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By Henry P. Wheeler

Natural gas was first stored underground in Welland, County, Ontario Province, Canada, in 1915.3/ The following year natural gas in the United States was first stored underground successfully in the Zoar field near Buffalo, N, Y. Only three additional storage fields were in use in the United States in 1930, but by 1940 the number had increased to over 30, and since that time growth has been more rapid. At least 80 fields, with a combined storage capacity of 440,828 MM c. f ., were being utilized by 1949.4 / In May 1952, 142 storage projects having a capacity of 915,000 MM c.f. were in operation .5/ These fields are distributed from New York to California--from Michigan to Texas. In the Appalachian region alone, there are 101 storage fields with a combined capacity exceeding 526,000 MM cu. ft. Why Natural Gas is Stored Natural gas is stored in order to be readily available to meet the needs of consumers.

Jan 1, 1952

By Gregory M. Molinda

The Bureau of Mines conducted an investigation into the occurrence of outbursts of salt known to be responsible for explosions, fatalities, and damage in domal salt mines. The purpose of the investigation was to develop a basis for predicting these outbursts based on geologic and associated physical properties of salt. The investigation was conducted at the Cote Blanche salt mine in southern Louisiana. Because outbursts are the primary mode of methane emission into the mine, more than 80 outbursts, ranging in size from 1 to 50 ft in diameter have been mapped. These outbursts generally are aligned and elongate parallel to the direction of salt layering. More than 200 salt samples, both random and selected, were tested for methane content. It was found that outburst zones are well correlated with high methane content. Detailed mapping also revealed that the zones are well defined, with salt crystal size abruptly increasing upon entry into the zone. The intensity of folding and kinking of the salt layering within the outburst zone also appears to increase. An interbedded sand layer occurring throughout the mine does not appear to be a significant source of methane. However, fine-grained salt may be related to outburst occurrence.

Jan 1, 1988

By Lisa Steiner, Robin Burgess-Limerick

In 2004, there were 646 underground coal mines in the USA employing 37,445 miners. These mines reported 3556 injuries to MSHA that year - 17% were associated with bolting machines (593 injuries), 8% with continuous miners (283 injuries), and 4% each with Scoop/LHD (1 51 injuries), shuttle cars (134 injuries), and personnel transport (145 injuries). The use of the frequency of reported injuries for the prioritization of risk control strategies has limitations because of the tendency to underestimate the importance of relatively rare but high-consequence events. Injury reports also underestimate the contribution of risk factors such as whole body vibration, which have a long-term cumulative contribution to an elevated risk of injury. However, taking these limitations into consideration, the results of the injury narrative analysis suggest the following hazards as the highest priority for elimination or control: • rock falling from supported roof • inadvertent or incorrect operation of bolting controls • handling continuous miner cable • collisions while driving LHD/Scoop, shuttle cars and personnel transport • rough road while driving or traveling in LHD/Scoop, SC & PT

By Donna L. Anderson

This U.S. Bureau of Mines report discusses the status of a laser-based guidance system to provide position and heading feedback and closed-loop control of tramming maneuvers for a continuous mining machine. The system has been developed and tested at the Bureau, and is now being prepared for underground experiments. The system hardware includes laser scanners, a sensor communication network, and host computer hardware. The system software includes a position and heading computation module and a tram control module. The description of the software includes discussions of laser data acquisition, error compensation methods, position and heading determination, safety checking for continuous miner tramming, and closed-loop tram control. The accuracy of the laser scanner's data, the reliability of the lasers in a dusty environment, and the system's accuracy on tracking the position and heading of the continuous mining machine are shown in the results of experiments performed at the Bureau. Conclusions are stated based on these experimental results, and further work to improve the system performance and prepare for underground testing is discussed.

Jan 1, 1990

By Martin A. Elliott

"INTRODUCTION During the recent war the Bureau of Mines was requested to obtain in¬formation on the temperature at which ammonium nitrate mixed with certa: contaminants would react rapidly. This information was desired in connection with an investigation of an explosion that had occurred during the evaporation, by air agitation, of volutions containing ammonium nitrate in which compressor oil that might have passed the filters was suspected of being a contaminant.During the course of this work it was found that mixtures of ammonium nitrate and zinc reacted rapidly at comparatively low temperatures: and since zinc could not positively be eliminated as a contaminant in the explosion in question, a series of tests was carried out, not only with mixtures of ammonium nitrate and compressor oil but also ammonium nitrate and zinc with and without oil. A few experiments were made with metals other than zinc.The investigation was not as extensive as might have been desired, owing to limitations -in time. The results are presented at this time in view of their current interest in connection with the Texas City disaster, in which a large quantity of ammonium nitrate detonated in the holds of two ships."

Mar 1, 1948

The head loss data for coal slurries over a range of concentrations and velocities and the laboratory screen analysis were selected as areas for investigation in the data analysis performed. The analysis resulted in the following: (1) Size distributions for the coal used in the horizontal pipeline tests were fitted to the Rosin - Rammler distribution function. Each of the fits was significant. Corresponding Rosin - Rammler parameters were obtained which were introduced into the regression analysis. (2) A regression equation was obtained which predicts the slurry head loss of 1-inch by 0 coal slurries ranging in volumetric concentration from 20 to 40 percent and line velocities from 1 to 14 feet per second as a function of the square of velocity. The addition of the term for concentration in the regression equation did not contribute significantly c head loss.

Jan 1, 1972

By E. G. King

Enthalpy increments above 298 K were determined by the Bureau of Mines for magnesium hydroxide (brucite) between 298 and 900 K by the method of drop calorimetry. Enthalpy and entropy increments from this investigation were combined with other data from the literature to calculate absolute entropies, free energy functions, enthalpies of formation, Gibbs energies of formation, and equilibrium constants of formation from 298 to 900 K. By the use of published PVT data for water, a table of Gibbs energy change was given for the reaction MgO (periclase) + H2O = Mg(OH)2 (brucite) as a function of temperature and pressure.

Jan 1, 1975

By J. W. Eckerd

Metal production rates of 42 to 45 tons per day were obtained with hollow-core anthracite briquets in an experimental blast furnace. Tuyere pressures were about the same for both coke and briquet operations, but from 150 to 175 pounds more of briquets were required per ton of metal than were needed with coke. Furnace operations were comparatively smooth, furnace hanging occurring less often than in previous tests with anthracite briquets. Dust production was substantially higher than with coke, however, and metal quality could not be controlled by corrective burdening and moisture control.

Jan 1, 1968

By Robert P. Vinson, Fred N. Kissell

This report describes three coal mine ventilation studies by the Bureau of Mines in which sulfur hexafluoride (SFG) was used as a tracer gas. One of these studies was conducted to determine air movement and leakage in a sealed area. Another was run to determine the ventilation efficiency of a bleeder system. Finally, a study was made of air leakage across permanent stoppings of parallel intake airways. These studies proved sulfur hexafluoride to be a useful addition to the equipment commonly used in coal mine ventilation analysis.

Jan 1, 1976

By T. C. Atchison

This report describes a mobile laboratory designed and constructed by the Bureau of Mines in 1950 to meet the needs of an experimental blasting research program. The laboratory has facilities for making; film recordings of 16 simultaneous transient electrical signals over a broad range of amplitude, frequency, and duration. The signals are recorded with specially designed oscilloscopes and high-speed drum cameras. Each of the 16 channels records on a separate strip of 35-millimeter film by using interchangeable input units, transducers having different sensitivities and output impedances can be accommodated. The laboratory can be used to record both steady-state and transient phenomena originating as electrical voltages or capable of being converted to electrical voltages by appropriate transducers. Thus, the laboratory can, be used in studying various types of vibration problems or high-speed phenomena, such as ground and building vibrations, machinery vibrations, airborne vibrations, electrical-circuit switching phenomena, millisecond timing, and seismic phenomena occurring when rock is broken by explosives.

Jan 1, 1956

By W. W. Adams, V. E. Wrenn

"Production of explosives in the United States during the calendar year 1936, as represented by reports of sales by manufacturing companies, totaled 391,604,500 pounds, an increase of 27 percent over the amount produced during 1935. This quantity included 81,698,375 pounds of black blasting powder (granular and pellet), 262,047,106 pounds of high explosives other than permissibles, and 47,859,019 pounds of permissible 5/ explosives.The manufacturers' reports to the Bureau of Mines classify the sales of explosives according to five main classes of work in connection with which the explosives were used.Coal mines used 87 percent of the total amount of black blasting powder sold, bituminous-coal mines 79 percent, and anthracite mines 8 percent; coal mines also consumed 98 percent of all permissible explosives and 9 percent of the high explosives other than permissibles. The coal-mining industry consumed 16 percent more explosives in 1936 than in the preceding year, the increase at bituminous mines being 21 percent and that at anthracite mines 4 percent.Metal mines used 29 percent of the high explosives other than permissibles and less than 1 percent of the black blasting powder and permissible explosives. The total quantity of the three classes of explosives used in metal mining in 1936 was 36 percent more than the quantity so used in 1935."

Jul 1, 1937

By Jerry L. Huiatt

An accurate and reproducible procedure was developed using the gas-liquid chromatograph to quantitatively measure oleic acid on flotation products and in flotation water phases. The method comprised extraction of the oleic acid from the mineral surfaces with alcoholic NaOH, esterification of the extracted oleate, and chromatography of the methyl ester with an internal standard. Quantitative analysis of oleic acid on flotation products from test tube and bench-scale flotation tests with pure minerals and with natural ores proved the applicability of the method on a variety of minerals. The accountability of oleic acid added was 100 percent, ±5 percent.

Jan 1, 1968

By J. H. Russell

A mathematical modeling method was developed by the U.S. Bureau of Mines for the prediction of the principal equilibrium species in the solvent extraction of nickel. Models were developed for the extraction of nickel from ammoniacal sulfate and carbonate solutions with commercial oxime extractants. Independent variables in the research were nickel concentration, ionic strength, pH of the initial aqueous phase, and extract ants and their concentrations in the organic phase. Results from laboratory shakeout tests compared fairly well with predictions of the equilibrium concentrations of nickel and pH values. For example, the loading of nickel onto the extractant was predicted on average within ±27 pct of the measured values, and the pH to within ± 0.17 pH unit.

Jan 1, 1991

By A. J. Rambosek

An evaluation of diamond-bit performance data accumulated from core drilling in quartzite shows that core recovery and physical characteristics of drill bits and diamonds have economic significance. Relatively inexpensive, low-quality, small Congo diamonds will perform as well as, or better than, other diamonds used as drill bart. M-type bits set with oriented Congo diamonds provide those engaged in core drilling with near optimum combination. Various factors that affect bit performance, including size of diamonds, size and type of bits, grade or quality of diamonds, and percentage of core recovered, are evaluated by means of tables, charts, and discussion.

Jan 1, 1958

By W. C. McBee

A family of modified-sulfur cements has been developed by the Bureau of Mines for the preparation of construction materials with improved properties. Various types of sulfur cements were prepared by reacting sulfur with mixtures of dicyclopentadiene (DCPD) and oligomers of cyclopentadiene (CPD). Durable cements were prepared with structural characteristics ranging from rigid to flexible. These cements were used to prepare corrosion-resistant materials for use in a wide variety of industrial applications where resistance to acidic and salt conditions is needed. These materials were prepared as rigid concretes, flexible pavings, spray coatings, and grouts. Production of modified-sulfur cements in a commercial-size plant was demonstrated.

Jan 1, 1981

By M. J. Reasor, M. DiMatteo, J. M. Antonini, K. Van Dyke, Z. Ye

"The inhalation of silica has been shown to produce a dramatic inflammatory and toxic response within the lungs of humans and laboratory animals. A variety of cellular and biochemical parameters are used to assess the silica-induced lung injury. The purpose of this paper is to introduce the use of luminok:Jependent chemiluminescence as a new method to study inflammation in both phagocytic cells and lung tissue recovered from silicaexposed animals. Chemiluminescence, or the emission of light, accompanies the release of reactive forms of oxygen when phagocytic cells are challenged. In this study, male Fischer 344 rats were intratracheally instilled with either silica (10 mg/100 g bw) or saline vehicle. One day after the instillations. a marked increase in the chemiluminescence was observed in the lung tissue and bronchoalveolar lavage cells recovered from the silica- treated animals when compared with the saline controls. The light reaction was markedly decreased by either superoxide dismutase or N-nitro-Larginine methyl ester hydrochloride. Superoxide dismutase is involved in the enzymatic breakdown of superoxide anion. while N-nitro-L-arginine methyl ester hydrocholoride, a nitric oxide synthase inhibitor, prevents the formation of nitric oxide. When superoxide anion and nitric oxide react. they form the highly oxidizing substance peroxynitrite. This study then implicates peroxynitrite as an agent that may be responsible for some of the oxidant lung injury that is associated with silica exposure. The use of luminol-dependent chemiluminescence may prove valuable as a method to measure the earliest events in the inflammatory process. and may be an adjunct in studying the mechanisms that produce inflammation. - Environ Health Perspect 102(Suppl 10):37-42 (1994) IntroductionResearch on inflammation has not produced a method that links the initial events of the process to the controlling events. Rather, a variety of parameters are measured that are the result of and not the basis of the inflammatory reaction. Parameters such as tissue weight, edema, blood flow, enzyme and protein release, or production of metabolites (prostaglandins, leukotrienes) have been used extensively. A method is needed that could be applied to cells of a particular type, groups of cells of different types, and even tissue, in an attempt to study the kinetics of the inflammation as well as being sensitive enough to monitor the early events of the process . Since inflammation is so complicated, the relationship between the control of the initial events and the oxidation process has never been explained nor studied in any derail."

Dec 1, 1995

By Charles L. Kimbell

Bulk carriers, freighters, and tankers are the three classes of seagoing vessels engaged in transporting mineral commodities. However, vessels in these classes are not wholly devoted to mineral commodity transport, as seen in tables 16 through 22. Bulk carriers move considerable tonnages of agricultural products as well as crude minerals, their concentrates, mineral fertilizers, and the like. Freighters, owing to their great variety, can be devoted wholly to hauling mineral products or wholly to non mineral goods, as well as carrying mixed mineral commodities and non mineral commodities. They include general cargo ships, full container ships, partial container ships, roll-on/roll-off ships, and barge carriers. Tankers, although largely engaged in moving crude oil and refinery products, also transport liquid chemicals, molasses, wine, liquefied natural gas, and other fluids. Table 16 shows the distribution of the world's merchant fleet by vessel type in terms of the number of vessels, their gross tonnage, and their deadweight tonnage. The increase of nearly 1.5 % in the number of vessels between 1990 and 1991 compared with a 2.7% growth in gross tonnage and a nearly 2.3 % increase in deadweight tonnage points to an increase in the average size of vessels. Of the four categories of vessels reported, all showed increases in number and in deadweight tonnage between 1990 and 1991 except for "other," and on the gross tonnage basis, all groups registered increases. Although physical characteristics of vessels such as size, draft, crew requirements, type of propulsion system, ratio of gross tonnage to cargo tonnage, and fuel costs have undeniable influences on shipping industry performance, problems of and changes in the quantity and types of materials moved also significantly affect the shipping sector of the world economy, and thus have a bearing on the minerals sector of that aggregate. Unfortunately, comprehensive global data reflecting changes in these critical variables are not published.

Jan 1, 1993

By C. M. McCulloch

A series of geological surveys were completed in six coal mines in connection with a Bureau of Mines research program on methane control. The aim of these surveys was twofold: First, to study the overall geology of the coalbed, and second to use the resulting data to evaluate the influence of the geological characteristics of the coalbed on safe and efficient coal extraction. This report explains the advantages of geologic maps and fence diagrams in coal mining, and how the knowledge gained from such geologic investigations of mines can help control many underground problems.

Jan 1, 1975

By J. P. Baur

The sensitivity of radiochemical techniques makes possible the study of the initial-stage sulfuric acid leaching kinetics of chalcopyrite and other copper sulfide minerals. This Bureau of Mines study of the initial leaching of chalcopyrite used techniques to evaluate the molecular and electrochemical processes. High-grade Transvaal chalcopyrite was neutron-irradiated in a TRIGA reactor4 to produce radioisotopes copper-64, iron-59, and sulfur-35. Dissolution rates were measured in the time interval zero to 60 minutes, during which time significant anomalies were observed. First was an initial period of rapid dissolution lasting a few minutes; second, an arrest or ?plateau? region usually lasting from 6 to 10 minutes; third, a second period of dissolution of lesser rate than the first. The effects of solution variables such as pH, oxygen partial pressure, and ferric ion concentration at different temperatures were measured.

Jan 1, 1974

By W. H. Eddy

The Bureau of Mines conducted laboratory batch and continuous flotation processing tests on waste granite fines from South Carolina to determine the possibility of recovering high-quality feldspar and glass sand. Three flotation systems were used for removal of the iron-bearing biotite: Two employed an alkaline anionic-cationic circuit and the third employed an acid cationic circuit. Commercial-grade products were obtained when the remaining biotite was magnetically removed from the feldspar and quartz concentrates. Continuous flotation processing yielded a feldspar concentrate containing, in percent, 3.60 Na20, 5.60 K20, and 2.25 Ca0, with recoveries of 75.3, 66.6, and 72.6 percent, respectively. The feldspar tailing was high quality glass sand containing 98.0 percent Si02 and 0.025 percent Fe203; about 60 percent of the quartz was recovered.

Jan 1, 1972