Search Documents

By Heine Kenworthy

"INTRODUCTION In 1930 the Shenandoah-Dives Mining Co. near Silverton, Colo., put into operation a newly erected, 300-ton selective flotation plant to mill complex ores from its nearby mine. The operation was a steady producer and was enlarged to treat 600 to 800 tons a day. In 1942 the company opened and started milling an area in the mine containing semioxidized ore. The valuable mineral content of this ore was considerably higher than in, the straight sulfide ore previously handled alone. The mixture of clean sulfide and semi-oxidized ore was difficult to treat; consequently, tailing losses, especially with respect to lead, were high. A few years later, in order to study the possibilities of obtaining higher recoveries by a modification of the mill flow sheet, a 1,200-pound sample of mill, feed, taken over a period of several days by the company, was submitted to the Mississippi Valley Experiment Sta¬tion for testing-. Although this sample proved to contain more than twice as much lead as the average yearly mill feed, the same problem of recovering the oxidized values was present.A résumé of the ore-dressing treatment used in the Shenandoah-Dives mill follows. After crushing, the ore passes through a ball mill, the minus 5-mesh discharge of which is distributed to three tables. A finished lead concentrate is made on the tables, and the table tailing goes to the classifier which is in closed circuit with the ball mill. The classifier overflow is treated -by flotation to obtain a bulk sulfide concentrate at a relatively coarse size. The bulk concentrate is thickened and reground to about 95 percent minus 325-mesh before flotation treatment to separate a lead-copper and a zinc concentrate. A typical monthly average showed that the table concentrate contained about 45 percent lead, 1 percent copper, 4 percent zinc, 12 ounces of gold, and 40 ounces of silver; that the lead flotation concentrate contained '35 percent load, 6 percent copper, 7 percent zinc, 3.5 ounces of gold, and 50 ounces of silver; and that the zinc flotation concentrate contained 2 percent lead, 0.5 percent copper, 60 percent zinc, 0.15 ounces of gold, and 4 ounces of silver. Recoveries in salable products were roughly b5 percent of the lead, 70 percent of the copper, 45 percent of the zinc, 85 percent of the gold, and b5 percent of the silver."

May 1, 1948

By N. S. Dalal, A. H. Hoffman, X. Shi, D. E. Banks, J. K. H. Ma, Y. Rojanasakul

Excessive production of reactive oxygen radicals by alveolar macrophages is proposed to play an important role in oxidative lung injury. A major product of oxygen radical formation is the highly reactive hydroxyl radical (•OH) generated via a biologic Fenton reaction. In addition to its known ability to induce lipid peroxidation, recent studies have suggested that the •OH may exert its cytotoxic effect through the alteration of [Ca2+], homeostasis. To test this potential mechanism as well as to investigate the relationship between •OH and Ca" overloading in cytotoxic injury, isolated rat alveolar macrophages were exposed to externally generated radical system, H2O2 (0.01 to 1 mM) and Fe (1 mM) and their [Ca2+] levels and cell injury were monitored using quantitative fluorescence microscopy with the aid of the specific Ca" indicator, Fura-2, and membrane integrity indicator, propidium iodide. Electron spin resonance measurements using the spin trap 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) confirmed the production of the .OH radical by this system. Upon the addition of the radicals, the macrophages displayed a rapid initial rise in [Ca2+] which was followed by a slower but more pronounced [Ca2+], elevation that reached a level 3 to 5 times higher than the basal level. This process preceded cell death as evident by nuclear propidium iodide fluorescence. Depletion of extracellular Ca" inhibited both the [Ca2+], response and cell injury. Preincubation of the cells with the Ca" channel blocker verapamil or .0H radical scavenger mannitol similarly inhibited the [Ca2+], rise and loss of viability. Firefly luciferase assay of cellular ATP content demonstrated that the alterations in [Ca2+], following .0H treatment preceded the depletion of ATP. Changes in membrane potential caused by Na* substitution with K* had no significant effect on either the unstimulated or stimulated [Ca"], levels. Taken together, these measurements indicate that .OH-induced injury in alveolar macrophages is associated with the alteration in [Ca2+], homeostasis. The mechanism of •OH-induced [Ca2+] loading is not due to nonspecific membrane damage or energy depletion, but mainly due to an increase in Ca2+ influx through Ca2+ selective channels. This Ca2+ over-load state as well as energy depletion caused by the oxidant may activate certain cellular degradative processes leading to cell injury and death.

Nov 1, 1995

By Richard G. Burdick

The Bureau of Mines conducted this research to determine the feasibility of using soil redox measurements, a relatively new method in mining geophysics, to locate or define a variety of conditions that are hazardous or otherwise of interest to the mining industry. The method was used in three widely separated areas in an attempt to de- fine subsurface concentrations of methane, the edges of coal-burn areas, and a hydrothermal vein set. Both a description of the method used and test cases are given in this report.

Jan 1, 1982

By A. Viksne

A series of tests were conducted by the Bureau of Mines to determine the best means of reducing noise generated by the detonating cord that is utilized for trunklines in quarry blasting. Ten different types of detonating cord were tested and evaluated for their acoustic qualities. The results of the investigation showed that noise levels produced by "low-core-load-per-foot" detonating cord "not covered" were lower than those produced by "high-core-load-per-foot" detonating cord covered with 6 inches of unconsolidated material.

Jan 1, 1972

By Jack D. Ramsdell

The objective of this investigation was to make a preliminary evaluation of titanium-vanadium-zirconium, alloys using room-temperature tensile properties as criteria for selecting promising alloys for future critical studies. Arc-melted titanium-vanadium-zirconium alloys ranging in composition from 5 to 20 a/o (atomic-percent) vanadium and 5 to 30 a/o zirconium, were investigated to evaluate hardness, hot workability, and room-temperature tensile properties. Metallographic examination coupled with hardness measurements were used to follow structural changes and aging response. Room-temperature tensile properties were criteria for evaluating mechanical and engineering properties of the alloys.

Jan 1, 1960

By C. J. Cohen, L. A. Dahners

"SUMMARYA method has been developed for surveying, drill holes without lowering into the hole any surveying equipment other than an etch tube. The orientation of the rods at the collar of the hole is maintained as the etch tube is lowered. The attitude of the etch ellipse in depth with respect to the rod orientation at the collar can then be observed. This relationship permits the bearing of the hole in depth to he calculated. The rod orientation is maintained during the lowering by means of a pair of alinement clamps. One clamp is fastened to the top of each rod as the rod is coupled and is removed when the alinement has been transferred to the other clamp at the top of the next succeeding rod. A particular advantage of this survey technique is that surveys can be readily made in magnetic country rock.PRINCIPLE OF THE TECHNIQUEAn axial lamina of the column of drill roes is the lamina in which one fiber would be the centerline of the rods. In the new survey technique, the rods are fed into the hole in such a manner that the axial lamina of each successive rod maintains its position at the collar of the hole. In depth, as the rods bend in following the drill hole, the axial laminae also bend. The lamina that was originally vertical will, in general, be tilted away from the vertical. The trace of this lamina is marked on the glass etch tube before the tube is lowered in the hole. The axial lamina that becomes vertical at the survey station is recognized as that axial lamina which contains the long axis of the etch ellipse. The angle between the lamina originally vertical and the lamina vertical at the survey station is thus measurable. When the vertical axial lamina at one survey station has been determined by the etch ellipse at that station, angle R between this lamina and the vertical axial lamina at the next survey station becomes measurable also. By moans of angle R, and dip angles D1 and D2 at the two stations, the change in bearing (z) of the drill hole between the two stations can be calculated."

Aug 1, 1944

By L. C. Marchont

This Bureau of Mines report tabulates data on nitrogen-gas reservoirs and isolated occurrences of inert gases in several Williston basin oilfields. Recoverable reserves of nitrogen gas in the Minnelusa nitrogen interval within the areas of five oilfields on the Nesson anticline in North Dakota are estimated at about 1.27 trillion standard cubic feet, based on computer analyses of logs from over 300 wells. This volume of nitrogen represents a large source of high-pressure inert gas and warrants consideration of possible application in oil-production operations. Drill-stem tests made in two of the fields indicated that nitrogen can be produced at rates up to 28 million cubic feet per day.

Jan 1, 1966

By E. G. Erspamer

Laboratory investigations were made by the Bureau of Mines on ore containing the sulfides of both mercury and antimony to develop a method or methods for the economic recovery of mercury metal and the concurrent recovery of antimony as metal or salts,. If standard mercury-recovery techniques are applied to such ores, the antimony content interferes with the effective production of mercury metal; further-more, the antimony is lost. This report presents the results of tests on a sample of cinnabar-stibnite ore from the Red Devil mine near Sleitmute, Alaska. Red Devil ore was chosen for the investigation because it is purported to be typical of ores of the Kuskokwim River area, which, in their aggregate, constitute large potential reserves of mercury and antimony. Studies included petrographic, spectrographic, and chemical analyses, gravity-separation tests, bulk flotation of mercury and antimony sulfides, differential flotation, leaching, and furnacing of crude ore and of flotation concentrate.

Jan 1, 1956

By W. W. Adams

"The present world-wide demand for increased production in all branches of essential industry involves a matter of vital concern t persons engaged in the mining industry, namely, the productive capacity of the individual mine employee. This applies particularly to coal-mining, upon which other industries so largely depend.The folded and faulted condition of the coal beds in some countries, as well as the thinness and depth of the seams, the adaptability to the beds of available mining machines and equipment are factors which cannot be overlooked in determining what increase in individual output may be looked for in any given country. This subject, while of fundamental importance, can only be referred to in a paper of this length, the primary object here being merely to present a comparative tatamant of individual output under prevailing conditions.The quantity of coal produced by a miner does not accurately indicate the miner's capacity as a workman, not only because of the natural conditions referred to above that limit his annual output, but also because of human factors which may possibly, however, be controlled, such as the demand for coal, the car supply, use of labor-saving machinery, number of days worked during the year, accidents in the mine, etc. It will, however, be an aid in answering the important question as to how and where the immediate need for coal throughout the world may best be surlier, if we examine the output of the miners in the important coal-producing countries over a period of years.Complete official information for recent years is, for several countries, jacking, particularly for France, Austria, and Prussia, but partial data from unofficial sources may be used to show the individual output of the miners in these countries."

Jul 1, 1920

By John C. Ferm

This report contains a summary of Phase I and complete results of Phase II portions of a study of geologic factors associated with roof falls in mines on the Pocahontas #3 coal seam in southern West Virginia and southwestern Virginia. Principal objectives of Phase I was the selection of five mines that best portrayed the spectrum of roof and mining conditions and Phase II consisted of a measurement and documentation program for each of the five mines. The documentation measurement program included reconnaissance mapping, detailed mapping, joint measurements and coring roof rock. 1.2 PHASE I RESULTS The results of Phase I consisted of the selection of the following five mines for detailed study: Virginia Pocahontas #3 (Island Creek Coal Company), Bishop (Consolidation Coal Company), Shannon Branch (Allied Chemical Company), Keystone II (Eastern Associated Coal Company) and Macalpine-East Gulf (Westmorelenad Coal Company). In addition, Phase I results, which were based on questionnaire data, indicated that the kind of rock in the roof --gray sandstone, crystallized sandstone, laminated sandstone and shale, grey shale, slickensided shale, and rider seams could be associated with good and bad top areas. Also presence of vertical separations, bolt length, entry and cross-cut width, length and torque on bolts and depth of overburden seemed to be related factors. These data provided a focus for the Phase II measurement program.

Jan 1, 1975

By Lloyd Carpenter

Eighteen elements were determined spectrochemically in vanadium metal and its compounds in the general range of 1 to 1,000 ppm by means of spark-ignited unidirectional arc excitation. The samples were converted to vanadium pentoxide and combined with a mixture of graphite, lithium carbonate, and gallium oxide. For the molybdenum determination, the oxidized samples were mixed with sodium chloride and packed in copper electrodes. Average precision of the method was 15.6 percent relative standard deviation and relative error was 4.4 percent.

Jan 1, 1963

By John B. Gayle

The probable inadequacy of physical tests of coke for the purposes for which they are made has been a subject for discussion for many years. However, little has been published in this connection, even though most workers in the field believe that the physical properties of coke are of major importance in its utilization in the steel and allied industries. In fact, the reproducibility of the recognized tests is largely unknown or can only be approximated. This situation occasions many difficulties when attempts are made to judge the coke-production qualities of various coals or coal blends. During World War II the Coke Production Committee, composed of representatives from industry and the Solid Fuels Administration, concluded that study of existing testing methods and possible improvements would be of material assistance in answering questions relating to coke quality. Since that time the Bureau of Mines has taken samples of coke produced in industrial slot-type coke ovens in connection with studies aimed at extending coking-coal reserves by adding to the list of sources known to be suitable for this purpose. Testing procedures on these cokes were arranged so that the data obtained would yield information on (1) the degree of precision of tests commonly used in the industry, (2) the causes of the known poor reproducibility in several of the physical tests, and (3) possible improvements or modifications of existing physical testing procedures.

Jan 1, 1953

By Thomas E. Green

A combined solvent extract ion-spectrophotometric method for the determination of as little as 1 ppm of copper in tungsten metal or tungstic oxide has been developed and evaluated. Metallic samples are converted to tungstic oxide by treatment with hydrofluoric and nitric acids. The oxide is then dissolved in sodium hydroxide, and the copper is extracted as the colored neocuproine complex. Total elapsed time for the analysis is approximately 1-1/2 days; however, actual working time for a group of six or eight determinations is less than 4 hours. Precision at the 2-ppm level is better than 0.1 ppm.

Jan 1, 1963

By E. C. Lane

During the past 15 years the Bureau of Mines has made and published several hundred analyses of typical petroleums and has developed a system of interpreting the analyses and of classifying crude oils. In describing crude petroleum frequent reference is made to the "base" of the oil, a usage the petroleum industry has found convenient. As part of its general study of the characteristics of crude oils, therefore, the Bureau of Mines has developed a system of classifying them according to "base." This system as first published in 1927 was limited to four classes and in its original form is no longer considered adequate. Since the system was first published the Bureau has analyzed a large number of crude oil, including representative samples from nearly every important producing field in the world, and has found that the system of classification could be revised and amplified to advantage. The revised system is presented herein.

Jan 1, 1935

By Jr. Joyce

This report describes sulfatization of nickeliferous laterites from Puerto Rico and the Philippines for recovery of water-soluble nickel and cobalt sulfates. Temperatures ranging from 665 C to 710 C and a 10-percent sulfur dioxide-air reaction gas were employed during batch-roasting tests and during continuous countercurrent treatment in a 2-inch-diameter shaft furnace. A maximum of 69 percent of the nickel and 76 percent of the cobalt were recovered from one sample of Puerto Rican laterite, and a maximum of 96 percent of the nickel and 91 percent of the cobalt were recovered from the Philippine laterite.

Jan 1, 1965

By G. W. Birge

Twenty-eight samples, representing the Pittsburgh, Lower Kittanning, Stockton-Lewiston, Coalburg, Winifrede, Cedar Grove, Peerless, No. 2 Gas, Powellton, and Eagle beds, were carbonized by the Bureau of Mines--American Gas Association (BM-AGA) method, and yields of products and physical properties of cokes were determined. Expanding characteristics of 22 of the samples were determined in the Bureau of Mines sole-heated oven. The Kanawha County coals tested were high-volatile A bituminous in rank, with dry, mineral-matter- free fixed- carbon contents ranging from 53.9 to 66.3 percent. With few exceptions, they were chemically satisfactory for metallurgical use, and most of the coke-strength indexes were within the industrially accepted range for high-volatile blending coals.

Jan 1, 1963

By William H. Lesser

Never before have mine managers in the anthracite region of Pennsylvania been so seriously concerned about the rising cost of pumping mine water. Many of them know that future pumping charges may affect their operating profits adversely to an extent that will make it necessary to abandon some mines. Increased pumping charges in the anthracite industry are currently comparable in importance with higher mining costs; in fact, profitable operation of some mines depends not only upon the cost of mining coal but also upon whether they can be kept free from water at reasonable cost. Pumping charges are relatively low during the early development of a mine, but they increase rapidly as development progresses. Numerous crop falls, strippings, and. abandoned adjacent properties contribute unfavorably to the volume of water produced during mining. The foregoing conditions and the existence of large underground pools below existing mining levels present water problems of such magnitude and cost that some mine owners cannot continue to operate profitably.

Jan 1, 1950

By Robert L. Mentch

CADMIUM is one of the metals apparently destined to remain relatively scarce. The en tire supply of primary cadmium is recovered as a byproduct, concurrently with the treatment of ores of other metals. Development of the cadmium industry is attributed to metallurgical improvements in the zinc industry; output depends almost wholly upon zinc production. Cadmium is a metal of specialized uses where its superior performance has developed a strong, expanding demand. The supply, however, has been relatively unresponsive to price because of its byproduct nature. Cadmium's outstanding properties would assure it a manyfold greater market if more were available at lower prices.

Jan 1, 1958

By J. E. Zeilinger, John Nagy, Irving Hartman

"INTRODUCTION Experience and research have shown that an effective way to reduce structural damage from explosions is to provide adequate pressure-relief vents in the walls of equipment and buildings within which explosions might occur. In general, free or unrestricted openings represent the most efficient type of vent. However, in many manufacturing operations it is impractical to use free vents, and it becomes necessary to cover the openings with diaphragms or blow-out disks, hinged panels, or other devices, in order to give protection against weather changes, to prevent the efflux of dusts or vapors from equipment during normal operations, or for other reasons.A few data on the pressure-relieving capacities of hinged panels and a paper diaphragm were published in Bureau of Mines Report of Investigations 3924,4/ which covered the first phase of the dust-explosion venting study made by the Bureau. The present report describes recent experiments that were made to determine the relative effectiveness of an unrestricted vent and 22 types of closures, including various paper, cloth, and metal-foil diaphragms, hinged doors or panels, and several kinds of scored and unscored glass panes.The tests showed that many of the vent closures were effective in releasing the explosions rapidly during their incipient stage, so that the development of destructive pressures was prevented. Vents of this type should prove useful in safeguarding industrial equipment from severe explosion damage. The experiments disclosed that the venting capacities of the diaphragms are approximately inversely proportional to their static bursting strengths."

Jan 1, 1950

By A. E. J. Gallagher

This report summarizes the results of flotation studies conducted by the Federal Bureau of Mines on samples of extremely fine-grained lead-zinc sulfide ores. Samples from five ore deposits in the Pine Creek area, Coeur d'Alene district, Idaho, and one deposit in the Metaline district, Washington, were studied at the Albany Metallurgy Research Center to determine the recovery of sulfide lead and zinc by flotation. During the investigation it was found that flotation could be effectively applied to the selective recovery of exceedingly fine-grained lead and zinc sulfide minerals. Separation of galena and sphalerite was obtained on pulps ground through 1,600-mesh, in which most of the particles were smaller than 5 microns. Selectivity and recovery of minerals in this fine size range were enhanced by use of a chemical dye, diphenylthiocarbazone, as a galena promoter. Although unsuccessful on one ore, application of the dye in treatment of two other very fine-grained ores yielded lead concentrates containing over 62 percent Pb at recoveries in excess of 85 percent. More than 55 percent of the lead in these concentrates occurred as particles smaller than 2 microns.

Jan 1, 1961