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By J. V. Calara, J. D. Miller

The sign of the surface potential for complex non-reactive ionic solids cannot be predicted solely from consideration of the hydration energy of gaseous ions which constitute the ionic lattice. Accurate analysis of these systems must involve the hydration energy of surface ions, which requires knowledge of the crystal structure, the identification of cleavage planes, and the calculation of binding energies of surface ions. Surface binding energies for ionic solids can be deter- mined if the Surface Madelung Constant is known. A computational technique was developed for the calculation of Madelung Constants for infinite lattices which gives excellent agreement with the values calculated by other more complicated methods reported in the literature. Extension of this technique permits the calculation of Surface Madelung Constants and binding energies of surface ions, ?Us, for semi-infinite solids. The hydration free energy of gaseous Ions, ?Fh, together with the calculated binding energy of surface ions, ?Us, allows calculation of the hydration energy of surface ions, ?Gh, as for the case of the ionic solid, MX:

Jan 1, 1976

This paper discusses how the link between design software tools and recycling models can be established in order to predict the recyclability of the car during the design phase, as well as to be able to apply design for recycling on a solid technological basis. Due to the complexity of the design of the car, optimisation of recycling can only be realised based on a sound technological basis, in which the dynamic and statistically distributed parameters affecting the recycling rate are described and understood. This paper gives a brief overview of the dynamic and recycling models, which are developed for optimisation of the recycling of the car and the calculation of recycling rates of the car in the design phase in view of EU legislation. Moreover the possibilities for modelling of shredding and liberation within the recycling system are discussed. The performance of experiments on a fundamental basis in order to collect statistically correct industrial data, supported by a closing mass balance, is referred to on the basis of a large scale industrial recycling experiment. It will be shown how design for recycling and environment can be supported by the sophisticated models as developed by the authors.

Jan 1, 2005

By S. A. F. Murrell, M. Hong, L. J. Bond

This paper investigates the propagation, interaction and scattering of explosively generated seismic waves with discontinuities in rock masses using numerical models which employ a finite difference method. The models consider 2-D systems and give a full solution including mode-conversion in the mid-frequency scattering region where feature dimensions are of the order of the wavelengths involved. The paper has two parts, the first of which considers wave propagation and diffraction by simulating an explosive body source in a half- space containing a step or a slot on the surface which represent a cliff and a rift valley that has dimensions of the order of the wavelengths in the source. The second part of the paper reports a hybrid technique which combines a perturbation method and the finite difference method for wave propagation again caused by an explosive body source in a 2-D half-space system but with a shallow surface obstacle, such as a smooth ridge, with elastic constants slightly different from bulk material and the slope of this surface topography are shallow. This hybrid technique is also reported being applied to a half-space with a horizontal void or insert.

Jan 1, 1986

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By John F. Spisak

Versatile living organisms, historically exploited as functionaries in the food processing, pharmaceutical and chemical industries, have not been successful in achieving similar or significant acceptance within the minerals industry. The current biotechnical revolution coupled with its expanded understanding, dictate that a flagging minerals industry reconsider the use of biotechnology in metallurgical applications. Living resources, either singly, in commensal association or in complex communities, are capable of duplicating fully integrated and complex processing functions. Organisms can mine and extract metals, detoxify chemical effluents and synthetically produce compounds. They have been criticized as exhibiting poor kinetics, excessive energy consumption and environmental sensitivity. However, expanding knowledge reveals that these organisms are surprisingly adaptable, variable and extremely durable. Applied biotechnology in specific cases offers favorable economic returns, environmental benefits and aesthetic value. Selective implementation of living systems can offer opportunities for reduced labor, increased productivity and technological advance. Success will not come easily. Capital must be risked, controversial decisions made and new ground plowed. Traditional, specialist thinkers will of necessity give way to interdisciplinary expertise and unorthodox methodology if success is to be achieved. Those who vigorously persevere, however, are likely to be rewarded with a dynamic and profitable new role in a restructured minerals industry.

Jan 1, 1985

By A. P. Schissler, S. Badr, U. Ozbay, M. D. G. Salamon

Yield pillars are used in deep coal longwall mines, where the depth of cover is so great that a conventional chain pillar design tends to be unsuccessful. The design of yield pillars in deep U.S. mines has been based mainly on experience, pressure arch theories, numerical modeling, and empirical methods that originated in the eastern U.S. coal mines. This paper offers field experience based guidelines for the design of yield pillars through analysis and evaluation of numerous case histories. Case histories of yield pillar applications were collated and critically reviewed to identify trends in data that can be used to formulate the design guidelines. Convincing trends observed in the case of successful case histories indicate that yield pillars should have a width to height ratio in the range from 2.8 to 6.0, a stability factor during development between 0.4 and 0.6, and shed between 94% to 98% of the cover and abutment load, as provided by the Carr-Wilson (1982) method. Also, yield pillars should be utilized in coalmines only where the roof and floor rock have a CMRR rating of 50 or better.

Jan 1, 2003

By C. H. Lee, F. Concha, L. G. Austin, P. T. Luckie

The Concha-Almendra batch-settling treatment for concentrated suspensions of single-diameter spheres has been modified. This modified version is used in the differential equations of simple batch settling of a particle size range of different density materials. The equations have been programmed for a finite difference solution, and a number of test cases have been analyzed. By cutting the settling column at a fixed fractional height, the material below this height can be treated as underflow and the material above as overflow. The predicted partition curves obtained from treating the settling in this way have Sharpness Indices in the range of 0.5 to 0.6, in the absence of dispersion effects. The Sharpness Indices decrease as dispersion increases. When the feed size distributions are of the Rosin-Rammler form, the partition curves (corrected for the bypass fraction) fit the Rosin-Rammler equation with reasonable accuracy. The predicted Sharpness Index of a component of a mixture of two materials of different densities was unchanged from that of the same materials settled alone. However, for the same, feed size distribution and volume fraction of solids in the feed, the heavier material settled faster, and the lighter settled slower, than when settled alone.

Jan 1, 1993

By H. Nematollahi

Numerous magnesite deposits are found in the south part of Khorasan state, east of Iran. During the past few years, production of high-grade magnesite ore was possible only by using selective mining method. The decreases of high-grade ore imply upgrading of the low-grade ore. To do so, the objective for the first phase is to obtain a material which contains less than 2.5% SiO2. The present study was carried out based on three different samples. The results obtained in laboratory indicate that the direct flotation of magnesite by fatty acids led to acceptable result.

Jan 1, 2003

By R. C. Beers, R. J. McKinley, R. D. Stewart

Preliminary test results at Occidental Research Corp.’s Irvine, CA, research facility indicate the viability of a new induced fluorescent sorting technique for preconcentration of limestone, coal, and oil shale. The patented “Oxylore”* process is a preconcentration stage that takes advantage of selective surface chemistry to label either ore or gangue particles with a fluorescent coating that can be detected by activation with ultraviolet light. The technology was originally developed by Ted Matthews (SME-AIME Fall Meeting, 1974, Preprint 74-B-328) and was acquired by Occidental in 1977. The firm has continued development of the process since its acquisition.

Jan 6, 1980

By F. Wendling, G. M. Peixoto, J. A. M. Cano

A brief introduction is made on the existence of sulfides in the top gas of the Midrex Shaft Furnace, giving consideration to the operation of the furnace and the liberation of sulfur, as well as its consequential effects on the reduction process. The text shows a study of sulfur distribution in the pellet, emphasizing the importance of this distribution in relation to the liberation of sulfur during the reduction. A study was made to determine the sulfur compounds that exist in the pellets, showing ways of controlling the sulfur distribution and reducing its liberation during reduction.

Jan 1, 1991

By A. D. Shuloyakov, V. A. Zukerman, G. A. Finkelstein, V. I. Kurets

Possibilities of electric pulse disintegration are discussed with emphasis on high selectivity of the process as compared to mechanical comminution methods especially when applied to polymineral ores. Physical explanation of this phenomenon is suggested. The authors present results of some experimental tests illustrating regularity of this phenomenon irrespective of origin of ores or dissemination pattern of valuable minerals including both dissipated and accessory minerals. Some operating plants applying this principle are described the plants used either for mineral research purposes or for obtaining pure monomineral fractions or for treatment of gems to be faceted. Obstacles for implementation of this technology are mentioned.

Jan 1, 1995

By M. Sagisaka

Coal is expected as one of the main energy sources for a long period because of vast deposits. However, two large barriers to utilize it are suggested, i.e. the carbon dioxide emissions and ash disposal. The authors chose principal methods and areas to utilize coal ash and analyzed the environmental impacts caused by the ash treatment considering the source of the ash. According to the analysis based on lifecycle thinking, an optimized ash treatment system can reduce the integrated environmental impact. It suggests that coal can carry out its role for several decades without disturbances from the point of ash treatment.

Jan 1, 2006

By K. P. Madhusudhanan, R. K. Bhatia, K. S. Narasimhan, R. N. Singh

A typical case study of a coal washery of capacity 500 t/h raw coal input has been presented and discussed with particular reference to the techno-economics for flotation column vis-a-vis the conventional flotation cells, keeping parameters like input capacity and product ash same. The results presented indicate that substitution of flotation cells by columns in a coal washery results in advantages of increased fine coal recovery, better quality of concentrates, lower capital and production costs etc.,. The effect of increasing the specific capacity of the column by design modifications on the cost benefit is also analysed.

Jan 1, 1988

By R. L. Grayson, T. L. Dickinson, C. G. Anderson

Sponsored by the EPA, USGS, DOE, and NSF through the Committee on Earth Resources, the National Research Council’s Committee on Material Flows Accounting of Natural Resources, Products, and Residuals, created in August 2002, studied the value that material flows accounting, which can track the flow of a material from the time it is extracted to its ultimate disposal, may provide for making better integrated economic, social, and environmental policy decisions. This could be a crucial technology for the mining industry to incorporate. This paper will recount the statement of tasks, the study process, and the science-based conclusions and recommendations reached.

Jan 1, 2004

By J. L. Post, L. Borer

Small seams of fibrous tremolite and actinolite commonly occur in many California counties. A number of larger seams of this fibrous material were mined from 1882 until about 1955. The fibers from these mines were used for making acid filters, battery cases and fire-resistant paint. With increasing population, new residential areas are being developed in the foothill regions, leading to increased contact with seams of fibrous amphiboles. These forms of asbestos can be particularly dangerous to human health. Thus, it is necessary to determine the locations of these mines and adjacent veins and to identify the specific amphibole minerals present.

Jan 1, 2003

By J. C. McLaughlin, Bill A. Hancock, David J. Meacham

Great Salt Lake Minerals (GSLM) uses flotation to utilize low grade harvest evaporites in the leaching/ crystallization process. A final potash product coloration problems was encountered that was attributed to AERO• 801s promoter - magnesium ion precipitation in flotation which carried into the dissolution/crystallization circuit. Bench studies resulted in changing 801s to 845 which provided acceptable product brightnesses and higher flotation potassium recoveries. This is a case history reviewing the unique GSLM processing scheme, the bench and plant work identifying the potash quality problem, the bench work and solution, and subsequent process study and circuit optimization efforts.

Jan 1, 1993

By J. W. Wilson, Y. Ding

In the ultrafine coal-cleaning process, small coal particles (-400 mesh) are produced during the pulverizing operation. After the coal-cleaning process, these ultrafine particles are very difficult to dewater and create problems in coal transportation, storage and handling at utility plants. Research on ultrafine coal dewatering and briquetting resulted in the development of a single-stage operation that is potentially more effective and economical than conventional thermal drying and briquetting processes. The final coal product has a moisture content of less than 15% and possesses high strength and water resistance that satisfies coal transportation, storage and handling requirements.

Jan 1, 1996

By B. Moudgil, M. Bogan

A bench-top centrifuge was used to study the consolidation behavior of phosphatic clays. A mathematical model (based on, first-order kinetics) was developed to describe the relationship between the void ratio (at any time) and the effective stress. The permeability of the sediment as a function of the void ratio is also described. The results of this analysis are then compared to data obtained by other consolidation testing methods. The centrifuge results indicate that consolidation data may be developed in a short period of time (hours) as compared to days or weeks when other techniques are used.

Jan 1, 1997

By M. M. Hajdasinski

In his recent paper, Torries (1998a) came to the defense of the much-criticized internal rate of return (IRR) as a project evaluation and ranking criterion. Torries also offered his own approach to the IRR-based project ranking, which he believes to be a more practical alternative to the conventional incremental-ranking approach, which Torries considers to be misleading. In an earlier paper (Hajdasinski, 2000), the author demonstrated that Torries' arguments vindicating the IRR concept are invalid. This paper provides logical and numerical evidence that the same is also true with regard to Torries' IRR based project-ranking approach.

Jan 1, 2000

By J. T. Gepford, K. A. Prisbrey, T. Scott, M. Spangler

Using neural networks for plant control is challenging. The objective was to show how to make a neural network effective, even with noise, lag times, and unmeasured disturbances in the plant. The procedure was to evaluate the neural network in a laboratory flotation vision system and in a plant refractory gold autoclave system. Although the resulting neural network easily conquered simple laboratory data, the noisy plant data was much more difficult, and adaptive linear models were equally effective. We concluded that the neural network needs support by combining it with other tools found in the best control packages.

Jan 1, 2000