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By Bill Dupley

We believe that the inability of employees to effectively manage information has reached an epidemic problem throughout the corporate world. ? All the available knowledge in the world is accelerating at a phenomenal rate. ? The whole world's codified knowledge base (all historical information in library books and electronic files) doubled every 30 years in the early 20th century. ? By the 1970s, the world's knowledge base doubled every seven years. ? Information researchers predict that by the year 2010, all the world's codified knowledge will double every 11 hours.

May 1, 2003

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By Xiaolin Cheng, A. J. Sinclair

"Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeo chemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:<equation>where all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemico-mineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By Xiaolin Cheng, A. J. Sinclair

"Abstract - Norm calculation procedures originally designed principally for igneous rocks are very rigid in their application and, in general, do not utilize important alteration minerals. For instance, volatile components are essential constituents of many metasomatic rocks but either are not used or are not used effectively in determining normative minerals by the CIPW norm or Niggli-Barth norm procedures. Our approach to determining norms for metasomatic rocks allots all major, minor and volatile constituents to a set of standard normative minerals which are commonly observed as products of hydrothermal alteration. A useful procedure is to have a metasomatic norm approximate the mode as closely as possible. Petrographic information helps to provide the necessary mineralogical constraints. With the recognition of an immobile component and knowledge of sampling and analytical errors in lithogeochemical data, it is possible to recast norms into amounts of alteration minerals relative to a given amount (100 grams) of parent rock. Combining these results with the calculations of absolute loss or gain of individual chemical constituents and considering errors (e) for an appropriate confidence level, an overall (net) material exchange equation can be presented as follows:SMineralparent rock ± e + SConstituentgained from solution ± e= SMineralaltered rock ± e + SConstituentlost from wall-rock ± ewhere all items have extensive units (e.g., grams). The model includes the initial and final mineralogy of rocks (evident in the field) as well as gains and losses of specific elements. Only those constituents whose calculated losses and gains are significantly different from zero are retained in the above model, and only the normative minerals with abundances significantly different from zero are included in the model (equation). One advantage of the chemicomineralogic model is that parent rock and product are modeled in mineralogical terms that are familiar to and easily usable by exploration geologists."

Jan 1, 1995

By Bonnie Cooper

3D printing by fused deposition can be used on lunar soil. The soil can be precisely size-separated to make the 3D printing process work efficiently. Using a MASER instead of a LASER would allow us to use the finest fraction of lunar soil, AS-IS, to manufacture things on the Moon.

May 1, 2013

By Mario Bureau

Need for a lab assembly reaching better and consistent static anchorage capacities

May 1, 2013

By A Smirnov

The problem of thin and very thin coal seam extraction is examined in a long perspective of Ukraine?s fuel and energy industry development. The technical and economic benefits of the coal seam selective mining technique are described, including beneficial environmental impact.

Aug 1, 2013

By Ali Bunjaku, Lauri Pesonen, Hannu Johto

It is well known that there are many ways to process copper concentrates into copper anodes using the pyrometallurgical route. All modern copper smelting technologies are fundamentally energy efficient and environmentally safe options, and therefore choosing one depends on the desired capacity range, feed impurity levels, plant location, flexibility needs, overall energy use, and of course smelter economics in both the short and long term. This paper focuses on comparing different solutions which have potentially the lowest variable opex (operational expense), meaning in practice finding out which technology offers the best chances for profit maximization under certain scenarios. For the comparison, we chose to have a closer look at Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC), Outotec Flash Smelting (FSF) – Outotec- Kennecott Flash Converting (FCF), Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC), Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF), Mitsubishi Smelting Process (MIT), Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC), and Side Blowing Furnace (SBF) - Top Blowing Converting (TBC) since these seem to be the main state-of-art technologies now being applied in many recent copper smelter projects around the world. The work was carried out by modelling each smelting route by using the new HSC SIM 9 simulation software and applying operation time, energy, and consumables consumption numbers for each unit process and stream. Combined with cost data, the exercise produced a rich set of information which will be shown in detail for each area per scenario. The authors’ goal here was to provide a fair comparison where each technology can be evaluated from various perspectives such as electricity use or refractory consumption. INTRODUCTION Copper can be produced either pyrometallurgically or hydrometallurgically. The hydrometallurgical route is used only for a limited amount of the world’s copper production (~20%) and is normally only considered in connection with in-situ leaching of copper ores. On the other hand, most of the copper extraction from Cu-Fe-S minerals is pyrometallurgical (~80%) (Schlesinger 2011, ICSG 2017). Thus, several different processes can be applied for copper production, including the following state-of-the-art technologies: Outotec Flash Smelting (FSF) – Outotec-Kennecott Flash Converting (FCF) Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF) Mitsubishi Smelting Process (MIT) Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC) Side Blowing Furnace (SBF) - Top Blowing Converting (TBC)

Jan 1, 2019

By I. Ueda, S. Ishikawa, T. Nagata

“O-SR process” in which the S-Furnace of the Mitsubishi process is followed by existing reverberatory furnaces (RFs) and Peirce Smith (PS) converters has been operated since December 2007. The S-Furnace smelts copper concentrates to produce molten matte containing 58-62%Cu which is then settled in the RFs and converted to blister copper in the PS converters. The SO2 gas generated from the S-Furnace and PS converters is converted to sulfuric acid in the acid plants. In addition to the smelting copper concentrates, the O-SR process has advantages in terms of recycling various waste/secondary materials. Automotive Shredder Residue (ASR) has been treated in the RF to reduce fossil-fuel consumption in RFs, and to recover various metals included in ASR as well, since 1993. Electronic circuit boards (E-scrap) has also been processed in order to recover not only copper but also rare resources such as gold, silver and PGMs since 2013. Strategic modifications have enabled expansion of the processing volume of E-scrap. Enhancing recycling of wastes and scraps from urban mines while reducing the consumption of natural resources in the “O-SR” process will be demonstrated and discussed in the present paper. INTRODUCTION Onahama smelter and refinery has been operating as a custom smelter since 1965. Smelting facilities were subsequently expanded to two green-charged RF furnaces and five PS converters in 1973. Since RF is a conventional old-fashioned smelting furnace that necessarily consumes a huge amount of fuel to smelt copper concentrates, saving fuel cost has been an important objective. In early 1980’s the fuel was changed from bunker oil to pulverized coal, while utilizing the combustion heat of waste tires. Furthermore, treatment of combustible waste such as shredder residue (SR) was initiated in order to save fossil fuel for smelting concentrates in the RFs. Since enhancing of the treatment of SR requires a reduction in concentrate smelted in the RFs, most concentrates were dried and injected through tuyeres into the PS.converters. These modifications enabled to reduce the amount of the pulverized coal combustion and to increase SR treatment in the RFs. SR treatment capacity has increased to 12,000mt/month because the SR market has grown after the enforcement of the Vehicles Recycling Law. Such business environment has been attributed to establish the thermal-materials recycling system of SR in which the RFs have changed their role from copper concentrates smelting furnaces to waste materials combustion furnaces.

Jan 1, 2019

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By Todd Smith

AGENDA Newalta overview Dewatering underground slimes: current technique & challenges Why centrifugation? Process improvements & advantages How centrifuge technology works Implementation: first step Summary of benefits

May 1, 2013

By D. W. Smith, J. J. Koskinen, T. A. Enwald, M. E. Ball

"A full-scale demonstration unit of Tampella&apos;s LIFAC desulphurization process was tested at SaskPower&apos;s Poplar River Power Station Unit No. I. The test program included a series of parametric tests, followed by a 1500 hour operational evaluation. This paper summarizes the results of the test program, and SaskPower&apos;s economic evaluation which led to selection of the LlFAC process for SaskPower&apos;s 300 MW Shand power station. IntroductionOne of the major influences on the coal mining industry today is public and legislative response to acid rain. When sulphur-bearing fuels such as coal are burned, the sulphur oxidizes to sulphur dioxid e (S00 which, if uncontrolled, enters the atmosphere as one of the by-products of combustion. S02 then combines with water in the air to form an acid and acid rain results. Combustion also produces nitrogen oxides (N0J which can combine with water in the air forming nitrogen based acid , also contributing to acid rain.Acid rain has become a significant international concern. Newspapers have reported on dying forests, dead lakes and crumbling statues. Papers also include articles professing that the physical results of acid rain are vastly overstated. In the United States, a IO-year, Y2-billion dollar study called the National Acid Precipitation Assessment Program (NAPAP) was commissioned to evaluate the effects of acid rain. Even this extensive scientific study did not resolve the controversy. Despite disagreement over the quantitative effects of acid rain, there is no doubt that public concern over the issue is widespread and deeply felt.In response to this concern, legislators throughout the world have reacted with programs that restrict the emission s o f SO, and NO,. To industries involved in the supply and use of coal, the impact of these legislative programs has been extensive. United States power plants will be spending 10 billion dollars in the next decade for flue gas clean-up equipment. Even all this new equipment will not stem the tide of change to low sulphur coals and to “clean “natural gas. The following summarizes legislative actions taken for Canada and the United States."

Jan 1, 1993

By N. Bartie

Realising the circular economy (CE) is faced with some significant challenges. Process metallurgy and its infrastructure play key roles at the heart of making the CE work. Therefore, the enabling role of process metallurgy within the CE will be central to the discussion in this paper, touching among others on product and system design as well as the key metallurgical and other process fundamentals that need to be investigated and understood to make the CE a reality. The central role of materials and its processing will be discussed in an integrated circular cities perspective. A key focus will be a discussion on designing a resilient “Smart Materials Grid” using and innovating metallurgical process engineering tools, which will manage the flows through Sustainable Circular Cities. The discussion will be using copper as leitmotiv of the discussion i.e. from copper ore, to metal, to complex products, recycling, product design and simulation and its impact. INTRODUCTION The transformation of our economies from linear to circular models in which waste materials become resources is the focus of the Circular Economy (CE) paradigm. Its important intentions: to take control of the damage we have been doing to the planet to ensure its livability and the welfare of future generations. This can only be achieved through careful utilisation of human, natural and economic resources. The concept is derived from several others (Beaulieu et al., 2015), of which Cradle-to-Cradle, Extended Producer Responsibility (EPR), Industrial Ecology, and Life Cycle Thinking are just a few. Other relevant concepts include resource efficiency (RE), design-for-recycling (DfR), and various others discussed by Blomsma and Brennan (2017) and Homrich et al. (2018), as well as various R-hierarchies e.g. Reduce, Reuse, Recycle (3R). However, does society comprehend these concepts, the actors and actions that influence them and how they interact? Do we know the limits of CE? Does society understand the key role of Copper and other metals to rendering the CE operable? True life cycle and systems thinking, focussed on simulation-based, process and metallurgical design are required to answer these questions. Lieder and Rashid (2016) identify nine widely-varying fields that study the concept ranging from sustainability sciences and engineering to economics, business, law, and social sciences. Overlap between questions addressed highlights the need for interdisciplinary collaboration (Nanz et al., 2017) in the assessment of the current status, and further steps needed to transform to CE. This doesn’t apply just in academia, but also in industry where concrete implementation of CE needs to occur at multiple levels, thus necessitating cooperation between government, civil society and other stakeholders (Beaulieu et al., 2015).

Jan 1, 2019

By Greg Gosson

"Early efforts to develop formal reporting systems to quantify and classify mineral deposits date back over 100 years. (e.g. Hoover 1909: “Proved, Probable, Prospective Ore”). This was at first driven by mine operators’ need for reliable estimates of what their mines could produce. Disruption of transportation routes by world wars prompted western governments to recognize the need for assessments of strategic sources of metals and minerals that could support domestic industry during times of crisis. Categories were created to quantify mineral potential which were additional to those of mine reserves. Terms such as hypothetical and undiscovered resources entered the lexicon. Capital markets serving the mining industry were traumatized during the latter part of the 20th century by undisciplined and fraudulent disclosure by exploration companies of mineral deposit potential. Government securities regulators pressed for the development of credible reporting codes (e.g. SEC Industry Guide 7: 1981; JORC 1989; SAMREC 1994, CIM 2000). Representative organizations from the major western mining countries generally agreed that there should only be three categories of mineral resources (measured, indicated, and inferred) and two categories of mineral reserves (proven and probable). This was formalized in 1997 with the “Denver Accord”. Acceptance of the standard terminology may have been the easy part, because the challenge for the 21st century is to get general industry acceptance and agreement of the principles behind the definitions of each category. There has been noticeable movement towards this objective in the last few years. This is reflected in part in the updated reporting codes by JORC 2004, CIM 2005; SAMREC 2007; SME 2007; and PERC 2008, and the development of the CRIRSCO International Reporting Template 2007."

Jan 1, 2003

By T. D. Brown

"A review of the current status of gasification technology shows that many engineering systems are immediately available for use in the gasification of coal. Widespread international experience can be brought to bear on the atmospheric pressure gasification of all Canadian coals.Unless a high ash content dictates the use of a fluid-bed gasifier, it appears that bituminous coals can be used in gravitating (fixed] bed systems and that the strongly caking coals are most suited to the high-pressure entrained-bed systems . Existing and developing technologies in fluid-bed gasification are attractive for reactive lignites and subbituminous coals.The Fischer-Tropsch based process is the only commercial embodiment of coal liquefaction; the use of Canadian coals in this process depends only on their gasification characteristics. Current developments in hydroliquefaction are directed toward carboniferous coals of medium or high rank. It is not clear that cretaceous coals of the same rank will give similar process yields and economics.IntroductionThe twin coal conversion processes of gasification and liquefaction have a history which dates back beyond the current energy shortages of the western world. Indeed, liquids and gas from coal were produced before this century.Coal gas produced from a coal carbonization process was originated before 1800, and the development of gasification of non-coking coals was patented by Siemens in 1860.This patent represented the first use of air and steam together in the gasmaking process. The pioneering development of coal gasification Using oxygen and steam was demonstrated by Lurgi in the late 1920s. This historical sequence was all carried out at atmospheric pressure, and it was not until the immediate pre-war (1939/45) years that operation of the coal gasification process at elevated pressure became a reality."

Jan 1, 1981

By Somchet Vongpaisal

This paper presents the R&D results on the development of a new knowledge-based system for predicting stope instability and associated unplanned dilution in deep underground mining operations. A new prototype was developed based on databases generated from 3D non-linear elasto-plastic finite element stress analysis, heuristic rules, and case histories. This prototype aims to assist mine operators to make decisions on strategic mine planning and feasibility in a quick and efficient manner thereby minimizing risk on ground failure and optimizing mining costs.

Jun 1, 2012

By Jian Deng, Haitian Sun, Zengqian Hou, Shuhe Song

"Abstract - Volcanogenic massive sulfide (VMS) deposits, an important base-metal deposit type in China, occur widely in submarine volcanic districts of variable magmatic affinities. These VMS deposits range in age from Archean to Mesozoic, but most are in Proterozoic and Paleozoic sequences. More than 60% of VMS deposits formed in the Paleozoic, the most important metallogenic eon. Three important Paleozoic VMS-metallogenic provinces include Northern Qilian, Sanjiang and Altai provinces. The Proterozoic constitutes the next important era, but with no VMS deposits in the middle Proterozoic. VMS deposits associated with the Proterozoic volcanic rocks occur around the Yangtze Platform and in the western Kunlun-Qinling. The Triassic is third in importance, with VMS deposits concentrated in the Sanjiang Tethys. The Archean has only one VMS deposit, on the northern margin of the Sino-Korea Platform.Five distinct compositional classes of Chinese VMS deposits have been distinguished: Cu, Cu- Zn (or Zn-Cu), Cu-Fe, Zn-Pb-Cu, and Pb-Zn (-Cu). The Cu, Cu-Co, and Cu-Zn types of deposits occur sporadically from the Archean to Paleozoic, and are closely associated with mafic and ultramafic volcanic sequences. The Zn-Pb-Cu and some Cu-Zn type deposits are restricted to the Paleozoic and Triassic, and are hosted by calc-alkaline felsic rocks in bimodal basalt-rhyolite sequences, whereas Cu-Fe and Pb-Zn type (except for the Laochang deposit) deposits are restricted to the Proterozoic and occur in calc-alkaline volcanic sequences. As large quantities of marine mafic volcanic rocks were deposited in western China, Cu and Cu-Zn deposits are major types of Chinese VMS deposits.Chinese VMS deposits formed in a wide range of paleo-tectonic settings and depositional environments, such as island-arcs, rifts, aulacogens, and ocean ridge hot spots. Among these, the rift and back-arc environments are the most important, containing about 60% of Chinese VMS deposits. Aulacogens are a subordinate environment where most of the Proterozoic VMS deposits formed. The oceanic ridge and hot-spot systems are common in the tectono-magmatic domains in China, but contain only a few small Cu and Cu-Zn type VMS deposits.The Chinese VMS deposits have usually been influenced by both deformation and metamorphism to various degrees, resulting in changes in the shape and metal distribution. Seven representative deposit styles have been recognized: sheets, sheet plus strata-bound stringer, cyclically zoned deposits, mounds, mound-like deposits, strata-bound stringer-disseminated, and stockwork-disseminated deposits. The formation of these various styles of deposits is controlled by several key factors, such as lithology and permeability of the host rocks, focused or unfocused discharge, temperature and chemical composition (e.g., salinity) of hydrothermal fluids, as well as depth of seawater."

Jan 1, 1999

By P. Cielo

"Nondestructive inspection is an important quality control tool in the material processing industry. Being nondestructive, such a control may be applied to the whole production, as long as the available techniques are fast and easily automated. Ideally, nondestructive testing (NDT) methods should operate in a noncontact configuration in order to be deployable on-line with minimum perturbation of the production process.After a short introduction to the most common NDT techniques, with particular emphasis on ultrasonic, radiographic and electromagnetic methods, a few new approaches which are under development at the Industrial Materials Research Institute, (Boucherville, Quebec), are reviewed. Noncontact techniques such as laser ultrasound, thermoelastic and thermographic methodologies will be described, and their applications to materials of industrial interest will be discussed."

Jan 1, 1989

By K. V. Gow, F. A. Jerabek

"THE NOVA SCOTIA TECHNICAL COLLEGE has been granting degrees in mining engineering since 1909. The college was established in 1907 to provide the final two years of the undergraduate program in engineering the earlier years of which are given at several small universities scattered around the Atlantic Provinces. Since the beginning of the program, 251 Bachelor of Engineering degrees have been awarded in mining engineering. Although the average class size has been small, increases in enrolment in the past few years have resulted in Nova Scotia Technical College being the second largest mining department in Canada, based on the number of graduates per year. This year 18 students received B.Eng. degrees, and next year 17 will graduate.In 1968, it was necessary to make a decision on whether or not to abandon, for economic reasons, the program in mining engineering. For several years enrolment had been very low and resignations among the mining engineering staff created a situation in which the program could easily have been dropped. However, it was decided to continue mining engineering, as it was the only such program in the Atlantic Provinces. New staff members with many years of practical experience in the mineral industry, not only in Canada but in the U.S.A., South America, Africa and the U.K., joined our department. At the same time the enrolment in mining engineering began to increase significantly."

Jan 1, 1972

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Ferrihydrite is ubiquitous in soils, groundwater and aquatic sediments and is usually classified as "2-line" or "6-line" according to the number of diffuse XRD peaks. It has high surface area and reactivity; therefore, it may serve as a sink for sequestering trace metals, metalloids and organic matters via adsorption and co-precipitation. Although considerable attention was paid to the transformation process of this thermodynamically metastable solid, there are still some controversies on the mechanisms of the formation of goethite or hematite from the ferrihydrite precursor. This work systematically investigated the transformation of 2-line ferrihydrite produced by using different neutralization regent (CaO vs. NaOH) into crystalline products at different pHs (4, 7 and 8), three temperatures (25, 40, 75 °C) and in different media (sulfate vs. nitrate). X-ray diffraction (XRD), Raman, Fourier transform infrared spectroscopy (FTIR) and chemical extraction were employed to characterize the transformed solids as well as the redistribution of Fe between the amorphous and more crystalline phases. The results showed that the transformation product in nitrate media was hematite (major) and goethite (minor), which was independent of pH, temperature or neutralization reagent. In sulfate media, goethite was the dominant solid under slightly acidic conditions (pH 4) with 6-line ferrihydrite as the intermediate product, whereas neutral to slightly alkaline conditions still favor the formation of hematite. Chemical extraction results indicated that there was only ~3 % of amorphous phase detectable after aging at 25 °C for 280 days at slight acidic pH. In contrast,~70 % of the iron remained as an amorphous phase under neutral to slightly alkaline conditions. The results suggested that the pH as well as the reaction media (sulfate ion) plays an important role in the 2-line ferrihydrite transformation process.

Jan 1, 2016