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By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By J. H. Baek, D. W. Lee, B. K. Kim

Nanostructured Cu-Al203 composite powders were synthesized by thermochemical process for an electrode application. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from copper and aluminum nitrates, 2) heat treatments to evaporate volatile components in the precursor powder and synthesis of nanostructured CuO+Al2O3, and 3) CuO reduction by hydrogen into Cu. The suggested procedures stimulated the formation of the gamma-Al2O3. The mean particle size of the final composite powders was 20nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/Al2O3 composite by the conventional internal oxidation process.

Jan 1, 2004

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By J. H. Baek, S. Alexandrovskii, D. W. Lee, B. K. Kim

Nano-phase titanium carbide was synthesized by Mg-thermal reduction process using a novel route of Mg-thermal reduction. The processes are based on I) feeding of TiC14+CxC14 x = 1, 2 ) solution into liquid magnesium, 2) Mg-reduction of metal chlorides, 3) TiC formation by the reaction of released Ti and C atoms, and 4) vacuum separation of residual liquid phases of Mg and MgCl2. In this study, the process for titanium carbide production with composition close to stoichiometry and the minimum content of impurities was optimized with the various process parameters such as concentration of initial solution, its feeding rate and reaction temperature, as well as a kinetic study.

Jan 1, 2004

By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

By Anne-Laure Bonnet

Les connaissances acquises au cours des dernières décennies sur les gîtes de métaux de base et précieux intensément métamorphisés (p. ex. Vokes, 1991; Cornell et al., 1992; Zaleski et Peterson, 1995) ont permis d?élaborer des guides d?exploration pour de tels gisements dans les terrains de haut-grade métamorphique (Spry et Scott, 1986; Rubin et al., 1993; Hand et al., 1994; Spry, 2000; Spry et al., 2000). Un transfert de ces connaissances à la cartographie des vastes terrains gneissiques non différentiés de la province de Grenville permet d?affiner l?approche cartographique nécessaire pour reconnaître les systèmes hydrothermaux métamorphisés en terrains vierges et peu diagnostiques puis d?en discriminer les divers halos d?altération (Corriveau et al.,1996, 1997, 1998, 2003; Williamson et al., ce volume). Cette approche prend en compte les « empreintes métamorphiques » observées sur le terrain, telles que les variations des assemblages minéralogiques, du mode et de la composition des minéraux métamorphiques, pour reconnaître des roches présentant une composition inhabituelle caractéristiques de protolites altérés par hydrothermalisme. Ces empreintes citées cidessus sont facilement reconnaissables dans les terrains de haut-grade où la recristallisation induit un grossissement des grains qui permet de déterminer la nature et le mode des minéraux dès les levés de terrain. Cette approche raffine la compréhension des terrains de haut-grade métamorphique et illustre que leur complexité (i.e. polyphasage de la déformation et du métamorphisme) n?est pas forcément une limite à leur exploration. Elle a donc été utilisée systématiquement lors des levés de terrain réalisés dans le cadre d?un projet de l?Initiative géoscientifique ciblée de RNCan. La zone cartographiée se situe le long de la marge sudest du Groupe de Wakeham dans le secteur est de la Province de Grenville. Deux régions ont été plus particulièrement étudiées, celle du lac Musquaro (SNRC 12K10, 11 et 14) et la région côtière comprise entre Kégashka, La Romaine et Baie des Loups (SNRC 12K1, 2, 3 et 7) (fig. 1).

May 1, 2003

By Burden of Occupational Cancer in Canada Project Team, Demers P. A., Kim J., Arrandale V. H., Jardine K.

"In 2012 diesel engine exhaust (DEE) was classified as a human carcinogen by the International Agency for Research on Cancer (IARC) and is one of the most common workplace carcinogens internationally. We estimate that approximately 2.4% of lung cancers (n=560) and a suspected 2.7% of bladder cancers (n=200) are attributable to occupational exposure to DEE annually in Canada. High levels of exposure to DEE in mining results in a disproportionate number of cancers in this sector (approximately 220 lung and 20 suspected bladder cancers annually). These could be prevented by reducing the number of workers exposed and level of exposure. KEYWORDS Bladder cancer, Diesel engine exhaust, Economic burden, Lung cancer, Mining, Occupational cancer, Prevention, Regulation INTRODUCTION Diesel engine exhaust is a complex mixture of gases and particulates containing known and suspected carcinogens such as benzene, polycyclic aromatic hydrocarbons (PAHs), and metals. Approximately 900,000 Canadians are exposed to diesel engine exhaust at work, making it the most prevalent occupational lung carcinogen in Canada (CAREX Canada). Diesel engine exhaust is recognized as one of the most common workplace carcinogens in the world, but its classification as a human carcinogen by the International Agency for Research on Cancer (IARC) was relatively recent. In 2012, after decades of mounting evidence, diesel engine exhaust was upgraded from a probable (IARC Group 2A) to a definite human carcinogen (IARC Group 1) (IARC, 2014). The IARC evaluation was based on strong evidence in humans for an increased risk of lung cancer, as well as strong evidence in animal studies. The key human evidence considered by IARC was from epidemiologic studies of workers in truck transportation, rail transportation, and mining industries, where the use of diesel engines is widespread. These studies provided strong sufficient evidence for an increased risk of lung cancer, as well as limited evidence for bladder cancer. The human studies used particulate matter, generally measured as elemental carbon (EC) or total carbon, as a surrogate for diesel engine exhaust to assess the risk associated with level of exposure. The animal studies reviewed by IARC showed sufficient evidence for cancer with exposure to whole diesel exhaust and the particulate matter fraction of diesel exhaust, but not for the gas phase components."

Jan 1, 2019

By J. R. Meyer, P. L. Dean

"The Department of Mines and Energy is at present investigating the dimension-stone potential of the Nain anorthosite complex. These rocks are known to host occurrences of labradorite, a semiprecious gemstone known for its beautiful play of colours (chatoyance). Test blocks that contain 5% to 18% chatoyant labradorite were extracted from three prospects south of Nain. These have been slabbed and polished for further evaluation.Second-grade labradorite stockpiled around the Grenfell quarry on Tabor Island is also being evaluated as a potential source of aggregate for use in terrazzo tiles, precast concrete and epoxy-backed wall panels.IntroductionThe Nain anorthosite complex consists of approximately 10000 km2 of anorthosite and related basic rocks , which are well exposed along the coast of Northern Labrador (Fig. 1) (Emslie et al., 1972). These rocks have been known for centuries to host deposits of gem-quality labradorite. The chatoyant nature (i.e. the play of colours or labradorescence) of this semiprecious feldspar has been utilized mostly in the making of jewelry and other polished, handcrafted products. In the early sixties, Brinex Limited (now Brinco Limited) attempted larger scale commercial exploitation of labradorite, including use &apos;as building stone and in polished precast concrete for facings on buildings&apos; (Brummer, 1984). After six years of work, which included market studies, Brinex decided that, at that time, the demand did not warrant further production.In recent years, there has been a dramatic increase in the markets for dimension-stone. In the period from 1980 to 1985, the demand in the United States for granite, much of which is imported, has increased 1735070 (Marble Institute of America, 1986). The dimension-stone industry&apos;s remarkable growth rate has, in part, resulted from new technology that makes it easier and faster to quarry and cut stone. This has allowed natural storie to compete with other building materials. Now, it is not only used for exterior cladding and walkways, but also on interior walls and floors, and in home and office furnishings, such as countertops for kitchens and bathrooms, table and desk tops, stairways, window sills, and fireplaces."

Jan 1, 1988

By J. R. Meyer, P. L. Dean

"The Department of Mines and Energy is at present investigating the dimension-stone potential of the Nain anorthosite complex. These rocks are known to host occurrences of labradorite, a semiprecious gemstone known for its beautiful play of colours (chatoyance). Test blocks that contain 5% to 18% chatoyant labradorite were extracted from three prospects south of Nain. These have been slabbed and polished for further evaluation.Second-grade labradorite stockpiled around the Grenfell quarry on Tabor Island is also being evaluated as a potential source of aggregate for use in terrazzo tiles, precast concrete and epoxy-backed wall panels.IntroductionThe Nain anorthosite complex consists of approximately 10000 km2 of anorthosite and related basic rocks , which are well exposed along the coast of Northern Labrador (Fig. 1) (Emslie et al., 1972). These rocks have been known for centuries to host deposits of gem-quality labradorite. The chatoyant nature (i.e. the play of colours or labradorescence) of this semiprecious feldspar has been utilized mostly in the making of jewelry and other polished, handcrafted products. In the early sixties, Brinex Limited (now Brinco Limited) attempted larger scale commercial exploitation of labradorite, including use &apos;as building stone and in polished precast concrete for facings on buildings&apos; (Brummer, 1984). After six years of work, which included market studies, Brinex decided that, at that time, the demand did not warrant further production.In recent years, there has been a dramatic increase in the markets for dimension-stone. In the period from 1980 to 1985, the demand in the United States for granite, much of which is imported, has increased 1735070 (Marble Institute of America, 1986). The dimension-stone industry&apos;s remarkable growth rate has, in part, resulted from new technology that makes it easier and faster to quarry and cut stone. This has allowed natural storie to compete with other building materials. Now, it is not only used for exterior cladding and walkways, but also on interior walls and floors, and in home and office furnishings, such as countertops for kitchens and bathrooms, table and desk tops, stairways, window sills, and fireplaces."

Jan 1, 1988

By P. W. Udo Graefe

"An interactive computer model of a dragline, windrow and spoil pile has been developed for modelling oil sands mining operations. The model is to be used in conj unction with models of other oil sands mining equipment, such as bucket-wheel excavators and reclaimers, conveyors, hoppers, bins, trucks and shovels, to study mining operations on a minute-by-minute basis. From the orebody description and mining selectivity, layers of ore and reject are determined and mined by the dragline. Reject is dumped on the pit floor; ore is either dumped on a windrow for later removal by a bucket-wheel reclaimer or directly dumped into a hopper feeding a conveyor. The model allows for the presence of pads as a dragline base, key cuts and a number of interruptions to the mining operation such as shift changes, boom checks, engineering services, repairs, delays, preventative maintenance, etc. A CRT display keeps the model operator informed about equipment status and performance. The model operator can direct the course of the simulation by issuing commands to the model at any time during the simulation.IntroductionThis paper describes an interactive computer model of a dragline, windrow and spoil pile. The model was designed by the author based on information and specifications provided by Canstar Oil Sands Ltd. The model design was implemented and tested on Petro-Canda&apos;s IBM computer system by DMR and Associates Ltd. of Calgary, Alberta.The model was designed to form three components of an oil sands mining operations model, described in reference I. Figure 1 shows the interaction of those components with the remainder of the oil sands mining model.An ""Ore/Waste Body"" data base provides information to the dragline model about the location and composition of or e and waste in the mine. The dragline model is used to simulate mining this ore/waste body, to build up spoil piles for center reject (waste) and to dump ore onto windrows or hoppers (situated over conveyors) to deliver the ore to the extraction plant. The windrow model component provides a data base which will be used by a model of a bucket-wheel reclaimer which simulates the loading of ore from the windrow on to a conveyor via a bridge."

Jan 1, 1982

By M. L. Jeremic

"Hydraulic mining consists of coal erosion by powerful jet s of water from hydraulic monitors operated by remote control. The broken coal is crushed and mixed with water and then transported from the face to the surface using gravity whenever possible. This is a simple, safe and productive method. It will easily satisfy North American productivity standards if the structural features and coal properties are favourable for water jet cutting technology (Kaiser Resources Ltd. , hydraulic mine). General ConsiderationIn open-pit mines, placer mining (Fig. I) and hydroelectric construction projects, hydraulic earth moving techniques have been successfully applied. The stripping and transporting of the overburden has been accomplished by means of large monitor jets augmented by slurry pumps and pipes. An extension of this technique has led to the underground extraction of coal and ores. To date, the method has been most successfully used in undergrond coal mining, because the coal can be easily cut and flushed away by water jets, and the rocks of the roof strata can be left behind. Due to this favourable situation, the hydraulic mining definition only relates to the underground coal mines.At present, there are four basic types of hydraulic mining, which can be defined according to the coal breaking technique used in each case. The methods are briefly discussed below:(1) Coal excavation may be carried out by conventional techniques, but the mine is designed and equipped for the hydraulic transport of the mineral from the working place to surface. Under these circumstances, the coal breaking may not be influenced by the water jet, however it may be indirectly involved. For example, pre-loosening of the coal may be done by water infusion-hydraulic fracturing. Water may also be used to flush the broken coal, which has been excavated either by drilling and blasting or by mechanical cutting, into the transport flumes. In other cases, a mechanical loader may load the coal directly into the hydraulic transport system, without using any water for the extraction process. This hydraulic mining concept is primarily used for hard and impermeable coal, such as anthracite."

Jan 1, 1980

By A. L. Mular

"On behalf of Bob Bruce and myself I would like to begin by stressing some key points.First, most of us know that the Canadian Mineral Processors was formed in 1969 and is an offshoot of the Canadian Gold Metallurgists. I attended that first meeting in 1969, and I haven't missed a meeting since! Pretty obvious that CMP serves the best booze! At any rate, we know that our meetings are supported by CANMET. Camsell Hall is always at our disposal; Bob Bruce acts as permanent secretary pretty much free of charge; we receive a financial grant from CANMET. This brings me to a second point.Second the Canadian Mineral Processors do not enjoy a free ride in this relationship. CMP provides a genuine service to the mining industry, to government, and to universities. For the industry, CMP serves as a forum for the rapid dissemination of new ideas and new technology developed at remote locations throughout Canada. New developments outside Canada are introduced by invited speakers at our meetings. The effect is to help reduce operating costs and increase efficiency.For government, problem areas and research priorities can be isolated through mutual discussions. Direct communication at our meetings can help CANMET to temper its goals and modify its national priorities.For universities, CMP provides a wealth of operating experience and practical know how. The yearly proceedings are a major current reference source fo1· those of us who teach mineral processing. Admittedly, the proceedings are publ-shed from CMP coffers. However, I note that our fees are up this year, which brings me to a third point.Third, we face some potential problems of a financial and political nature. From a financial view, we may lose our CANMET grant and other financial good will simply because of spending constraints. Our fees are expected to climb each year thereafter.From a political view, we know that the metallurgical society of CIM is anxious to incorporate CMP as a section. The pros and cons of such a merger have been described in a recent mailing. In th2 final analysis, the political and financial problems are interrelated. There are several alternative solutions to both problems, which brings me to a fourth point"

Jan 1, 1979

By Zorigtkhuu Davaanyam, Fisher Wang, Bern Klein, Amit Kumar

"The High Pressure Grinding Roll (HPGR) is an increasingly popular energy efficient solution for comminution of competent ore deposits that primarily competes with conventional crushers and tumbling mills. A significant barrier to increased adoption of HPGRs is the requirement for large amounts (one tonne or more) of sample for pilot testing which may not be feasible for most early staged projects.Various researchers have worked towards developing piston-die and JK drop weight tests to model and predict the energy requirements for an HPGR. Two small scale laboratory test procedures (the SMC test (Morrell, 2009) and the piston press tests (Davaanyam, 2015)) have been developed in recent years to provide necessary information to size an HPGR.These two methods were used to estimate the required specific energy for an HPGR unit and compared to HPGR pilot scale test results from a copper deposit. The comparison provides insight into the benefits and limitations of these tests.INTRODUCTIONHigh pressure grinding rolls (HPGR) have gained popularity in recent years because of their energy efficiency in comminution. Various researchers have suggested that approximately 50–80% of the total energy consumed in a mineral processing plant is used by the comminution equipment (Haque, 1999; Abouzeid & Fuerstenau, 2009; Wang, 2013). Haque (1999) showed that the efficiency of grinding equipment can be as low as 1%. Due to the energy intensive nature of comminution, mining industry has been forced to explore alternative energy efficient processes.An HPGR based circuit has been shown to be 10–25% more energy efficient than a conventional SABC circuit (Von Michaelis, 2009; Wang, 2013). A significant barrier to the increased adaptation of HPGRs is the requirement for a large amount of sample for pilot testing (up to 5 tons), even on a prefeasibility level. Numerous studies have been performed to utilize piston press test to analyze the performance of the HPGR circuit and to predict the energy consumption for an industrial application. This paper uses two small scale laboratory test procedures, the SMC test and a piston press test, to compare the energy requirement to the pilot HPGR data."

Jan 1, 2016

By Alfred W. G. Wilson

MR. F. E. LATHE: In studying any subject whatever, one should at least occasionally stand back from the canvas, as it were, and take a broad view of the picture. It is such a view of the subject of industrial minerals that Dr. Wilson has given us today, and, in consideration of our efforts to utilize Canada&apos;s resources to the utmost in the present emergency, it seems most timely. I shall confine my remarks on the subject to the resources of the atmosphere and hydrosphere. We seldom stop to realize our dependence upon the atmosphere, not merely as a source of the oxygen we breathe but also of other indispensable elements. As recently as the beginning of the present century, grave concern was felt lest the rapidly increasing population of the world should ultimately starve for lack of the nitrogen required for crop growth. I recently noticed a reference to the Scientific American for March, 1890-just fifty years ago-in which an account is given of work on the fixation of nitrogen, which, said the article, "leads to the conclusion that while cyanides and ammonia may be thus produced experimentally, there are as yet insuperable difficulties in the way of adapting those methods to industrial purposes". Y et, in the early part of the present century, the development of the arc, cyanamide, and synthetic ammonia processes of nitrogen fixation was such as to remove, for all time to come the possibility of a shortage of nitrogen. Today, the atmosphere is by far our greatest source of nitrogen, and the capacity of the nitrogen fixation plants of the world is at least 4,000,000 tons annually-much more than can at present be utilized. Pure oxygen or oxygen-enriched air offers great possibilities in metallurgy and industrial chemistry, but, so far, little application has been made. In a paper presented to the Institute in 1926, 1 pointed out the theoretical savings which could be effected by the use of oxygen in burning carbon-when the gases pass off at 2,460°F., the fuel saving is no less than 50 percent. The use of oxygen on a commercial scale is intimately tied up with the question of refractories, but we should not forget that the possible changes in metallurgical practice by the use of oxygen are truly of revolutionary character.

Jan 1, 1940

By H. Helmstaedt, P. Thurston, R. Harrap

"Evolution of the continental lithosphere over Earth’s 4.6 billion year history is one of the fundamental questions of geoscience. Much of the Earth’s present-day continental crust formed during the first 2 billion years, the Archean eon, of the planet’s lifetime and thus, Archean processes of lithospheric formation must be studied in order to address this question. Until recently, the processes of Archean lithospheric evolution were thought to be fundamentally different from present-day plate tectonic processes. However, subsequent evidence suggests that the growth of Archean continents may be explained in terms of modern tectonic accretionary tectonics similar to those presently operating in the southwest Pacific region. The evidence supporting this hypothesis was compiled largely by Canadian geoscientists working in the Superior Province of the Canadian Shield in northwestern Ontario, over the past 15 years. Study of Archean rocks is also economically important because the Archean rocks of the world, although comprising only a relatively small fraction of the exposed continental crust, contain much of the world’s mineral wealth, including more than half of the world’s gold, as well as significant base metal reserves. Furthermore, the vast majority of primary economic diamond deposits are derived from the lithospheric roots beneath Archean cratons.The LITHOPROBE Western Superior Transect is located within the western part of the Superior Province in northwestern Ontario (Fig. 1). The Superior Province is the largest and best exposed Archean crustal block in the world and forms the nucleus of the North American continent. The internal structure of the Superior Province records a history of the processes that formed the earliest lithospheric elements of the Earth into cratons, thus providing an ideal laboratory for investigating early crustal evolution. The Western Superior Province is characterized by a regional pattern of alternating, 100 km to 200 km wide geological belts (Fig. 2). The observed geologic relationships between and within these subprovinces have been explained in terms of a modern tectonic model of terrane accretion. Oceanic floor, volcanic island arcs, oceanic sediments and continental fragments were accreted successively from north to south against the southern margin of a cratonic nucleus (North Caribou terrane, Fig. 2) which grew steadily in size with the arrival of new terranes through geologic time. If this model is correct, it suggests that the tectonic processes operating today have been active without major variation over the past 3 billion years."

Jan 1, 1998

By Ross Gilders, Leo Cheung, C. David Desjardins

"For the past twenty years significant progress has been made in bacterial leaching. In fact, a recent article in the Northern Miner has cited that nearly all new copper production is based on bioleaching. The bacteria that play the predominant role in bioleaching is an obligate chemolithoautotroph called thiobacillus ferrooxidans. These bacteria thrive in areas rich in sulphide and prefer low acid media. In the simplest sense, they metabolize sulphide converting it to sulphate either as acid or as soluble metal sulphates. This process is well known because these bacteria generate acid mine water. Over the last five( 5) years, we have been carrying out development work on creating optimum bioleach conditions for the extraction of metals from sulphide rich ores and concentrates. Recently, a study was carried out on a byproduct sulphide concentrate produced in a tin flowsheet developed for the Mt. Pleasant Mine of ADEX Mining Corp. The objective was to determine whether a bioleach process might successfully leach this sulphide material which contains copper, zinc, iron and, what is more important, trace metals such as Indium, Gallium, and Bismuth. The current work describes the successful recovery of these metals achieving extractions of more than 80% by applying bioleaching techniques. An overview of this technical program forms the basis of this paper.IntroductionBio-Oxidation of metal sulphides has emerged to be one of the leading edge hydrometallurgical processes for the economic extraction of metals from ore and concentrates. The fundamental process involves the bacterial assisted oxidation of sulphide to sulphate yielding metal sulphates which can be subsequently leached by conventional means. The bacteria that play the predominate role is an obligate chemolithoautotroph named thiobacillus ferrooxidans (TF). These bacteria thrive in areas rich in sulphide and occur naturally worldwide. In fact, TF is responsible for generating acid in water (acid mine water) from exposed sulphide surfaces primarily through the oxidation of pyrite. TF bacteria thrive under the proper conditions of temperature and oxygen supply in the presence of sulphides and populations in excess of a million per millilitre (ml) of solution are achievable. Typically, at room temperature, the bacteria will bio-oxidize in a pH range of 1.0 to 3.0. Today, bio-oxidation has been applied commercially with great success for the extraction of uranium, copper, and gold."

Jan 1, 1996

By Joël P. T. Kapusta, Liam J. Watt

The last extended copper smelting and converting survey dates back to the 2003 International Copper Conference held in Santiago, Chile. The following year, the Minerals, Metals, and Materials Society of AIME (TMS) started a new series in its Journal of Metals (JOM) called JOM World Nonferrous Smelters Survey devoting its first Part to Copper. The copper smelting landscape has significantly changed in the past 15 years, both in geographical terms with the shift of copper smelting production from the Americas to China and in technological terms with the growing adoption rate of Top-Submerged Lancing (TSL) technologies and the development and implementation of Bottom-Blowing technologies. A copper smelting survey update, even if not as in-depth as the 2003 Copper Smelting Survey, is therefore in order. The authors will review the latest trends in copper smelting technologies and production worldwide in comparison to the landscape of the early 2000s. INTRODUCTION This 2019 copper smelting survey is different from previous surveys as our data does not originate exclusively from responses to a questionnaire sent to all the copper smelters. Our data comes from several sources. We are therefore very thankful to the International Copper Study Group (ICSG) and Wood Mackenzie for sharing some of their information and to ENFI, Outotec, and Glencore Technologies for helping us cross-check our numbers for the Chinese smelters, flash smelting, Ausmelt, and Isasmelt technologies. Our survey presents data reporting from a total of 96 operating copper smelters from around the globe, which is significantly higher than the 50 surveyed in 2003. Although secondary smelting numbers have steadily increased over time, this paper focuses on primary smelting operations with copper concentrate as feed material. The list in this survey is still far from complete, with missing information from several known smelting operations. The total primary copper production tonnage of the smelters we surveyed amounts to 18.3 million metric tonnes from 29 countries representing 92% and 94% of total world primary production for 2018 estimated by ICSG and Wood Mackenzie, respectively. This representation has increased from 2003 when the total was 9.71 million metric tonnes from 23 countries accounting for 73% of world production. The trends presented and analyzed within this paper have stronger significance because of the increase in production accounted for. The Chinese and Russian smelter information collected is more detailed than years past. Our complete dataset is summarized in Table 1 at the end of our paper.

Jan 1, 2019

By Scott D. Long

"Abstract-Grass roots exploration has an emphasis on good precision at low (sub-economic) concentrations of an element, in order to identify "anomalies" which may lead to drilling targets. Although it is wise to have well-defined quality controls in place during early stage sampling, the control procedures at this stage tend to be rudimentary. When a deposit warrants detailed delineation, the need for accurate geological characterization and assaying of ore-grade rock must be supported by appropriate quality control procedures.As a project returns more promising results, and the likelihood of the project warranting a prefeasibility study increases, it is time to tighten quality assurance requirements and quality control protocols. Delays in instituting adequate quality control and verification procedures may lead to costly remedial actions that can also delay completion of the prefeasibility or feasibility study. Sometimes, as a project matures, the quality control and quality assurance aspects fail to keep pace with the changing nature of the work: an increasing emphasis on precise and accurate assaying of oregrade rock.A resource model is like a house of cards. The foundation of the house is the geological observations, the sampling methods and the geological interpretations performed upon those samples. Upon the sampling, which includes all the sub-sampling steps of sample preparation, rest the assay results. The quality of the assays can be no better than the quality of the sampling. Good assaying technique will preserve all biases and imprecisions introduced during sampling and sample preparation; it cannot remove them. If the sub-samples and/or assays are bad and must be redone, all the succeeding levels of the house of cards must also be rebuilt, or at least patched up.From geological observations, a geological interpretation is built, the quality of which is critical to the construction of an acceptable resource model. Geological elements are difficult to assess, and are not discussed here; they are dependent upon the expertise of the geologists involved. Geological knowledge contributes essential quality control elements to resource/reserve determinations (Sinclair and Postolski, 1999; Postolski and Sinclair, 1999).This paper consists of five sections: (1) overview of quality control protocols, (2) maintaining quality control of databases, (3) quality control of drill sampling, (4) optimizing crushing and grinding requirements, and (5) quality control of assay data acquisition."

Jan 1, 1998

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016

By S. B. Mishra

Ni-20Cr metallic coating was deposited on a Ni-based Superalloy (3Fe-19.5Cr¬0.3Ti-Balance Ni) by a shrouded plasma spray process; NiCrA1Y was used as a bond coat. Erosion studies were conducted on uncoated and plasma-spray coated superalloy specimens using an air-jet erosion test rig at a velocity of 40 m/s and impingement angles of 30° and 90°. The coating has been characterized for porosity, microhardness and microstructure and X-Ray Diffraction (XRD). An electron probe micro analyzer (EPMA) was used to obtain X-ray elemental mappings of the coating along the cross-section. Scanning electron microscope (SEM) with EDAX attachment was used to analyze the eroded surfaces.

Jan 1, 2005