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By A. Gene Collins

This report discusses some of the chemistry and geochemistry of cesium and rubidium. Knowledge of the cesium and rubidium content of oilfield waters aids in resolving the origin of waters and petroleum, exploring for petroleum and other valuable minerals, discovering water pollution sources, and augmenting the knowledge of geologic formations. The methods described in this report permit the detection of less than 0.01 mg/l of cesium and/or rubidium in a complex oilfield brine or water. Solvents possessing high-dielectric constants were evaluated for their ability to extract cesium and rubidium tetraphenylboron from oilfield waters and for their flame emission characteristics. Nitroethane was selected and used for the extraction and flame spectrophotometric determinations because it gave the highest sensitivity. Cesium 137 and rubidium 86 were used to determine the extraction efficiencies, which were about 87 percent and 58 percent respectively using a single 10 ml nitroethane extraction from a distilled water matrix. The standard deviation of the determination was 0.0008 mg for cesium and 0.0007 mg for rubidium in the 0.01 mg range.

Jan 1, 1965

By R. F. Droullard

The Bureau of Mines has developed test facilities for use in a research program that deals with radiation hazards in mining. This report describes the radon test chamber located at the Denver Research Center and the Twilight experimental mine located near Uravan, CO.

Jan 1, 1984

By B. H. Eccleston

The effect upon automobile emissions in changing from leaded to lead-free gasolines was studied in experiments by the Bureau of Mines in cooperation with the American Petroleum Institute. Typical U.S. leaded gasolines and prototype lead-free gasolines of comparable octane quality were used in eight vehicles operated to simulate city driving. The experiments were run at 70° and 95° F. Exhaust and evaporative emissions were measured and the photochemical effect of the emissions was experimentally observed in an artificial smog chamber. Results of the study reveal the manner and degree in which the changes in fuel composition alter the amount and characteristics of both exhaust and evaporative emissions. Briefly, it is shown that the compositional differences between leaded and prototype lead-free fuels resulted in higher photo-chemical pollution potential of the emissions from the lead-free fuels. The effect is attributed to the photochemical characteristics of high-octane fuel components that are used in greater quantity in the lead-free fuels.

Jan 1, 1970

By George Watkin Evans

The United States Geological Survey has estimated 1 that the State of Washington contains 11,412,000,000 tons of bituminous coal and 52,442,000,000 tons of subbituminous coal, in beds more than 14 inches thick. As the present rate of production is about 4,000,000 tons a year, Washington apparently contains coal enough to supply Pacific coast markets for many years. The character of the coal beds of Washington renders the production of clean coal very difficult, and a considerable proportion of the output is washed before it is marketed. In 1915 Washington ranked fifth among the States in the amount of coal washed, though only twentieth in total output. In that year 37.9 per cent of the coal produced in the State was treated in surface cleaning plants.

Jan 1, 1924

By George S. Rice

The prevention of coal-mine explosions has been one of the chief purposes of the Bureau of Mines. In facti the first Federal appropriation relating to mining methods, in 1908, authorized the investigation of the causes of mine explosions and the possible methods of preventing them. When that investigation started the mining industry had not determined the real causes of a succession of terrible coal-mine explosions in various countries, culminating in the great disasters at CoulTièl'es, France, and Monongah, W. Va. Coal dust as an agent of widespread explosions had been under suspicion, and watering to allay the dust was recommended by some mining engineers but the watering of coal-mine dust was adopted in comparatively few mines of the United States and Great Britain, and had not been introduced widely in any country except Germany. Rock dusting, another method of preventing explosions of coal dust, was early tested with success by the Bureau of Mines in its fist gallery at Pittsburgh and, beginnig in 1911, at the experimental mine, Bruceton, Pa. Several of the fist publications i of the bureau suggested that rock dust be used in gaseous or dusty bituminous mines, and in 1915 Technical Paper 842 strongly recommended it. Since that time additional tests in the experimental mine have fully confied this :ft judgment.

Jan 1, 1924

By E. P. Youngman

By a decree of March 14, 1929,5 the President of the Faitian Repub- lic, considering it to be necessary, until the mining legislation of the Republic shall have been revised, to put into effect the mining law of Decem- Der 4, 1860 (relative to mines, diggings, and quarries), by the authority given in article 55 of the Constitution, declared the law of February 14, 1919, to be abrogated and the provisions of the earlier mining law (December 4, 1050) again to be valid. No concessions were granted under the law of 1919. All citations in this paper, unless otherwise designated, refer to the law of 1930.

Jun 1, 1932

By Lloyd H. Banning

With the ever-increasing demand for energy in all forms, electrical energy generated from geothermal resources could become an important energy source in the next few decades. Geothermal fluids, which contain appreciable quantities of dissolved salts and gases, are generally corrosive to materials of construction. Since data on corrosion of materials in geothermal brines is limited, the literature was surveyed through February 1972 to obtain a compilation of information on corrosion resistance of aluminum and its alloys, copper and copper-base alloys, carbon steel and cast iron, stainless steels, chromium-iron alloys, nickel-and cobalt-base alloys, and titanium in heated brines including sea water.

Jan 1, 1973

By William A. Beck

Bauxite was discovered in the Springvale district in 1916. About 16, 000 tons was mined in the period 1916 to 1922, but no bauxite mining has been done since that time. The Bureau of Mines explored for bauxite in the district from September 5 to November 18, 1943. During the life of the project, the Bureau of Mines obtained mineral exploration agreements covering a total of 11,330 acres from 50 property owners. A total of 388 holes were drilled on five of these properties and 164 samples were taken and analyzed. The Springvale bauxite district includes an area of about 30 square miles in the northwestern part of Randolph County, Ga. The village of Springvale is in the west central part of the district, and Cuthbert is 8 miles southeast of it (fig. 1).

Jan 1, 1949

By W. K. Collins

Engineered scavenger compounds (ESC's) developed by the U.S. Bureau of Mines are a novel class of compounds that selectively can recover a desired element from a solid or molten alloy. Lithium titanate (L2Ti307 or Li2O?3Ti02) is used as an ESC to recover lithium (Li) from aluminum-lithium (Al-Li) alloys. X-ray diffraction measurements have shown that Li2Ti307 undergoes a phase change during scavenging from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of lithium in the matrix of the material and the effect of temperature. Although both phases are metastable, the hexagonal phase that forms during the scavenging of lithium from Al-Li alloys appears to be the more stable phase. Recovering lithium from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. The orthorhombic and the hexagonal structures of Li2Ti307 have similar scavenging capacities for lithium. This report proposes a new mechanism for the phase transformation.

Jan 1, 2010

By Young W. A.

The Eagle Silver mine is in the Rush Valley mining district, Tooele County, Utah, and is now operated by the Hampton Mining Co. The property, originally referred to as the Argent, is reported to have been one of the first discoveries in the district. The early operators mined ore to a depth of 850 feet, at which point the property was abandoned because of excessive water. During 1905 the Honerine tunnel was driven into the area approximately 1,800 feet below the collar of the Argent shaft. This tunnel served to drain the levels above and operations were resumed. Ore deposits in the Eagle Silver mine occur in the Galena King lime-stone, a 20-to 60-foot member of interbedded quartzite and limestone in the Oquirrh formation of Pennsylvanian age. This member has been faulted along the bedding, forming the Galena King gouge. Mineralization commonly occurs in or near this gouge area in a brecciated, highly altered, pipelike zone. The known ore shoots occur in association with the breccia pipe, commonly adjacent to cross faulting and porphyry intrusions. In general, two ore shoots have been mined on the upper levels of the mine, one lying to the east and the other to the west of the breccia zone. The Bureau of Mines diamond-drilling program was begun during the latter part of 1948 and completed early in 1949. Nine holes were drilled, aggregating 852.8 feet. Sludge and core samples from mineralized sections were analyzed in the Salt Lake City laboratories. A total of 87 sludge, 71 core, and 11 chip samples was submitted for analysis.

Jan 1, 1950

By Carl L. Bieniewski

U.S. molybdenum production increased fivefold from 18.2 million pounds in 1946 to 90.5 million pounds in 1966, and constituted 87.3 percent of the total free world supply in the 1946-66 period. Mining development in other free world countries in the next few years may reduce the magnitude of the U.S. position, although similar development planned for the United States may counteract some of the relative gains by those countries. In 1966 two-thirds of the reported molybdenum consumption in the United States by end uses was as an alloying element in steel. Molybdenum also has important use as an alloying element in iron and high-temperature alloys. Consumption of molybdenum metal for making fabricated parts has increased in the past few years, especially in the space and nuclear industries. Molybdenum compounds are used mainly for making pigment, catalysts, and lubricants. Based on producer reports of shipments of primary products to domestic customers, U.S. consumption of molybdenum increased from 16.5 million pounds of molybdenum in 1946 to 65.6 million pounds in 1966. U.S. molybdenum reserves are now estimated to be 5.9 billion pounds of recoverable molybdenum, an increase of 2.1 billion pounds above previous estimates. Molybdenum ores account for 71.4 percent of the reserves, copper ores for 22.3 percent and copper-molybdenum, tungsten, and uranium ores for 6.3 percent. Several methods for predicting future demand are illustrated and estimates of demand using these methods were made for 1975. Based on present capacities and announced company plans for future developments, estimates of annual production were made for 1967 through 1975 for the United States, Canada. Chile, Peru, and the free world. These data indicate that molybdenum production in 1975 for the free world is expected to be 246 million pounds with the United States producing 68.2 percent and Canada, Chile, and Peru 30.3 percent.

Jan 1, 1970

By J. L. Eakin

Systematic flooding was introduced into Nowata County, Okla., in May 1931. The results of this means of stimulating the nearly depleted Bartlesville reservoir in the county has been the subject of four Bureau of Mines Reports of Investigations.2-5/ This report presents a discussion of four full-scale water-flooding projects in the Delaware-Childers field and 1 pilot project in the Curl Creek field (fig. 1). All five plants have been in operation for only a few months. Although substantial increases in the rates of oil production have been obtained 1 by the injection of water, the projects are of particular interest at this time because of the novel methods of operation and new equipment that are being employed. One project utilizes a portable "package" plant designed for a pilot operation. All of the controls for this project are centrally located. The design makes it possible to remove the test plant to another location if the project is unsuccessful or if the unit is to be replaced by a larger plant. This project also utilizes diatomaceous-earth filters successfully for the first time and makes use of plastic pipe. Another novel feature of the operation is the aeration of Arbuckle limestone water through an airlift in the supply well.

Jan 1, 1955

By John C. Machisak

The Nation's mining and quarrying industries have again met the annual challenge to their ingenuity--that of reducing disabling work injuries among their employees. The effectiveness of management in facing this problem and in meeting this responsibility is evident from the results of the 1961 National Safety Competition. Three hundred ninety-three or 45.3 percent of the mines and quarries participating in the competition established a new record number of participants operating throughout the competition year without a disabling work injury. Another record established in the 1961 contest was the number of participants (868) enrolled in the competition. This annual safety competition was begun in 1925 and is conducted by the Bureau of Mines, U.S. Department of the Interior. It provides for six bronze Sentinels of safety trophies which are awarded each year to the winning participant in each group. Since its inception, the competition has exerted a strong influence in the field of safety promotion. The statistical record of its accomplishments over the years gives strong support to the theory that well-organized and well- administered safety programs are effective tools to be used to reduce the number of disabling work injuries. It stimulates and holds the interest of employees and management in accident prevention. Because of this, mines and quarries participating in the contest have a more favorable safety record than those operations not enrolled.

Jan 1, 1963

By K. B. Rojiani

Surface mining activities disturb large tracts of land resulting in the potential for greatly increased downstream sediment loads. The Surface Mining Control and Reclamation Act of 1977 places increased emphasis on the protection of the environment from the adverse effects of surface mining operations. Surface mining activities must be planned to minimize disturbance to the hydrologic balance, erosion and sediment contributions to receiving streams. Sediment ponds must provide a sediment storage volume equal to the accumulated sediment volume from the drainage area as determined by the Universal Soil Loss Equation (USLE) or other empirical methods established by the regulatory authority. It has thus become extremely important for the mining industry to secure more accurate estimates of potential erosion losses and sediment yield. Accurate estimates of sediment yield are required for the planning, design and successful operation of sediment control systems such as detention ponds and other alternative control structures and for evaluating the effectiveness of land management practices. The principal soil loss prediction procedure available for use is the LISLE. The USLE procedure is inadequate for use in predicting soil loss from surface mine regions for a number of reasons. These include: 1. The USLE was developed to estimate average average annual loss from agricultural soils. It cannot predict accurately soil loss for specific storm events. In surface mine regions a major portion of the soil loss occurs during the initial six months to one year of active mining. Accurate estimates of soil loss over short periods are thus required for the design of control structures. 2. The slope length and gradient factors used in the USLE were obtained from data or cropland having slopes ranging

Jan 1, 1983

By J. B. Gayle

During the past several decades, there has been a steady increase in the number and size of experimental ovens used for carbonization research. Although many were originally intended principally for studies of coal expansion, current practice usually includes determinations of the properties of the experimental cokes. With respect to size and shatter characteristics, the cokes from the larger experimental ovens closely approximate those from duplicate charges carbonized in commercial ovens; however, they are consistently lighter and frequently less resistant to degradation by abrasive forces. To minimize these differences, some operators dry the experimental charges before carbonization. The resulting higher dry coal charge densities do, in fact, yield cokes with gravities closely approximating those produced commercially from the same coal or blend but without drying. The drying of the experimental charges may be criticized on the grounds that it represents a departure from commercial practice and may result in oxidation of the samples; for these reasons, the practice has not been universally adopted.

Jan 1, 1961

By C. P. Mishra

The Bureau of Mines investigated the availability of mercury from 22 deposits in market economy countries. The 15 significant deposits evaluated have demonstrated resources of approximately 25 million metric tons of ore containing 5.3 million flasks of mercury and account for more than 85 pct of the demonstrated resources for market economy countries. Using data gathered as part of its Minerals Availability Program, the Bureau determined the mercury production potential of each deposit. At a January 1984 mercury market price of $300 per flask, the deposits evaluated could economically produce an estimated 2.5 million flasks of mercury from six mines operating at the time of this study; no mercury is available at this price from nonproducing operations. At $600 per flask, approximately 4.5 million flasks of mercury are available. For production costs up to $300 per flask, operating mines could supply mercury at the current production rate of 114,000 flasks per year until 1988, when the amount of mercury available from these deposits would decrease. This decline could be offset by the development of resources currently reported at the identified level (17 million flasks) at much higher production costs.

Jan 1, 1985

By Rena I. Geroyan

This U.S. Bureau of Mines report presents an evaluation of the coal mining industry's impact on the economy of Pike County, KY. A software package called IMPLAN was used to perform the analysis. The results of this study show that coal mining was the primary income producing industry in Pike County in 1990, accounting for about 46% of the county's Total Industry Output, and 21% of the total employment.. Coal production in that year amounted to 29.6 M mt (32.6 M st). Two alternate economic scenarios were developed to study the potential effects of changing coal market conditions on the county. Scenario A assumes market changes result in a coal production increase of 4.5 M mt/yr (5.0 M st/yr), and scenario B assumes a decrease of 4.5 M mt/yr (5.0 M st/yr). Scenario A would result in a 15.3% rise in the value of Pike County's Total Industry Output, adding a total of 1,663 jobs (+6.1%) in all sectors in the county. Scenario B would have the opposite effect, decreasing the Total Industry Output and employment by identical amounts. Such knowledge would allow local and regional officials to anticipate the economic and social impacts of shifts in coal production, and plan accordingly to mitigate impending changes.

Jan 1, 1994

By H. L. Riley

This report describes the methods and equipment used by the Watauga Stone Co. to drill und blast limestone in a two-level quarry, and to crush, screen, blend, and load this stone. Power requirements per ton of stone produced are reported. The personnel requirements for individual phases of the operation are tabulated in man-hours per ton of stone produced.

Jan 1, 1963

By H. L. Riley

This report describes the methods and equipment used by the Watauga Stone Co. to drill and blast limestone in a two-level quarry, and to crush, screen, blend, and load this stone. Power requirements per ton of stone produced are reported. The personnel requirements for individual phases of the operation are tabulated in man-hours per ton of stone produced.

Jan 1, 1963

By Raja V. Ramani

The potential usefulness of reclaimed surface-mined land has received much attention recently. In an effort to develop a procedure for evaluating postmining land use potentials, specific mines in various regions of the U.S. were studied to determine the extent of current mined-land planning and to discover characteristics that are regional in nature. As part of this investigation, the Chinook Mine-West Field, located in western Indiana, has been studied. The Chinook Mine is presently operated by AMAX Coal Company and has been in continuous operation since 1928 under various ownership. The status of current reclamation and land use planning was reviewed. In addition, site planning principles were applied to the active mine area. This application included formation of a data base and development of postmining land use plan alternatives. Key factors affecting site potential realization for midwestern area mines have been identified along with suggestions for applying land use planning processes to mined-land planning.

Jan 1, 1983