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By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By A. Burduk

The traditional approach to managing information flow between a mine underground and overground, applied in copper mines of KGHM Polska Miedz S.A., is mostly based on exchanging spoken information using the mine telephone network and printed documentation. This way of information flow significantly influences effective use of time of a shift foreman employed at a mining division. In order to minimise multiplication of significant information generated as paper documentation, a concept of an IT system module to input basic data concerning operation of the mining division was developed. The idea is based on computer software that permits inputting data in the underground and their immediate sending to the overground. The above-mentioned solution will permit significant reduction of administrative work time that each foreman has to do on each shift. The time saved on filling forms and communication will permit the foreman and the other workers involved in information flow to spend more time for execution of their basic duties. In the case of the supervision employees working in the overground, the IT system will allow all the interested persons to be informed directly, with no necessity to transfer the information on the situation in the given mining division by turns from one to another. On the other hand, saving time on administrative works will permit the foreman employed in the underground executing more detailed inspection of workplaces in his subordinate mine division. Thus, availability of the foreman for the mining division operation will be improved. KEYWORDS

Aug 1, 2013

By D Martín, G. Díaz, F. Cubeddu, A. B. Mejias

The Modified ZINCEXTM Process (MZP), developed by Técnicas Reunidas, is an industrially proven flexible process. It can handle a wide range of primary and secondary raw materials, producing SHG zinc. The core of the Modified ZINCEXTM Process is the zinc solvent extraction unit. This unit is an effective barrier for any leachable impurities present in the raw material. As a result of this an ultra-pure zinc solution is always obtained. The high versatility of the process makes the application of the technology in different scenarios possible. MZP can be effectively applied when developing a whole new plant (Skorpion) or adapting its scheme to an existing refinery (Akita), in both cases giving the same results. Flexibility in terms of capacity of the plant is a great advantage of the MZP, there is the possibility to adapt the global process to a wide range of production capacities. Zinc production capacities of over 150 000 t/a may be achieved with a single solvent extraction plant train. The robustness of the Modified ZINCEXTM Process has been recently proven on two new plants currently in operation: Portovesme (Italy) and Horsehead (USA) after start up during 2013. The status of both plants is described in this paper.

Jan 1, 2014

By N. Razavinia

Most mining and metallurgical industries produce relatively large quantities of low grade waste heat which they vent, for the most part, to the environment. To date, little is being done to recover some of this heat and transform it from low grade to a high grade energy form such as electricity. A few decades back this was also true of paper, plastics and metals. Recycling was not a prominent activity. Today, we all know that it is and that recycling is a must for sustainable development. To this end, we feel that we are now at that point in time when the recycling of waste heat to electricity must be given serious consideration. By recycling waste heat one can achieve at least one if not two of the following benefits: 1) reduction in the carbon footprint ? by improving the overall energy efficiency of a process, and 2) production of electricity at an economically viable cost. We have developed a process that captures, concentrates and converts (3 C?s) waste heat to electricity. The process comprises 3 distinct interacting units. The first unit captures and concentrates waste heat using heat pipe technology. The second unit converts some of the concentrated heat to mechanical work which can then be readily converted to electricity. This unit is based on the classical piston/cylinder engine arrangement that is widely used by consumers to power systems with compressed air, for example. The third unit of the process dissipates the heat that the engine cannot convert to high grade energy. It also uses heat pipe technology to achieve this. The combination of the 3 units forms a unique system for recycling waste heat. This paper describes the system and it presents some results that show how the system can be made to be economically viable.

Aug 1, 2013

By Nelson Lawrence

An Electrical Risk Management/Inspection Program has been designed specifically for the mining sector in order to provide electrical code expertise and systemic gaps in electrical systems. Goals include improved safety and productivity, reduced injuries and help to enable businesses to better comply with the electrical codes and regulations that govern them. The Electrical Risk Management/Inspection Program is now recognized by some of the world?s largest mining organizations. Since June, 2001 these electrical safety advisory services have been available to underground and surface mine sites throughout Ontario and are now offered throughout Canada and around the globe. This program is also currently being applied to review new electrical installations for mine construction projects thus improving the safety and reliability of mine site electrical systems.

May 1, 2006

By William James Kempson

This paper discusses ore handling systems in shafts. These are considered from the loading facility at shaft bottom all the way through to the discharge mechanism in the headframe. These systems will be discussed from the following perspective: i. Intrinsic safety of the systems ii. The efficacy of the systems to perform consistently iii. The maintainability of the systems iv. Overall system cycle times Particular emphasis is placed on the following specific areas: 1. The Shaft Bottom Loading Facilities The various shaft loading systems currently in use are discussed, the selection parameters surrounding these are quantified and the specific selection criteria are outlined. 2. The Various Skip Configurations In this section the various skip configurations in use around the world will be described and the specific design details associated with these will be highlighted. The advantages and disadvantages of these systems will be compared and the overall efficacy of these will be discussed. 3. The effect of the loading and skip configurations on the Load Cycle Times. The overall cycle time which can be achieved by a shaft system is strongly dependant by the speed and efficiency with which the ore can be loaded and transported out of the mine. The potential of the various systems to be optimized will be discussed. The emphasis of this paper is to highlight the lessons which have been learned with respect to ore transport system design and provide a common basis against which these can be compared in future applications.

May 1, 2013

To produce high quality castings, one must monitor the melt quality by evaluating such parameters as the grain refinement and silicon inoculation and modification during the production of the commercial casting. Thermal analysis is a tool one can use for both monitoring and providing input to the process control of the operation. The current technique of performing thermal analysis in commercial foundries is to pour a relatively small quantity of the molten aluminum alloy into a sampling cup and to then acquire the cooling curve. This approach is somewhat simplistic in that one has limited control of the cooling rate and hence the solidification rate of the sample. Moreover, this process requires a fair amount of user intervention and effort. In the past, studies have been conducted in an attempt to develop a system for conducting thermal analysis in-situ. In a study at McGill University, an alkali based heat pipe system was developed for conducting thermal analysis in-situ. While the concept was deemed as very desirable, the complexity of the equipment and procedure was a substantial negative component. In order to improve the technique of accomplishing real-time thermal analysis with an in-situ probe, a new method that is based on McGill heat pipe technology was developed. In the new system, a controllable and flexible water based heat pipe probe is used to solidify a small quantity of metal while residing in the melt. The solidified aluminum is remelted after completing the thermal analysis. This is a key feature of the probe. It resides permanently in the melt yet it is able to both solidify a sample of the melt and then to subsequently remelt it. Various solidification rates encountered in commercial castings are attainable by adjusting the heat extraction rate of the unit.

Jan 1, 2004

By M. A. Bérubé

Le but principal de cette étude était de vérifier certaines hypothèses de nature minéralogique susceptibles d'expliquer en tout ou en partie les variations importantes observées au concentrateur no 1 de Mines Gaspé quant aux performances du circuit B de broyage et de flottation. A cette fin, nous avons examiné six séries d'échantillons prélevés lors d'une campagne de mesures effectuée au cours de l'été 1980. Ainsi, la capacité du circuit de broyage semble dépendre principalement devariation s dans les caractéristiques minéralogiqu es et texturales du minerai, par exemple du rapport grenat/quartz, le grenat ayant une influence néfaste sur le rendement de cette étape, contrairement au quartz . Quant au processus de concentration, la fraction du cuivre sous f orme de minéraux difficilement récupérés par flottation, en particulier des carbonates de cuivre, varie de façon significative dans le minerai, et cela peut certes expliquer en partie des récupérations parfois plus basses. Malgré ces variations important es de la composition minéralogique globale du minerai et de sa broyabilité, le degréde libération des sulfures de cuivre dans le produit de broyage dépend presque seulement de la granulométrie de ce produit. Afin de garantir des performances égales à l'étape de concentration, il est fortement suggéré de contrôler cette granulométrie à un niveau constant.

Jan 1, 1984

Most of automotive magnesium applications are presently produced by high-pressure die casting processes, For further expansion of the alloy usage in automobiles, novel-manufacturing processes needs to be developed, In this study, squeeze casting of AM50 alloy was carried out using a hydraulic press with an applied pressure of 70 MPa, Tensile properties and fracture behavior of the squeeze-cast AM50 were characterized in comparison with the die cast counterpart, The squeeze-cast AM50 alloy exhibits virtually no porosity in the microstructure evaluated by optical microscopy, The results of tensile testing indicate that the improved tensile properties for the squeeze-cast samples over the conventional high-pressure die-cast parts, The analysis of tensile behavior shows that the strain-hardening rate during the plastic deformation of the squeeze-cast specimens is constantly higher than that of the die-cast specimens. The SEM fractography evidently reveals the ductile fracture features of the squeeze-cast alloy AM50.

Jan 1, 2005

By H. R. Manouchehri, A. Weh

"High voltage electric pulse comminution (SELFRAG) relies on inducing electrical breakdown that occurs when the resistivity of a dielectric is insufficient to completely block all transfer of electricity while the conductivity is not high enough to fully accommodate the flow of electricity without considerable changes to the crystal lattice. The technology is based on introducing the electrical discharges into solids immersed in water and placed between two electrodes. The technology has received significant attention since investigations have revealed the potential for fully fragmenting particles or pre-weakening rocks in order to reduce the energy consumption in comminution practices, improve liberation and potentially increase the recovery in mineral processing. Mineralogical analysis of samples showed possible liberation at coarser sizes by high voltage breakage in comparison with conventional mechanical comminution.This study explored the potential of implementing SELFRAG to treat the Sandvik’s Mittersill mine tungsten ore (scheelite) for recovery improvement. Accordingly, standard SELFRAG tests were conducted on four samples from the tungsten process plant to evaluate the energy-breakage relation and potential to liberate the value minerals at coarser size fraction for recovery improvement. The size reduction of the ore after processing with SELFRAG revealed that size deportment occurs at 0.4, 0.2, and 0.1 mm, which indicated potential liberation of gangue and target minerals at respective sizes. In comparison with conventional milling, the difference is the deportment of values into 0.4 mm sizes, which was, to some extent, confirmed by SEM liberation analysis. However, more tests are needed to proof the concept. The study has indicated that, despite consuming more energy in comparison with conventional mechanical comminution, there are promising prospects in liberating the values at coarser fraction and improve recovery by making use of SELFRAG. The energy consumption can be reduced through customized generator and equipment setup, which must be further investigated."

Jan 1, 2016

By Darrell McClarty, Roger Payne, Matt Haggis, Michael Courtin, Deborah Berthelot

"Over forty years of uranium mining in the Elliot Lake region of Ontario (I 956-1996) has resulted in the production of over 300 million pounds of uranium. With the completion of mining activity, Rio Algom Limited and Denison Mines Limited are utilizing progressive environmental technologies and management systems to reduce and manage the environmental risks associated with the 150 million tonnes of potentially acid-generating tailings in nine regional waste management areas. Water covers designed to reduce oxygen entry and thereby significantly inhibit acid generation have been applied at six of the sites with the Quirke site serving as a demonstration site for the Mine Environmental Neutral Drainage program. All five of Rio Algom Limited' s effluent treatment plants are monitored and controlled from a central control station utilizing a Supervisory Control and Data Acquisition (SCADA) system based on ""Fix Dmacs"" technology. Scheduling, auditing and reporting of plant operating and environmental monitoring programs for the entire watershed are controlled utilizing the Regional Environmental Information Management System (REIMS). Proper application of these technologies and management systems facilitates delivery of cost-effective environmental monitoring, care and maintenance programs at these sites and provides tools to demonstrate compliance with all environmental performance criteria.IntroductionCost-effective management of multiple tailings management areas distributed throughout a 35 km watershed requires the application of leading-edge environmental technologies. Long-term monitoring, care and maintenance costs must first be minimized through the application of decommissioning technologies that inhibit acid generation and minimize the release of contaminants from the sites. On-going operating costs must then be controlled through the application of environmental management strategies that optimize the allocation of resources while ensuring compliance with regulatory and Company environmental requirements.Using sites in the Serpent River Watershed as an example, this paper demonstrates the effectiveness of water covers as a decommissioning strategy to inhibit acid generation. In addition, the Telemetered Environmental Operating Control System and Regional Environmental Information Management System are reviewed as examples of the application of environmental technologies to the management of environmental programs."

Jan 1, 1998

By G. A. Gross

"Nearly 90 per cent of the iron ore produced in Canada is derived from iron-formation or bedded iron deposits. About 70 per cent of this consists of concentrates obtained from iron-formation; another 20 per cent was formed by natural enrichment processes.Four principal varieties of iron-formation are recognized -the Algoma, Superior, Clinton and Minette types. Differences in their geology, mineralogy, chemical com-position and environment of deposition are of special significance in their evaluation as ore.The properties of the ores, including grade, beneficiation qualities and minor element content in taconites, metataconites and naturally enriched ores, reflect characteristics of the primary stratigraphie units from which they are derived. A detailed description of the stratigraphie facies is essential for efficient utilization of these source beds."

Jan 1, 1966

By I. A. Cameron, F. Ham, R. Sriram

"Planned increases in electric furnace productivity and higher matte temperatures needed for the Sudbury Smelter's S02 Abatement Plan, require an improved matte tap hole. Since startup in 1978, the matte tap holes have been incrementally improved by the addition of copper cooling blocks around the refractory tap blocks. These improvements provided a tap block life of about 100 taps per campaign.In July 1993, a prototype matte taphole was installed in Number 2 Electric Furnace to develop the technology to increase tap hole service life. The design was based on a heat transfer model of the tapping process to determine candidate refractory materials and cooler arrangements. The prototype tap hole features increased copper cooling, high conductivity refractories and extensive instrumentation. Eight trial campaigns are reviewed outlining the performance of silicon carbide and graphite refractories and typical heat loads during tapping.IntroductionFalconbridge Limited operates two 36 MYA, 6 electrode submerged arc electric furnaces in Falconbridge, Ontario. The furnaces, commissioned in 1978, smelt a partially roasted nickel-copper calcine, to produce matte for converting and slag for discard. Additional details of the smelter are available in the literature(1-4).Each furnace was equipped with two matte tap holes located in the furnace end wall. Early in the campaign, matte tap holes were identified as a weak area in the furnace which could be improved. From 1981 to 1987, incremental improvements were made to the design by the addition of water cooled copper blocks. In 1993, a prototype matte tap hole was designed and installed in Number 2 electric furnace to develop the technology to increase tap hole service life. Improved service life is required to meet planned increases in electric fWl1ace productivity and the higher matte temperature needed for the smelter's S02 Abatement Plan.This paper reviews matte tap hole development since 1978; outlines the prototype matte tap hole design, refractory selection and installation; and details the performance of the prototype tap hole during the first eight campaigns."

Jan 1, 1995

By Brian Lewis

"IntroductionThe ion exchange process is classed as a purification and concentration stage. In the uranium industry it is used to separate, and recover uranium, from a solution produced in the leach and subsequent solid washing circuit, that contains uranium as well as some impurities. The final product from this circuit is a solution, containing uranium at a 15 to 25 fold increase in concentration, with a chemical composition suitable for the ""Precipitation"" circuit.The process is a reversible chemical ""ION"" exchange, between a solution, and solid phase, with the ""resin"" being the solid phase. Various chemical changes in the solution phase will permit the resin to remove uranium from a solution or have the uranium removed from the resin back into a solution phase. The former loads uranium onto the resin, and is called the ""adsorption cycle"", and the removal or stripping is known as the ""elution cycle"".Ion Exchange resin is a semi-rigid polystyrene spherical bead, approximately 10 to 30 mesh. It is used by placing the resin in a vessel, so that a porous bed of resin is formed, through which the solution may flow.There are many different types of vessels, and systems used to hold the resin, but it is not the intention of this chapter to describe them all, but to describe two methods used in Elliot Lake. These are the ""fixed bed"", and ""moving bed"" systems, the condition of the bed during normal operation signifies the name of the system.Chemical and Physical Characteristicslon Exchange ResinThe resin used is a strange base Anionic resin, semi-rigid, and spherical in shape. The size of the wet resin is approximately 9007o between 20 and 40 mesh. Physically the beads of resin are broken early, but some have lasted over 15 years and are still in use."

Jan 1, 1989

By K. Barbetti, J. Avraamides

"The processing of gold ores with high silver contents can provide operational challenges, such as high cyanide consumption, retardation of gold leaching and competition during adsorption stages of carbon-in-pulp/leach/column (CIP/CIL/CIC) circuits. In particular, the silver, which is about 1.5% of the value of gold, competes with gold during carbon adsorption due to its higher concentration in many Ag-Au ores, potentially leading to gold solution losses. Fresh and partially fouled (barren and regenerated) activated carbons were evaluated at various Ag:Au ratios and total metal concentrations with regard to the adsorption kinetics and equilibrium loadings. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the competitive adsorption environment. An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. The model performance and some of its salient features will be discussed.INTRODUCTIONThe processing of gold ores with high silver contents can present a range of operational challenges, such as high cyanide consumption, retardation of gold leaching and competition in carbon adsorption circuits. Silver is often present at significantly higher concentrations than gold in many gold-silver ores and competes with gold in carbon adsorption circuits, limiting the gold loading rate and capacity, resulting in gold solution losses and reduced gold recovery.Curtin University’s Gold Technology Group has evaluated fresh and partially fouled (barren and regenerated) activated carbons at various Ag:Au ratios and total metal concentrations to determine the adsorption kinetics and equilibrium loadings for gold and silver. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the presence of both gold and silver.An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. This paper describes the model performance and some of its salient features."

Jan 1, 2016

By R. U. Seneviratne, B. K. Ahlgren

In this paper we follow various technological discoveries and developments in the purification of minerals and metals in the mining industry by ion exchange. For approximately 100 years, ion exchange has been a known and variously applied purification and separation technology used by scientists and producers. It would seem obvious that the producer’s objectives have always been to achieve the highest quality products and the lowest operation costs, but also with the least amount of technological complexity. As a strategy to reach these goals, much effort has been expended in the quest to improve continuous ion exchange (CIX) systems by reducing utility needs and resin degradation or loss while at the same time improving productivity and reliability. Recent developments from a number of companies have pushed equipment boundaries, resulting in a variety of unique commercial equipment designs each with a varying degree of success. The challenge set forth for all new designs has been a truly continuous process with no sacrifice in the afore mentioned benefits. One very recent equipment design based on system symmetry appears to meet many of these objectives with greater flexibility and less complexity resulting in better economics for the producer.

Jan 1, 2014

By Guichao Wang, Geoffrey M. Evans, Graeme J. Jameson

"In this paper we present a new method for studying the detachment of particles from bubbles in a rotating turbulent eddy. The eddy is formed in a wall cavity in a two-dimensional water tunnel with transparent walls. When water flows through the tunnel, a vortical flow field develops in the cavity. The properties of the eddy can be modulated by changing the free-stream velocity of the water in the tunnel. Bubbles are pre-loaded with one or more particles in a fluidized bed flotation device located beneath the vortex cavity. Loaded bubbles are released one at a time into the cavity, and the motion of the bubbleparticle aggregate is studied using a high-speed video camera. The diameters of the particles and the bubbles, and the number of particles initially attached to the bubble, can be varied. The trajectories taken by the bubbles are quite complicated. In some cases, the bubble moves to the centre of the eddy, and particles rotate around its axis. If the rotational speed is sufficient, particles may detach due to centrifugal force. However, other modes were observed, including inertial detachment due to rapid changes in direction of the surface of the bubble, because of changes in trajectory of the bubble as a whole, or because of pulsations and oscillations of the bubble surface. Clusters of bubbles held together by particles were seen to form and reform. In the traditional explanation for the detachment of particles in flotation cells, it is assumed that particles detach from bubbles rotating in an eddy due to centrifugal force (Schulze, 1977). Although the conditions assumed in Schulze's theory may exist, it is only one of a range of phenomena that can lead to the detachment of particles from bubbles in a turbulent vortex.INTRODUCTIONThe recovery of particles by flotation methods is dependent on the particle size. The recovery in the existing flotation machines reaches a peak for particle size, typically in the range of 20 to 100 µm. This size range varies as a function of the particle’s properties (type and composites). For coarser particles, the recovery drops very quickly (Gaudin, Groh & Henderson, 1931; Jowett, 1980). If the upper size limit can be increased for flotation, dramatic savings in the grinding energy can be achieved."

Jan 1, 2016

By Christian M. Bauer

Modern surface mines are among the world's largest single consumers of diesel fuel. A typical mine site can consume in excess of 200 million liters of diesel fuel per year. Delivered diesel fuel is not necessarily clean. Depending on the mode of transportation, handling practices and local climate, incoming bulk fuel can contain up to 20 mg/L suspended solid contaminants and also significant quantities of free water, which can amount to substantial quantities ? for a typical mine site 200 to 400 kg of dirt per year. Standard on-board fuel filters are not designed to handle high levels of contamination, and most engine manufacturers have specific fuel cleanliness requirements to ensure reliable engine operation. New developments in fuel injector technology, such as high pressure, common rail injectors require even cleaner fuel. In order to ensure reliable operation, it is therefore recommended to control particulate contamination throughout the entire Diesel supply chain - from the bulk storage on mine sites to the injection systems on-board through the use of particulate filtration and liquid coalescence technologies. In this work, the author introduces a comprehensive approach to contamination control for the entire fuel supply chain, and discusses the benefits of using advanced filtration and separation technologies, with a particular focus on the requirements of modern high pressure, common rail (HPCR) fuel injection systems.

Nov 1, 2011

By C. J. Clayton, A. J. Haynes, D. A. Hickson, B. Thiele

The Meadowbank Gold Project, formerly owned by Cumberland Resources Ltd. and currently owned by Agnico Mines Ltd., is currently being developed approximately 70 km north of Baker Lake, Nunavut, in the eastern Canadian Arctic region. The Meadowbank Gold Project currently consists of a series of gold-bearing deposits within relatively close proximity to one another, which are planned to be mined primarily as a truck-and-shovel open pit operation using conventional gold milling and extraction. The mining plan indicates that approximately 20 million tonnes of ore will be mined over a mine life of eight to ten years. The operation will generate approximately 160 million tonnes of mine waste rock and about 20 million tonnes of tailings. The site is located in an area of continuous permafrost with mean annual average air temperature of -11°C and average annual precipitation in the range of 100 to 200 mm. Lakes cover a large portion of the site, including some of the ore deposits. The location of the site and the physical environment pose challenges to development. This paper presents some of the designs considered to effectively manage and utilize the waste products of mining at the project. Note that volumes, tonnages, construction concepts, and data presented in this paper are accurate for the time of writing and are subject to change and modification as the project progresses, additional modelling is carried out, and additional data are obtained.

Jan 1, 2007

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019