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By J. W. Mausteller

Chemical oxygen supplies have been used for nearly 60 years, with their greatest application during the last 25 years. They are of two types, the superoxides and chlorate "candles", The superoxides are demand chemicals, responding to the needs of the user and to supply oxygen and remove carbon dioxide. Chlorate candles are formed solid element which furnish oxygen only and do not remove carbon dioxide. Properties of these materials will be described, with comments on the respiratory requirements of a man under various workloads, types of equipment which use chemical oxygen, comparison with other systems and potential application to an underground mine survival system.

Jan 1, 1971

By I. Iwasaki, R. H. Heerema

The presence of calcium and magnesium ions in iron ore pulps that are upgraded by selective desliming can result in indiscriminate flocculation of both iron oxide and siliceous gangue slimes. The removal of these alkaline earth cations in pulp solutions by chemical precipitation was ineffective as a means of deflocculation of quartz. It was shown by using various techniques (electron micrographs, abstraction, and streaming potential measurements, and cationic flotation tests) that heterocoagulation between the precipitates [Mg(OH)2, hydroxyapatite, and CaCO3] and quartz particles was the reason behind that observation. In addition, the precipitates adversely affected the recovery of quartz by cationic flotation, due to slime coating, a case of heterocoagulation. Magnesium hydroxide produced a uniform layer of coating across the quartz surface, while hydroxyapatite and calcite produced discrete, localized deposits dotting the surface.

Jan 1, 1981

By José Brant, Douglas Torres, Rogério Navarro, Rodrigo Souza, Eduardo Brocchi

The steelmaking process requires the input of ferro-alloys to implement the adjustment of some elements composition in the final product. In the particular case of stainless steel production, the high carbon FeCr alloy stands out as one important precursor. However in the production of this material a certain quantity of fine powder with remarkable chromium and carbon content is also generated, which, in turn, could be processed through alkaline roasting in order to selectively recovery this element in a subsequent aqueous route. In the present work, this process is investigated, using excess of NaOH as oxidizing agent, and H2O2 for precipitating chromium as Cr(OH)3, which is next calcinated to Cr2O3. According to the results, the global achieved recovery has shown to be around 98%, suggesting that the proposed route can be seen as a potential process for chromium oxide production from the mentioned fine powder.

Jan 1, 2015

By K. C. Li

The scope of this subject is a broad one. The demand for a metal with high refractory properties, great strength at elevated temperatures and high nuclear cross section, has put tungsten in the foreground as: the most promising metal to fill some of these requirements. Recently developed techniques have made it possible to roll large tungsten sheet and-the availability of fabricated tungsten is already upon us. More and more, the demand is for purer and still purer metals. Tungsten is no exception. As technology improves, we are learning more about the effect of foreign elements in minor amounts upon the chemical and physical properties of metals. As equipment and technology improve, specifications become more rigid, and reasonably so. Pure metals have revealed properties hitherto unknown in metals produced by former technology.

Jan 1, 1961

By John Dasher

Chemical processing is descended from alchemy, which developed our major lixivants. The profession might have done more if it had been less preoccupied with turning base metals into gold-a process that still hasn't been developed. Georg Agricola, over 400 years ago, gave us ten recipes for "aqua valens" to part gold and silver, and described cementation of gold and silver on base metals. His text stood for 200 years, by which time heap roasting, leaching and cementation were winning copper from pyrites at Rio Tinto and the Barba furnace was distilling mercury from the ores of Almaden.

Jan 1, 1971

By J. K. Brooke, R. M. Dreyer

For mining engineers and geologists accustomed evaluating metallic mineral deposits, the problems inherent in determining the worth of non- metallic industrial minerals deposits for the chemical processing industry often comes as a rude shock. These difficulties lead to different, and often much greater, problems in financing the development of such deposits than would normally be anticipated for economic sources of copper, molybdenum, iron, nickel and other metallic minerals. The chemical processing industry is one of the two principal consumers of non-metallic mineral production, the other being the construction industry. In the last decade, the volume of industrial minerals consumed by chemical processers has in- creased by 30%, and further increases are forecasted. To satisfy this growing demand, many new sources of these minerals must be found and developed. For those of us who will become involved in such work, the following brief analysis of the major problems to be expected may be of help in developing a realistic approach to evaluating and financing such a deposit and selling the product to consumers.

Jan 8, 1962

By Cheng Zhengbing, Sun Baoqi

This paper summarizes several chemical purification methods used for producing high-pure industrial minerals These methods, mainly including alkali melting, acid leaching, oxidation-reduction bleaching, are respectively used to eliminate the impurities such as silicates in graphite and diamond, ferric oxides in quartz sand or other valuable silicate minerals, colouring impurities in kaoline, barite and other minerals which are required to have a high-whiteness. The fundamentals of the chemical purification methods and some practical examples in China are introduced in the paper.

Jan 1, 1995

By Raj Mutharasan

The phenomena of gas-molten metal reactions for the production of metal matrix composites consist typically of a combination of one or more gas transport steps and a liquid gas reaction step. Reaction products include such strength enhancers, grain refiners, or high thermal conductivity phases as TiC, AIN, SIC, Si3N4, TiN in aluminum alloys. Nitrides, carbides and oxides can be produced at various volume fractions and in fairly fine sizes (500 am to 5 um) in laboratory melts by Reactive Gas Injection method (RGI). Gas injection methodology to produce the reinforcements is attractive because it can potentially be scaled to production scales in excess of 10,000 kg/h. For continuous production, the reactant molten metal can be continuously fed into the .crucible where the reactive gas is injected. The molten metal phase reactant may also be involved in a controlling transport step, depending on its concentration and viscosity. It is well known that the reaction product reinforcement size and shape of these phases have significant impact on the physical, mechanical and thermal properties. The current state of knowledge is unable to predict the kinetics and growth of solid reaction products obtained. The primary goal is to develop a fundamental framework for the understanding and prediction of the particle size in such reaction systems. In addition, the role of gas transport, liquid hydrodynamics and decomposition are important issues. A reaction-transport model is being developed using a reaction, transport, and thermodynamic framework, both at macro and at atomistic level to assess gas - liquid interactions.

Jan 1, 1996

By Arthur Taggart

SOME years ago, A. M. Gaudin and one of the authors published a paper showing removal of tar acids from solution by sulfides preferentially as compared to gangues (specifically by galena as compared to quartz).1 The underlying phenomenon was classed as adsorption, and the paper went on to develop the general thesis that so far as water-soluble frothing and collecting agents in flotation are concerned, the phenomenon of adsorption is one of controlling importance. Adsorption was defined in that paper as "a process of rearrangement of a system, which results in establishing a difference in concentration, as between the interfacial layers and the bulk of the phases, of a substance or substances initially uniformly dispersed in one or several of the phases." The paper went on to develop the relation between adsorption and surface energy according to Gibbs' equation (which may be thrown into the form U/c = KdT/dc, where U = excess concentration in surface layer, c = concentration, T = surface tension, and K is a constant), and pointed out that, according to this equation, degree of adsorption and change in surface tension vary directly. The present paper offers a somewhat different definition for the term adsorption; and sets up, in sweeping terms, the generalization that simple chemical reaction underlies the functioning of the flotation reagents which control mineral collection, when these reagents are soluble in and act from solution in the water of the pulp.

Jan 1, 1930

By Gabriel K. Nzulu, Lars Hultman, Per Eklund, Martin Magnuson, Abu Yaya, Prosper M. Nude, Hans Högberg

This study aims to identify individual elements and to gain an understanding of the surface reaction mechanisms, as well as the properties of precipitated pyrite particles observed during the hydrothermal formation of an ore deposit. A combination of X-ray diffraction (XRD), air annealing in a furnace, scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX), and X-ray photoelectron spectroscopy (XPS) was applied to investigate the crystal structure and identify the individual elements, permanence, transformation and chemical/electronic properties of such pyrite.

Jun 1, 2024

By Gabriel K. Nzulu, Lars Hultman, Per Eklund, Martin Magnuson, Abu Yaya, Prosper M. Nude, Hans Högberg

Pyrite is the most common among the group of sulfide minerals in the Earth and abundant in most geological settings. This gangue mineral in association with garnet, hematite, magnetite, and other sulfide minerals acts as an indicator mineral in the Kubi concession of the Asante Gold corporation in Ghana. X-ray diffraction (XRD), air annealing in a furnace, energydispersive x-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) were applied to investigate the crystal structure, identify individual elements, permanence, transformation, and chemical/electronic properties of such pyrite. The study aims to identify individual elements and to gain an understanding of the surface reaction mechanisms, as well as the properties of precipitated pyrite particles observed during the hydrothermal formation of the ore deposit. XRD shows that pristine and annealed samples contain some hematite and quartz besides pyrite. Results from air annealing indicate that the relationship between pyrite and hematite-magnetite is controlled by temperature. EDX reveals that the sample has O and C as contaminants, while XPS in addition reveals Ba, Au, P, Al, and N. These elements are attributed to pyrite that bonds metallically or covalently to neighboring ligands/impurity minerals such as oxides, chalcogenide sulfides, as well as the gangue alteration minerals of magnetite and hematite in the pyrite sample. These findings suggest that during the hydrothermal flow regime, pyrite, pathfinder elements, and impurity minerals/metals were in contact with quartz minerals before undergoing hematite transformation, which thus becomes an indicator mineral in the Kubi gold concession.

Feb 27, 2024

By R. Frenette, A. W. Mo, H. A. Hamza

Fine particles present major technical and economic problems to those who deal with solid/liquid separation processes. In the coal industry the problem is compounded by the large amounts of produced fines such as those present in Western Canadian coals. Flocculants in the form of high molecular weight water soluble polymers are commonly considered an effective solution for the enhancement of the separation process. These reagents are relatively expensive especially when considering a low-price commodity such as coal. Optimization of the use of these reagents is therefore an operational necessity. Six polymers were evaluated as to their effectiveness in flocculating a fine coal tailing. Results were compared with those for a reference flocculant, in-use at that time in the washery. It was shown that, in general, flocculants significantly improve the solid/liquid separation process. The ranking of the flocculants as to their effectiveness in settling and filtration indicated that the best flocculants for settling were not necessarily the most effective for filtration. Flocculants that showed the best filtration improvement were generally cationic and those best for settling were anionic.

Jan 1, 1988

By Frank M. Kimmerle

Spent Potlining (SPL) contains recoverable chemical elements (C, F, Na and Al) which are lost in stabilization or immobilization processes primarily aimed at eliminating cyanides and reducing leach rates of soluble fluorides prior to landfiling. They can be recovered in a variety of mineral forms for recycling in the aluminum industry and elsewhere. Alcan has developed a cost-effective hydrometallurgical route, combining a number of proven unit processes to destroy cyanides, recycle the chemical values and provide a zero-discharge process. Pilot plant studies of this Low Caustic Leach and Liming (LCL&L) Process prove that the fluoride scan be converted to acid grade fluorspar, while the sodium and aluminum are recovered as a sodium aluminate and caustic feed to the Bayer Plant operations. The remaining brick and carbon fraction constitutes a high ash solid fuel which meets TCLP leach criteria and whose reduced sodium content enhances its value as a chemical reducing agent.

Jan 1, 1994

By M. M. Bugarin, P. J. van Staden, V. T. Conic, S. S. Dragulovic, R. M. Kovacevic, D. B. Milanovic

"The mineralogical and physico-chemical characteristics of a polymetallic sample from a mine of West Serbia suggest that it can be classified as a SEDEX type of ore. Those ores contain multiple value components, being inter-dispersed as fine grained aggregates. This prevents concentration by gravity or flotation concentration processes. Mineralogically, the valuable metals (Cu;Zn;Pb;Au and Ag) occur as pyrite, sphalerite, galena, tetrahedrite, chalcopyrite, covellite, arsenopyrite, and non-metallic minerals (barite, and waste minerals). Novel technologies are under development within this project for the recovery of all valuable metals from this very complex material. The work comprises the further treatment of solid residue obtained after Cu and Zn extraction by bioleaching, for the subsequent recovery of Pb and the precious metals Ag and Au. The residue is first treated with a saturated sodium chloride solution, whereupon a chloride solution of lead (NaPbCl3) is obtained. From the chloride solution, lead was deposited in the form of lead carbonate, followed by reductive melting, whereupon lead anode was obtained. Electrolytic refining of the lead anode, using a solution of PbCO3 in methane sulphonic acid (MSA-Methanesulfonic acid, min 99.5% CH4O3S, density 1.48 kg/dm3, Manufacturer: Carl Roth) as an electrolyte, yielded refined lead cathode. It should be noted that, after precipitation and separation of lead carbonate, the sodium chloride solution is restored to its original composition by the addition of make-up reagents and returned for another lead-sulfate leaching cycle. The solid residue obtained after leaching lead-sulphate, is leached in thiosulphate solution, with the addition of an activator, a catalyst and lixiviant for gold, to yield a thiosulphate solution of gold and silver. Since the content of gold and silver in solution is low (below 1 mg/dm3), they are first electrolytically concentrated on steel cathode and then refined to pure metals using well-known chemical methods. Note that, after the electrolytic separation of gold and silver, thiosulphate solution is recycled to the leaching step."

Jan 1, 2018

By Rubén J. Sánchez Rodriguez, Carlos M. Fontes Vieira, Carlos E. Gomes Ribeiro

Ornamental compound stone are produced by industry for decades, however, few published studies describe these materials. Brazil has many deposits of stone wastes and a big potential to produce these materials. This work aims to evaluate the chemical resistance of ornamental compound stones produced with marble waste and unsaturated polyester. An adaptation of Annex H of ABNT NBR 13818:97 standard, with reagents commonly used in household products, was used. The results were compared with those obtained for natural stone used in composite production.

Jan 1, 2015

By A. Aitio

Sustainable development is one of the central themes of the work of the World Health Organization; chemical safety is one of its important components. For more than 25 years, WHO has had specialized units for assisting member countries in dealing with their problems in chemical safety. For one of the units involved, International Programme on Chemical Safety, a reorientation is in progress to make best use of existing resources, and to prioritise the work to optimally correspond to the needs of the member countries. The risk assessment work of IPCS, and specifically, the work on chromium and chromium compounds, are discussed.

Jan 1, 2004

By C. B. Alcock

The control of high temperature processes requires the ability to measure significant variables during operations. With increasing automatic computerized control there is need for sensors which can provide on-line chemical analyses of all phases present in a reactor without the necessity to withdraw samples from the high temperature reaction zone. Probes using electrochemical cells and conductivity measuring devices have provided the answers to some of these problems, notably the measurement of oxygen in liquid metals, and similar potential systems based on the same fundamental principles for the analysis of non-metallic and metallic elements appear feasible. In this discussion, the state-of-the-art in chemical sensors will be discussed in terms of the potential materials of construction, and, in some cases, the limitations of upper temperature at which some promising systems can, at present, be applied. It is concluded that a new phase of basic research could improve the outlook substantially by providing solutions for some problems in chemical sensors which are now well-defined.

Jan 1, 1990

By Omar A. Muhtadi, David A. Milligan

7.1 INTRODUCTION The circulating fluid (generally an aqueous cyanide solution) is the major active component of heap leaching. This solution extracts precious metal from the heap and is then processed to recover the precious metal. The solution continuously recycles through the heap to recover more precious metal. With each cycle through the heap, water and chemicals are lost. Make-up water and chemicals must be added to balance losses from evaporation, seepage, entrainment, and chemical reaction in the heap, as well as any other processing losses. Adding more water than needed can result in a build-up of water as inventory in the various ponds and can eventually require that water be discharged from the operation. This is an extremely undesirable condition, and can often be very expensive in both investment in water treating facilities and operating costs. Most heap leach facilities operate under a zero discharge permit; thus, a situation requiring water discharge can result in permit violation. Chemical solution control must be managed to maintain the optimum pH, dissolved oxygen content, and cyanide content, while preventing "scaling". Calcium-based precipitation is a common scaling problem in mill reclaim waters. A buildup of these deposits can result in severe reduction of water flow, loss of pump efficiency and eventual interruption in metal production. In addition, problems of plugged sprinkler heads, blinded leach pads and fouled carbon (in carbon recovery systems) can be and often are experienced when scale control is not maintained. The remainder of this chapter discusses chemical solution control and scaling prediction/prevention in the context of a "closed" system. Sizing of ponds to accommodate precipitation and runoff, collection systems, and other similar design considerations are not discussed here. These topics are deferred to later chapters, e.g. Chapter 10 considers design of collection systems while Chapter 12 discusses pond sizing. 7.2 CHEMICAL CONTROL Chemical composition of the circulating solution must be controlled by the operator if the heap leaching process is to be successful. The primary or essential chemical control parameters in any heap leaching operation are:

Jan 1, 1988

By May P. M

The role of chemical speciation in alkaline cyanide solutions is discussed by reference to recent experimental data from the authors' laboratories. It is shown that serious gaps exist in our present knowledge of the thermodynamics of cyanide complexes in solution. Nevertheless, using the available data and the JESS suite of computer programs it has been possible to develop a simplified chemical speciation model for alkaline cyanide solutions under conditions relevant to the gold extraction process. Some possible implications of the model for plant operations are Discussed.

Jan 1, 1991

By David C. Sanders, Rodney H. Sergent, Victor C. Storhok, Batric Pesic

In the past, considerable work has been done on the applica­bility of bromine chemistry in the extractive metallurgy of gold. While the research in this area spanned from the understanding of fundamental dissolution chemistry to the demonstration on a pilot plant scale, no work was done on the fate of discarded leach residues with respect to the stability of accompanied heavy met­als. Because the leach residues were the discharge products of halide/halogen systems, the general perception was that the con­tained heavy metals would be more susceptible to dissolution than in typical sulfate systems, thus causing increased environ­mental problems. A long-term study was performed to obtain the information on the stability of heavy metals contained in the leaching residues after bromination. The study involved the leach residues of three different ores, as well the precipitates prepared from the synthetic solutions (not presented here). The conclusion of this study is that the stability of solid residues produced by bromination leaching was same as the sta­bility of leach residues produced by leaching in the sulfate sys­tems. Also, contrary to the past expectations, the presence of bromide ions in the test solutions (up to 1 g/L NaBr) did not enhance the solubility of heavy metals (Cu, Zn, Pb, As) beyond the solubilities found in the sulfate systems.

Jan 1, 1998