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By Adrian White

Agenda Overview of pastefill at Kidd Mine Pipeline wear and the need to monitor Steel Loop monitoring Steel Borehole monitoring Monitoring pipe linings

May 1, 2013

By G. Azimi, C. A. Ang, F. Zhang

"Nickel recovery from laterite ores generates large amounts of solid and liquid wastes. This is primarily due to the low concentration of Ni (about 1.4 wt%) in the feed ore to the High-Pressure-Acid-Leaching (HPAL) process. It is known that the HPAL residue contains a high concentration of hematite, a commercially important source of iron in the steelmaking industry. However, the balance is natroalunite, containing sulfur, which is a detrimental element in the steelmaking process. Hence, to make the HPAL residue a suitable feed for steelmaking, natroalunite must be removed. The current work is focused on: 1) a thorough characterization of the HPAL residue obtained from Vale, and 2) a systematic investigation of an alkaline leach process to remove natroalunite. The characterization results indicated that there are about 83 and 12 wt% hematite and natroalunite in the HPAL residue, respectively. The leaching results indicate that sodium hydroxide is the best leaching agent, which results in 55 wt% reduction in the sulfur content. The results of this work enable the conversion of an otherwise waste product into a useful feedstock for steelmaking. Furthermore, this project could potentially have significant environmental benefits by reducing the amount of residue produced during the HPAL process.INTRODUCTION Conventionally, crude steel has been obtained by reducing iron ore containing oxides such as hematite (Fe2O3), magnetite (Fe3O4), and wüstite (FeO) in a blast furnace with coke. The product is then refined in a basic oxygen furnace to produce steel with useful properties (McGannon, 1969; Turkdogan, 1978). Steel has been sought for its desirable properties and its application is widespread throughout modern civilizations. Surpassing the growth rate of other materials, the annual demand of steel has increased at a compound growth rate of 5% over the last 20 years (Baddoo, 2008). The global demand for steel was reported to be 1501 Mt in 2016 and demand is expected to double by 2050 (Cullen, Allwood, & Bambach, 2012; World Steel Association, 2016). In recent years, to meet the rapid growth of demand, secondary resources for iron have been identified as strategic sources of iron (Das, Kumar, & Ramachandrarao, 2000; Li, Sun, Bai, & Li, 2010; Matschullat et al., 2000). The residue produced from high-pressure acid leaching (HPAL) of laterite ore has been identified as one of the important secondary sources of iron (McDonald & Whittington, 2008). Laterite ore represents 60% of the world’s nickel resources and accounts for approximately 40-50% of the world annual nickel production (U.S. Geological Survey, 2016). Therefore, the amount of iron residue produced by the process is substantial and its utilization will produce both economic and environmental benefits."

Jan 1, 2017

By G. T. Lapidus, A. Garcés, O. J. Restrepo

"Colombian nickel laterites have historically been processed by pyrometallurgy. However, due to the depletion in ore grades, alternative processes are required. Hydrometallurgical processes, such as pressure acid leaching, have been proposed as alternatives to extract nickel from deposits with suitable characteristics. Such a leaching process requires high concentrations of acid to achieve acceptable extractions, and is not selective. In this study, an alternative aqueous alkaline glycine system has been employed to evaluate the leaching behaviour of a Colombian nickel laterite which contains 1.15% Ni, 0.12% Co and 41.1% Fe. Additionally, the effect of the addition of chloride ions, the use of a reducing agent and the application of a pre-treatment to improve the extraction of nickel were evaluated. Extractions of 4.63% Ni, 42.16% Co and 0.33% Fe were obtained using a 1M solution of glycine at pH 9. In addition, an increase in nickel extraction from 4.63% to 25.68% was achieved by applying a pre-treatment to the sample. The results show that even though nickel dissolution was much slower than in acid leaching, it was selective over other metals such as iron, proving the proposed method to have potential as a process for the extraction of nickel from Colombian laterites.INTRODUCTION Before 2010, most of the industrial operations used pyrometallurgical processes for the extraction of nickel, mainly in saprolitic regions of deposits, with greater contents of the metal. Nevertheless, due to the gradual depletion of such deposits, different hydrometallurgical processes have been studied as alternatives to process those nickel laterites with low grade and those which present problems of refractoriness due to the presence of acid consuming materials (McDonald & Whittington, 2008; Oxley & Barcza, 2013; Wang et al., 2012). However, such leaching processes require high concentrations of acid to achieve acceptable extractions and they are not selective. Facing lateritic nickel ore deposits containing high levels of acid consuming materials, an alkaline leaching medium becomes an advantageous alternative over acidic media, due to the increase in selectivity and decreased corrosiveness and reagent consumption (Tanda, Eksteen, & Oraby, 2017). Unlike conventional acidic reagents used for metal recovery, alkaline reagents can selectively dissolve the desired metal, leaving in the solid residue other elements such as iron, magnesium and aluminum, which are problematic in subsequent stages of metals separation and recovery. Furthermore, there are no serious corrosion problems associated with alkaline leaching, even at higher reagent concentrations, or at elevated temperature and pressure (Ntumba Malenga, Mulaba-Bafubiandi, & Nheta, 2015)."

Jan 1, 2017

By Colin E. Dunn

Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By Colin E. Dunn

Abstract-Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By N. Kacira

"Canada's largest known chromite deposit occurs in a layered intrusion in the Bird River area of Manitoba. However, numerically most of the chromite occurrences are in the Appalachians. Few, apparently minor, occurrences are also known in the Cordillera.In the Appalachians, chromite occurs as lenses and pods in dunite; they are of ""podiform"" type. The individual concentrations vary in size from a few pounds to tens of thousands of tons. Locally, chromite concentrations form discontinuous zones extending several hundred feet along strike and presumably down dip, therefore resembling boudinaged layers. Chromite layering and lineation are commonly concordant to those of the host rocks.The Appalachian chromite occurrences are thought to have been formed by fractional crystallization and perhaps also by liquid immiscibility. Their present shape and distribution are largely the result of deformation mostly prior to complete solidification of their host rocks. Therefore, the attitude of layering, foliation, lineation and other features related to deformation provide valuable guides in predicting the probable distribution of chromite, and hence are helpful in exploration.Chromites fulfilling the requirements for metallurgical, refractory and chemical grades occur in the Appalachians. Although the Appalachian deposits are similar in size and grade to some of the chromite deposits being mined elsewhere, they are unlikely to be economic, at present, in the higher wage Canadian environment. However, in case of shortages in chromite ore supply which may result, among other reasons, from increasing tendency to further processing in the producing countries, the Appalachian occurrences may become sources of ore. Such eventual shortages combined with relative abundance of electricity in Canada and recent innovations in oxide ore reduction technology may hasten the time when ferrochrome manufacture based on local chromite sources becomes economically viable."

Jan 1, 1982

Adaptive processing is often related to the mineral composition of the mining block currently processed. The portions of waste, ore and secondary product minerals considered are always positive and typically sum to 100% (i.e. a composition). A typical solution to predict block averages of spatially dependent quantities would be block kriging. However, kriging is based on spatial correlations and it has been repeatedly shown that correlations of compositional data are spurious and blurred by the constant sum constraint. Aitchison (1982) proposed a general solution for compositional problems, based on transforming the compositional data to a set of logarithms of ratios of components, and analysing the transformed scores. The transform is chosen to be invertible to ensure that no information is lost in the process. This methodology avoids spurious correlation problems and ensures coherence between results obtained with different subcompositions. Pawlowsky-Glahn and Olea (2004) adapted the approach for point-support geostatistics, allowing the prediction of point compositions from spatially neighbouring data, without the artefacts induced by standard multivariate cokriging. Unfortunately upscaling the results of this approach with block cokriging is not straightforward, because of the nonlinearity of logratio transforms. Furthermore, we have to consider those nonlinearities created by the dependence on the block composition of extraction efficiency and processing costs of the possible processing choices. This paper proposes a solution for predicting the conditional expectations of the benefit of processing the block with each processing choice using geostatistical simulations of the local values of the composition and the resulting block integrals. The computation for a large number of blocks can be done efficiently using Cholesky decomposition. The approach also allows the calculation of prediction errors for expected compositions and expected benefit at almost no additional computational cost. Such compositional approach is necessary, for example when processing choices depend on proportions of certain minerals after other components have been removed; or if processing alters the composition in a multiplicative way, by partially removing a portion of some components.

Aug 1, 2013

By J. R. Donald

"Project development has been increasingly formalized in the past decade, with most organizations having extensive and descriptive deliverables documents and processes to govern the stage gate progress of capital projects. Although this has improved the general governance of capital project development and execution, it has perhaps not led to improved business success. This paper identifies specific challenges associated with developing complex projects with multiple stakeholder interests over the long timeframe of the project life cycle. The paper outlines these challenges and suggests management approaches and aspects of project development where increased focus is required to achieve improved business outcomes."

Jan 1, 2015

By Y. Kashiwaya, J. Yagi, P. R. Austin

The problems of global environment and resources have become important issues in recent years, and the iron and steelmaking industry is requested to decrease energy consumption and carbon dioxide emission. The improvement of efficiency of ironmaking system is one of the countermeasures for these problems because more than a half of total energy input to the integrated steelwork is input to the ironmaking system. Various approaches to improve the blast furnace process have been made. The authors examined their performances through mathematical simulations of blast furnace operation, and confirmed the improvement of blast furnace efficiency under some operating conditions. The ironmaking system consists of various processes, and the materials and the energy are transported among these processes. Thus it is necessary to evaluate the efficiency of the novel operation of blast furnace based on the ironmaking system. In this study, the balances of material and energy on ironmaking system that consists of blast furnace, coke oven, sintering and hot stove processes were analyzed. The operation status of each process in the system was adjusted according to the results of the operation simulation of the blast furnace under novel operating conditions. The analysis clarified the effect of the blast furnace operation on the energy balance and CO2 emission of the ironmaking system.

Jan 1, 2015

By M. Kosugi, Y. Kon, M. Kawata, J. V. Satur, K. Mitsuhashi, C. Tokoro, K. Horiuchi, R. Kawarabuki, B. Calabia

"Liberation of copper minerals is important in ensuring high flotation efficiency in copper sulfide flotation. The high pressure grinding roll (HPGR), microwave (MW), and electric disintegration (ED) are known to feature enhanced liberation over conventional comminution machines such as jaw crushers and ball mills by producing internal stresses on minerals or mineral grain boundaries through high compressive forces, thermal expansion of minerals, and pulsed high voltage discharges, respectively. In this study, each of these methods was applied before ball mill grinding to investigate its effect on enhancing the liberation of copper minerals in a low grade and fine-grained copper ore. The copper minerals observed in the tested ore sample are bornite, chalcocite, and chalcopyrite, and their grain sizes range from 10 to over 100 µm. Calcite, quartz, and feldsparare confirmed as gangue minerals. The liberation of the copper minerals by the different methods was analyzed using the mineral liberation analyzer (MLA) and compared. The result showed that the HPGR crushing was the most effective for enhancing copper mineral liberation. HPGR bench-scale test was then conducted on the copper ore and flotation was applied on a HPGR-treated sample to confirm the improvement in the flotation performance by applying HPGR.INTRODUCTIONIn order to recover copper minerals by flotation, copper ore is usually ground by ball milling to liberate the copper minerals from gangue minerals. In the case that the fine size copper minerals are targeted, grinding of the copper ore to a finer size is necessary to increase the copper recovery. However, finer size grinding by ball mill increases energy consumption significantly, which might deteriorate the economies of the mineral processing operation. HPGR, MW, and ED have been recently the focus of researchers as new techniques for enhancing the mineral liberation in mineral processing (Tavares, 2004; Kingman, 1998; Wang, 2010).HPGR crushing is considered to generate micro cracks along mineral boundary when rocks pass between two rolls by applying high compressive force. In the MW treatment, micro cracks are reported to be generated at crystal boundaries by differential thermal expansion of crystals attached to each other. In the ED treatment, micro cracks are known to be produced by plasma current flowing along mineral grain boundaries. These treatments are expected to increase mineral liberation (Fujita, 2001),improve flotation performance(Michaelis, 2005), and reduce ball mill work index(Kaya, 2010)."

Jan 1, 2017

By N Berkowitz

Slurry pipelining, as now under-stood and practised, can only command marginal interest in Canada, as long-distance railway freight charges in this country are generally lower than slurry pipeline tariffs. Several alternatives to conventional slurry transmission are, however, now emerging, and two such alternatives are briefly discussed with reference to coal pipelining. In one, coal is transported as a suspension in oil; the other contemplates the movement of paste "slugs." Preliminary economic estimates indicate that the resulant process simplification and adoption of common carrier principles could lead to cost reductions that might make Western coal competitive with imported fuel in the power generating stations of eastern Canada. R ECENT appraisals of slurry pipelining techniques, some-what incongruously 'based upon the performance of successful installations (1,2), are making it increasingly apparent that current solids pipelining methods can only command marginal interest as methods of bulk commodity transportation (3). Although some uncertainties remain in matters of detail, it is now generally conceded that long-distance slurry pipelining cannot compete against rationalized railway transportation unless movement of

Jan 1, 1963

By G. Granata, C. Tokoro, M. Matsuoka, K. Horiuchi

"Given the high demand of copper and the lack of new high-grade deposits, low grade copper ores containing copper oxides and refractory sulfides need to be processed as well. However, in order to recover copper from refractory copper ores, the leaching performances should be improved. In this study, we investigated the effect of the mechanical activation in the leaching of copper from covellite. The influence of a mechanical treatment by planetary ball milling on leaching rate in sulfuric leaching media was evaluated by using X-ray diffraction (XRD), mineral liberation analysis (MLA) and X-ray absorption fine structure (XAFS). Results showed a significant increase in copper leaching from around 50%up to 100% along with an improvement of the leaching kinetics when using planetary ball milling. XRD spectra showed the disappearance of the covellite peak from (101) face, thus suggesting the amorphization of covellite associated with the use of planetary ball milling. XAFS results showed that the coordination number of Cu changed from 6 to 3, thereby confirming the effectiveness of the mechanochemical effect.INTRODUCTIONDuring the last decades, while the copper grade in copper ores has been decreasing, the concentration of impurities such as arsenic tends to increase, thus requiring for the processing of low grade copper ores. For a suitable processing of copper minerals, hydrometallurgical processes are preferable due to the lower costs, the lower environmental impact and the easier implementation (Watling, 2006). However, for an economical recovery of copper, the leaching performances must be improved.Among the recent advancements in leaching technologies, the mechanochemical activation allows for an improvement of the leaching performances by means of high-intensity grinding(Mohammadabad et al., 2016). In the first place, the improvement is the result of the dramatic decrease of particle size, which results in an increase of the mineral surface area and the consequent enhancement of leaching kinetics. Furthermore, the intense mechanical stress due to the high-intensity grinding could induce the rupture of the crystal structure producing a decrease of crystallinity. Such changes of the mineralogical structure, also known as mechanochemical effect, can lead to more leachable mineral, thereby resulting in a greater dissolution of copper. Last but not least, whereas the mineral surface might undergo passivation during leaching, the high-intensity grinding can continuously refresh the surface of the mineral, thus exposing portions of unleached bulk mineral."

Jan 1, 2017

By J. Scrimgeour

"The word ""instrumentation"" has expanded from its original meaning, which in engineering perhaps referred to measuring apparatus alone. In its broadest form, it now includes sensors, display instrumentation, standard pack-aged controllers and, most recently, the use of stored program computers for on-line process control. The paper traces the evolution, in tutorial form, of the successive application of mechanization, measurement instrumentation, automatic control, central operating systems, programmed control, process computer control, direct digital control and, finally, hierarchies of computers used for process control and corporate management as a fully integrated business system. In the field of industrial minerals, the cement industry has seen the most widespread acceptance of these techniques. Computer control has been accepted as the way of life for the blending of chemical materials and for on-line control of the cement kiln. Accordingly, the cement application is selected for further presentation in the paper. This illustrates the trend progressing from control of single loops on process variables toward the objective of total control of the product quality. The economic justification for instrumentation, centralized control, automatic control and computer control is .discussed with reference to savings in fuel, maintenance, operating labour, depreciation, power and product quality improvements."

Jan 1, 1967

By K. E. Waters, N. Brodusch, R. Gauvin, A. Jordens, Teng. C., H. Demers

Rare earth elements (REEs) become increasingly significant for renewable energy devices and high-technology electronic products because of their large-scale popularity and applications. In this project, a field-emission scanning electron microscope was used to characterize the composition and distribution of REEs-bearing minerals. X-ray elemental maps were acquired with a large area x-ray detector (60 and 80 mm2 collecting area) and annular detector (60 mm2 collecting area), which allow fast x-ray acquisition at high count rate. These elemental maps were transformed into phase maps, which are used to identify the composition of the mineral phases and the REEs distribution over a large area. The phase maps are an easy way to distinguish the phases with and without REEs and compare the efficiency of different REEs extraction processes. Different methods (manual and automatic) for producing phase map were studied by comparing the distribution of REEs obtained from the same area.

Jan 1, 2015

By T. Senga, T. Namihira, S. Terada, S. Owada

"Electrical disintegration (ED) has been well known as a good comminution method to improve liberation of compositional phases because it was reported that electron avalanche could occur preferentially at phase boundary. But the detailed mechanism of the ED has been still not known. This paper describes the results of ED experiments using synthetic binary sample, copper/resin, under the conditions of various distance between electrodes, and discusses the energy distribution in the three kinds of phenomena in the ED process, which are(1) streamer progression in water, (2) electron avalanche in water, and (3) electron avalanche in solid sample, by measuring current and voltage with elapsed time. Then, it has been found that the energy distribution in the phenomenon (1) is quite low and that the distribution in the phenomenon(2) had a considerably large compared with that in the(3), which indicates that the shockwave generated in water could contribute much to the sample breakage.INTRODUCTIONElectrical disintegration (ED) has been well known as a specific comminution technology which enhanced selective breakage at phase boundary and lead to a good liberation among compositional phases1-6),but the detailed mechanism has not been clarified yet. This study describes energy distribution among the phenomena in the ED process by using a synthetic binary sample, copper/resin, the phenomena of which are (1) streamer progression in water, (2) electron avalanche and shockwave generation in water and (3) electron avalanche in solid sample usually at phase boundary. The energy distribution could be calculated from ED experiments and from voltage-current changes between electrodes as a function of elapsed time.SAMPLE AND EXPERIMENTALSampleThe sample used in this paper was a synthetic binary solid of copper/resin as shown in Figure1.Cut and polished pure copper lump was put into silicone mold and melted epoxy resin was poured into it and cooled, then, finally the binary sample was polished and molded in the form of 10 mm * 10 mm * 10 mm."

Jan 1, 2017

By Schrade F. Radtke

THE law of our present industrial society is the law of the jungle. By this I mean survival of the fittest. I do not refer to man or animal or the development of superior genetic strain. Rather do I refer to one's product, one's process, or one's material of construction. Each must perform in a superior manner or it is doomed to extinction; it must be steadily improved so that it can meet the competition of ether materials, of other equipment, or other processes. We have before us the classic examples of the horse and buggy vs the automo-bile, cf silk vs nylon, of the steam locomotive vs the diesel engine; in each case, a superior product has virtually wiped out its predecessor. Furthermore, a product, process, or piece of equipment is sold on its performance, together with engineering data which define its •characteristics and performance. For the most part, the present day sales-man must deal in terms of engineering performance of his product; he must know competitive materials -their strength and limitations as well N either old fashioned salesmanship, tradition, nor custom could have saved the horse and buggy from extinction; a superior product which has been steadily and con-sistently improved won out, 'and in turn, this change-over caused a dramatic• change in our whole way of life.

Jan 1, 1960

Real Time Monitoring of Cemented Paste Backfill Introduction Methods ?how to instrument a Long Hole stope Key Results from 2 case studies: barricade pressures and displacement, in-stope pressures Importance of Real Time Monitoring How binder, rise rate, cement content affect fence pressures

May 1, 2010

By K. Woo

"With ever-increasing global demand for mineral resources, mining companies are considering developing deeper, more complex and lower grade ore bodies. Recent years have seen the transition from surface to underground mass mining operations to access deeper resources, with mass mining methods such as block and panel caving being favoured due to the tonnages and economics achievable when dealing with lower grade ore. However, the rock engineering interactions involved with such plans are complex and challenging given the significant disturbance caused to the surface environment. If not properly accounted for, the unexpected propagation of a cave breaking through to surface or the differential surface displacements otherwise produced may threaten the safety and integrity of overlying mine and civil infrastructure.This paper reports the findings of a comprehensive research programme focussed on investigating and integrating new developments in remote sensing characterization and monitoring technologies with state-of-the-art numerical modelling to better manage the challenges and geo-risk associated with the transitioning from open pit to underground mass mining. Procedures were developed to integrate discrete fracture networks (DFN) into finite-element/discrete-element analyses to simulate the influence of rock mass fabric on cave propagation and the evolution of caving-induced surface subsidence and step-path failure of large open pit slopes through the progressive failure of rock bridges. The results clearly showed that caving-induced surface deformations tend to be discontinuous and asymmetric due to large movements around the cave controlled by geologic structures, rock mass heterogeneity and topographic effects. Although parallel investigations of empirical design charts used to predict caving-induced deformations were found to be moderately sufficient for assessing the extent of macro deformations directly above the undercut (i.e. caving collapse features), numerical modelling was found to provide the only means to confidently estimate the lateral extent of smaller strain subsidence.These results were further supported by the use of high-resolution synthetic aperture radar (SAR) data to monitor the ground deformations associated with block caving production, and to use these to calibrate and constrain a series of predictive 3-D numerical models focussed on Rio Tinto's Palabora mine in South Africa. The InSAR data was obtained from Canada’s recently launched RADARSAT-2. The close fit achieved between the predictive 3-D numerical model and InSAR monitoring data demonstrates the significant value of InSAR calibrated 3-D numerical models applied to subsidence prediction.Collectively, the results from this research programme have helped to further the characterization, assessment and understanding of mass mining-induced subsidence, and its evolution, by addressing existing limitations in the use of empirical and numerical design methods. The limitations and uncertainty arising from mine site data were detailed, specifically the representation of mine geology, rock mass properties, in-situ stresses and cave propagation, together with means to constrain these inputs and calibrate sophisticated 3-D numerical models through back analysis and integration with high resolution monitoring data."

Jan 1, 2015

By G. E. Peacock

SIGMA MINES is situated in the township of Bourlamaque, Abitibi County, Quebec. It is a gold producer, and presently treats an average of 1,200 tons of ore per day, at a grade of approximately 0.18 oz. per ton recovered. The mill started operations in March, I937, at a rate of 300 tons per day. This was increased to 800 tons in I940, and to 1,000 tons by I943. The rate was cut back during the war years, but was brought back up to capacity by I948. The mill tonnage was in-creased to the present 1,200 tons per day in I960. The underground workings are serviced through No. 2 Shaft (Figure 1), which, with 24 operating levels, extends from surface to a depth of 3,317 feet. When depth exploration was decided upon, two possibilities were considered: (a) deepen the main shaft by1,000 feet; (b) put down a winze for the same distance.

Jan 1, 1962

By G. Granata, C. Tokoro, T. Kato

"The goal of this study was to evaluate the effectiveness of mechanochemical activation by planetary milling as method to enhance the recovery of cerium from rare earth ores. For this purpose, a weathered ore was first ground by planetary milling and then leached by sulfuric acid. The influence of planetary milling was investigated by assisting the experiments with X-ray absorption fine structure (XAFS) in cerium LIII-edge and inductively coupled plasma spectrometry to measure the concentration of cerium dissolved by leaching. Results showed that, by increasing the grinding time, although the particle size of the specimen increased due to agglomeration, the recovery of cerium significantly increased. This finding clearly indicated that a smaller particle size actually hinders the recovery of cerium. In particular, XAFS analysis revealed that the longer the grinding time, the more tetravalent cerium could be converted into trivalent cerium and such conversion, also called mechanochemical reaction was beneficial to the recovery of cerium. Based on the obtained results, it was confirmed that approximately 70% of cerium could be recovered by mechanochemically activated leaching of rare earth ores.INTRODUCTION Rare earth elements (REEs) are a group of 17 chemically similar metallic elements comprising lanthanides, scandium and yttrium. Since REEs have various unique physical and/or chemical properties, they have become essential materials for advanced application (Adachi, 2015). REEs used in industry are usually supplied as rare earth minerals. In the last decades, flotation, gravity separation, magnetic separation and leaching have been widely applied to recovery of REEs from rare earth minerals like monazite (Archana, Rekha, Manis, Jitendra, & Jin, 2015). Among these operations, leaching has been widely studied in the recent years to improve the state of the art (Archana, Rekha, Manis, Jitendra, & Jin, 2015; Xiao, Feng, Huang, Huang, Chen, Liu, Wang, & Long, 2016; Farzaneh, Fereshteh, & Ahmad, 2017). Aiming to enhance recovery of REEs from rare earth minerals, a possible advancement of leaching technology could be the mechanochemically activation of the ore by high-intensity milling (Alorro, 2016). In the mechanochemical activation, an improvement of the leaching performances can be achieved through high-intensity milling operations which result into a dramatic decrease of the mineral particle size with a consequent improvement of the physical kinetics of leaching. Furthermore, the high mechanical energy provided to the sample during milling can determine the rupture of the crystal structure of the mineral, thereby transforming it into a more leachable form."

Jan 1, 2017