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By K. D. Peaslee, J. M. Soto, IéDé Smith, A. D. Saikia

Spinel-forming refractories reduce penetration of metal and slags through a tightening of the lining resulting from the volume expansion associated with spinel formation. Sintered spinel is often added to reduce the overall volume increase that results. Tests were carried out to evaluate the difference between performance in spinel¬forming and spinel-containing refractory mixes. Eight refractory linings, one (1) pure magnesia, three (3) magnesia-base spinel-forming and four (4) alumina-base spinel- containing dry vibratable mixes, were tested for four hours in contact with a low-carbon, low-manganese steel in a coreless induction furnace at temperatures in excess of 1600°C. Afterwards, sample were cut, and wear and penetration were measured. For magnesia-based mixes wear was minimized using 20-30wt. spinel formation although further experiments are required to determine the optimal value. For alumina-based mixes, there seemed to be an optimal ratio of spinel added to spinel formed that minimized penetration and wear at the slag line. Sidewall accretion occurred and the accretion was the highest for the mix with the ratio of spinel formed to spinel added near the optimum value. Therefore to design an optimum refractory mix the benefits of higher ratios of spinel added to reduce penetration and wear at the slag line will need to be balanced with the tendency to form accretions on the sidewalls of the furnace.

Jan 1, 2004

By C. Barnett

"A description of the Geco orebody has been given by W .L. Brown and R.C.E. Bray (1). The mill flowsheet and equipment were described by M.J.S. Bennett, D. Wild and C. Lawton (2). Mill capacity is now 4, 150 tons per operating day of copper, silver, zinc and lead ore. A recent flowsheet has been published in the - Canadian Mining Manual (1966).Soon after the start of production in September 1957, it became apparent that large tonnages of sand would be required by the mine for backfill pruposes. Initial experimental work on the preparation of sand fill from the flotation tailings was begun in late 19 59. Cyclones of local manufacture, in a variety of sizes, were tested quite successfully. There were, however, several obvious advantages with some of the custom-built cyclones and a recommendation was obtained from the Techniquip Company. A single Krebs D-10-B cyclone was tested experimentally in 1960.INITIAL TESTWORKExperimental results showed that with our relatively coarse grind (in the order of 53 % minus 200 mesh) 75 - 80% of the flotation tailings could be recovered as backfill sand with one stage of treatment. Percolation rates of four inches per hour were obtained with cyclone inlet pressures in the range of 20 - 25 psi and feed densities of 20 - 23% solids."

Jan 1, 1968

By W. E. Cockfield

THE object of this paper is to review recent geological work in the Cariboo district and to present notes on the recent development of mineral properties. The Geological Survey has done considerable work in the Cariboo district, extending over a period of years. In 1885 and 1886, Bowman (1) mapped the geology of a large area. In 1922 and 1923, Johnston and Uglow (2) mapped Barkerville area in some detail and prepared a report on the placer and lode gold deposits. In 1931 and 1932, Cockfield and Walker (3) mapped the Quesnel Forks area. In 1933, Hanson reported on Willow River area ( 4), and in 1934 made a detailed examination of part of the Barkerville area (5). In 1935, Lang commenced work on the Keithley area, lying to the southeast of the Barkerville area, and in 1936 published a preliminary re-port (6). The work on Keithley area was continued in 1936 by both authors of the present paper. As the results of the earlier work have been published, this paper will be concerned largely with Keithley area, that is, the part of the region lyinp between longitudes 121° 00' and 121° 30', and latitudes 52° 45' and 53° 00 . This area lies astride Cariboo (Swamp) river and extends north some 17 miles from Keithley, which is situated near the southern border of the map-area (see sketch-map). Points in the western part of the map-area are fairly accessible. A road extends from Barkerville to upper Cunningham creek, and from this a trail crosses Snowshoe plateau to Keithley. A second trail from this road leads to the lower falls on Cariboo river. From this road, a branch road leads to upper Antler creek, with a trail leading from this branch road to Keithley. Part of this western half of the area is made up of the Snowshoe plateau, which constitutes a gently rolling surface, at or above timber line, where trails are largely unnecessary.

Jan 1, 1937

By C. C. Allen, H. H. North

"The Young-Davidson mine is in the southeastern part of Powell township, in the district of Matachewan. It is 32 miles southwest of Kirkland Lake, 48 miles southeast of Timmins, and 25 miles by road Northwest of Elk Lake. The Young-Davidson and its neighbour, the Matachewan Consolidated mine, are the two present producing properties in the district. The Matachewan area is the southwestern extension of the Kirkland Lake belt or 'break'. The Young-Davidson mine since coming into production in 1934 has been operated by Hollinger Consolidated Gold Mines, Limited. ""Desultory prospecting(1) has been carried on in the Matachewan area from time to time since the discovery in 1906 of silver in James township at Elk Lake, and some gold has been found in the southeastern part of Alma township and in the central part of Cairo township. The first real interest in the area, however, was started by Jake Davidson's discovery in 1916 of gold on Davidson creek, on what is now part of the Young-Davidson property, and by Sam Otisse's discovery shortly afterwards on claims a short distance to the east, now part of the Matachewan Consolidated property. In subsequent years both of these properties were investigated by various companies; the Young-Davidson chiefly by the Porcupine Gold fields Development and Finance Company, Limited, and the Matachewan Canadian by the Colorado-Ontario Development Company, Limited, which in 1919 was reorganized under the name of Matachewan Gold Mines, Limited. Work was discontinued as the ore was considered too low in grade to be mined"". However, in 1933 Hollinger Consolidated Gold Mines, Limited, undertook to bring the property into production and this became a reality in 1934.The total production to the end of year 1945 was 319,185.59 oz. gold and 73,541.94 oz. silver from 3,228,845 tons of ore. This represents an average grade of $3.67, including exchange and premiums."

Jan 1, 1954

By Laurier Juteau

"NOT TOO LONG AGO, the CIM Education Committee saw the need for an information campaign to promote interest in mineral industry careers among young people. Today, times have changed and the Committee has now placed emphasis on the definition and function of the mining engineer. This situation, we believe, is entirely normal and the change of emphasis is not due to a change in the needs of the industry but more to a diversification of these needs. In years past, the Canadian mineral industry, although a very important part of our economy, was looked upon as a specialized craft and, because of the richness of our resources, did not suffer too much from competition. Now, times have changed and we are increasingly at the mercy of the competition and damaging inroads of price fluctuations, etc. We will therefore answer the questions raised in this discussion in the light of the role played in the past and the role to be played in the future by the Canadian mining engineer. We will begin with the following premises : (a) If mining engineers are to be involved in the massive problems of society, their traditional background is not sufficient. (b) Councils for professional development are working on criteria for the accreditation of advanced degree programs in the United States as well as in Canada, and, simultaneously, three-year technology programs are being developed along with professional engineering degree programs. (c) The difference between European and American industries regarding philosophy of life is that in Europe they appreciate wisdom more than HPs while in America the HP seems to be more important. The Engineering Digest of February 1972 reported that in the United States, during June and July of 1971, the second highest rate of unemployment was for the 55 to 64 age group ( 4.1 per cent). This survey certainly applies to Canadian industry as well. (d) Degrees to be awarded in Canadian universities and technical schools in 1972 will be:"

Jan 1, 1972

By G. R. Tostengard

"The paper identifies functional areas which frequently can yield significant productivity improvement. Emphasis is placed on the repair and maintenance, material supply and training functions. Successful approaches are discussed in some detail, and typical results which have been achieved are reviewed.IntroductionA challenge which at all times confronts the manager o f any mineral operation is the potential to improve his operation no matter how effective it might be a t the present time. The challenge has been present through my entire lifetime and I suspect a good many years prior to that and, I expect, will continue many year s and decades in the future. The competitive and economic situation in which we in the minerals industry find ourselves today makes the challenge eve n more important during the 1980s. In many cases it’s a question of survival, not simply pr of it improvement.There are, of course, many avenues to improving profitability; technological changes, new equipment and facilities, improved products, improved mine plans, etc. All of these are important and must be addressed by each manager. This paper focusses on just one avenue to improvement and that is ""improved management"", not so much of management at the boardroom level but of improved management o f the facilities and workforce as the y currently exist. Management implies control. There are three areas where control is often found lacking:1, Repair and maintenance of equipment and facilities;2. Material supply including procurement, inventory control and warehousing; and3. Training.These three areas are all complex and difficult to manage and they are all but ignored in the formal education which our industry's manager s normally receive. They are areas which can be improved with relatively small investments and therefore, they represent especially attractive improvement targets during the 80s when, for most of us, investment dollars are very difficult to come by."

Jan 1, 1983

By B. J. Morash

"The six mineable coal seams at Quintette Coal Limited (QCL) vary in thickness from 0.75 m to 9.5 m and include waste partings varying from 0.2 m to 4 m thick. They are highly faulted and folded in some areas and dip angles range from horizontal to 90 degrees. Due to this variation in thickness and orientation of the seams, several different mining methods are used to economically recover the coal. The key to QCL's success depends on the timely collection of detailed geology data and on mine planning which allows selection of the best method of mining to achieve maximum coal recovery with minimum dilution and cost. This paper will describe the various methods of mining employed and the criteria used to select them. IntroductionThe unique challenge in mining at Quintette Coal Limited (QCL) is to extract large quantities of coal and waste, from a complex orebody, with constricted areas for mining and waste disposal. This challenge dictates the mining of as many as four 10 m benches per year, through complicated coal structures, from three separate open pits with a total of 19coal seams. This total is made up of 5 seams at Mesa, 8 seams at Wolverine and 6 seams at Shikano (Fig. 1).Computer-aided mine planning and scheduling is carried out on a routine basis to ensure the prudent selection of methods of mining, to produce plans which ensure delivery of appropriately blended raw coals to the plant, and to coordinate disposal of large quantities of waste.Several methods of mining are applied simultaneously, and as a result coal and waste are released at different rates from twelve to fifteen mining faces. In order to ensure uninterrupted flow of material from excavators and to utilize the truck fleet effectively, a computerized dispatch system is employed.GeologyGenerally, geological conditions can be related to structural (faults and dip angle) and/or stratigraphic (coal seam and interseam waste thickness) sources"

Jan 1, 1988

By J. -P. Tshibangu, M. Ramos da Silva, F. Descamps, C. Schroeder, J. -C. Verbrugge

"The mechanical behaviour of rock materials is largely influenced by the stress state and pore pressure; this needs to be considered in many applications, such as petroleum engineering, tunnelling or stability of underground excavations.Conventional triaxial tests (d2 = d 3) are generally used to assess the influence of confining and pore pressure. In this work, those tests are performed on a porous rock named Sorcy limestone, along with more advanced stress paths like triaxial extension (d 2 = d 1) and purely deviatoric tests with independent pore pressure control. Those tests are combined to a true triaxial study on the dry rock in order to investigate the effect of true triaxial stresses and, hence, build three-dimensional limiting envelopes accounting for the influence of pore pressure.Three-dimensional limiting envelopes of dry Sorcy limestone are built in meridian and octahedral planes. The shape of the octahedral sections changes with the mean stress from triangular to hexagonal and then quasi circular. At even higher mean stresses, the evolution continues towards a triangle with apexes oriented in the direction of triaxial extension stress states. In meridian sections, the deviatoric stress first increases with the mean stress. The transition between this deviatoric mechanism and the cap surface occurs at different mean pressures depending on the Lode angle.Terzaghi’s effective stress is found to govern the yield and plastic behaviour of saturated Sorcy limestone. Triaxial tests show that the limiting envelope does not depend on the loading path (conventional compression and purely deviatoric stress paths). In triaxial extension, the brittle-ductile transition is observed for a higher mean pressure than in triaxial compression, as previously found for true triaxial tests on the dry rock.Finally, it is shown that upon appropriate normalisation, the dry and saturated yield envelopes come very close one to each other. This suggests that only the size of the yield envelope changes between dry and saturated state (pore pressure = 5 MPa); its shape does not seem to evolve."

Jan 1, 2015

By R. J. McLeod

"Grinding at Giant Yellowknife is done in two stages. The first stage consists of two ball mills in closed circuit will: mechanical classifiers, the classifier overflow goes to flotation. The tailings from this flotation circuit are separated into slime and sand portions, the slimes go to an additional flotation circuit while the sand portion goes to the secondary grinding mills.Milltronic automatic sound control units were installed on each of the two primary ball mills and put into operation September 3, 1966. After about two months adjustments to the control units the operators were taken off the grinding circuit on November 1, 1966. The operators duties were taken over by the automatic control units while miscellaneous work was taken over by the helpers in the mill. The labour saving by the installation is approximately $2250.00 per month.After a short period of operation it was apparent there was a slight change in grind. The screen analysis of the primary classifier overflows for the period May to August 1966 averaged 62.23% minus 200 mesh while for the period September to December 1966 averaged 62.0% minus 200 mesh. This is a slight coarsening of the grind. The change in the primary grind has manifested itself also in the screen analysis of the final grind. Before automation the final grind was 80% minus 200 mesh, while after automation it was 7 5% minus 200 mesh. A change of grind was also noted in the flotation concentrates. Before automation the screen analysis of the concentrates was 35% plus 200 mesh and 50% minus 3 25 mesh. A ft er automation it was 35% plus 200 mesh and 47 .5% minus 325 mesh. In other words the grind got coarser or perhaps we should say there was less overgrinding. Another significant change took place in the assays of the slime and sand portion of the primary flotation tailings. It was usual under manual control for the slime portion to assay higher in gold than the sand portion. The reverse is now true."

Jan 1, 1967

By A. Malfliet, A. Van den Bulck, D. Willems, M. Guo

The feed stock of copper fire refining processes consists of two major constituents: blister copper and high-Cu secondary scrap. A large fraction of this secondary scrap, originating from urban mining, is quite high in impurities such as Fe, Ni, Pb and Sn. Problems arise in electro-refining when these elements exceed certain limits. As a consequence, transformation of the secondary copper raw materials into high grade copper has become troublesome. However, the behavior of impurities relevant to fire refining conditions, essential for anode refineries, has not been studied in detail. Furthermore, limited research has been performed on the distribution of Ni between copper metal and slag. In this study, equilibration at 1300°C of liquid Cu-1wt.% Ni alloy and CaO-CuOx- FeOy-SiO2 slag in vacuum sealed quartz ampoules was performed for 12 hours, followed by water quenching. Electron Probe X-ray Microanalysis was employed to investigate the composition of the equilibrated alloy and slag. The distribution coefficients of Ni between slag and alloy were determined as a function of oxygen partial pressure and CaO concentration. INTRODUCTION Europe’s initiatives for a circular economy, pushing for resource-efficient ways for a sustainable future, puts Europe at the forefront of the globe. In Europe, 50% of the copper originates from recycling, being an excellent example of Europe’s circular economy (Juncker, 2018; Lacasse, 2018). High-grade copper recyclates are made available which regularly contain impurities like Fe, Ni, Sn and Pb. Aurubis Belgium is responsible for recycling these types of recyclates to anodes, cathodes and copper products. However, after fire refining of copper, the aforementioned impurities remain in the anode copper, leading to problems in electrorefining. During the fire refining of copper, a CaO-“Cu2O”-“Fe2O3”-SiO2 slag is used. Fundamental information of the distribution of impurities between the copper and this slag system is therefore essential to understand and improve the copper fire refining process at Aurubis Belgium.

Jan 1, 2019

By Roy EI. Durr, Glen R. Davidge

"This paper presents the results of structural analyses and full-scale destructive tests conducted on liner plate culverts. The purpose of this work was to establish a design method and evaluate the suitability of using these structures in potential roof-fall areas for a rehabilitation application in lower stress and relaxed mining environments. Field evaluation of the design is currently in progress.Theoretical ultimate resistance functions were established for two different culvert shapes and were found to be representative of their experimental behaviour. The ultimate resistance function was used to determine their plastic behaviour to a rapidly increasing deflection condition, to determine the energy absorption capacity of these structures, and to predict their response to impact loading.IntroductionThe Kidd Creek mine of Falconbridge Limited is located justnorth of Timmins, Ontario. The area under rehabilitation for which this program was developed is the 2600 level of the No. I mine. The problem of effectively securing selected drifts at the 2600 level in NO.1 mine, for access to a high-grade ore block, is key to the economics of the operation. Diamond drill test holes had indicated a loosened rock mass above the 2600 level of about 7.5 m thick in response to the extensive mining operation below this level. This level forms the arbitrary boundary between the No. I and No. 2 mines, and has extensive volumes of cemented rock fill below it and largely untouched ore above it to the 2000 level in the North orebody. The walls at that level were showing relaxed ground conditions typical of de-stress: sub-horizontal joints opening up, and peeling.Due to the ground conditions, the consequent safety risks, the high grade of the ore, the potential production delays, and the likelihood of several phases of rehabilitation, regularly used drift rehabilitation employing rock bolts, cable bolting, or shotcrete was not practical. Two options were deemed possible alternatives to suit these conditions, steel sets with blocking and lagging, and liner plate culverts with backfill. Culverts were chosen."

Jan 1, 1995

By Joseph Bradley

THROUGHOUT this article, minerals used in the paint industry are designated 'pigments'. They may be classified in two groups: (1) Pigments which are used in the state in which they occur in nature, requiring only mechanical preparation. (2) Pigments which require heating or chemical treatment before use, in order to obtain from them a product of the desired quality or shade of colour. They may be further classified according to colour, as follows: White Pigments .-These include calcium carbonate (chalk, marble), gypsum and alabaster, kaolin-or china-clay, and magnesia. However, the white pigments most extensively used are compounds prepared chemically from minerals containing lead, zinc, titanium, and antimony. The white pigments are of particular importance because, not only are they used by themselves, but they also serve as adjuncts to other colours for the production of special shades. Yellow Pigments.-These are mainly naturally occurring ferric hydroxides, as limonite and bog iron ore, or similar. compounds prepared artificially. Brown Pigments .-Pigments of this group are distinguished for their beauty and depth of colour, and many of them are used in the finest of paintings. Familiar names are sienna, umber, and Vandyke brown. They are for the most part ferric hydroxides, containing varying amounts of water; but the group also includes a manganese brown, which consists chiefly of a mixture of oxide and hydroxide of manganese. Red Pigments.-Chief among this group is ferric oxide, known under various trade-names, such as Canadian red, Persian red, etc., and also the much prized and somewhat rare vermilion. The pigment used is either naturally occurring hematite, de-hydrated limonite, or artificially produced red ferric oxide.

Jan 1, 1937

By Mark Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the Autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the Open Pit and Process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of: 1) Electronic caps for more precision and flexibility, as well as for allowing extremely fast shots. 2) Explosives with a higher velocity of detonation (VOD), to provide for improved shock energy. 3) Improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by six tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster ?hard ore? (BWI >17), as well as autoclave ?hard ore? (BWI >15). Approximately six million tons of D2M material is expected be shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

May 1, 2003

By G. W. H. Norman

"The Indian Molybdenum deposit occurs in granite near the centre of Indian peninsula, Kewagama lake, in Preissac township, Abitibi county, Quebec, about 40 miles east of Noranda. Quartz veins containing molybdenite were discovered in the vicinity of the deposit in 1901 by J. F. E. Johnston of the Geological Survey of Canada. Innumerable trenches and a few pits were excavated during and prior to the first great war, but there was no production. During the second great war systematic drilling along a favourable zone disclosed by the earlier trenching outlined an orebody of 225,000 tons with a molybdenite content of 0.46 per cent.A 500 on mill was built in 1943, and 91,489 tons of ore underwent treatment, from which 699,568 lb . of molybdenite was recovered. The mill closed down early in 1944 when the wartime need for Canadian molybdenum production eased .GEOLOGYThe general geology in the vicinity of the deposit is shown in Fig. 1. The deposit lies at the north edge of a muscovite-biotite granite mass about 2 miles wide and several miles long. West of Kewagama lake this granite is cut by great swarms of quartz veins . The only other granite in the district known to contain similar swarms of quartz veins, and which similarly has become a source of mo!ybdenite, occurs 20 miles east in La Corne township. The non-molybdenite-bearing granites of the district are either more basic and contain frw dykes except aplite or are distinctly pegmatitic types and contain up to 50 per cent pegmatite dykes with molybdenite only here and there in small amount."

Jan 1, 1954

By M. P. Brameld, G. Archambault, R. H. McCorkell

"The rates. J. at which materials emit radon are of interest in studies of the sources of radon in mines. buildings. soils overburden and other places where it may indicate the location of ore or be a health hazard. Here J values were determined by measuring the radon concentrations by means of scintillation counters or alpha-particle track detectors in chambers in which specimens were sealed. Errors in the measurements due to leakage from the chambers. lack of secular equilibrium in the decay series of the radon measured, or the limited rate of diffusion of radon from powders or within the chambers were shown to be insignificant or could be corrected. Scintillation counter measurements are highly reproducible; track detector measurements also appear useable and may be made on many small samples using small, simple chambers. J measurements were made for uranium ores, drill cores, standard CANMET pulps. concrete and gypsum board. Powdering of ores had little effect on their J values.IntroductionIn the mining and mineral sciences, radon (222Rn) is of interest chiefly for two reasons: in geochemical exploration for mineral deposits its presence in soil. overburden and water in more than background concentrations may indicate the existence and locations of uranium deposits and, if present in sufficient concentrations, it is a possible health hazard in mines, mills and other places where people live and work. The latter aspect of radon's role has received considerable attention recently(1,2,3,4,5), and surveys of soil-gas radon concentrations have been used for some time in searches for uranium deposits(6,7,8,9,)."

Jan 1, 1981

By L. C. Bird, A. I. A. Salama, M. W. Mikhail

"A program of sampling in Canadian washeries was carried out by the Coal Research Laboratory (CRL) over a period of two years to evaluate the performance of various density separators in these operations(1). Operating data on quality and recovery of products, separation efficiencies and cutpoints for each separator type are compared with data predicted using computer models developed from previously existing data.The Heavy Medium Cyclone (HMC), Heavy Medium Bath (HMB) and jig models give predictions of recoveries and qualities of products for sizes coarser than 10mm with absolute value of error mean less than 7 per cent, whereas predictions of the Water Only Cyclone (WOC) model for -10mmfine coal are with absolute value of error mean less than 8 per cent. Although less accurate for -10 mm fine coal, the HMC and jig models produce predictions of recoveries with absolute value of error mean less than 2 per cent and quality of products predictions with absolute value of error mean less than 28per cent which are generally acceptable because more liberation in the fine fractions appears to compensate for any difference in the accuracy of separation, resulting in good prediction of the clean product. However, ash content of the actual fine refuse was lower than predicted. The difference is attributed to the highly friable nature of Canadian coals which tends to cause an excessive loss of coal fines to the fine refuse.A comparison study based on quality and recovery of products is made between the Dutch State Mines (DSM) models and the recently modified models, both produced comparable predictions."

Jan 1, 1985

By Y. A. Grinin, M. A. Liamina, V. A. Shumskij, Y. I. Sannikov, M. V. Radashin

"A brief history of the development of the Kivcet flash smelting process is presented. The broad scope of the process with an ability to treat high grade lead sulphide concentrates, as well as oxidized lead-zinc residues, is emphasized. Fine coal in the charge serves two purposes, one as auxiliary fuel and the other as a pre-reductant for ferric iron in residues. Current Kivcet operations incorporate a layer of coke or “coke checker” at the surface of the slag in the reaction shaft that acts as a reducing agent for flame products or slag that flow through it. Details of this invention, are given. IntroductionFor many years, the sinter-blast furnace lead smelting process has been the main internationally accepted method used for the production of primary lead metal. In recent times, this process has been unable to meet legislated environmental restrictions and it became clear in the mid-1960s that a new and cleaner process would have to be developed. The present level of Kivcet performance was developed in three main stages:1. flash smelting natural sulphide lead raw materials with the attached electric furnace for production of lead bullion and crude zinc;2. natural raw material smelting with lead and zinc separation in a “coke filter” or “coke checker” at the surface of the slag in the reaction shaft to produce lead bullion and ZnO-bearing slag that can be fed to conventional slag fuming; and3. processing of oxidized lead-bearing raw materials, such as low grade zinc plant residues, with the production of lead bullion and ZnO-bearing slag periodically directed to slag fuming."

Jan 1, 1998

By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2'-bipyridine (bipy) (1), 6-alkyl-2,2'-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2'-bipyridine (bipyR') (3), R' = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

By Gary Walters, Matthew White, Thomas W. Gonzales

The copper smelting industry has transitioned into the 21st century compliant with environmental regulations, new smelter installations and brown field expansions. The industry faces new challenges as copper in concentrate grades have decreased while contained impurities have increased. A new benchmarking survey was undertaken to update the last survey of 2016 for operating copper smelters in the world. The information collected was separated based on primary smelting technology rather than by geographical location and supplemented from published literature. Each smelting technology’s unique use of specialized process equipment, concentrate smelting capacity, and impurity flexibility are discussed INTRODUCTION The 20th century was a remarkable time for the growth of copper smelting. Electric, blast and reverberator furnaces dominated the smelting technology well past WWII. In the 1970s, SO2 regulations and high energy cost drove the development of new primary smelting technology. Technological advancements decreased energy consumption and enriched sulfur dioxide concentrations of the process off-gas to levels where sulfur capture in sulfuric acid plants was economically viable. The new smelting technologies began to replace reverberatory and electric furnaces starting in the late 1940s. A new paradigm in copper smelting was established and the enabler was then Outkumpu’s® flash smelting technology from the 1940s through to today. Now, Outotec had become the dominant primary smelting technology with over 44 copper flash smelting furnace installations world-wide. Figure 1 shows the historical installation statistics of primary smelting technologies over the last 70 years (ICSG 2018). The dominance and acceptance of the Outotec® smelting technology from the 1940s to current can be seen. Isasmelt® technology for copper was introduced in the 1970s and did not see advancement in new installations until the 1990s through today. Isasmelt® has 12 world-wide copper furnace installations to date. Mitsubishi® also introduced continuous smelting and converting technology in the 1970s, but had no new installations until the 1990s with a total of 5 copper smelters. Outotec Ausmelt® smelting technology had 3 installations in the 1990s and totals 10 furnaces. Most recently the Chinese technology of Bottom Blown and Submerged Lance Smelting began commercial operations in 2005 for total installations of 11, mostly in China. Other technologies, such as, El Teniente, Noranda, Inco, and Vanyukov furnaces have contributed to the overall global smelting capacity, but have not penetrated the smelting industry to challenge the existing dominant smelting technologies. The technology distribution in Figure 1 also shows flash smelting technology for sulfide concentrate domination untill 2000, bottom blow technology has become the preference in China. Currently, China is the only country building new smelting capacity. Isasmelt® technology also seen a large increase in installations in the current decade.

Jan 1, 2019

By J. Koponen, K. S. Stadler, A. Fuerst, S. Gaulocher, Th. von Hoff, R. Veldsman

"Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO).A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components:1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user.2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer.3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD.In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples."

Jan 1, 2012