Search Documents

By Kenneth H. Johnston

Information on oil and water production, volume of water injected, core analyses, and well completion data was collected on 28 Red Fork sand water-flood projects for comparison and evaluation of results. An average water injection efficiency of 35 percent, an average water-injected to oil-produced ratio of 16.8:1, and an average loss outside the flood pattern of approximately 45 percent of the injected fluid resulted in an oil recovery to January 1, 1969, of only 5.6 percent of the pore volume, or 9.1 percent of the initial stock-tank oil in place. The principal causes of poor oil recovery from these projects are the losses of large quantities of injection water from the flood patterns through oriented, natural fracture systems or zones of high permeability and excessive channeling of injection fluids from input wells to oil wells. For more efficient operation and a higher percentage of oil recovery from the Red Fork sand and other low-permeability-sand waterflood projects, directional orientation of both induced-and natural-fracture systems should be determined during early development. The success of a low-permeability-sand waterflood project depends to a large extent upon the orientation of the injection wells with the fracture system.

Jan 1, 1970

By J. Whyatt

A variety of dynamic failure cases with regional impact were described at a bump symposium held in 1958. These types of events, while rare, are of particular interest because their ability to impact a large area has disaster potential. These cases can be grouped into two broad classes of events by mechanism. These are (1) slip along steeply dipping faults and (2) fracturing of strong strata above, or below, the coal seam. Both failure modes produce dynamic or ?shock? loads on the perimeter (roof, rib, floor) of mine openings. Special consideration should be given to these failure modes in planning of deep coal mines since their occurrence is not within the professional experience of many contemporary workers, and their potential is not evaluated by many of the analysis tools commonly used to evaluate hazards in coal mine plans.

Jan 1, 2009

By Charles W. Huggins

The Bureau of Mines investigated palygorskite, a natural asbestiform material, to accumulate knowledge that might serve as a foundation for future synthesis of a similar material. Unit cell, chemical analysis, DTA, TGA, optical constants, and electron microscopy data were obtained. Selected palygorskite samples of bettor than 97-percent purity were used to obtain this information. Chemical analysis revealed the following formula: (OH2)4 (OH)2 Ca0.01Fe0.02K0 .c3Mg2.10A12.00Si7.93020.3.91 H2O. The optical constants for sodium light are a = 1.522; S = 1.530; ?=1.533; biaxially (-). The following orthorhomibic unit cell constants were determined: ao = 12.690 A, Z = 2, bo = 17.857 A, Dx = 2.327. co = 5.207 A, Identical diffraction patterns resulted from the three palygorskite samples that were studied. X-ray, chemical, DTA, TGA, and optical data were compared with literature values for similar fibrous materials. X-ray diffraction lines were indexed. Several electron micrographs were made to compare the structures of palygorskite and attapulgite with that of chrysotile. The micrographs revealed extremely short laths for attapulgite, very long flexible laths for palygorskite, and tubular structure for chrysotile.

Jan 1, 1962

By C. M. Frost

Crude shale oil produced during in situ retorting by the Bureau of Mines at Rock Springs, Wyo., was refined by three schemes. In the first, the crude oil was fractionated to raw naphtha and 400° F+ residuum. The residuum was hydrogenated over cobalt molybdate catalyst at 815° F and 1,100 psig. The blended raw and 160°-400° F hydrogenated naphthas were hydrodenitrified and then catalytically reformed. The 400° F+ hydrogenated oil was catalytically cracked. In the second scheme, the crude was hydrogenated over nickel-tungsten catalyst at 800° F and 1,500 psig. The hydrogenated fractions were processed by methods used in the first scheme. The third scheme resembled the second but, prior to hydrogenation, the crude was "hydrostabilized" over cobalt molybdate at 500° F and 500 psig. Yields of reformate and cat-cracked gasoline as volume-percents of the crude, and research-method octane numbers (with 3 ml TEL) for the three methods were as follows: First method, 32 pet reformate, 90 octane; 19.5 pct cracked gasoline, 99.2 octane. Second method, 29 pet reformate, 81.1 octane; 21.3 pct cracked gasoline, 99.6 octane. Third method, 28.2 pet reformate, 86 octane; 28.7 pct cracked gasoline, 95.9 octane.

Jan 1, 1974

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of certain solvents and hydraulic fluids used in underground mining operations. The following halogenated solvents were studied in view of their usefulness and their flame retardant property: tetrachloroethylene, C12C = CC12; 1, 1, 2-trichloroethane, CIH2CCHC12: and trichloroethylene, C12C = CHC1. The hydraulic fluids studied were representative of five groups approved by the Mine Safety and Health Administration for underground operation, namely: glycol-water solutions, mineral oil-water emulsions, synthetics other than phosphate esters, synthetic phosphate esters, and mixtures of phosphate esters with mineral oils and other ingredients. It was observed that the partially halogenated solvents present a greater potential toxic hazard than the fully halogenated materials, due not only to the easy production of hydrogen chloride but also to their ease of oxidation leading to the formation of phosgene and carbon monoxide. The pure phosphate esters exhibited the best thermal oxidative stability of the five groups of hydraulic fluids tested. A fluid containing phosphate esters mixed with mineral oils and other unidentified ingredients appeared to be the most hazardous On the basis that it produced very toxic acrolein and phosphine.

Jan 1, 1980

By R. E. Brown

The objective of this Bureau of Mines study was a laboratory-scale evaluation of the sodium sulfate refining process for removing copper from molten ferrous scrap. Maximum copper removal is achieved in carbon-saturated melts at 1,300° C. Low carbon concentrations and higher temperatures result in a less efficient copper removal and an increased sulfur concentration in the iron. Sodium sulfate refining significantly lowers the concentration of aluminum, manganese, and silicon; however, the copper removal efficiency is adversely affected by the presence of manganese and silicon. Compared with other reagents tested, sodium sulfide-forming slags were found to be the most suitable for both copper removal and sulfur control. The sulfur content of the refined iron was higher in tests conducted in acid-type refractory crucibles. Earlier studies showed that tin, a significant metallurgical impurity, is not removed by the sulfate process. During the present investigation, results showed that chlorination, using organic solid sources of chlorine, reduced the tin concentration to acceptable levels in molten iron.

Jan 1, 1975

Lower costs associated with hands-on training in donning and using a CSE ,self-contained self-rescuer (SCSR). Background In June 1987, the Mine Safety and Heath Administration (MSHA) issued an Emergency Temporary Standard (ETS) requiring that all persons entering underground coal mines must be given bands-on SCSR training. The ETS will shortly be replaced by a new standard requiring this hands-on training. Bureau of Mines research has shown that the most effective means of delivering this training is to have the trainee go through a six-step training procedure while in a kneeling position. Once the miner has looped the neckstrap over his or her head, he or she completes the donning sequence in this order: 1) activate oxygen; 2) insert mouthpiece; 3) put on nose clips; 4) put on goggles; 5) adjust neck and waist straps; and 6) replace miner's cap and prepare to move out. This procedure is repeated until the miner demonstrates that he or she is proficient at the task.

Jan 1, 1988

Reduce face methane concentrations and help prevent miners from working under unsupported roof while moving the curtain. Approach Use water sprays on the continuous mining machine to move and direct air to the face, and also provide appropriate installation guidelines for the most effective use of the system. I n laboratory tests and under actual mining conditions, the spray fan has proved an effective means of ventilation. Recent observations in the field, however, have shown that not enough technical information is widely available on proper installation of the spray fan. This Technology News is designed to rectify that situation by providing a concise guide for spray fan installation. How the System Works Good ventilation is essential for methane control. The spray fan system repositions regular water sprays to help the normal exhaust face ventilation do a more effective job. The various water sprays help in many ways: 1. Side sprays bring clean air along the side of the miner into the off-curtain corner.

Jan 1, 1983

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By Joseph A. DeCarlo

This publication presents a tabulation of oven-and beehive-coke plants in the United States as well as pertinent statistical data on the number, capacity, kind, and condition of the ovens. Coke is an essential raw material in pig-iron production and the coal-chemical materials produced during the coking process are used to manufacture fertilizers, paints, plastics, synthetic rubber, explosives, detergents, nylon, pharmaceuticals; dyes, and many other products necessary to the high standard of living in this country. In table 1 the oven-coke plants in the United States on December 31, 1959, are listed. This shows the name and address of the company, location of the plant, classification or type of ownership, number and type of ovens, annual coke capacity, and the coal-chemical materials produced. The "furnace" plants I are those owned by iron and steel companies and most of them are integrated with blast furnaces to facilitate transportation of raw materials for steel making. Furnace plants represented 87 percent of the total coking capacity and their average annual capacity was 1. 3 million tons. The "merchant" plants are those associated with chemical companies, gas utilities, as well as those that produce metallurgical, industrial, and residential-heating grades of coke and coal-chemical materials for sale on the open market. These coke plants are smaller than furnace plants and in 1959 their average coke capacity was only 520 thousand tons annually. On December 3l, 1959, there were 54 furnace and 20 merchant oven-coke plants in existence in the United States.

Jan 1, 1960

By Robert F. Chaiken, Alex C. Smith

INTRODUCTION The National Institute for Occupational Safety and Health (NIOSH) at its Pittsburgh Research Laboratory (PRC) is interested in the application of water mist sprays to extinguish diesel fie1 fires in underground mine diesel refueling areas. To this end experimental studies have been carried out on the extinguishment of diesel fuel fires at PRL's large enclosed fire suppression facility (FSP) at its Lake Lynn Laboratory (LLL). Two sizes of shallow fuel pans (3x3 ft and 5x7 ft) contained the fires, and a number of commercial mist spray nozzles (at roof locations) and spray/fire locations were tested (52 fires in all). Visual observations of the pool fire extinguishment process by the overhead sprays with an infra-red sensitive videocom suggests that there are two distinct actions involved in extinguishment due to two different transport mechanisms by which the water droplets can enter the fire plume. First, is a direct injection of water droplets into the plume from overhead. This is believed to involve larger water drops and leads to an extinguishment time of several minutes. Second, is an indirect injection process involving small water drops which are entrained in the sideways air flow that feeds oxygen to the fire. This second process apparently leads to relatively fast quenching of the fire in less than 1 minute - a highly useful attribute for a fire protection system. This paper describes a relatively simple parametric model for the indirect water injection process, and defines the critical spray conditions for achieving rapid quenching of the pool fire. While the model is consistent with the pool fire data obtained to date, the PRL studies are continuing with more complex pool fire scenarios. It remains to be seen if this simple parametric approach applies to these future fire tests. THEORETICAL Critical Drop Size In the two-dimensional representation of figure I, an oil pool fire is considered to be a cone whose base is the vaporizing liquid oil surface having an area n?, above which exists a fire plume diffusion flame) of height, L. The rising plume induces a horizontal air flow into the side of the plume supplying the oxygen necessary for propagating gas phase combustion reactions. Water droplets suspended in the air around the plume will tend to follow the horizontal air flows into the plume. The rate of air entrainment by the plume will be determined by the overall combustion reaction which is assumed to be

By J. W. Paul

The tests described herein were made in the course of a series of experiments on coal-mine ventilation factors which the Bureau of Mines has beep; conducting for the past two years at its experimental mine near Bruceton, Pa. The object of the present tests was to determine the leakage of two air locks which had been placed in the experimental mine as hart of the equipment for tests on friction factors. Position of the Doors. The first or inner lock gas across the aircourse between No. 1 and No. 2 left butt entries, and forced the air through these butts. An air-measuring suction in No. 1 butt determined tae volume passing at tent point.

Jan 1, 1924

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of selected ingredients employed in the formulation and manufacture of conveyor belts. This work was done to supplement similar studies of samples from finished conveyor belts and thus provide basic data for correlation of the potential toxic behavior of a finished belt with that of the individual ingredients. This report covers the study of (1) basic polymers (styrene-butadiene, neoprene), (2) reinforcing fibers (Nylon 6,6, Dacron, viscose rayon), (3) flame-retardant plasticizers (tritolyl phosphate-isomeric mixture, tri-p-tolyl phosphate, tributyl phosphate, tris (dichloropropyl) phosphate), (4) plasticizers (diphenylphtha1ate, di-(2-ethylhexyl) sebacate), and (5) a vulcanization accelerator (2-mercaptobenzothiazole).

Jan 1, 1977

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

TEST DECK - ALTIMETER SURVEY WITHOUT ALTMETER TEMPERATURE CORRECTION 1 BAS 8: 22 1391 1391 53. 49.

Jan 1, 1977

Table 1.-Employment and injury experience at metal mines in the United States, by industry groups [ ]

Jan 1, 1967

By T. J. Ballard

"The Hog Creek mine, in lot 92 of the 17th district in Towns County, Georgia, was examined in 1890 by F. P. King, who reported the existence there of a 4-foot vein of corundum. The mine is about 2 miles west of Hiawassee, on the southern side of Ramey Mountain. Ed Burch, of Hog Creek, holds the surface rights, and the mineral rights appear to be vested in the heirs of William R. McConnell, who formerly owned and prospected the property.Examination by the Bureau of Mines showed the workings to be caved, but it was thought advisable to open the mine and uncover the reported vein. The Bureau's work consisted, of trenching and cleaning out the pits and shaft.William R. McConnell, the former owner, prospected the property in about 1890. At some tine during that operation, the prospect was visited by Francis P. Kings a geologist with the Georgia Geological Survey.3/King reported that a 4-foot vein of corundum was exposed g feet below the surface in the main cut and was opened for 20 feet along the strike. He also reported that the so-called ""Georgia rubies"" were taken from this mine.The main mine is about 2,000 feet- north of Hoc Creek on a timbered southern slope of Ramey Mountain. It lies at an altitude of about 2,100 feet, approximately 100 feet above the high-water level of the Catuga reservoir, which floods Hog Creek to a quarter of a mile above its confluence with the Hiawassee River. The nearest water is a small branch about 1,000 feet to the west.Chlorite schist is the principal host rock. It has been intruded by irregular masses of a very herd periodtite rock possibly troctolite. The schist near the surface is extremely weathered, presenting white and red laminations parallel to the schistosity. At a depth of 40 feet in the cross-cut it appears as a fine-grained green-chlorite schist. The schist strikes about N. 350 E. and dips 800 to the southeast.No corundum vein was found, and if any existed it must have been mined out after King's visit. In the pit, about 15 feet west of the shaft, approximately 150 pounds of zoisite and an occasiona1 small crystal of corundum were found imbedded in schist about 18 feet below the surface, near hard, dense troctolite."

Mar 1, 1946

By Launa G. Mallett, Kathleen M. Kowalski, Michael J. Brnich

The characteristics of leaders under the duress of an emergency are important in the development of emergency planning, training, and in the management of an actual emergency. Knowledge of human behavior is an important component in the formation of emergency strategies. The U.S. Bureau of Mines analyzed the leadership behavior in three underground mine fire escapes. The subjects described their escapes during open-ended interviews. Data were coded according to: (1) evidence of leadership behavior, (2) evidence of lack of leadership behavior, and (3) characteristics of the individual in each group who led the subjects out of the mines. This paper discusses the profile of six individual leadership characteristics which emerged from the data.

This is the final report on Project CR-102 under the auspices of the Department of Environmental Resources, Commonwealth of Pennsylvania .1 The project was activated on January 5, 1970, with financial support from Bituminous Coal Research, Inc., the Pennsylvania Coal Research Board, and the Water Quality Office of the Environmental Protection Agency (WQO-EPA)2 through Grant 14010 EST to the Commonwealth of Pennsylvania Work on the project was conducted according to the procedures outlined in BCR Research Program Proposal RPP-164R, dated April 24, 1969, and a subsequent Revulsion of Scope, dated February 25, 1970. This report covers the entire project period from January 5, 1970, through March 25, 1971.

Jan 1, 1971

By Lloyd A. Morley, Alan M. Christman

This report was prepared by the Department of Mineral Engineering, The Pennsylvania State University, University Park, Pennsylvania under USBM Grant Number G0155102. The grant was initiated under the Metal and Nonmetal Health and Safety Research Program. It was administered under the technical direction of the Pittsburgh Mining and Safety Research Center with Mr. Roger L. King acting as the Technical Project Officer. Mr. J. A. Herickes was the contract administrator for the Bureau of Mines. This report is a summary of the work recently completed as part of this grant during the period February 1, 1975 to July 31, 1976. This report was submitted by the authors on August 31, 1976.

Jan 1, 1976

By L. A. Haas

The degree of reduction of various silica-graphite mixtures was studied in a batch reactor to determine optimum physical conditions for maximizing the carbothermic reduction of silica. The extent of interaction was determined for reactant mixtures in loose powder and briquet forms at pressures less than 0.01 torr and temperatures up to 1,445° C. Molar ratios were varied from 0.05 to 6.5 with maximum reaction at a ratio of about 1.5. The solid-solid reaction did not appear to involve gaseous intermediates. The extent of reaction better correlated with the number of interparticle contacts than with the true surface area of the reactants. Carbonized dextrose was a better reductant than graphite.

Jan 1, 1968