than potassium chloride. To this end, we have undertaken studies on methods of preparing potassium sulphate or potassium magnesium sulphate by rather simple conversion. When mixtures of sodium and magnesium sulphates are reacted with potassium chloride, the ratio of sodium to magnesium is quite pertinent. A range of ratios has been selected and the conversions of potassium chloride to sulphate have been assessed by cyclic operations. Results from experimental procedures for producing potassium nitrate are also avail-able. The influence on recovery for systems including organic solvents is assessed for a variety of situations.

Jan 1, 1971

By J. Manchisi

This study has investigated the use of blast furnace slag as functional adsorbent for metal ions in acid mine drainage treatment. This opportunity has not yet been developed into a practical process partly because of limited understanding of rates and mechanisms of adsorption process and inconsistency in interpretations of adsorption data. The overall objectives were to determine the efficiency and mechanisms of sorption process of metal ions in a multiadsorbate system. We employed standard materials characterisation techniques to analyse composition, structure and surface morphology of the slag. Batch adsorption experiments were then conducted to study the mechanisms, kinetics and efficiency of metal sorption as a function of pH, phase ratio, mixing time, mass and particle sizes of slag. Both XRF and adsorption data suggested the slag to possess acid neutralising capacity. This slag is non-crystalline based on XRD pattern, has adequate porosity and pore volume comparable to similar commercial adsorbents but it has inferior pore structure, pore size distribution and BET surface area to be effective under wide applications. Metal sorption increased with decrease in slag particle diameter, decrease in initial metal concentration and increase in the mass of slag. Although slags have demonstrated to efficiently treat low concentrations of single and multiadsorbate effluents using fine particle sizes, they have limited capacity to treat multiadsorbate systems for some metal ions. This is probably due to low affinity, competitive adsorption or limitation in material?s adsorptive properties. Sorption mechanisms probably involve precipitation and ion exchange on the basis of alkaline pH and exchangeable slag surface ions. Sorption preference is proposed as Fe2+>Cu2+>>Cd2+>Co2+>Mn2+. Despite these limitations, deeper understanding of sorption behaviour of metal ions by slags for application in dilute and large volumes of effluents is necessary where precipitation and other standard techniques are either inefficient or uneconomic. Thus, this study has established that sorption capacity of slag to remove metal ions from acidic effluents is selective, limited to certain metal ions and for other ions only at low concentrations. Further adsorption studies in multiple solutes under various experimental conditions or those that can propose an economic slag activation process are needed that improves or widens adsorption window.

Aug 1, 2013

By Constantin D. Pitis

?Demand-side measure" means a rate, measure, action or program undertaken to conserve energy or promote energy efficiency?? (BCUC, 1996) In actual economical environment, business sustainability requires high-efficiency technological processes. That is why the efficiency concept has to be present at all levels of industrial activities. Nowadays, some purchasing decisions are still driven predominately by the purchase price, in spite of the evidence that such price represents up to 5 % to 7 % of the total costs of ownership with full consequences of energy efficiency and the impact on total ownership costs. The paper presents essentials of converter types and basics of the Global Efficiency (GEff) Concept that has been promoted over the last few years in South African industries (Pitis et al., 2006/7). GEff concept is proven as a useful tool used on price-efficiency decisions. Theoretical and technical aspects of this concept were substantiated with case studies. First part presented in this paper will describe how GEff concept was used on price ? efficiency decisions when single input or direct converters and systems (considered as low value equipments) have been replaced. Besides the impact of energy savings and new innovative developments, the paper suggests general other benefits of: ? Technical and economical performance improvements and competitiveness of mining corporations to international standards; ? Defusing incipient energy crisis in the sector; ? Improving environmental conditions; ? Creating new job opportunities in mining sector. Proposed concept in this paper could be further developed as models of improving companies? corporate energy policies.

May 1, 2010

By William F. Caley, A. MacKinnon, P. W. Kingston

"The purpose of this paper is to identify a number of currently available opportunities for exploration and/or mine development in the industrial minerals field in southeastern Ontario. The paper is not intended as a complete review of the industrial minerals industry in southeastern Ontario, but highlights what are seen by the authors as areas where there are immediate opportunities for investment and growth.Traditional exploration targets in the Grenville Supergroup in southeastern Ontario have been vein-hosted gold deposits, industrial minerals, and base metals. In recent years, emphasis has increasingly shifted to industrial minerals, in response to changing technologies in the minerals-consuming manufacturing industries, and to an increasing awareness of the industrial mineral potential in this area.This paper examines the resurgence of interest in exploring for and developing a wide variety of industrial minerals, and it examines the work the Ontario Ministry of Northern Development and Mines has done under the current Canada-Ontario Mineral Development Agreement. Specific development opportunities are identified in various commodity areas. Use oj the industrial minerals wollastonite and nepheline as substitutes for fluorspar in the formulation of synthetic steelmaking slags is also discussed."

Jan 1, 1990

By D. Assmus, S. Daly

"Poor fragmentation, high toe areas, excessive shovel wear and tear and frequent re-drilling and blasting of certain tough waste rock zones in the Lomex pit in the early 1980snecessitateda better understanding of these zones.A combination of geotechnical mapping, penetration rate data, toe elevation contouring and observations on shovel and drill performance were used to determine the character and extent of these zones. This complementary information was brought together by the geotechnical mapper and the explosives supervisor.Distinct zones with particular geological characteristics were determined. A classification system with three types of blast and dig-ability was developed for the Lomex pit and later applied to the Valley pit, with considerable success. The three blast zone types are called ""poor"", ""f air"", and ""good"". This system will be described in detail.The explosives supervisor adjusted the blasting parameters to each zone, in particular, pattern spacing and burden. The resulting powder factors showed considerable variation between the poor, fair and good zones within each pit as well as between the two pits. Pattern geometry and length of collar were also adjusted to improve fragmentation. Cost savings resulted from less re-drilling and less wear and tear on drills and shovels in the poor zones and more efficient use of explosives in all the zones. An annual estimated cost savings of well in excess of $1,000,000 is realized at Highland Valley Copper. A by-product of the mapping was the determination of unstable structures and water flowing zones. Blasting was then adapted to this information for enhanced slope stability."

Jan 1, 1992

By G. W. Smith

"The adsorption of dehydroabietylamine acetate on quartz, hematite, rutile and baddeleyite has been deter-mined for concentrations ranging from 0.3 to 5,600 µ. moles/I and for pH values ranging from 2.5 to 10.5.The surface tension, UV and IR spectra, equivalent conductance and ion concentrations for dehydroabiety lamine acetate solutions have been determined.Contact-angle and flotability studies have established that good collection may be obtained with this amine but that selectivity depends on the suitable use of depressants for some of the minerals."

Jan 1, 1971

By Jarrett. K. M.

Nobody has, as yet, made a perfect machine. Therefore, when a machine is operating and functioning as it is designed to do, there is always some vibration present. This is easily and simply measurable with present-day equipment and any increase in the amount of vibration will indicate a potential failure. When an increase is noted, vibration analysis can pinpoint the cause of the potential failure and remedial action can be taken before an unscheduled shutdown is necessary or a breakdown occurs.

Jan 1, 1972

By Roger Lacroix

L?arrivée de nouvelles technologies sur le marché des foreuses portables combinée au besoin des mines à mieux consommer l?énergie électrique ont permis d?identifier le potentiel de deux nouveaux type de foreuses présentement utilisées en Afrique du Sud, à savoir les foreuses électriques et les foreuses hydrauliques actionnées à l?eau. Grâce à la collaboration de mines Niobec et Géant Dormant de Cambior Inc., ainsi que d?Hydro-Québec, le potentiel réel d?économie énergétique des foreuses portables hydrauliques et électriques par rapport aux foreuses conventionnelles à air comprimé a été évalué pour des roches dures et moles. Ainsi, cet article a pour objectif d faire ressortir ces potentiels d?économie énergétiques. En outre, les résultats pour une mine mécanisée et une autre mine de type filonien, dans lesquelles on retrouve des conditions de terrain différentes, seront présentés. Les résultats montrent un potentiel d?économie énergétique d?environ 70% pour la foreuse électrique et d?environ 50% pour la foreuse actionnée à l?eau. Ces résultats montrent qu?il est possible d?obtenir une meilleure efficacité énergétique par mètre foré. Ainsi, il apparaît maintenant intéressant de poursuivre les travaux de développement des deux technologies pour les applications de forage vertical et de tensionnement des boulons, et de viser à accroitre le taux de pénétration de la foreuse électrique pour le rendre équivalent à celui de la foreuse à air comprimé.

May 1, 2007