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By D. V. Venugopal, W. W. Gardiner

Spessartine-quartz rocks are manganiferous sedimentary rocks rich in spessartine and quartz which occur in north-central New Brunswick. They represent a recrystallised manganiferous siltstone/chert that is contained in or associated with red manganiferous siltstone (RMS) units. The spessartine-quartz rocks and RMS form part of an Ordovician volcanic and sedimentary succession within the Appalachian-Caledonian orogen which hosts numerous massive sulphides and polymetallic vein deposits. The New Brunswick spessartine-quartz rocks are spatially and temporally associated with stratiform base-metal, precious metal and hydrothermal tin-tungsten deposits. This suggests that spessartine-bearing lithologies and zones can be useful in predictive metallogeny and for the understanding of the stratigraphy and palaeographic setting of the early Palaeozoic rocks of the Appalachian-Caledonian orogen.

Jan 12, 1992

By I S. Lowndes, K. Moloney

Diesel powered equipment is currently used extensively in mining and tunnelling operations around the world due to its mobility, flexibility and through selective application to enhance productivity. However, the increased use of diesel equipment has exacerbated the pollutant load (including heat, humidity, exhaust gases and particulates) placed upon the environmental systems of many underground operations. This expansion in the use of diesel equipment has prom pted researchers to evaluate m easure ment and control technology. This paper reviews the recent research conducted in various countries.

Jan 10, 1996

By L. G. Billington

"The Agnew nickel deposit occurs in a major linear greenstone belt in the Archaean Eastern Goldfields Province of Western Australia, and has been subjected to mid-amphibolite facies nietamorphism of dynamic style. The largest dunitic ultramafic body in the Perseverance Block is host to the bulk of the nickel mineralization. The Perseverance Ultramafic is mineralogically zoned and has an embayed western margin against a mixed metasedimentarv-metavolcanic wallrock sequence.Three categories of nickel sulphide mineralization are concentrated on this western margin at the thickest part of the ultramafic exposure. Massive sulphides characteristically occur as contact mineralization, internal mineralization and as remobilized concentrations in vein form structures. Disseminated ore constitutes the largest volume of mineralized materials in the deposit and occurs in three separate shoots in en-echelon relation. Weakly mineralized 'cloud sulphide' zones surround and envelop the shoots and persist much further along strike. In the upper mine levels the shoots are truncated by a shear or crush zone, which inhibits geological knowledge to the south but marks a major fundamental structural break.Most of the ore types have suffered supergene alteration and there is a complex variable distribution of the mineralogical facies. The ore types have been metamorphically retextured, but the oreshoots can be characterized by their Ni tenor and some chemical ratios. S/Se values, PGF. and precious metal values are distinctly different from those of other nickel sulphide ores extracted.Despite intense structural and metamorphic modification of the mineralizations, some features support an original magmatic derivation for the sulphides. These include the localization of massive sulphide ore types on one marginal contact within an emhayment structure, the general distribution of disseminated mineralizations located immediately above the massive sulphides and the Ni/Cu, Ni/Co, Fe/Ni ratios of the oreshoots being similar to those of deposits that typify the intrusive dunite- associated class of nickel sulphide deposit. Varying S/Ni ratios between different shoots suggest a revision of the single magmatic intrusion model in favour of a changing composition between successive magmatic episodes."

Jan 1, 1984

By J. Ostwald, L. T. Matthews, C. E. Loo

Australia has large reserves of pisolitic limonite. Mining recently commenced on the Yandicoogina deposit to produce a high-grade sintering ore. The ore contains about 10 wt% combined water and simulated sintering temperature profiles indicate that progressive dehydration of ore particles occurs in the temperature range 300-700 degrees C. Studies by optical microscopy show that although the dehyrdrated ore particles contain numerous cracks, there is no change in the microstructure of the ore because topotactic transformation to haematite results in the formation of compact masses of very fine-grained haematite microcrysts. When the ore is held at around 1 200 degrees C for 1 min significant recrystallisation of these microcrysts occurs, resulting in the formation of optically visible, micrometre sized haematite crystallites. Studies to simulate the behaviour of ore particles during sintering (as nuclear particles surrounded by a standard adhering fines mixture) show that the recrystallisation process occurs much earlier at temperatures of about 900 degrees C. Further studies indicate that CaO in the adhering fines mixture enhances the recrystallisation of the ore nuclei. The results of the investigation indicate that the pseudo-relict haematite in sinters produced from ore blends that contain significant levels of pisolitic limonite consists of dehydrated goethite that has undergone significant recrystallisation and grain growth, a phenomenon that is facilitated by the presence of lime derived from the sintering melt.

Jan 12, 1992

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By S K. Das

An intensive investigation into modern roof support technology, including hy draulic and control systems, has been carried out against the perspective of global development and support behaviour on longwall faces across the Indian sub-continent. The wide ranging study examined various types and designs of modern supports used in seams of varying thickness and inclination where caving and stowing were practised. Consideration has been given to structural analysis, support resistance, the various forces acting over and on the powered supports and to support compatibility. The examination of the phy sical parameters has been allied to field experience and, together, have led to the formulation of standard designs for both the powered support structure and structural systems. A realistic mathematical model has been formulated for calculating the capacity of roof support requirements resulting from the actual behaviour of the immediate roof stratum. As a result of the work, it should be possible to readily select the most appropriate type of support sy stem for the conditions and longwall mining method that is to be employed.

Jan 4, 1997

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992

By M. Dobias, N. Mayor, J. Lillo, A. Gonzalez, R. Lunar, R. Oyarzun

The central domain of the Spanish Central System contains a series of Ba-(F)-(base metal sulphide) hydrothermal vein deposits that are hosted by adamellitic granitoids. Fluid inclusion and sulphur isotope data suggest that the mineralisation was formed by low-salinity hydrothermal solutions that incorporated fluids, metals and sulphur from a magmatic source. Mineralisation occurred in two main stages; a first stage of open-space filling with quartz-Ba-(F)-(base metals) ; and a second stage of brecciation and deposition of quartz-barite. The two mineralising events can be clearly related to two tectonic episodes of late Variscan age that involved extension along east-west trends followed by ductile transcurrent movements along northeast-southwest trends.

Jan 4, 1992

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By B. W. Hester

Report of discussion at January, 1971, general meeting (Chairman: M. J. Cahalan, President) of the paper published in Transactions/Section B (Applied Earth Science), vol. 79, May, 1970, pp. B60-B67, and contributed remarks. Comments were made by Taylor J.T.M., James C.H., Lethbridge R.F. and Heath K.C.G.

Dec 1, 1971

By C. M. Lesher, R. R. Keays

"The komatnte-associated Fe-Ni-Cu sulphide mineralization at Kanihalda, Western Australia, is generally believed to be magmatic in origin, but a number of postmagmatic processes significantly modified the original distribution, structure, texture, mineralogy and chemistry of the ores. Two important types of mobilized magmatic sulphides are interpillow/interbreccia sulphides and hydrothermal vein-type sulphides. Interpillow and interbreccia sulphides occur interstitial to pillowed or volcaniclastic footwall metabasalts beneath or adjacent to the stratiform contact ore horizons. They are mineralogically and compositionally similar to massive ores (and are similarly depleted in PGE relative to the compositions of bulk samples of mined ores), but normally do not contain the distinctive chalco-phile ferrochromites characteristic of contact ores. They are interpreted as magmatic sulphides that have been mobilized from the overlying or adjacent massive sulphide layer during peak tectono-nietamorphism.Hydrothermal sulphide-quartz + albite veins also occur in the footwall metabasalt and contain unannealed deformation fabrics indicative of emplacement during retrograde metamorphism. The high Ni and Pd contents of these sulphides (7-13% Ni, up to 70 ppm Pd) indicate that the metals have been derived from the spatially associated komatiites and/or contact ores, consistent with the Pd depletion previously inferred for massive ores. Very low Ir contents and high Pd/Ir ratios of the vein-type sulphides confirm an aqueous transportation-deposition mechanism; hydrothermal transfer of PGE results in strong decoupling of Pd from Ir.There appears to be a complete continuum of sulphide mobilization at Kambalda ranging from whole-scale phy sical dislocation (fault offset ores) and selective mobilization (stringer sulphides) through nietamorphie replacement (interpillow/interbrec- cia sulphides) to jiydrothermal dissolution and redeposition (vein-type sulphides)."

Jan 1, 1984

By A. Paulin, A. W. D. Hills

The work has shown that packed-bed behaviour can be predicted from the results of single-particle experiments, total reaction times being predicted somewhat more accurately than gas and solid temperatures and gas compositions. A small laboratory packed-bed reactor was built and used to study the decomposition of beds of specially prepared CaCO3 spheres, steps being taken to minimise the effects exerted by the walls of the bed on processes occurring within the bed. Gas and solid temperatures and gas compositions were measured at various points in the bed and compared with theoretical predictions based on kinetic data determined in previous single-particle experiments. The measured solid temperatures and total reaction times agreed remarkably well with the values predicted theoretically. Gas and solid temperatures measured after the reaction had finished at any point in the bed did not agree with the theory. This was because solid temperatures in the bed rose very rapidly once the reaction was completed and the walls of the bed could not be heated at a sufficient rate for their temperatures to rise as rapidly; thus some loss of heat from the bed to the walls was inevitable, and this could not be accounted for in the theory. In addition, the theory did not allow for the conduction of heat within the bed, and this resulted in some further slight discrepancy between the measured and predicted values, particularly after the reaction was completed. Gas compositions measured in the bed were rather scattered, but, even so, they agreed moderately well with the predictions of the theory.

Dec 1, 1971

By W. S. Fyfe, G. V. Albino, Ekawat Sitthithaworn

The mineralisation is associated with a composite diorite to quartz monzonite stock of Permian to Triassic age that intrudes Devonian carbonate strata. In the intrusive rocks it is associated with potassic alteration and in the carbonate wall rocks it is hosted by prograde garnet-rich and retrograde epidote-rich skarn. Both porphyry and skarn mineralisation include disseminated and fracture-controlled mineralisation, the latter probably accounting for the major part of the contained minerals. Copper, gold, silver and zinc are strongly positively correlated within the mineralised zones, although there are small differences in metal ratios between the different ore types; molybdenum appears to be negatively correlated with copper and gold. Ore minerals include chalcopyrite, magnetite and pyrite in porphyry-type mineralisation and bornite, chalcopyrite, pyrite, magnetite and lesser haematite in skarn.

Jan 12, 1993

The first part describes a model (the C model) based on the motion of the grinding charge. The charge is treated as a continuum, which allows analytical solutions to the equations that are developed. The C model is equally applicable to ball-, semi-autogenous and autogenous mills and contains a description of the power draw of both the cylindrical section and the cone-ends. Differences between the power draw of grate- and overflow-discharge mills are described from consideration of the different shapes and compositions of their charges. A large database of industrial mill data is used to demonstrate the accuracy of the model. Part 2 describes a simpler, empirical model (the E model) whose performance is based on that of the C model. The same database was used to assess the predictive capabilities of the E model. The model was shown to be only slightly less accurate than the C model despite its much simpler structure

Jun 18, 1905

By E. H. W. Hornbrook, P. W. B. Friske

Paper presented at the 28th International Geological Congress, Washington DC, July 1989 (International geochemical mapping sessions). The objective of the programme is to establish and maintain a nationally consistent geochemical drainage database. Towards this end systematic surveys have been conducted since 1973. To date more than 200 surveys have been completed to the required standards, representing 180 000 sites and covering about 2 100 000 km2 throughout Canada

Jun 13, 1905

"The sulphide nickel resources of Australia are concentrated in the Western Australian Shield. This shield is considered to have developed by extensive, but incomplete, Proterozoic reworking of once-continuous Archaean crust. It now constitutes relic Archaean cratons and intervening orogenic mobile belts transected by narrow, curvilinear tectono-thermal mobile belts of younger Proterozoic age. Remnants of the Archaean cratons are exposed in the Yilgarn and Pilbara Blocks. In the former an ancient (to ca 3600 m.y.) high-grade gneiss terrain (Western Gneiss Terrain) occurs along the western margin of the block and is interpreted to flank younger (ca3000-2800 m.y.) greenstone belts to the east. Ancient (to ca3500 m.y.) granitoid-greenstone terrains dominate the Pilbara Block.Proterozoic mobile belts contain only traces of nickel mineralization, except for one locality in the Halls Creek Province. The Archaean high-grade gneiss terrains contain no important mineralization, and the Pilbara granitoid-greenstone terrains contain only scattered examples of less important types of mineralization.The important deposits (e.g. Kambalda, Windarra, Agnew, Mt Keith) are all of komatiitic affinity and are best developed in the youngest greenstone belts of the eastern part of the Yilgarn Block. In particular, they are concentrated within, and adjacent to, the Norseman-Wiluna Belt, which contrasts in age, lithofacies and structural style with all other greenstone belts in the shield. It is interpreted to have been a rift zone. Within this belt the two main deposit types—the volcanic peridotite-associated and intrusive dunite-associated deposits—are concentrated into spatially separate zones. Precise controls on this heterogeneous distribution cannot be determined unequivocally from available data. One possibility is that the major volcanic peridotite-associated deposits were developed selectively in the actively subsiding axial part of the rift zone during the early extensional phase, whereas intrusive dunite-associated deposits were formed during a subsequent (less active?) stage of volcanic basin development. Distinctive sub-types (facies) of the volcanic peridotite-associated deposits form clusters that are generally within the rift zone. These may represent deposits related to discrete eruption centres, and at least part of their variation is due to relative position within extensive, topographically confined, linear flows."

Jan 1, 1984

By S. Vardy

The paper notes that the extraction of 22% of the remaining workable reserves in the north western area involves a risk of spontaneous combustion higher than is normal in Britain. Mining systems have been tailor made in order to minimize the risk of spontaneous heatings, and these systems are described. Well-proved methods of combating spontaneous combustion are referred to, as well as the limitations which now apply to them as the result of the introduction of modern mining techniques. A substantial part of the paper is devoted to the circumstances in which spontaneous combustion occurs underground in the north western area. Several actual incidents which have occurred in the last few years, along with the practical application of the lessons learned, are described. Of particular note are: a) the procedure adopted in the north western area to equalize pressure differences across stoppings using pressure chambers, and b) a retreat mining system, primarily designed to deal with high methane emission and steep gradients, which also affords some protection against spontaneous combustion.

May 23, 1905

By W. H. McAllister

The paper considers the geology and the coalfields that comprise the Scottish south area. It traces the history of known sources of spontaneous combustion and indicates the collieries concerned, with the position of the seams in the geological series where heatings have occurred. The methods of work over the years are described. It relates in detail the circumstances surrounding a fire at Bilston Glen Colliery in the Lothian Coalfield, and the heating at Killoch Colliery in the Ayrshire Coalfield, and the steps taken to deal with them. It also describes some of the difficulties in steep seam working. Methods adopted to prevent spontaneous combustion throughout the area are discussed, and some detail of the UNOR gas analyser is given. Finally, it comments on the present techniques in use in the area, particularly at Bilston Glen Colliery, to prevent spontaneous combustion.

May 23, 1905

By D. Newman

Mineral production in the Highlands and Islands of Scotland during the last ten years has been confined to the sporadic production of industrial minerals—for example marble, anorthosite, limestone, talc and silica. From 1962 onwards there has been an upsurge in mineral exploration in the Highlands, increasing in tempo from 1966 onwards due to the efforts of the Institute of Geological Sciences, the Highlands and Islands Development Board, and private and public companies. Geological, chemical and economic aspects of some of the more interesting mineral prospects are discussed: these include anorthosite, feldspar, magnetite, quartzite and brucite marble. Reference is made to a geochemical survey undertaken in the Rosehall district of Sutherland, the results obtained being summarised. Problems that affect the future of mineral exploration in the Highlands are stated.

Dec 1, 1971

By D. C. Yates, G. V. Jolliffe

In the five coalfields of Staffordshire, there have been some 43 incidents of spontaneous fires and heatings which have required special attention in the past ten years. This total excludes incidents in the Thick Coal Seam of South Staffordshire, which was worked until 1967, and which was subject to an almost continuous series of heatings. The incidents have been classified to show the sites of occurrence, the contributory factors which may have caused them and the treatments applied to them. The remedial techniques, as practised in Staffordshire, are dealt with in detail, with particular reference to standard methods of stopping-off. Precautionary measures taken are described, including a "liability to spontaneous combustion" classification of all seams, and the setting up of an emergency organization with emergency stocks of materials and equipment. The paper is concluded by a few words on the organization and control at the time of an incident.

May 23, 1905