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By C. Caballero, A. Warczok, K. Itagaki, A. Moyano, J. Font

The Codelco Norte Smelter process 2,500 tpd of arsenic-bearing concentrates with an arsenic content of up to 1.5% in one of its two main smelting units, the Teniente Converter. The product, 1,100 tpd high-grade matte or white metal, is traditionally fed to the PS converters, while the 1,700 tpd of slag is fed to the slag cleaning electric furnace for copper recovery. This is achieved in a very reductive environment which reduces the viscosity of the slag and enhances the sedimentation of the high-grade matte droplets. The behavior of arsenic in this non-oxidative environment was studied at lab-scale and fundamental thermodynamic data were obtained. Based on these data a thermodynamicbase model to assess the arsenic behavior in reductive environment was developed. It is based on a mass balance for the reduction and sedimentation stages performed in an electric furnace which allows the recovery of high-grade matte droplets after decreasing the viscosity of the slag. This model can be a very suitable tool for predicting fractional distribution of arsenic in the slag cleaning electric furnace, when the distribution ratio, vapor saturation degree, temperature, y As and pO2 are given.

Jan 1, 2007

By Erica J. Wanless, Ghislain Bournival, Seher Ata, Jose Hamilton Tavares

In froth flotation valuable particles are captured by bubbles and transferred to a froth layer where bubbles are in close proximity. Bubble coalescence frequently occurs in flotation, especially in the froth layer. The coalescence of two bubbles causes a release of energy, which may expel particles from the bubble surface. A series of experiments were carried out to determine the effect of bubble interfacial properties on the detachment of particles upon the coalescence of capillary-held bubbles of 2 mm in size. The interfacial properties of the bubbles were changed by the addition of low molecular weight alcohols, namely 1-pentanol or methyl isobutyl carbinol (MIBC). Using esterified glass particles (? = 43 °) with a 10 % and 90 % cumulative passing diameter of 47.2 and 92.5 µm, respectively, as model particles, it was found a certain concentration of frother, different for each additive, is needed in order to observe a reduction in the detachment of particles. In the presence of frother, the detachment was evaluated at approximately 65 % which was a considerable reduction in the detachment compared with the value of approximately 85 % found in the absence of frother. Frother molecules changed the properties of the airwater interface. Upon the coalescence of two bubbles, the release of energy caused the merged bubble to oscillate; effectively resulting in the detachment of particles. The addition of frothing agents augmented the elasticity of the bubbles, which appeared to be related to the detachment of particles. Whereas frothing agents are generally used to prevent bubble coalescence and stabilise the froth phase, only transient stability is imparted. The results suggested that an additional role of frothers in flotation is to decrease the detachment of particles from bubble surfaces. The type and concentration of frother can be strategically selected to improve metallurgical recovery as an economic incentive.

Jan 1, 2016

By F. Fournier Dit Chabert, F. Tancret, J. François Castagné, R. Le Gall

During the repair of turbine blades by a laser cladding process, it is observed that interdendritic cracking occurs in the heat affected zone (HAZ). Auger electron spectroscopy, performed on sample broken at high temperature, reveals interfacial sulfur segregation, which is known to be one of the main causes of microcraking in the HAZ during welding processes. Moreover, thermal gradients generated by the process are responsible for important thermomechanical stresses. In the present work, the finite element code Comsol Multiphysics is used to simulate the laser cladding process in order to determine both the thermal field and, using an elastoplastic law, the stress field inside the component. The originality is that the temperature history calculated in the thermomechanical model is extracted then injected in a segregation model in order to calculate the local segregation behavior. This model can be eventually used to predict the risk of cracking as a function of process parameters and alloy chemistry.

Jan 1, 2006

By G. Plascencia, C. López, J. González, D. Jaramillo, M. A. Barrón

Air jet and molten matte interaction within a Peirce - Smith converter is analyzed during the first stages of blowing using Computational Fluid Dynamics (CFD), by means of the Large Eddy Simulation and Reynolds Stress turbulence models. Jet velocities ranging from 5 to 150 mis, which involve the bubbling and open jet regimes, were considered in 2 and in 3-D numerical simulations. As a result of the computer simulations, it was found that low velocities results in gas bubbling in the molten copper, whereas higher gas velocities results in well defined plumes. The consequence of such different behaviours results in an increment in the rate of refractory wear or in copper splashing respectively. The analysis of the results may lead to improve the design of the tuyeres currently used in copper converting. Bottom blowing of air is also explored in this work. Numerical results show a strong non-linear parabolic behaviour of the jet velocity on the average velocity of copper; which means that beyond certain jet velocity, the copper de-accelerates thus reducing its velocity. This may be due to the open nature of the jet, which prevents the momentum transfer from the injected gas to the molten copper.

Jan 1, 2007

The dissolution of chalcopyrite has received a significant amount of attention. The predominant paradigm of investigation is that its rate of dissolution is limited or passivated by a surface coating or film of material. The common candidates for such a passivating coating are numerous: polysulfide coating, metal deficient layers, copper sulfide coating, bornite layers, jarosite precipitates, and elemental sulfur films. While this line of explanation, that is, the explanation based on passivation, seems to have won some form of consensus with researchers, there is another explanation for the results that can account for all the results observed. Crundwell (1988) proposed that the solid state properties of chalcopyrite, in particular, the semiconducting properties, are responsible for the observed behaviour of chalcopyrite. The purpose of this paper is to outline the semiconductor mechanism of dissolution, and to show how this mechanism accounts for all the observed phenomena recently reported in the literature. The paper outlines the semiconductor mechanism of dissolution, shows how this mechanism accounts for the dissolution

Jan 1, 2014

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By S. Kodama, G. Sasaki, K. Matsugi, K. Sugio, Y. B. Choi

"Pure aluminum (Al) matrix composites with changing the volume fraction of TiB2 particle content from 10 to 30% was fabricated by spark plasma sintering (SPS) process. Then the microstructure, density, dispersibility and thermal conductivity of the composites was estimated. As increasing TiB2 content, the dispersibility of particles and the density of the composites degraded slightly. And, the effect of the dispersibility of TiB2 particles on the thermal conductivity was quite little. The thermal conductivity of the composites was less than the theoretical value calculated by Maxwell-Eucken equation considering the effect of the density. It is due the influence of the interface heat transfer rate, because these composites have many small sized particles and have high interface density.INTRODUCTION Recently, metal matrix composites (MMCs) have been used widely in electric / electronic components, architectural materials, transportation equipment, aerospace and a precision instruments, because it’s superior properties have been greatly watched. Demand of MMC for industrial use has been increasing gradually. Furthermore, multifunction properties are required for the composites strongly. By integrating the dissimilar materials, the composites have various properties that we cannot get from monolithic materials. On the other hand, the response to the thermal management is required for materials, recently, and the need for the structural material controlling the thermal conductivity has been increasing. Especially, superior thermal conductivity and good mechanical properties from room temperature to high temperature are required for heat sink and heat exchanger at the same time. In late years, a study on the composites combining carbon materials and aluminum and copper has been developing, and actually the composites with high thermal conductivity which is not provided in the conventional materials is developed. On the other hand, non-oxide ceramics particles such as SiC and AlN, TiB2 have good thermal conductivity. Particularly, as TiB2 has good electrical conductivity, TiB2 containing MMCs is expected as innovative materials used as electric/ electronic components. Furthermore, as TiB2 has low density, high melting point, low thermal expansion and good deformation resistance, the development of high performance composites with multi-functional properties is expected. As thermal conductivity of pure Al and TiB2 are 225 and 66.4 W/mK, respectively, it is expected that the degradation of thermal conductivity by adding dispersant in Al matrix is suppressed. The authors have carried out a thermal conductivity, electrical conductivity, mechanical properties of 20 vol.% TiB2 dispersed Al composites (Sugio, 2016, Sasaki, 2016). In this study, the influence of quantity of addition of TiB2 on microstructure, thermal conductivity was studied minutely."

Jan 1, 2018

By G. K. Rutherford, G. W. Van Loon

"Tailings in the mining and smelting industry are reject products of the refining process which are deemed too deficient in native are to warrant smelting. They are essentially finely ground rock materials which have been moved by alluvial suspension from the site of crushing to a deposit site. It is realized that components of flotation chemicals used in specific gravity separation may become part of the tailings and also that sewage sludge or other materials may be added at some stage to the tailing deposits.It would seem, then, that as tailings have a similar parent material to soils, namely rocks, and that they have also been comminuted to similar size fractions, they would react in similar ways to soils. There is an increasing body of evidence and experience which both supports and negates this supposition. It is the object of this paper to point out similarities and contrasts between these two materials which may influence the vegetation and rehabilitation of tailings.Soil-Formlnq FactorsThere are considered to be six soil-forming factors which impart the particular and unique properties harboured by a soil at any site. It is .relevant to consider each of these in turn, as each provides an historically based parameter with which to judge tailing properties.Parent MaterialsAlthough all mineral soils have originally come from rocks, for most soils the route has been rather circuitous. Soils may be formed directly from underlying rocks, as in some parts of tropical and semitropical regions today; these are sedentary soils. However, most soils of the world have been formed by materials which were transported to their present site by ice, water or wind, or as volcanic ash. Virtually all soils in Canada have been transported by ice or water and deposited on an extraneous rock surface during the last glacial retreat. Ice-deposited materials are extraordinarily heterogeneous in their size components and may range from very bouldery and gravelly to predominantly clay-sized materials. Water deposited sediments are usually homogeneous, but nevertheless these also show considerable level variations. In many parts of Canada, clay-sized materials deposited in ephemeral post-glacial lakes form the parent material for soils."

Jan 1, 1982

By A. Y. Senchenko, S. G. Rybkin, A. V. Aksenov

In gravity processing of gold-containing ore the target produced concentrate which is high gold grade primary concentrate contains a significant amount of cassiterite (SnO2). The plant attempts aiming at concentrate processing using a standard pyrometallurgical technology did not provide any positive results. The present paper is dedicated to development and testing of improved technology for pyrometallurgical processing of rich gold primary concentrate with high cassiterite content. According to material composition study primary concentrates produced at the plant contained 1.5–2.0% Au, 0.1–0.3% Ag, 55–65% SnO2, 20–25% Fe2O3, and 10–15% Fe3O4. The developed technology included alkaline nodulizing of primary concentrate mixed with sodium hydroxide and carbonate at 350–650°? with cake production. In blend nodulizing stannum and iron passed into sodium stannate (Na2SnO3) and sodium ferrate (NaFeO2) respectively. The blend of cake and fluxing agents was smelted at 1,150–1,200°? resulting in dore gold and slag production. Sodium stannate with 360°? melting point is well dissolved in slag system Na2OSiO2- B2O3-CaO. During plant tests 18.5 kg of high gold grade primary concentrate were processed, 1350 g of dore gold and 75 kg of slag were produced. Dore gold contained 16.5% Au, 0.95% Ag, 78.0% Sn, 3.1% Fe. Slag contained 12.4 g/t Au, 6.7 g/t Ag, 9.8% Sn, and 5.6% Fe. Gold recovery to target alloy was equal to 99.58 %, 87.8% of Sn passed into slag. This new technology was accepted for application at the plant.

Jan 1, 2016

By M. Normandin

The performance of various polymers and other macromolecules used to flocculate red mud particulate materials in the Bayer process can be evaluated on the basis of their efficiency to achieve adequate settling velocity and turbidity level, The Jar Test is widely used in the mineral industry to determine the efficiency of solid-liquid separation processes, particularly for gravity settler of the Bayer process. However, a high level of variability is found in the data obtained by this methodology, In this study, different parameters of the cylinder test procedure are evaluated to determine their role in the overall variability of the method, As demonstrated by laboratory testing, the overall variability can be considerably reduced by good laboratory practices.

Jan 1, 2005

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004

By M. J. Steffens

ESPLIM is a novel separation technique that combines the advantages of solvent extraction and electrostatic dispersion but its application in the extraction of nickel by the direct solvent extraction route and the effect of high electrostatic field on the stability of organics have not been explored. These were investigated in this study and it was found that the technique allows 97% extraction of the nickel in a single stage compared with 3 stages by the conventional solvent extraction. Also, three months of exposure to 5.0 kV under simulated operational conditions had no adverse effect on the stability of organics.

Jan 1, 2005

By D. Sammut, F. Houllis, J-L. Huens, J. Moyes

The Intec Gold Process has been developed as a halide-based alternative for the recovery of gold from refractory sulphide deposits. The halide medium allows sulphide oxidation and gold extraction to be performed concurrently at moderate temperature and atmospheric pressure sourcing oxygen from direct air injection. The dissolved gold is loaded onto activated carbon and stripped in a conventional Zadra circuit. High gold extractions have been achieved from a range of refractory gold concentrates at laboratory scale, which has led to a continuous locked-cycle pilot plant program. The pilot plant operated at >99% availability, with a maximum of 96.5% gold extraction from a concentrate containing 58.6 g/t gold. >99% of the dissolved gold was loaded onto carbon at up to 1% w/w, with no loss of carbon activity detected over five loading/washing/elution cycles. This paper describes the process and presents both laboratory and pilot plant results as well as economic data from two costing studies.

Jan 1, 2005

By W. B. Boggs

Part 1 Originally, the copper produced at the Noranda ?smelter was shipped in the form of blister bars to the Laurel Hill refinery of the Nichols Copper Co., New York. In 1930 a refinery was built at Montreal East for the purpose of refining Noranda copper and copper from the Hudson Bay Mining and Smelting Co., at Flin Flon. After investigation of the probable costs of making anodes at Noranda and at Montreal, it was decided to make them at Noranda rather than to continue to make blister bars there. Fuel is a major item of expense in making anodes: and since less fuel would be required in making anodes from molten copper than in making them from blister bars, a lower anode furnace cost could be expected at Noranda than at Montreal. Further, the expense connected with making blister bars at Noranda would be eliminated. The cost of treating anode and wire bar furnace slags is a serious item in a refinery, and it was found that the cheapest method would be to ship such slags back to Noranda. With the anode furnace at Noranda, much less anode furnace slag would be made at the refinery. Against these savings which would be effected by making anodes at Noranda must be set the high operating cost of an anode furnace at Montreal, using only tank-room scrap and the Flin Flon copper. This furnace would be handling a comparatively small tonnage and would have a high cost per ton. The usual equipment for making anodes from. liquid copper consists of either a stationary reverberatory furnace or a tilting Tacoma-type furnace together with an anode wheel of the Clark or Walker type. The reverberatory type of furnace has been developed from the furnace used in the old Welsh process of smelting and refining copper, while the tilting furnace is a development of the holding furnace, which is essentially a Peirce Smith converter without tuyeres and provided with burners.

Jan 1, 1932

By M. Carvalho

The primary motivation underlying the proposal of polygeneration systems for mine sites is to increase the efficient use of natural resources by combining different technologies and energy resources while satisfying energy service demands. For many mineral producers, particularly in Canada?s mining extremes of climate and depth, energy in support of mineral production can be the second largest cost centre after labour. A generic methodology is proposed for the design of energy supply systems in mine sites, based on a search for the minimum discounted cost of energy supplied for all feasible different plant configurations. These configurations can be represented within a connectivity matrix which corresponds to a network representation. A Mixed Integer Programming formulation is set out for the multiperiod synthesis and operational planning problem. This is characterized by i) binary variables for the selection of technologies, ii) integer variables for the determination of the number of units installed, and iii) by continuous variables for the representation of energy and economic flows. Through the integration of particular energy supply strategies matching specific mine circumstances (on-grid, remote, degree days, etc) and consideration of technologies that improve energy efficiency, hitherto not considered new technologies and demand management systems or new perspectives on optimal mine site energy supply can be investigated. Some of these investigations identify the economic conditions through which biomass energy feedstocks should be used, for direct heat production, for gasification and providing for Fischer-Tropsch syndiesel manufacture. As well as integrating demand from mobile diesel-fuelled plant into an optimization procedure that hitherto has only been considered for static energy production and consumption plant, this analysis shows how the techniques can be used to explore economic conditions of threshold prices for biomass (purpose-grown biomass and peat are considered herein) and trucked-in diesel. The methodology also allows for electricity and syngas storage and diesel and biomass bunkering. Within the paper the energy demands for a remote, open pit mining operation located in Northern Ontario are considered as a case study to illustrate the technique and investigations. As expected, for mines close to electricity, natural gas, and diesel distribution infrastructures, the optimal choice is to connect. When a constraint is applied specifying that connection is not possible, as would be for the case exemplified, the optimal choice includes some of the more exotic options for mine site energy supply.

Aug 1, 2013

By W. F. J. Cosser

AN agreement having been arrived at in 1935 whereby McIntyre Porcupine Mines would purchase gravel for back-filling purposes from Hollinger Consolidated Gold Mines, the aerial gear as described below was installed. As originally discussed, the plan called for installation of a loading bin at the junction to the Hollinger tram, so making the McIntyre tram an entirely separate unit. The experience of the Hollinger engineers, however, went to prove that the operation of a bin (remote from sources of heat) should be avoided if possible, owing to the severe winter conditions (35° to 40° F. below zero).

Jan 1, 1938

By M. Potesser

In the past, different furnace types have been developed for use within the copper industry, with two common anode furnace designs typically used in copper smelting plants worldwide: the tiltable reverberatory furnace (KPO) generally used for the secondary copper industry and the cylindrical or drum type anode furnace (TRO) for handling a liquid blister charge generated in primary copper production. The disadvantage of the KPO is its design related to the longer refining period, because of the low bath depth, however it provides good conditions in the melting period due to its large bath surface. On the other hand, small amounts of scrap charged into the TRO increase the melting and dissolution period, but it provides good conditions for the refining period. The newly-developed elliptical furnace concept (TRE) offers the advantages of each of these furnace types. The special design allows melting of the scrap more efficiently than in the KPO and refining the liquid copper more efficiently than the TRO. This paper shows a metallurgical comparison of the three furnace types in regard to the melting period by heat technological considerations (optimized arch design) and of the refining period done by CFD with concentration on current, recirculation and dwell time of the gas in the melt. The paper outlines the possibilities for a reduction of the tap-to-tap time and energy consumption as well as for an increase of the production capacity, which can be achieved by applying the TRE instead of the conventional furnace designs.

Jan 1, 2007

By Michel Ruel, Ali Soltanzadeh, Benjamin Légaré

High fidelity commercial process simulation packages can be used at different stages of a greenfield project, from initial plant design to operator training in the later stages. However, there are several factors that make the software less attractive for small and medium size brownfield projects, such as the licensing cost and the fact-finding manpower required for model design and simulator maintenance. In this paper a different approach is described. The knowledge gathered from operating personnel was used to implement higher level models based on plant data, operating heuristics, and experience rather than detailed component-level models. The computing platform used was a low-cost, well-established, control system vendor-independent software. Throughout this paper we demonstrate the success of implementing this model-based approach using two industrial examples. The first example is a simulation of the carbon monoxide (CO) distribution system at a metallurgical complex. The purpose of this simulator was to test new control strategies and PLC programs prior to implementation. CO being a toxic combustible gas, validation of the suggested control system changes was necessary for plant safety. Simulation of specific operating conditions helped alleviate concerns and improved plant-wide acceptability of the new operating philosophy. The second example is a boiler simulator at a petrochemical plant. The operator training simulator (OTS) was designed as a platform for experienced operators to practice handling rare or abnormal conditions. A customized medium-fidelity model was developed for this targeted application where the cost of a full scale high-fidelity model could not be justified.

Jan 1, 2016

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016