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By Robert W. Geehan

The Bureau of Mines has been developing deposits of critical and essential minerals in the United States since 1939. A preliminary examination of the Union lead mine was made in November 1944 and January 1945 by W. T. Benson, a Bureau of Mines engineer, who recommended development by diamond drilling. The Bureau conducted a drilling project at the mine from February 12 to May 16, 1947. The property is in sec.12, T. 17'N., R. 19 E., Mount Diablo Base and Meridian, in. southern Washoe County, Nev., about 15 miles south of Reno. The Union lead mane, also known 4s the Commonwealth mine, has been an intermittent producer of zinc-lead-silver ore since 1860. During World War II, ore was shipped to smelter& near: salt Lake City, Utah. The Bureau drilled 21 diamond-drill holes having a total length of 1,549 feet and 20 long percussion-drill holes with a total length of 359 feet. The program was designed to test for horizontal and vertical extensions of the ore body and to prospect for parallel ore bodies. As a result of this program, extensions of the ore zone were established, but no parallel ore-bearing structures were found. The areas drilled were limited by drill sites available.

Jan 1, 1950

By R. C. Buehl

A pyrometallurgical process for recovering manganese from open-hearth furnace slags or low-grade manganiferous iron ores is described. The slag or ore is smelted in a blast furnace to produce spiegeleisen; the speigeleisen is then blown with air in a basic converter to give an oxide slag. This slag product contains 60 to 75 percent manganous oxide and may be considered a synthetic manganese ore. In the smelting operations coke rates for five test periods ranged from 3,255 to 4,130 lb per ton of spiegeleisen. The recovery of manganese in the spiegeleisen varied from 60 to 76 percent. Recovery increased to 83 percent when the open-hearth slag feed to the blast furnace was diluted with a high-? grade iron ore sinter to facilitate smelting. In blowing the spiegeleisen a cyclic procedure was developed that gave nearly 90 percent recovery of manganese in the slag product (synthetic ore) yet prevented excessive contamination of the slag by phosphorus and iron. The overall recovery of manganese was about 75 percent when iron ore sinter was used with the open-hearth slag in the smelting step. The metal remaining after oxidizing the manganese from the spiegeleisen contained approximately 3.5 percent phosphorus. It was refined in a basic converter by blowing with air in the presence of lime" A high--grade iron and a basic phosphate slag were produced.

Jan 1, 1965

By E. Chin

The countries of Asia and the Pacific have large resources of diverse minerals. Australia and China have extensive mineralization that are commercially being exploited. The major minerals in Australia with known reserves adequate for both domestic demand and export markets include bauxite, clays, copper, diamond, gold, iron ore, lead, manganese, mineral sands (titanium minerals), nickel, salt, silver, tin, uranium, and zinc. China is the world leader in proven reserves of antimony, barite, magnesite, molybdenum, rare earths, titanium (ilmenite), tungsten, and vanadium. It also has about 55 billion tons of iron ore, albeit with an average grade of only 30 % to 35 % elemental iron content. With the exception of chromium and copper, China has significant resources of a wide array of minerals and metals, based on its production and/or export capability for these commodities. Additionally, India has significant resources of bauxite and mineral sands; Indonesia, bauxite, copper, nickel, and tin; Malaysia, tin and associated titanium; Mongolia, copper, fluorspar, and lead-zinc; New Caledonia, nickel; New Zealand, gold and iron sand; North Korea, magnesite; Papua New Guinea, copper, gold and mineral sands; Philippines, copper, chromite, and gold; and Sri Lanka, gemstones. Moreover, there appears to be extensive mineralization III Burma (Myanmar), Cambodia, Laos, Thailand, and Vietnam, but they have yet to be definitively delineated.

Jan 1, 1994

By L. T. Grose

The Bureau of Mines conducted a comprehensive study of the Kanab, Kolob, Kaiparowits, and Harmony coalfields of southwestern Utah to obtain additional information and to determine the potentials of these coalfields as sources of energy for steam-electric power-generating plants. Field examinations were made to ascertain the geologic structure and the stratigraphy of the coalfields, the accessibility of the coal-bearing strata, and the general nature of the coal-bearing strata and the terrain. Many mines, both active and abandoned, were examined, and key personnel in the coal industry in the area were consulted. Available analyses of southwestern Utah coals were compiled, and tentative conclusions regarding the rank and quality of the coals were drawn. Coals have been classified by rank according to the standards established by the American Society for Testing and Materials in 1964. The Parr formula for moist, mineral-matter-free British thermal units has been used to calculate the rank of each sample, except as otherwise noted. Water resources related to the areas of the coal reserves also were investigated. Existing literature and maps pertaining to the geology of the areas were reviewed. Production potentials of the coalfields and economic conditions affecting the possible utilization of the coal reserves as sources of energy for steam-powered electricity-generating plants were investigated and analyzed. The data obtained and the conclusions reached as a result of this study are included in this document. The total reserves of subbituminous A and high-volatile bituminous C coals in the fields of southwestern Utah are estimated to be at least 8 billion short tons at depths generally less than 2,000 feet. It appears likely that this estimate will be increased as additional data are made available through exploration and other investigations. Sufficient coal is available in four southwestern Utah counties to supply three or four large steam-electric plants. If the States involved grant water rights to companies planning to build steam-electric plants, the cost of producing power with coal might be attractive and might justify the construction of one or more of these plants.

Jan 1, 1967

By J. J. Taber

This is the final report on Grant No. G0144067. The report presents the results of a number of laboratory studies carried cut in several different ways to determine the effectiveness of foam for blocking the flow of gas in coal. The effectiveness; (of foam for retarding or blocking the flow gas in various porous media has been observed by many investigators1-4 but we are not aware of similar detailed studies in coal. Because of the diversity of our experiments, the key findings and general conclusions are presented very briefly in Section II. As a convenience to the reader a complete table of cements is included to enable the reader to find those experiments and studies of greatest interest.

Jan 1, 1976

By V. L. Burdick

A literature review of current uses of Mn02 in ceramic applications with suggestions for future research. Historical background, oceanographic distribution, geology, exploitation, law and politics. Uses of Mn02 in ferrites, semiconductors, catalytic processes, thermo-luminescence and photochromic materials. Select bibliography of 33 items, plus 129 references.

Jan 1, 1980

By Jr. Brinkley

For a theoretical description of power plants that derive their energy from the combustion of a fuel, it is necessary to solve, to an appropriate degree of precision, a hydrodynamic problem that requires for its solution a knowledge of the thermodynamic properties of the working fluid com-posed of the products of the combustion reaction. It is usually a good approximation to assume that the properties of the combustion gas are determined by the conditions of thermal equilibrium, and it is thus possible to employ the methods of Classical thermodynamics for their computation. The thermodynamic properties of fuel gases also are of considerable importance, as they form the basis for the design of appropriate means for their effective utilization. The specification of the operating conditions to produce a gas for use as an intermediate in a chemical process, such as the synthesis of liquid fuels, may be based upon a study of the variation of the composition of the synthesis gas with changes in the various process variables. Although there exists a large number of important scientific and technical applications of the data that can be obtained from the systematic determination of the thermodynamic properties of combustion gases, such application has been greatly handicapped by the extremely tedious and time-consuming computational methods required. The development of large-scale automatic computational equipment makes feasible the initiation of a systematic program for the determination of the thermodynamic properties of combustion gases and for the application of such data to specific problems of scientific and technical importance. As a part of its program of basic research in flame and combustion phenomena, the Explosives and Physical Sciences Division of the Bureau of Mines is engaged in such a program. The present communication is designed to introduce a series of reports presenting the results of this program.

Jan 1, 1951

By F. Matanzo

[Nine wire rope terminations were pull tested and fatigue tested to destruction to measure the termination efficiency and relative fatigue life. The terminations were selected on the basis off mine site visits and the specimen were assembled in a manner similar to industrial slings. To measure a termination's sensitivity to poor workmanship, both standard and modified assembly specimen were tested. Lang and Regular construction of the 6x19 and 6x37 class wire ropes were used in diameters of 13 mm (1/2 in.), 19 mm (3/4 in.), 25 mm (1 in.), 38 mm (1 1/2 in.), and 51 mm (2 in.). In static pull tests rope class, construction, and diameter interacted with the termination to influence the efficiency of the termination. In axial fatigue tests using only the 6x19 class rope, the effect of rope construction was negligible since failure was primarily dependent on the termination type. The Swaged Socket, a termination requiring a high capacity hydraulic press, gave the best overall performance in terms of efficiency and fatigue life. The short body length of the Zinc Poured Socket (RR-S-550) was attributed with the short fatigue life of this termination. The use of thermosetting resins as a replacement for zinc was demonstrated successfully for some socket designs. The fatigue life of the termination, expressed as a percentage of the fatigue life of the wire rope, was shown to be a guide for the retirement of the wire in these applications where the wiry' rope is primarily in axial loading.]

Jan 1, 1978

By J. F. Papp

The microstructures of a CF2Br2-inhibited methane flame and its uninhibited analog have been determined using molecular beam-mass spectrometry. The slightly lean flames were stabilized on a cooled porous plug burner at reduced pressure. Composition profiles of stable, intermediate, and radical species and temperature profiles were obtained. Comparisons of the uninhibited and inhibited flame profiles revealed the following inhibition effects; a shift of the primary reaction zone to higher temperatures, a higher maximum flame temperature, an increase in the CH3 concentration, and a reduction in the H2CO, H, 0, and OH concentrations. Kinetic analyses of the data yielded rate coefficients at flame temperatures for the reactions H + CH4 ? CH3 + H2, H + O2 ? OH + O, CO + OH ? CO2 + H, and CH3 + O ? H2CO + H. CF2Br2 is judged to decay by thermal decomposition and abstraction reactions.

Jan 1, 1981

By Seth C. Schaefer

The Bureau of Mines investigated the thermodynamic properties of Bi203 (bismuth sesquioxide) and Sn02 (stannic oxide). Standard Gibbs energies of formation (AGfO) of these compounds were determined with high-temperature electromotive force (emf) cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained from the cell

Jan 1, 1984

By Sarkis G. Ampian

Extraction of alumina was correlated with the sinter and leach products from the lime soda sinter process for anorthosite. The effect of composition and grain size of reactants, time and temperature of sintering, and techniques of sample preparation were investigated. Greater than 90 percent Al2O3 extractions were obtained from dry-mixed minus 200-mesh anorthosite sinter mixes having mole ratios of CaO/SiO2 = 1.8 and Na2O/Al2O3 = 0.8. These sinter mixes were briquetted at 15,000 psi and fired between 1,200° C and 1,320° C for 20 to 60 minutes. The sinter phases that contribute to low alumina recovery were determined by X-ray diffractometry, optical microscopy, and electron probe X-ray spectrography. The mechanism of the sintering reaction was investigated by high-temperature X-ray diffractometry. The contrast in the lime soda sinter process for clays and for anorthosites are discussed. Explanations and suggested solutions are presented for problems such as gelation and variable alumina recovery encountered by previous investigations.

Jan 1, 1967

By W. T. Benson

Peacetime production of mercury in the United States is controlled by world mercury prices, with significant lags to be expected between price increases or decreases and resultant increased or decreased production. Twenty-four mercury-bearing mines and prospects in widely separated districts in western and central Nevada and one property on the Nevada-Oregon border were examined and sampled. The purpose of the project was to determine if some of the properties warranted more extensive exploration work to obtain information on possible reserves of commercial-and sub-commercial-grade ores. The investigation of mercury deposits in Nevada was sufficiently widespread and indicated several areas of interest in the State that merit further exploration work.

Jan 1, 1956

By J. Fletcher Smoak

Consumption of abrasive materials in the United States increased 22% in value over that of 1982 to $320 million; of which, 59% was manufactured abrasive, 35% was industrial diamond (natural and synthetic), and 6% was natural abrasive. Production value of natural abrasives, excluding industrial diamond, remained virtually unchanged. Production of crude tripol, a porous siliceous rock, decreased slightly; however, shipments of processed tripoli increased 13% in quantity and 32% in value. Production of garnet, an abundant iron-aluminum silicate, continued to increase primarily because of further increases in production from one plant that had completed an expansion program in late 1981. Production of special silica stone, both crude and finished, decreased in 1983 because of reduced demand for oilstones

Jan 1, 1984

Volume 2 presents the results of studies of Phelps Dodge Corporation's tailings embankments numbers 1West and 2 West, at Morenci, Ariz. The work involved compilation and description of pertinent factors relating to the physical features and operational characteristics of the facility, including information on embankment construction practices; investigation and research of the general geologic and seismicity characteristics of the site and vicinity; limited field exploration and materials sampling and testing at the site; installation and limited monitoring of piezometers, surface movement markers, and slope indicator casing; limited laboratory testing of materials to evaluate the basic index and engineering properties of the embankment and tailings materials; selected engineering analyses of the embankment for various types of potential "failure" conditions; and includes appendices.

Jan 1, 1974

By F. F. Netzeband

This report relates to the sulfur industry of seven States--Arkansas, Kansas, Louisiana, Mississippi, Missouri, Oklahoma, and Texas--and is part of a national study of the sulfur industry by the Bureau of Mines. Markets as used 1n this report are divided into two components for individual analysis--(1) supplier markets which include regional Frasch and byproduct sulfur producers and (2) consumer markets which include processors and manufacturers requiring sulfur in their operations. The term sulfur as used in this report includes brimstone, native sulfur, elemental sulfur, or sulfur equivalents.

Jan 1, 1964

By Gary L. Hundley

The Bureau of Mines has devised and demonstrated a process for recovering Ni and Co from low-grade domestic laterites. The process consists of four major steps: (1) reduction roast, (2) ammoniacal leach, (3) solvent extraction, and (4) electrowinning. Several solid-liquid separation steps are required that affect the economics of the overall pro-cess. In this study, two techniques for solid-liquid separation, centrifugation and thickening, were investigated. This report presents the results of (1) laboratory and pilot plant studies to determine parameters for sizing centrifuges and thickeners and (2) an economic study of the two techniques, based on the requirements of a commercial-size (5,OOO-tpd) laterite processing plant. Sizing and other equipment-related recommendations, based on data from the Bureau's studies, were obtained from commercial manufacturers. The costs of thickening and centrifugation, including all the unit operations affected, were determined by the Bureau's process evaluation group. The total operating costs ~or separation using the two techniques (including depreciation on the capital cost of equipment) were found to be quite close: $17.26 per ton of laterite for centrifugation and $18.15 per ton of laterite for thickening. For centrifugal separation, the greatest cost was found to be the initial capital cost for the separation equipment; using thickeners, the greatest cost was for re-agent recovery.

Jan 1, 1984

By F. D. Stevenson

Thermodynamic properties of metal halides and, in particular, vapor pressures have become of great importance in recent years owing to increased application of chemical processing to extraction of metals from their ores. Vapor pressure data serve not only as a valuable source of latent heat of vaporization and fusion values but also differences in metal-halide vapor pressures often provide the basis for their separation by conventional mass transfer operations. This literature search was made to provide a ready reference to experimental vapor-pressure data of metal halides and oxyhalides. Results are reported in two main sections: (1) A tabulation of vapor- pressure references for each of the metal halides (listed by metal) for which actual experimental data are reported (table 1), and (2) a bibliography of the citations. Metal halides and oxyhalides are listed by chemical formula and chemical name, based on the stock4 system. To facilitate location of the references, a listing of the journal titles and their abbreviations follows the bibliography.

Jan 1, 1963

By C. H. Riggs

THIS REPORT give's the results of a study of the central and south parts of the Cushing oilfield, including a description of the geology, a review of the production history, and estimates of oil reserves available by secondary-recovery methods. Each of the major producing zones of the field is treated separately. The report, which is one of a long series of field studies the Bureau of Mines has conducted over the past 40 years, was prepared to aid operators to increase oil recovery and to help prevent underground waste in the Cushing field, in the State of Oklahoma, and in the United States. The geology and production history are presented not as a review of past behavior of the Cushing field but rather to interpret the possibilities for increased oil recovery by future development of this and similar areas. The field, which is in the northwest corner of Creek County, Okla., was discovered in 1912 and developed during 1913 and 1914. For several years it, was one of the most important areas producing high-grade crude oil in Oklahoma. Although some oil has been recovered from each of 10 separate reservoirs, nearly 98 percent of the total recovery of oil in the area studied was from 4 major producing formations (table 1). Of these, only the Bartlesville [ ]

Jan 1, 1958

By H. E. Harris

An extensive experimental program was carried out to determine the variability of respirable dust samplers and to determine whether area dust sampling is feasible in coal mines. For sampler variability, it was found under laboratory conditions, that a single dust measurement could be as much as 0.30 mg/M3 from the true value at the 95% confidence level. Under actual underground mining operations, this difference could be as much as 0.52 mg/M3 in the 0 -5.0 mg/M3 range. The results from dust sampling on 175 production shifts involving over 2,500 on-man and area dust samples showed that area sampling is viable, but the field investigation did not establish necessarily where the best area locations were.

Jan 1, 1976

By Leonard Obert

Between 1927 and 1957, sodium borate minerals were mined by underground methods in the Kramer District, Kern County, Calif. In 1957, surface mining methods were initiated, and during the next two or more decades it is probable that most of the production from the district will be obtained from open pits. However, part of this borate deposit is sufficiently deep that surface mining may not be economical and, hence, at some future date underground methods may again be employed. This report was prepared to document the underground mining methods employed in the district before 1957. The general geology of the district and the detailed geology of each of four mine sites are presented, together with a mineral and mechanical description of the ore and enveloping rock. The report also describes the stoping, extraction, pillar support, methods of artificial support, and other factors that affect the structural characteristics of these mines.

Jan 1, 1962