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By Tracy. L. D.

"Since the introduction of pulverized coal as a substitute fuel for natural gas in the various types of heating furnaces used, in steel mills, a number of fires and explosions have occurred, resulting in the loss of life and property.As one of the primary functions of the Bureau of Mines is to conduct investigations in the utilization of mineral substances with a view to increasing safety in the use thereof, it was deemed advisable to investigate the hazards involved in the industrial use of pulverized coal and, if possible, to devise methods of preventing future accidents arising therefrom. The knowledge of the explosive qualities of coal dust which the Bureau has gained in studies affecting dust explosions in coal mines was of material assistance in these investigations.Several plants were visited in which either fires or explosions had occurred, and data obtained as to the probable cause of the accidents.There was found to exist, among some of those employed about the furnaces, a lack of knowledge of the explosive and inflammable qualities of powdered coal.A small stream of pulverized coal leaking down from a defective joint in a coal transport line did not attract much attention, whereas, had a leak in a natural gas line occurred -wider similar circumstances, no doubt it would have had immediate attention.As a matter of fact, if by any means the duet cloud should come in contact with an open flame or hot metal, the effects would be as disastrous as if it had been gas.This is exceedingly well illustrated by an accident which came to the writer's attention. In the system used at this particular plant, the pulverized coal is transported to the furnace through compressed-air lines. The fuel is fed from a storage bin to a blowing tank in quantities as desired, after which compressed air is admitted and the powdered coal blown to the furnaces. At the time of the accident some repairs were being made to the tank, and it was supposed that the air pressure had been entirely released as the pressure gage stood at zero. There was, however, one or two pounds air pressure remaining and when one of the connections was taken off, a cloud of dust was blown across the room, 30 or 40 feet towards the drier furnace where it came in contact with some live coals. Immediately the entire room was filled with flame which rolled back and forth over a specs 50 feet or so in length."

Apr 1, 1921

By J. W. Horne, W. B. Shirey

"INTRODUCTION The United States Bureau of Mines in cooperation with the State of Colorado at the University of Colorado has conducted experiments to determine the amount and composition of the noncondensable gases evolved when crude shale oil is distilled under pressure.Hydrogen sulphide is one of the components found in the complex mixture of gases produced by the distillation of shale oil under pressure. This paper deals with the apparatus and method used in determining the amount of hydrogen sulphide evolved in the laboratory experimental cracking stills.The study required a complete extraction of all the hydrogen sulphide from the gas stream after it left the water-cooled distillate condensers and before the as stream entered the charcoal absorber for removing the light naphtha. In devising the method it was necessary to take into account a constant variation of velocity, pressure, and percentage of sulphide in the total gas stream coming from the still.Ordinarily, the quantitative determination of hydrogen sulphide in Gas is made by analyzing small samples taken at regular intervals. This estimation can be accomplished by use of the Bunte gas burette as modified by Tutriler,4 or by a similar method. In the industries where the flow of as is constant end of uniform composition, this practice is sufficiently accurate for plant control. For experimental work where many variables have to be taken into consideration, as in the case at hand, these methods are not applicable."

Oct 1, 1931

By R. L. Loofbourow

The adjacent towns of Rouyn and Noranda, centers of the Rouyn mining district of western Quebec, are 360 miles by air line almost duo north of Toronto. Rouyn is reached from the main lines of the Canadian National Railways and the Canadian Pacific Railway at North Bay, Ontario, by the Temiskaming & Northern Ontario Railway and its subsidiary, the Nipissing Central Railway. Noranda is the southwestern terminus of a branch from the Canadian National Railway between Winnipeg and Quebec. The Rouyn mining district is a part of a mineralized zone that has been traced for a distance of 140 miles from Kirkland Lake in Ontario eastward into the Province of Quebec to the Pascalis district. From Rouyn the mine is 5 miler almost duo south over a gravel rend built by the company with assistance from the Province of Quebec.

Jan 1, 1933

By K. C. Dean

A flotation method was developed by the Bureau of Mines for concentrating pollucite, a cesium-aluminum-silicate mineral that may contain from 20 to 40 percent cesium oxide. Separation of the pollucite from three typical ores was achieved by froth flotation of the associated micas, feldspars, and other gangue minerals, using sulfuric and hydrofluoric acids and a cationic-type collector. A low-tenor, 8 percent cesium ore from Maine was upgraded to 20 percent cesium with recovery of 87 percent of the cesium. Relatively high- grade ores from Canada and Southern Rhodesia were beneficiated at lower ratios of concentration to 28 and 29 percent cesium content respectively with recovery of over 92 percent of the cesium. In addition to concentrating the cesium content of ores, the method also effectively separates cesium from sodium, potassium, and lithium, and in certain ores from rubidium. This is accomplished by selective froth flotation of the alkali metal-bearing gangue minerals such as lepidolite, other micas, and feldspars. Since the alkali metals, especially potassium and rubidium, are difficult to separate chemically or thermally from cesium to prepare high- purity cesium products, separation by physical mans is important.

Jan 1, 1962

Improve the strength and other properties of steel alloys. Approach Research by the U.S. Bureau of Mines indicates that steels melted and solidified under high nitrogen pressure acquire yield and tensile strengths that are up to four times the strengths of comparable stainless steel alloys without nitrogen. Fatigue strength, creep strength, and other mechanical properties are also improved. Strengthening occurs by two mechanisms: (1) increasing dissolved nitrogen in the lattice and (2) formation of dispersed metal nitride phases. Nitrogen Alloying Nitrogen alloying of a steel is generally done by introducing metal nitrides during melting of the steel. The concentration of nitrogen is limited to its equilibrium solubility at 1 atmosphere. For face-centered-cubic (fee) iron, that solubility is approximately 0.4 weight percent (wt%). For body-centered-cubic (bee) iron, solubility is 0.05 wt%. This solubility limitation can be overcome by melting the metal in a pressurized vessel. European steelmakers currently have metal-processing systems that can melt and pour tons of steel under nitrogen pressures exceeding 4 megapascals (MPa) (40 atmospheres). They have achieved nitrogen concentrations as high as 1.0 wt% in these (stainless) steels. The tensile strength is approximately twice the tensile strength of similar steels without nitrogen.

Jan 1, 1992

By Ludwig Schmidt

Steel tanks often corrode rapidly in oil fields where the gas produced with crude petroleum contains an appreciable quantity of hydrogen sulphide. In many instances working tanks have been discarded after only six months of service because of failure induced by corrosion. Aluminum has been used for some time in the fabrication of certain equipment incidental to the handling of oils containing hydrogen sulphide gas in solution, and has exhibited no serious corrosive action. These uses indicated that aluminum tanks might be equally effective in counteracting hydrogen sulphide corrosion. Consequently, in the spring of 1928, an all-aluminum stock tank of 500 barrels capacity and a "composite" tank of equal capacity, having a steel bottom and bottom ring and an aluminum top and top ring, were placed in service on the State-Lassiter lease of the Gulf Production Co. in Crane County, Tex. These tanks were under observation for one year, the test being sponsored by the Gulf Production Co., the Aluminum Co. of America, rind the Parkersburg Ric and Real Co. The results of this preliminary test sustained the belief that aluminum is highly resistant to hydrogen sulphide gas and likewise indicated the type or grade of aluminum which could be most economically used for lease tankage. However, in this preliminary test the Wake were not subjected to contact with the large quantities of highly concentrated brines such as often are associated and produced with crude oil. Therefore, it was suggested by representatives of .the Aluminum Co. that additional tests be made to include production conditions in which large quantities of brine would be handled, for past experience had shown that aluminum often is susceptible to the corrosive action of brines.

Jan 1, 1931

By Ludwig Schmidt

[Steel tanks often corrode rapidly in oil fields where the gas produced with crude petroleum contains an appreciable quantity of hydrogen sulphide. In many instances working tanks have been discarded after only six months of service because of failure induced by corrosion. Aluminum has been used for some time in the fabrication of certain equipment incidental to the handling of oils containing hydrogen sulphide L; as in solution, and has exhibited no serious corrosive action. These uses indicated that aluminum tanks might be equally effective in counteracting hydrogen sulphide corrosion. Consequently, in the spring of 1928, an all-aluminum stock tank of 500 carrels capacity and a "composite" tank of equal capacity, having a steel bottom and bottom ring and an aluminum top and top ring, were placed in service on the State-Lassiter lease of the Gulf Production Co. in Crane County, Tex. These tanks were under observation for one year, the test being sponsored by the Gulf Production Co., the Aluminum Co. of America, and the Parkersburg Rig and Real Co. The results of this preliminary test sustained the belief that aluminum is highly resistant to hydrogen sulphide gas and likewise indicated the type or grade of aluminum which could be most economically used for lease tankage. However, in this preliminary test the tanks were not subjected to contact with the large quantities of highly concentrated brines such as often are associated and produced with crude oil. Therefore, it was suggested by representatives of the Aluminum Co. that additional tests be made to include production conditions in which large quantities of brine would be handled, for pact experience had known that aluminum often is susceptible to the corrosive action of brines.]

Jan 1, 1931

By Doris M. Hyde

The petroleum sector continued to dominate Ecuador's economic activity in 1978, accounting for nearly 10% of the gross domestic product (GDP) and 42% of total export earnings. In 1978, a more flexible petroleum export price was adopted which permitted an expansion of foreign market opportunities. During 1979, Ecuador took advantage of disruptions in the world petroleum supply and renegotiated existing export contracts to accomodate the rapidly escalating world market price. Petroleum sales on the spot market were maximized, and prices reached unprecedented levels. By taking royalty payments in-kind, Ecuador increased its volume of petroleum available for term and spot sales. Although the volume remained about the same as in 1978, the total value of 1979 petroleum exports increased to about $920 million, reflecting a 76% increase over the $523 million received for 1978 crude oil exports. Concerned about its steadily decreasing petroleum reserves (recently estimated at about 1.1 billion barrels), rapidly increasing and heavily subsidized domestic consumption, and the prospect of having to import substantial amounts of petroleum by 1983, Ecuador announced plane which it anticipates will double reserves within the next 5 years. The Government plans to spend $1 billion over the 5-year period. Plans include drilling 325 exploration and development wells and establishment of a secondary recovery program for the Sachs and shushufindi fields. Some exploration wells are expected to reach a depth of 17,000 feet. It is thought that substantial reserves exist in the southeast Amazon region. Late in 1979, it was announced that some 10 million hectares will be available for exploration tenders-probably in blocks of about 200,000 hectares each-in the Amazon jungle of the Orients and in the coastal and offshore regions. The Government planned to commission a private, independent analysis of Ecuador's petroleum reserves that would also include recommendations on efficient production levels.

Jan 1, 1981

By F. D. Cannon

"In metal and nonmetallic mineral mines during the 15-year period 1911 to 1925, 30.17 per cent of all fatalities and 16.57 per cent of all injuries were caused by falls of rock or ore from the back or roof or from the wail; 1.24 per cent of the fatalities and 11.05 per cent of the injuries were caused by rock or ore while loading at the working face; 6.66 per cent of the .fatalities and 2.49 per cent of the injuries resulted from men falling down 3 chute, winze, raise, or stope; and run of ore from chute or pocket caused 1.48 per cent of the fatalities and 1.93 per cent of the injuries.3 Hence, accidents due to falls of men and material caused. 39.55 per cent of the fatalities and 34.05 per cent of the injuries in these mines. Accident prevention can best be assisted by each company's preserving complete records of accidents classified according to cause and rate per thousand or 10,000 shifts. A systematic method of recording accidents and the employment of graphs or charts will be helpful to the company safety department in analyzing the cruses of accidents. The purpose of this publication is to analyze data on accidents caused by falls of men and material in metal -mines of the United States, and to suggest methods of preventing or reducing such accidents."

Jun 1, 1929

By R. H. Lien

The Bureau of Mines investigated nitrous oxide (N20) stability when used as a solvent for organic removal from metal powder surfaces. Both supercritical and subcritical conditions were studied. This investigation was prompted by the occurrence of a violent reaction when supercritical N20 was being used to deoil a metal powder grinding waste sample that contained 20 to 25 wt pct cutting oil. Tests were conducted to determine the cause of the reaction and to define stability limits. Test data showed that the waste's oil fraction reacted violently with N20 acting as an oxidizer; the metal powder acted as a promoter to reduce the ignition temperature. Although the data were scattered, this temperature appeared to reach a minimum at a certain pressure (dependent on vessel and sample size). The minimum ignition temperature for a 0.64-g sample in a 72-cm3 vessel was 360° C at 200 psig. As the sample size increased, the ignition temperature decreased. For example, when the sample size was increased to 10 g, a reaction occurred at 240° C and 600 psig. Because of the variability of ignition temperature with pressure and sample size, safe operating conditions were not established. Overall, this research showed that extreme caution should be exercised when using N20 in an organic or organic-metal system.

Jan 1, 2011

By Oliver Bowles

The wire saw, introduced by the Bureau of Mines about two years ago, has revolutionized slate quarrying in Pennsylvania. The success of the saw since its early accomplishments has become greater and greater as the equipment has been perfected and skill acquired .in its use. In the first test made, a cutting rate of 9.7 square feet per hour was attained; in the next four cuts, made early in 1927, the average rate of cutting was increased to 12.8 square feet per hour; in 1928 a maximum of 34 square feet per hour had been attained, with a general average of about 20 to 25 square feet, The wire saw is now regarded as essential equipment in practically all of the quarries in the Bangor, Pen Argyl, and Windgap districts. The wire saw consists of a three-strand steel cable of 3/16 or 1/4 inch diameter running as an endless belt. The driving pulley is a 40-inch double-groove cast-iron sheave. A tension pulley supported by a frame mounted on wheels may travel back and forth on a short track. A weight of 800 to 2,000 pounds gives the desired tension on the wire. The driving units consist of electric motors with direct-drive compactly enclosed gear reduction, or double-belt speed-reduction units; the former is preferred. Silent chain and. pinion gear reductions are used to a limited extent. The travelling speed of the wire is about 15 feet per second. The driving and tension equipment are shown in Figure 1, A.

Jan 1, 1929

By M. Shabbir

A study was made to determine the optimum conditions for precipitation of uranium from mill solutions using hydrogen peroxide. Precipitation tests were made on both synthetic and actual mill solutions. Parameters studied included amount of hydrogen peroxide, initial pH, reaction pH, time, and temperature. Also investigated was the effect of varied amounts of vanadium, molybdenum, and sulfate in the test solution on uranium precipitation and product quality. The optimum conditions for complete precipitation and high product quality were (1) the use of 150 percent of the stoichiometric requirement of hydrogen peroxide, (2) initial pH of 1.0, (3) reaction pH between 3.4 and 5.0, (4) 4 hours reaction time, and (5) ambient reaction temperature. The excess hydrogen peroxide requirement is partially dependent on the amount of impurities present in the feed solution. The hydrogen peroxide process appeared applicable to treatment of the several mill eluate and strip solutions tested. The experimental studies also indicated that the hydrogen peroxide technique gives substantially better product quality than that produced by ammonia precipitation.

Jan 1, 1974

By W. H. Ode, W. A. Selvig

Briefly, this swelling test consists in heating 1 gram of pulverized coal in a silica crucible over a gas flame under prescribed conditions to form a coke button which is compared in size and shape with a series of standard profiles numbered 1 to 9. These profiles are intended to cover the size and shape of buttons obtained from coals covering a wide range in plastic properties. The number of the standard profile with which the maximum cross-sectional area of the button most nearly corresponds is recorded as the swelling index. Although the swelling test showed poor relationships with the various tests that were used for measuring expansion or contraction of coal during carbonization, it gave indications of having value in measuring free-swelling and coking properties of coals when burned on fuel tests. An opportunity to investigate this occurred when an engineering company reported pronounced differences in burning characteristics on grates of various shipments of Pocahontas coal. Some of these coals gave trouble by swelling excessively and clogging the grate. Samples were obtained, and it was found that the troublesome coals gave radically higher free-swelling numbers than did the coals that performed satisfactorily. Also, it was found that the free-swelling index test gave better differentiation between coals than could be obtained from the coke buttons from the standard volatile-matter test or iron agglutination-value results. The results of the free-swelling test were confirmed by the Subcommittee on Plasticity and Swelling, Coal, a special group of the Subcommittee, under the chairmanship of R.A. Shuman, worked along with the test method. Estberg, Limacher, and Shuman of the Battelle Memorial Institute investigated the various factors affecting the test and found that the swelling index was a good indication of the suitability of coal for performance on residential-type stokers from the swelling characteristics of the coal. Data were presented that also showed that the index was helpful in the selection of coal for industrial underfeed stokers.

Feb 1, 1948

By John W. Buch

Upon review of German World War II mining practices and equipment for planning coal, the Federal Bureau of Mines initiated research leading to the development of a pneumatic planer for anthracite. The results of tests are reported in this manuscript. It was demonstrated (1) that hard anthracite can be planed and (2) that the design and operating requirements are within the limits of present-day engineering and technology. For hard anthracite, the depth of cut indicated is 4 to 6 inches; with a chain pull of 20 to 40 tons and the speed of planer travel of 18 to 20 feet per minute, a 40-hp. motor will be required for the planer hoist. Compressed-air requirements for the planer will be 250 to 300 c, f, m, at 60 to 70 p. s, i. It was learned that the length of the 4 individual sections of the planer should not exceed that of the individual troughs of the armored chain conveyor (5 feet in this instance); otherwise, bottom coal will be left in synclines, and the planer will override the conveyor at anticlines. Pneumatic pushers should be operated from a separate compressed-air line fitted with a pressure regulator. Results indicate that additional development work is warranted.

Jan 1, 1957

By Timothy A. Clancy

In support of research on forming ceramics from mining and processing wastes, the Bureau of Mines tested various commercial refractories to evaluate their resistance to melts of these wastes. Sixteen refractories of various types were exposed in slag erosion tests to two siliceous waste melts with Si02/CaO ratios of 4.0 and 2.2, The extent and nature of slag attack were then determined for each refractory. The nature of slag attack was investigated through scanning electron micrographs and microprobe elemental distributions. The refractories that performed best in resisting attack by the melts were high-alumina types, and of the refractories tested, the most resistant was a 90-pct-Al203, 10-pct-Cr203 refractory.

Jan 1, 1983

By R. L. Crosby, L. W. Higley

Magnesium- rich magnesium- aluminum- zirconium alloys in the cast and in the extruded and heat- treated condition were studied to identify the phases present and to determine phase distribution . In cast alloys , two intermetallic compounds were identified : ZrAla by X- ray diffraction ; and Mg₁ Al₁₂ by microscopical observation . Based on microscopical comparisons between the known phases in the cast structures and the phases in the structures of extruded and heat - treated rods , ZrAl₂ and Mg1 , Al12 were identified in the structure of the latter . The presence of these intermetallic compounds in rod specimens could not be confirmed by X- ray diffraction . ZrAl₂ was observed in the structure of extruded and heat - treated rod specimens containing as little as 0.01 weight - percent zirconium . The presence of aluminum restricts the solubility of zirconium in magnesium because of the strong tendency to form ZrAla . This intermetallic compound segregated in clusters of small particles in the matrix of cast alloys , and only slight improvement in distribution was noted when the alloying techniques were varied .

Jan 1, 1964

By A. W. Frolli

This paper, describing the mining and reduction methods and costs at the Oceanic quicksilver mine, is one of a series of similar reports being prepared by the Bureau of Mines on various mines in the United states. The property, which is owned and operated by the Anglo American Mining Corporation, Ltd., is 5 miles east of Cambria, San Luis Obispo County, Calif. It lies in a region of steep hills and sharply incised canyons on the west slope of the Santa Lucia Range at an elevation of about 500 feet above sea level. The climate is ideal for living and operating conditions. A 40-mile paved highway connects the mine with San Luis Obispo, the nearest convenient railroad town.

Jan 1, 1937

By M. V. HANSEN, Frank PERZ, Edward Thomas, C. H. SEELING

This is the second of a series of information circulars dealing with the control of roof and the prevention of accidents from falls of rock and coal . Their purpose is to focus the attention of the coal-mining industry on the most - common source of fatalities and injuries in mining coal and to disseminate information that may be helpful in combating the roof - fall hazard . Inasmuch as approximately 85 percent of roof - fall accidents occur in the face region , the importance of analyzing the accident - producing aspects of methods of roof support at the face or lack of method overemphasized . - - cannot be This circular is not intended to be an exhaustive treatise on methods of roof support in face regions but rather is a description of several methods of support that appear to offer distinct advantages with respect to safety and efficient operation .

May 1, 1948

By James C. Cawley

This report presents results of recent Bureau of Mines research to establish the probability of spark ignition as a function of current (or voltage, for capacitor circuits) for resistive, inductive, and ca-pacitive circuits in 8.3% methane-air atmospheres. The data presented quantify the explosion hazard created when low-power electronic devices catastrophically fail in an explosive mine atmosphere. Previous litera-ture dealt with levels of probability between 10-3 and 10-4. This re-port extends the probability data to levels as low as 10-7. This study has verified that when the probability of ignition, PI, is plotted on a log-log coordinate system versus the current (or voltage), a continuous, straight-line relationship is formed. An interesting result that can be statistically hypothesized is that at some low level of igniting current the ignition process ceases altogether.

Jan 1, 1988

By W. D. Riley

The Bureau of Mines is conducting research on methods for the rapid identification and sorting of mixed scrap metals and alloys so that domestic scrap resources can be fully utilized. One method, spark testing, is the examination of the pattern of sparks that results when a metal or alloy is ground on an abrasive wheel. This technique requires experienced sorters. Bureau researchers have shown that spectrophotometric methods can be used in lieu of the highly skilled sorter. The spectra of a mild steel, an HSLA steel, several stainless steels, and four nickel-base alloys have been measured. Differences in the spectra that are sufficient for identification are apparent.

Jan 1, 1985