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By W. R. Matizamhuka

"The consolidation of nano-sized composite materials presents a challenge using conventional hot pressing methods. Spark plasma sintering (SPS) technology has shown great promise in the successful sintering of nanoreinforced composite materials. This qualitative review seeks to impart knowledge gathered, and progress made over the years on the consolidation of nanocomposite materials using SPS technology. The review is aimed at introducing this technology to the South African science and engineering community. Emphasis is on improving the mechanical properties of structural ceramic nanocomposite materials, which over the years have shown great promise in a wide range of applications, including transport, energy, mining, and the environment. Although success has been achieved within the laboratory for research purposes, there are still great opportunities to commercialize the technology for the production of larger components with more complex shapes.IntroductionSince the pioneering work of Niihara and Nakahira (1991) over a decade ago there have been extensive attempts to harness the potential of nanostructural metals, ceramics, and composites in a number of applications (Niihara and Nakahira, 1991; Selaho et al., 1997; Sekino and Niihara, 1995; Khalil, 2012; Aalund, 2008). It is generally realized that reducing the grain size of materials to nanoscale offers a significant improvement in properties. Attempts to synthesize nanostructured compacts by conventional sintering methods have not succeeded owing to the uncontrollable high rates of grain growth driven by long dwelling times at the sintering temperatures and large powder surface areas (Sergueeva et al., 2009; Gua, Khora, and Chieng, 2004; Tang et al., 2009). Following the development of spark plasma sintering (SPS) technology, it is now possible to process nanocrystalline materials with controlled grain growth. SPS, also referred to as the field-assisted sintering technique (FAST) or pulsed electric current sintering (PECS), was developed with the aim of improving on the well-established hot pressing (HP) technology (Kessel and Hennicke, 2007;"

Jan 1, 2016

EMMES Sampling Conference BACKGROUND & INTRODUCTION ?Impala acquires toll material to supplement production from ROM ?Toll material consists of filter cake, slurry and catalysts ?Samples are collected to determine the commercial values of the lots ?Slurry deliveries projected to remain relatively constant at 120tons dry solids per month, whereas filter cake deliveries set to increase five-fold to 800 tons dry solids per month ?Due to projected increase in toll material, new sampling and offloading facility presently under construction at Impala ?Presentation will cover two projects aimed at reducing the uncertainty associated with sampling of toll deliveries ?i.e. slurries and filter cake.

Jan 1, 2005

By B. Moritz, W. Schubert, E. A. Button

ABSTRACT: Geological conditions associated with alpine environments in combination with high overburden in many tunnelling projects lead to squeezing behaviour. The main problems associated with such conditions include large deformations, overstressing of supports, and lack of face stability. In the past during Alpine tunnelling the problem of large displacements incompatible with rockbolt – shotcrete support systems have been solved by leaving gaps in the lining to accommodate excessive deformations. In the late nineties, yielding elements have been developed, which are integrated into the lining. The paper deals with the basic concept, the design and the application of that system, which has been successfully used in several Alpine tunnels. ZUSAMMENFASSUNG: Die geologischen Verhältnisse in den Alpen führen bei großer Überlagerung häufig zu starken Deformationen während des Baues von Tunneln. Die großen Verformungen führen in vielen Fällen zu einer Überbeanspruchung des Ausbaues und Problemen mit der Ortsbruststabilität. Früher ist man dem Problem der Unverträglichkeit des Ausbaues mit den hohen Dehnungen durch Freilassen von Deformationschlitzen im Spritzbeton begegnet. Vor etwa 10 Jahren wurden duktile Stahlelemente entwickelt, welche in die Spritzbetonschale integriert werden. Der Beitrag beschäftigt sich mit dem Konzept, der Planung und der Ausführung. RÉSUMÉ: Les conditions géologiques dans les Alpes conduisent fréquemment lors d'un grand recouvrement à des déformations fortes pendant la construction des tunnels. Les grandes déformations conduisent dans beaucoup de cas à une surtension du revêtement et à des problèmes avec la stabilité de front de taille. On a fait face plus tôt au problème de l'incompatibilité du revêtement avec les extensions élevées par libérer des rainures dans le béton projeté. Il y a environ 10 ans, des éléments sidérurgiques ductiles qui sont intégrés dans le béton projeté ont été développés. La contribution s'occupe de concept, de planification et de mise en oeuvre.

Jan 1, 2003

By K. M. Seiler

Automation in mining requires accurate maps of road networks on site. Because roads on open-cut mines are dynamic in nature and continuously changing, manually updating road maps is tedious and error-prone. This paper investigates the possibility of automatically deriving an accurate representation of the road network using GPS data available from haul trucks operating on site. We present an overview of approaches proposed in literature and test the performance of publicly available methods on GPS data collected from trucks operating on site. Based on shortcomings seen in all tested algorithms, a post-processing step is developed which geometrically analyses the created road map for artefacts typical of free-drive areas on mine sites and significantly improves the quality of the final road network graph.

Sep 1, 2021

By J. Ungar, F. X. McGarvey

The selectivity of ion-exchange sites varies with the matrix of the polymer, the nature of the site. and the method of application. The effect of these variables on the recovery of uranium is examined. with particular attention to vinyl pyridine and to symmetrical and asymmetrical quaternary ammonium sites. The effect, on the loading. of high concentrations of chlorides in the liquors is discussed. and other components of the liquors that may cause fouling of the resin are also considered. The discussion is supported by the results of tests conducted on various types of resins. The economics of the process is discussed briefly.

Jan 1, 1981

By J. Ungar, F. X. McGarvey

The selectivity of ion-exchange sites varies with the matrix of the polymer, the nature of the site. and the method of application. The effect of these variables on the recovery of uranium is examined. with particular attention to vinyl pyridine and to symmetrical and asymmetrical quaternary ammonium sites. The effect, on the loading. of high concentrations of chlorides in the liquors is discussed. and other components of the liquors that may cause fouling of the resin are also considered. The discussion is supported by the results of tests conducted on various types of resins. The economics of the process is discussed briefly.

Jan 1, 1981

By J. M. Stewart, C. H. Wyndham

Suggested thermal stress limits for safe physiological strain in underground environments by J. M. STEW ART M.Sc. (Eng) (Witwatersrand) (Visitor) and C. H. WYNDHAM M.B., D.Sc. (Witwatersrand), F.R.C.P. (Land) (Fellow) A comparison of safe temperature limits, based on Mitchell and Whillier's equations for specific cooling power (SCP), with similar limits determined experimentally shows the SCP-based limits to be unnecessarily conservative. It is argued that, while a small part of this conservatism may be attributed to an erroneous extrapolation of the heat transfer dependence on wind speed, the major part is probably due to the use of too Iowa limiting mean skin temperature in the calculation of SCP. A combination of Mitche/l's basic data with results available in the literature permits the derivation of modified heat transfer equations based on data that fully cover the range of wind speeds of interest. These equations, using a mean skin temperature of 36°C as the basis for the calculation of safe temperature limits, are then shown to agree favourably with those determined empirically. Furthermore, values of SCP based on these equations are shown to correlate reasonably well with wet kata readings, giving positive support to the wet kata thermometer as a heat stress meter.

Jan 8, 1975

By K. I. Afewu, L. C. Woollacott

The design of in-pulp adsorption vessels in the gold industry has, for the most part, been seen as a problem involving the suspension of fine particles o ore in a slurry. The need for the vessel to be designed as a mass-transfer contactor has received insufficient attention. The current series of papers addresses this need The previous paper considered the question of the scale dependence of the film transfer coefficient. This paper examines the mixing considerations that are relevant. A review of the literature and an examination of a limited set of data provide some insight into the mixing conditions needed for the dispersion of the particles of adsorbent. The mixing requirements for the suspension of the ore particles are also considered, and conclusions are drawn in regard to the design of mechanically agitated vessels for gold in-pulp adsorption circuits.

Jan 1, 1995

By M. J. Nicol, P. D. Scott

The kinetics of the non-oxidative dissolution in acids ofthe iron sulphides FeS, Fe-FeS, and Fe9S10 were studied by the use of rotating-disc electrodes of the various compounds. It was found that the rates of dissolution vary by orders of magnitude with changes in surface potential. The dissolution rates depend on non-integral orders of hydrogen-ion concentration, which in turn vary with potential. A mechanism based on the following premises is proposed to explain the kinetics of dissolution of the iron sulphides. (I) Only an FeS compound that is exactly stoichiometric dissolves in accordance with the accepted theory of ionic charge transfer. (2) Any non-stoichiometric iron-deficient iron sulphides must be reduced to exactly stoichiometric FeS before spontaneous non-oxidative dissolution can occur. The dissolution of Fe.S1o and slightly iron-deficient FeS compounds under open-circuit conditions occurs only when an oxidation reaction (usually the oxidation of hydrogen sulphide to elemental sulphur) can provide the electrons necessary for the production of exactly stoichiometric FeS. The establishment of such a mixed-potential system is the reason for the induction period that occurs during the dissolution of pyrrhotites in acids.

Jan 1, 1979

By M. D. G. Salamon

If a transition from one equilibrium state to another occurs during the course of mining, energy transfer takes place in the rock mass, which is assumed to be an elastic continuum. The energy components are defined as follows: the work done by external and body forces, W; the increase in stored energy in the mass, Uc; the strain energy in the rock mined during the transition, Urn; the work done on mine support or backfill, Ws; and the released energy, Wr. The energy balance is defined as (W + Urn) - (Uc + Ws) = Wr> 0, where the first set of components in parentheses represents the sources of energy, while that of the second corresponds to the known modes of energy expenditure and the component on the right is the unaccounted-for energy surplus, which must be released and dissipated in some form. The inequality Wr ~ Urn> 0 applies. Expressions for the energy components are derived first for the general case and then for the 'slit' modal used to simulate tabular excavations. Through specific examples, the importance of the progressive nature of mining is emphasized. The size of the steps used to enlarge the excavations appears to play a significant role in the mode of energy transfer. This observation forms the basis of the second paper in this series of two papers.

Jan 1, 1984

By G. P. N. Venter

A method of evaluating the possible effect of an industry on the environment is presented, and the method is illustrated by its application to a hypothetical problem. An analysis is offered based on an actual survey of four industrial sites in the Lydenburg area of the eastern Transvaal. The survey showed that there is a high incidence of potentially unfavourable conditions, and there is a distinct possibility that a topographically induced eddying motion will extend over the town and the industrial sites. This moving air could entrap air pollutants, resulting in high concentrations of pollutants over the town. It is concluded that none of the sites is suitable for industries that pollute the atmosphere.

Jan 1, 1978

By C Smit

SYNOPSIS A prototype collimated radiometric face scanner was tested in the Harmony Gold Mine. The results obtained during the pilot study indicate that in situ radiometric uranium assays are statistically indistinguishable from those obtained conventionally from channel chip samples. In addition, the study demonstrated that reasonably reliable gold estimates can be deduced from the radiometric measurements, by use of the ratio of gold to uranium within a mine. The instrumentation, calibration procedures, and background determination are described briefly.

Jan 1, 1985

By Karl-Heinz Obst, Juergen Stradtman

The importance of the chemical and physical properties of lime has been overlooked for years although the quality of lime plays an important role in the production of steel. With the introduction of the oxygen injection process these properties have been re-evaluated. The CaO, MgO, S, and P2O5 contents of lime are important, but so are the physical properties such as granulation, reactivity with respect to slag formation, and the degree of burning. Soft burnt lime enhances de-phosphorisation and de-sulphurisation, and facilitates the smelting process in general, mainly due to its large specific surface. Special lime, prepared as briquettes from quicklime and fluxes or as pellets from limestone and various fluxes with or without binding agents, clearly accelerates lime dissolution during the slag formation process, lowers the melting point, and enhances de-phosphorisation, de-sulphurisatlon, and de-carburisation even more than soft burnt lime. The introduction of special limes in the oxygen injection process for steel production has opened up new fields for commercial exploitation of slags as well as improved operational techniques.

By D. R. Young

Drilling exploration over the Wesizwe Platinum Limited?s Pilanesberg Project has identified the Merensky Reef at depths varying from 594 m to 1 552 m depth. Merensky Reef thickness varies from 0.05 m to 3.63 m and contains PGE(4) mineralization above a cut-off grade of 1.0 g/t over intersection widths of 0.95 m to 2.63 m. Four distinct facies types have been identified over the property, viz.1) Normal Merensky Reef, generally 1.2 m thick, bounded by thin top and basal chromitite layers and composed of upper feldspathic pyroxenite and lower feldspathic olivine pegmatoids containing base metal sulphide mineralization overlying poikilitic anorthosites. 2) Single chromitite Merensky Reef, generally0.15 m thick and usually devoid of internal silicate material, overlying variable stratigraphy containing significant base metal sulphide mineralization. 3) Detached Merensky Reef, generally1.0 m thick, bounded by thin top and basal chromitite layers and composed of feldspathic pyroxenite or pyroxenite containing base metal sulphide mineralization overlying Merensky Pyroxenite. 4) Normal footwall Merensky Reef, generally 1.8 m thick, bounded by thin top and basal chromitite layers and composed of feldspathic pyroxenite containing base metal sulphide mineralization overlying norites also containing significant base metal sulphide mineralization. The PGE(4) content?s (g/m2) distribution for the global intersection data appears to be lognormal, and conversion to lognormal space produces a near normal distribution which could be interpreted as a compound lognormal distribution. The mean PGE(4) contents estimated by these three different distributions are the same, and thus do not impact on the contained metal. Data for the Normal Merensky Reef facies type are sufficient to indicate that a normal distribution is followed for this facies type, and therefore does not need to be transformed to log space for estimation of the mean and the 90% confidence limits. A global evaluation based on all of the data is compared with a facies-weighted evaluation. The latter method is noted to provide a better definition of the associated estimation errors and thus potential classification of Mineral Resources. A valuation of $20.95 for Inferred and $41.90 for Indicated PGE(4) ounces is applied to both of the evaluations and compared. The global evaluation is considered to over-value the project by approximately 40%, thus indicating that valuations based on global summary sampling data that have a compound distribution may be materially flawed, and that cognizance of the underlying geology is crucial for unbiased valuation.

Jan 1, 2006

By T. Könighofer

Processing of copper-cobalt orebodies in Africa?s Copper Belt has received much recent attention with various flowsheet options being developed specifically for the refining of cobalt. The upfront leach and copper refining routes are well understood whereas the refining of cobalt is more complex, requiring numerous impurity removal steps to produce high purity metal. This paper describes an investigation into one of the possible processing steps in the refining of cobalt, namely, cobalt solvent extraction. The paper emphasizes the importance of upstream impurity removal to achieve the required cobalt solvent extraction feed composition. 18% (v/v) Cyanex 272 in an aliphatic diluents is used as the organic phase. The pH profiles in the various stages are evaluated in order to obtain a raffinate containing <10mg/l cobalt and with a low magnesium content reporting to the stripping section. The pH profile is also used to minimize the impurity deportment to the cobalt electrolyte. The effect of adding a pre-neutralization stage before feeding the organic phase to the extraction circuit is investigated. Zinc build-up in the stripping stages is also looked at. It is recommended for the purpose of this study that four extraction stages at an O:A ratio of 1 with a pH profile from 4.9 to 5.7 be employed. The pH is controlled with 40g/l NaOH. A pre-neutralization stage is required, where the organic phase is contacted with 10 M NaOH. Two scrubbing stages are recommended at an O:A ratio of 40, using the cobalt electrowinning advance electrolyte as the scrub liquor. Three strip stages are to be employed at an O:A ratio of 0.67.

Jan 1, 2009

By K. G. Lomberg, M. D. Lionnet

The Bafokeng Rasimone Platinum Mine (BRPM) is a joint venture between Rustenburg Platinum Mines Limited and Royal Bafokeng Resources (Pty) Ltd (Bafokeng). The mining lease has been granted over Boschkoppie 104JQ and is located approximately 10km south of the Pilanesberg Alkaline Complex. The Merensky Reef, which constitutes the principal ore body, is geologically complex. A relationship between its geological variability and the associated mineralisation has been established by defining a number of facies types. The Merensky Reef has been sub-divided into seven distinct facies types: the pegmatoidal facies, contact facies, FW1 pothole facies, FW3pothole facies, FW6 pothole facies, and FW7 pothole facies. The Merensky Reef, which does not form part of the potholed reef, has a large component of footwall mineralisation. The pothole facies, in contrast, has mineralisation located in the hangingwall. Statistical analysis of the facies types indicates that they are unique populations and hence need to be evaluated independently. The mining lease has distinct structural domains that have added additional complications to evaluation of the Merensky Reef. The Merensky facies on BRPM exhibit unique geological and statistical characteristics within well-defined structural blocks. Due to the extreme variability of the Merensky Reef on BRPM a unique approach has been developed, within Anglo Platinum, to evaluate the deposit. Mining cuts are defined and composited for the individual facies types, and then modelled individually by applying known geological controls. The resultant grade models are weighted based on statistical and local geological knowledge. The object of weighting the facies is to replicate the variability observed in the ore body. The introduction of stringent geological controls to the evaluation process has resulted in increased confidence in the in situgrades estimated as an input to the mine planning process

Jan 1, 2006

By J. A. Kinnaird, B. J. Youlton, K. L. Youlton

Methods for treating and processing refractory gold ores are well established. However, what is less well understood is how the formation of the gold-bearing deposits affects gold processing and extraction. In order to evaluate the effect of ore genesis on gold extraction a number of South African gold deposits were studied. These included complex Pilgrim’s Rest samples as well as refractory Fairview, Barbrook, and Consolidated Murchison samples. We found the refractory nature of gold ores is controlled by a limited number of well-understood mineralogical factors. Solid solution gold is linked to low temperature and pressure conditions in fine-grained sedimentary lithologies, while reactive pyrrhotite can form from hydrothermal fluids associated with mafic magmatic rocks. These formational controls can be used to identify and avoid complex deposits at a desktop study phase, or address and reduce complications further along the pipeline using early mineralogical studies.

Jun 1, 2021

By I. C. R. Gilchrist

A principal requirement in the design of a backfill transportation pipeline is the accurate prediction of the values of key slurry flow parameters. Input variables, such as particle size and solids concentration, are usually determined by the load-bearing requirements of the placed fill. It is therefore necessary to identify the optimum conditions of transport for a particular combination of input variables. This paper critically reviews the methods available to predict the values of flow parameters in slurry pipeline systems in the light of experimental data generated at a test facility. Particular reference is made to rod milled waste and deslimed tailings transport systems and, in the case of the former, it is shown that both pumping and load-bearing requirements can be optimized.

Jan 1, 1988

By Jürgen Antrekowitsch, Harald Osthof, Stefan Steinlechner

"In the case of feasibility assessments or feasibility studies, an important point of discussion is often how to calculate the capital (CAPEX) and operating expenditure (OPEX) of a plant. Generally, there is also the request to know how the CAPEX varies when the size of the plant is increased. Nowadays, many databases give an indication of specific equipment costs in relation to the production rate. These data are based on cost information from equipment suppliers and have to be continuously updated by the owner of the database. The approach presented here is a model which allows sizing of process equipment, for example a leach tank, based on process data in combination with the calculation of mechanical properties. Furthermore, it calculates the CAPEX based on construction material cost and adequate machining surcharges. Thus, a single cost model for a leach tank is adequate for both copper and other hydrometallurgical plants and stays valid with changing construction material prices. To summarize, the advantage of this model is the more versatile approach and thus the flexibility due to the inclusion of design aspects, process and mechanical engineering aspects and an updatable database. The database, which is in regard to material cost and is the basis for the cost estimation, is easily updatable from commonly accessible data. This model thus approaches the procedures of an engineering company when designing a plant and executing a cost calculation. INTRODUCTION Hydrometallurgy nowadays plays an important role in processing of primary and secondary resources. In copper metallurgy, hydrometallurgy accounts for roughly 20 % of worldwide primary production, especially in the case of oxide or low copper-containing ores. Zinc smelters changed their method of production from a pyrometallurgical-dominated concept decades ago to mainly hydrometallurgical routes today. Gold production processes using leaching, especially, have a long history without any development which would not be competitive if not based on hydrometallurgical concepts (Pawlek, 1983; Winnacker-Küchler, 2006)."

Jan 1, 2015

By P. Gonzalez

Minera La Parreña, S.A. de C.V., Milpillas operation is an underground mine designed to process 8 352 tons of ore per day for the recovery of copper through crushing, heap leaching, solvent extraction and electrowinning facilities. In order to optimize copper recovery during leaching, the ore is crushed to 13 mm and subjected to primary sampling every 15 minutes for metallurgical accounting. At the same particle size, primary sample goes to secondary sampling and then, the secondary sample is crushed to 2 mm before tertiary sampling. The tertiary sample is sent to laboratory where a final sample is obtained and pulverized to 106 microns for copper assay. This paper shows a review of sampling strategy focused on minimizing or eliminating sampling errors and an experiment designed to determine copper head grade profile as well as the best sampling frequency.

Jan 1, 2009