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By Ying Mao, Zhancheng Guo, Long Ma, Huiqing Tang

"A new 2D computational fluid dynamic (CFD) model was developed for the gaseous reduction of iron ore fines in an innovative reactor-multilayer moving-fluidized bed. The solution of the proposed model was performed by integration of FLUENT and PHOENICS. Numerical results of cold state were compared with the experimental data and the agreement between them was good. A hot case-gaseous reduction of iron ore fines using syngas with this reactor was simulated using the present CFD mode. Results indicate that under the given simulation conditions, total pressure drop is 90 Pa less than that under cold state though the gas supply rate is increased about 4m3 under hot state. Gas temperature decreases from 1073 K at the bottom to 500 K at the top, Utilization efficiency of the gas reduction potential is about 27 %. For ore fines reduction, the final reduction fraction could reach 0. 70 and solid temperature 900 K.IntroductionWith the development of coal gasification technology, various coals could be converted to Syngas with air or steam. Therefore gaseous reduction of iron ore fmes becomes an acceptable alternative process for iron making besides blast furnace route[!] and moreover it still has some advantages in processing low grade iron ore fines[2]. Gaseous reduction using fluidized bed technologies is the most competitive in all direct reduction iron-making processes up to now. It has the advantage that ore fines can be directly charged to the process without prior treatment while its disadvantages are particle agglomeration and high gas/solid ratio[3]. To avoid these advantages, a new reactor, multilayer moving-fluidized bed reactor has been developed for carrying out the gaseous reduction. Hydrodynamic behaviors of gas and fines in the reactor were studied and the results were satisfying[4]. However, due to its unique structure of the multilayer moving-fluidized bed and unique gas-solid flow pattern, models of multiphase flow as IPSA, DPM and Eulerian Model could not give a satisfying solution. The current paper is developed a new CFD model and a new solution approach for simulation of the reactive gas-solid flow in the multilayer moving-fluidized bed for its optimization, design improvement and future scale-up."

Jan 1, 2013

By K. Krishnapisharody

A mathematical model has been developed to predict the interface dynamics and droplet generation of the buoyant phase in a two-fluid system. The model employs the well-known SIMPLE algorithm for obtaining flow fields and the Volume of Fluid (VOF) method, for interface tracking. The implementation of the model in water-oil systems, where the oil layer is placed above a recirculating water bath, is discussed. The evolution of the water-oil interface leading to the formation of oil droplets is computed realistically.

Jan 1, 2008

By Lanre Oshinowo

Computational Fluid Dynamics (CFD) is used in conjunction with process modelling at HATCH to achieve a superior level of confidence in the process design of hydrometallurgical process plants. The use of these tools to evaluate designs through virtual prototyping reduces the risks associated with making design decisions. This paper highlights the development of a co-simulation strategy at Hatch for the seamless integration of process modeling software addressing different scales (process time and space): flowsheet level models and .equipment level models. With co-simulation, the process design engineers can improve design accuracy, troubleshoot and optimize performance and influence decisions impacting equipment operation by representing specific unit operations in the flowsheet model software with detailed CFD models. Specifically, this paper will focus on the co-simulation of a Ni/Co high-pressure acid leach (HPAL) process including heaters/heat exchangers and flash system, autoclave and quench/scrubber system. The knowledge developed can be transferable to other processes.

Jan 1, 2004

By Suman Das, Justin J. Gambone, Rohan Bansal, Ranadip Acharya, Paul Cilino

"This paper focuses on generating a quantitative microstructure prediction model for Scanning Laser Epitaxy (SLE) process based on coupled flow-thermal modeling using Finite Volume method. SLE is a laser-based additive manufacturing process for the deposition of equiaxed, directionally solidified and single-crystal nickel superalloys through the melting of alloy powders onto superalloy substrates. In the current work, the detailed effects of natural and Marangoni convection on the flow field are studied and the results are analyzed in terms of the temperature gradient, vorticity parameter, melt pool dimensions and mushy region extent. The detailed property data of the processed superalloy and the laser scan path are incorporated in the model to predict the microstructure in realistic scenario. An optimization study is carried out to evaluate the critical parameter values at which the columnar-to-equiaxed and the oriented-tomisoriented transition take place. This work is sponsored by the Office of Naval Research through grant N00014-11-1-0670.IntroductionSLE is a laser-based additive manufacturing process for the creation of structures in equiaxed, directionally solidified and single-crystal nickel superalloys through the selective melting and resolidification of superalloy powders. In SLE, a tightly focused laser beam is guided by a highspeed galvanometer scanners allowing for tight control of the amount of energy being applied to the top of the powder bed, as well as the speed at which the melt pool moves across the substrate. Under the proper operating conditions and with sufficient substrate meltback, the solidification microstructure follows the morphology of the underlying substrate, allowing for directional and even SX growth.Several reports on the modeling aspects of laser cladding-based additive manufacturing approaches can be found in the literature. Approaches based on Finite Element Methods (FEM) and Finite Volume Methods (FVM) are employed for the thermal modeling of the system [1, 2]. Gaumann coupled the Columnar to Equiaxed Transition (CET) modeling with the Rosenthal solution in earlier work based on laser cladding [3]. Rappaz et. al. provided a detailed modeling of the microstructure/columnar orientation based on the solidification velocity and crystalline orientation [4]. This approach is based on the selection of the growth direction that closely follows the melt pool normal direction. Later on, substrate orientation is also taken into account [5, 6]."

Jan 1, 2013

By F. Rivard, L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. Retrofitting plasma torches in place of fuel oil burners lead to lower operating costs, capital cost and greenhouse gas emissions.INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes [!]. Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid start-up and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate [2]. Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates."

Jan 1, 2013

By N. Verbaan, E. Bourricaudy, M. Dry

"Starfield Resources is developing a novel circuit for the recovery of nickel, copper, cobalt, iron oxide, sulphuric acid and precious metals from the Ferguson Lake deposit in Nunavut, Canada. In this deposit, pentlandite is too finely disseminated in pyrrhotite for the production of a smelter-grade nickel concentrate at an acceptable nickel recovery, so established technology is not applicable and a novel chloride-based circuit is under development. The enabling aspect of this circuit is the hydrolysis of ferric chloride to hematite, releasing gaseous hydrochloric acid that is recycled. Conventional steps are used for separating and recovering the valuable metals from the chloride solution generated. This paper briefly outlines the circuit and presents the results of experimental work on the enabling steps, viz. the oxidation and hydrolysis of iron chloride to hematite and gaseous hydrochloric acid.IntroductionThe Ferguson Lake bulk sulphide ore body in Nunavut, Canada, owned by Starfield Resources Inc., contains significant amounts of base and precious metals but its mineralogy is such that it is not amenable to conventional processing. Pentlandite, for example, is too finely disseminated in pyrhhotite for even modem techniques such as fine grinding and improved flotation reagents to be effective [ 1] and extracting the value requires processing the entire bulk sulphide, including the pyrrhotite. To give the project a total green footprint, in terms of both carbon emissions and acid rock drainage, Starfield imposed the following requirements:• No reactive tailings to generate acid rock drainage.• No gaseous emissions other than normal atmospheric constituents.• No liquid effluents.• No regular consumption of fossil fuel.• High recoveries of all the valuable metals."

Jan 1, 2011

By C. Hennesmann, D. Maijer, S. L. Cockcroft, P. Yo

"Die cast aluminum wheels are one of the most difficult automotive castings to produce because of stringent cast surface and internal quality requirements. As part of a collaborative research agreement between researchers at the University of British Columbia and Canadian Auto Parts Toyota Incorporated, work has been underway to predict heat transport and porosity formation in die cast A356 wheels. The basic heat transfer equations have been solved using the commercial finite element package ABAQUS to which specialized routines have been added to predict porosity. Preliminary work on predicting porosity formation focused on using the Niyama parameter as a measure of the probability of porosity. The latest version of the model incorporates a new fundamentally based porosity criterion, which takes into account the effect of hydrogen concentration. The development of this model together with its application to a series of cylindrical test castings as well as a production cast wheel are presented.I. IntroductionDie cast aluminum wheels are one of the most difficult automotive castings to produce because of stringent cast surface and internal quality requirements. Microporosity, in particular, is a common defect that can adversely affect wheel quality. The mechanism of microporosity formation in aluminum alloys is complex owing to its dependence on the interaction of a number of phenomena occurring during solidification including the decrease in hydrogen solubility, the decrease in volume, the development of the solidification structure, and the increase in difficulty in interdendritic feeding [1]. As a result, the amount, size, and distribution of microporosity is affected by a large number of casting parameters including thermal variables, melt composition, grain structure, modification, and inclusion content, making optimization by trial-and-error methodologies difficult.The use of criteria functions, based on thermal conditions during casting, offers a relatively simple approach to predicting microporosity. In practical terms, they are useful because they provide a straightforward method of assessing the impact of varying casting parameters on porosity through various thermal parametersl21 such as thermal gradient, cooling rate, solidification time, and solidus velocity. Drawbacks of criteria functions include insensitivity to varying hydrogen concentration and the limitation to qualitative predictions. Consequently, in aluminum alloys, attempts have been made to develop models incorporating the effects of hydrogen gas and microstructure evolution. However, these types of models represent a significant increase in complexity and sacrifice the simplicity and ease of application of the thermally based criteria functions."

Jan 1, 2001

By Jin-yan TIE, Ke-xin JIAO, Qian Li, Hai-bin ZUO, Jian-Liang Zhang, Meng SHEN

This paper designs three factors such as temperature, pH, conductivity and three levels of orthogonal test. Temperature is a significant factor. However PH and conductivity are not significant through poor analysis. Further research is conducted on the temperature. Temperature stability is 50 . Suitable water velocity is 2.3m/s, which is calculated based on the largest part of the heat flux intensity and the corresponding water temperature should be controlled with 1.5. Meanwhile, water velocity increased has little effect on the heat transfer capabilities.

Jan 1, 2015

By A. J. Williams, T. N. Croft, M. Cross

"The computational modelling of extrusion and forging processes is now well established. In this work a novel approach is described which utilises finite volume methods on unstructured meshes. This technique can be used to solve simultaneously for fluid flow, heat transfer and non-linear solid mechanics and their interactions. The approach involves the solution of free surface non-Newtonian fluid flow equations in an Eulerian context to track the behaviour of the workpiece and its extrusion/forging, and the solution of the solid mechanics equations in the Lagrangian context to predict the deformation/stress behaviour of the die. Some preliminary examples of this approach will be discussed.IntroductionThe computational modelling of extrusion and forging processes is now well established. Within the last 20 years the finite element method has become the most commonly used technique to simulate metal forming processes [1]-[4]. The Lagrangian and Eulerian type of formulation have been the two major approaches to this problem.Lagrangian methods are efficient and suitable for handling non-linear problems in which small strains prevail, boundary conditions do not change with the course of deformation, and where mesh distortion is not a critical factor in the analysis. Unfortunately, the above points are essential to any accurate metal forming analysis. The problems of mesh distortion and element entanglement pose a serious drawback on the use of such methods. Some automatic remeshing techniques have been developed for Lagrangian finite element analyses of metal forming problems [5]-[7]. However, these methods are not robust and efficient enough to remedy the mesh distortion problems in general. An alternative is to update the mesh manually but this is not always possible, and even when it is feasible it involves major interaction by the user. In addition, remeshing is usually applied to the whole domain which is not necessary and increases CPU time. The complexities associated with remeshing also affect the ability to parallelise the code."

Jan 1, 2001

By S. Peng, Vaughan R. Voller

"Free boundary problems are a common occurrence in materials processing operations. An important example is the filling of material into molds. This paper looks at filling problems associated with polymer processing, in particular Resin Transfer Molding (RTM) and Compression Molding. A general, single governing equation is developed which on numerical solution provides predictions for the position of the polymer front in the mold during filling. Both fixed and deforming finite element solutions are developed. Application to polymer filling test problems reveal that the fixed and deforming grid scheme are accurate and compare closely with each other.IntroductionProblems arising from the analysis of material processing operations often involve the tracking of a moving boundary, on which a balance conditions needs to be met, or the locating of a free surface that defines the solution domain. Material processing examples of so called ""free and moving boundary problems"" include; the tracking of solidification/melting fronts[l], the tracking of the metal/gas interface during the filling of a mold[2] and location and shape of a skull (freeze line) in a melting furnace[3].Computational solution of free and moving boundary problems usually fit into one of two classes, viz.1. Fixed grid scheme: In which the spatial domain is covered by a fixed grid (mesh) of node points and the solution uses an auxiliary variable (e.g. a local liquid fraction) to track the moving boundary or locate the free surface.2. Deforming grid scheme: In which the grid in the spatial domain is continuously deformed (or adapted in a steady state problem) such that a specified set of grid points lie on the moving boundary or the free surface.Details on the basic underlying features in these two classes of solution can be found in the excellent monograph by Crank [4]."

Jan 1, 1994

By D. W. Hoey

Eight years use of the ISA Process is reviewed and current design and operations described. Nodern Technology used for impurity control and disposal as well as the use of mechanised electrode handling equipment, cell voltage monitoring, cell insulation and an efficient contact bar system are described. Improvements achieved in terms of energy usage and plant productivity are detailed.

Jan 1, 1987

By T. A. George, David J. Sellmyer

"The concept of achieving a useful high-energy-product magnet through appropriate nanostructuring of known hard and soft phases has been tantalizing researchers since the idea was first proposed. The fabrication of exchange-coupled nanocomposite magnets faces several challenges including aligning the easy anisotropy axes of the hard-phase grains. Here we investigate experimentally two-phase nanostructures of hard Lio-ordered FePt and soft iron-rich/cc Fe(Pt). The Fe-Pt thin films were produced by epitaxial cosputtering onto MgO (001) single-crystal substrates which lead to strong (001) texturing. The measured hysteresis loops indicate nearly ideal exchange coupling. Excellent magnetic properties are obtained, with largest values of coercivity (51 kOe), saturation magnetization (1287 emu/ cm3, J, = 16.2 kG), and nominal maximum energy product (58 MGOe).1. IntroductionA key figure of merit for permanent magnets is the maximum energy product (BH)rrw.x. The achievable maximum energy product is determined by a magnet's saturation magnetization M, and its magnetic anisotropy. For example, it is well known that (BH)rrw.x :S 4n2M,2• In the past, record energy products have been the result of discovering new compounds with high values of magnetization and anisotropy. However, finding new compounds with better magnetic properties than the current record-holding magnet Nd2Fe14B has proven to be difficult. A different approach is to exploit the exchange coupling mechanism between known hard and soft magnetic phases to enhance the maximum energy product [1-5]. In such a composite system, high coercivity is achieved due to the anisotropy of the hard phase as well as a nanostructure which prohibits large-scale domain wall reversal mechanisms. Magnetization is enhanced by the soft phase and loop squareness results from texturing of the hard phase easy-axis as well as complete exchange coupling between the coexisting hard and soft grains."

Jan 1, 2012

By G. S. Hanumanth

Sedimentation of particles during the liquid metal processing of particulate metal-matrix composites can affect the homogeneity, and thereby the properties, of the cast product. A novel electrical probe has been developed to measure the in-situ volume fraction of ceramic particles in molten metal baths. Using this probe, sedimentation rates for 90 pm silicon carbide particles dispersed in molten aluminum A356 alloy were measured over a wide range of particle volume fraction, 0.05 to 0.3. The sedimentation rate was found to depend strongly on particle volume fraction; the time to clarify a 0.15 m depth increased from approximately 60 to 500 seconds as the volume fraction increased from 0.05 to 0.3. Measured sedimentation rates agree well with the predictions of a sedimentation model based on one-dimensional, two-phase flow theory in which the inter-phase drag function is derived from the momentum equation, utilizing the Richardson-Zaki Equation for sedimentation in aqueous systems. The implications for solidification are discussed.

Jan 1, 1993

By S. Sugiyama, M. Kiuchi

"New metal working processes, such as the mashy-state mixing, mashy-state forging, mashy-state rolling and mashy-state extrusion are developed and applied to manufacture the so-called particle reinforced metals, fiber reinforced metals, particle reinforced cladding metals and so forth. These metal-ceramics composites are made of metal sheets, metal powders, ceramics particles and ceramics fibers. The mashy-state processes are also used to work those composites into bars, wires, tubes, plates, sheets, machine parts and other products. The working conditions necessary to manufacture sound composite products are clarified and the mechanical properties of the products are investigated. Through the investigation, it becomes clear that the mashy-state processes are useful and effective to manufacture metal-ceramics composites. It is al so known that these processes may be applied in various ways to development of new metal matrix compounds. IntroductionThe so-called metal-ceramics composites and processes to manufacture them are now being widely investigated in order to comply with increasing demands for new materials with novel and excellent mechanical properties and functions. The metal-ceramics composites are expected to have superior characteristics with respect to the elastic modulus, hardness, anti-wear resistance, high temperature strength and other mechanical properties to those of conventional metallic materials.The present authors ha v e been investigating into new metal working processes which are based upon the characteristics of metals and their alloys in the mashy-state. In the mashy-state, the metal (or alloy) includes both of the solid and liquid components. According to the fact that the partial melting takes place and the liquid component usually exists at grain boundaries, the metal in the mashy-state has quite different mechanical properties from those of the metal in the solid-state. Because of that the bonding force among grains is very weak due to the partial melting occurred at grain boundaries, the mashy metal has distinctively low flow-stress and high deformability. The mashy metal splits into grains or particles and sticks to others very easily. It is so soft as to be stirred up just like a lump of sherbet, but it is sufficiently viscous to be mixed up with other materials, such as ceramics particles and ceramics short-cut fibers."

Jan 1, 1988

By Deepu Philip, Pratik Agarwal, Ajay Kumar Shukla, Ishani Shukla, G Rajesh

Steel plants generally employ static BOF end point control models to arrive at a given temperature and chemistry at the end of blow. These end point models have now been supplemented with chaos control models to steer the blowing process in the right direction while the blow is in progress. Merely arriving at the correct end point temperature is however not adequate because in the subsequent stages as well the temperature variations can be large and unpredictable. The present paper deals with an integrated model to take into account the effect of all parameters affecting temperature and composition from tapping to the start of casting to minimize the use of LF or aluminum heating, and also minimize grade mixing. The application of lean operations strategy is explained in which the previous “Push System’ is changed to a “Pull System”, minimizing the use of ladle furnace or aluminum heating during steelmaking.

Jan 1, 2014

By Stein Tore Johansen

The flow of a liquid through a large grain filter has been considered. An improved form of the fluid dynamic equations describing flows through porous media is proposed. The theory is applicable to all Reynolds numbers. Particulate inclusions are described by passive scalar fields where only very simple mechanisms for particle removal are included. However, the deposition of particles are allowed to change the "porosity" of the filter. Hence, the flow pattern through the filter will change as the filter ages. The theory is employed to the filtration of aluminum in an industrial grain filter. The model shows that the filter is not effectively designed and there is room for considerable improvement. The dynamic "aging" process of the filter is shown to change the filtration from bed filtration to cake filtration. Finally, the predicted inclusion collection efficiencies are compared to efficiencies measured in an industrial filter. The predicted initial efficiencies are in very good agreement with experimental results.

Jan 1, 1990

By Fumitaka Tsukihashi

Phase diagrams of the CaO-SiO2-FeOx-MgO, Al2O3 systems are necessary for the analysis of copper smelting reactions and sintering process of iron ore. The effect of MgO and Al2O3 addition on the liquidus of the phase diagram of the CaO-SiO2-FeOx system at low oxygen partial pressure was observed. The liquid phase area changed by the addition of MgO and Al2O3 with a changing oxygen partial pressure from 10-8 to 10-3 atm (10-1 to 102 Pa) at 1573K. The effect of Fe3+/Fe2+ ratio on the melting mechanism is discussed.

Jan 1, 2003

By Xuemei Zheng, Aiyuan Ma, Jing Li, Jinhui Peng, Shaohua Yin, Libo Zhang

Zinc recovery from zinc oxide flue dust (ZOFD) by ultrasound enhanced neutral leaching process was investigated. In this study, the effects of leaching temperature, liquid/solid ratio, leaching time and ultrasound power were studied, and the conventional leaching experiments were also performed. The experimental results showed that the leaching time was greatly shortened and the leaching rate of zinc was effectively improved by the assistance of ultrasound. The optimum conditions of ultrasound-assisted leaching were determined as leaching time 20 min, temperature 35℃, and the liquid/solid ratio of 5. Under these conditions, the leaching rate of zinc was close to 80% as the ultrasound power of 540W, which was increased by 7% or so, in comparison with that of conventional leaching process.

Jan 1, 2015

By Ditze A., C. Scharf

Magnesium type 1 - scrap can be remelted without flux in the presence of different sulfur containing protective gases. Beside the draw back in the use of these gases, that either are contributing to the global warming potential (SF6) or are poisonous (S02), residues like dross and crucible sludge are produced. Dross and sludge now a days must be utilized. Partly these byproducts can be used in the aluminum industry and partly for desulphurisation of hot metal and steel. Another possibility is melting of dross and sludge with flux for the production of a secondary magnesium alloy. Then again residues are generated that must be processed. Therefore, the whole material cycle has to be considered to decide which kind of utilization practice is optimum. Based on experiments this question is discussed and the material balances for fluxfree melting, melting with flux and fluxfree melting plus other utilization of the residues are presented.

Jan 1, 2000

By William Petrul

Image analysis studies were performed on mill products from laboratory flotation tests of the Zn-Pb ore from the Faro deposit in Yukon, Canada, to determine mineral liberations at specific grinds and to predict recoveries at optimum flotation conditions. The minimum and optimum grinds for liberating sphalerite and galena were predicted from size analysis data for the minerals in large ore pieces, and determined by image analysis studies of the mill products. The determined optimum grinds are about 2 Tyler mesh sizes larger than predicted because sane of the fine grained sphalerite and galena occurs in interstices between coarser grained pyrite and is liberated when the pyrite grains are broken apart. Materials balance calculations were performed on the analyzed values for the liberated and unliberated sphalerite and galenaa to determine their distributions in the mill products. The laboratory flotation tests recovered 74% of the sphalerite and 83% of the galena in Zn and Pb concentrates respectively. The mineral evaluation study indicates that the optimum recovery for sphalerite and galena are 85 and 83% respectively. The company is currently recovering 80% 'of the sphalerite and 82% of the galena.

Jan 1, 1989