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By Yasser Ghobara

Phosphorus is a problematic impurity that has challenged steelmakers for decades. Steel producers have developed specific technologies to eliminate phosphorus prior to and during steelmaking. These process technologies reduce phosphorus to various degrees and increase the cost of making steel. The state-of-the art dephosphorization technologies are described and operating costs compared for each of the established technologies. Costs are discussed in terms of price penalties for high P iron ore and selling premiums for low P steel. From this, strategies to control P in a cost effective manner are described.

Aug 17, 2017

By Raíza da Silva Juvenal, Suelen Silva Rocha, Artur Ângelo Alcântara de Assis, Jorge Luiz Valença Mariz

Um estudo de viabilidade econômica deve considerar parâmetros e incertezas inerentes a um projeto para produzir resultados econômicos consistentes, fornecendo ao investidor uma ferramenta de tomada de decisão. O presente estudo objetivou efetuar inicialmente a avaliação econômica convencional do cenário realista de uma mineração de agregados em fase de implantação localizada em Pernambuco, cujo Valor Presente Líquido (VPL) obtido foi R$ 24.006.309,20, o que representa um resultado positivo. Através da metodologia de Monte Carlo foi efetuada uma análise de risco considerando incertezas em 100.000 cenários, nos quais nove variáveis assumiram valores estocásticos dentro dos domínios definidos, produzindo assim uma distribuição estatística do VPL ao invés de um único número, sendo ainda efetuada uma análise de sensibilidade para identificar e quantificar as variáveis que mais impactam no resultado da avaliação. Por fim, os dois fatores mais influentes identificados na análise de sensibilidade inicial foram isolados e submetidos a uma nova análise de risco em outros 100.000 cenários. Foi concluído que o projeto é economicamente viável e que a probabilidade de gerar lucro aos investidores é de 99,77%, embora a probabilidade do VPL ser igual ou maior que o previsto pelo método convencional seja de 49,98%.

Oct 3, 2019

By Patrick Tassot

Increased worldwide highly competition in steel market imposes innovative measure for the steelmaker targeting cost reduction and climate-friendly steelmaking process in order to have the ability to withstand the pressure of the market. At the same time the demand for high purity and highest quality steels continues to grow from year to year, especially in the sector automotive in transportation of oil and gas, in the construction Industry and in the manufacture of heavy plate. As they allow producers to be up to the requirements while allowing expanding their product mix, new secondary metallurgical treatments have become a must additionally to standard equipment elements of steel plants modern. Most of these treatments occurs in the steel ladle increasing the pressure to ensure a reliable and as possible neutral reactor. Intelligent solutions for refractory lining ladles should integrate better adaptation to the operational process parameters and the high reliability/availability at the best cost/performance. This challenge has conducted Refratechnik to develop new concepts to overcome the frontier between shaped and unshaped materials and that’s what will be covered in this paper.

Aug 17, 2017

By Fabiano Soares

Strand guide rolls in continuous casters are crucial components for guaranteeing an optimum process for the production of high-quality steel grades. The properties of these rolls greatly influence the quality of the slab produced. The most commonly used designs so far have been the axle roll and the solid roll. A quite new roll concept is the STEC-Roll®. It combines the advantages of the axle roll with those of the solid roll. This paper explains the development of this roll type and shows the current design. The characteristics of the STEC-Roll® are presented in greater detail and are underlined by a number of simulation results. Beside the design itself, the benefits for casting and maintenance are explained, including for example the easy assembly and dismantling or the use of the roll for dry casting. A brief examination is made of the TCO for the STEC-Roll® and an estimation is provided of the exchangeability of this roll. To conclude, an overview on the current applications is presented.

Aug 17, 2017

By Henrique Silva Furtado

This paper presents the results obtained on the exchange of an original old blow charge model for a new up-to-date state of art global model, employing optimization techniques and process modelling, and, the results obtained in terms of fluxes consumption reduction and the introduction of user friendly tools and practices.

Aug 17, 2017

By Patrizio Damiano

Competitiveness in Electric Arc Furnace production is pushing steelmakers to increase the throughput at the lowest expenditure. The technological challenge is therefore to operate the existing facilities at their top capabilities and to exploit materials and energy sources at the upmost yield and efficiency. Moreover, seizing the opportunity offered from the price variability of metallic feedstock calls for flexible practices, versatile equipment and tools to rapidly tune the melting profiles without hindering steel quality and equipment lifetime. The innovative Danieli Q-MELT Automatic EAF system addresses these aspects implementing a centralized control system which interacts with multiple technological packages. Each of these cutting-edge technologies focuses on one aspect of the EAF cycle, increasing machine availability and resource efficiency, by means of electrode regulation and foamy slag control, charging optimization, off-gas analysis and closed loop injectors control. Moreover, these modules provide the process supervisor application (Melt Model) with important information regarding the process status, thus allowing the adoption of a unified control strategy. The supervisor implements a robust statistical approach to identify process deviations in real time. The first results and technology perspectives inferred from the field immediately after the start-up are described in this paper.

Oct 30, 2017

By Andrea Codutti, Gianni Tiussi, Andrea Tonnicchi, Morris Codarin

Essar Algoma Steel, Canada, awarded Danieli Transimissions a strategic order for the upgrade of the main drive spindles belonging to the most loaded stands of the Hot Strip Mill, F1-F2, F5 and F6. Featuring special heavy duty design and advanced torque monitoring system, these spindles replace existing competitors’ grease lubricated design with the efficient continuous oil lubricated solution to withstand the tough working conditions, increase life expectations and provide room for a product mix extension. The first couple of spindles have been installed in September 2017 by the expert Service team and are showing already good and reliable performance. Progressively all the others are being installed.

Oct 1, 2019

By Cristiano José Scheuer

The effect of low-temperature plasma carburizing treatment on the micro-abrasive wear resistance of AISI 420 steel was investigated by mean of a CSM Calowear ball-cratering equipment. Carburized samples were treated at temperatures of 350, 400, 450 and 500°C for a fixed time of 12 h, using a gas mixture containing 99.5% (80% H2+20% Ar)+0.5% CH4. Micro-scale abrasive wear tests were conducted with a 25.4 mm AISI 420 steel sphere, using an abrasive suspension of alumina (Al2O3) with particle size of 1 ?m (abrasive concentration of 0.11 g/cm³). The contact normal force, abrasive flow and ball rotation speed were fixed at: 0.5 N, 0,2 drop/s, and 120 rpm. The wear craters were analyzed using a confocal laser microscope, Olympus OLS 3000. The wear analyses were performed for test times of: 30, 60, 90, 120, 180, 360, 540, 720 and 900 s (equivalent sliding distance: 0.84, 1.68, 2.52, 3.36, 5.04, 10.09, 15.14, 20.19 and 25.23 m, respectively). The results indicate that the wear coefficient in the outer layer and in the diffusion layer are different, being lower in the latter. It was also verified that the wear coefficient on the outer layer region decreases with increasing treatment temperature in the range of 350 to 450 °C, and increase again for 500ºC. The diffusion layer wear coefficient is similar for all the carburized samples. Finally, for all studied conditions, the analysis of the wear craters surface indicates the occurrence of grooving and micro-rolling abrasion wear modes.

Aug 8, 2018

By Uwe Wilhelm

Pittini Group has contracted Danieli in 2011 for the supply and replacement of the existing EAF at Ferriere Nord Plant in Osoppo. This was a very challenging project: giving the fact that the Meltshop was operating already under very high performance level, there were many elements involved for the project to improve (reduce the amount of charges, promote highest possible chemical energy utilization, allow best optimization on existing transformer power, modification on Drop Out box and Water Cooled Duct, Hydraulic System for EAF, Scrap Bucket design to fit to new EAF with existing loading and transport system, Automation System Review and Upgrade) as well as limitations of the existing installation (limited space, lifting capacity building and cranes and the required solutions for fast shell and roof exchange). All furnace parts, as well as installation engineering, were developed and discussed carefully with the Customer to either provide proven and reliable concepts, but also to define solutions for fast installation/maintenance access and quick exchange for offline turnaround. In the end, from disassembly of existing equipment up to the first heat of the new furnace, only 38 days were necessary. First heat was made on January 24th 2013, on the 6th production day 32 heats where produced at nominal design capacity and 28 days after start up 100,000 t liquid steel have already been produced.

Jul 30, 2018

By Helênio Resende Silva Júnior

PT. Krakatau-POSCO coke making plant, located in Cilegon, Indonesia, is the results of the know-how and experience of Paul Wurth (PW) in coke making field. The plant has a capacity of 1,321,000 t/y of gross coke achieved by two coke oven batteries with 42 top charging Paul Wurth “Jumbo” ovens each. PW “Jumbo” oven with a useful volume of 78,92 m3 allows decreasing drastically the number of pushing/charging operation per day with a consequent reduction of the diffuse emissions. Gas treatment plant with a capacity of 88000 Nm3/h has been designed in collaboration with DMT GmbH & Co. KG, adopting the latest technologies with specific design know-how. PT. POSCO-Krakatau plant has been successfully commissioned and started-up in October 2013. The present paper will highlight the main technology features applied in PT. Krakatau-POSCO project for both coke oven and gas treatment plants.

Aug 17, 2017

By Delvaux Carlos de Miranda Sobrinho, Hegler Zurick Arantes Assunção, Marco Venicio Mendonça de Souza, Luciano Toledo Ribeiro

This paper aims to present the development of a 600mm U-Pile that was done in Gerdau’s Ouro Branco Heavy Section Mill in order to feed the local market with a product.The focus of this study is to show the developmental process the Mill went through until it was prepared for hot trials. All roll pass and guide designs were developed by our own team. Analytical tools like Finite Element Analysis and reduced scale lead trials will be shown and how these tools impacted on the development timeframe and accuracy of the final results on steel.

Oct 1, 2019

By Waleska Campos Guaglianoni

With the growth of nanoscience and nanotechnology, the synthesis of nanostructured oxides has received a special attention. Metal oxides are widely used in the manufacture of microelectronic circuits, piezoelectric devices, fuel cells, catalysts, filters and bactericides systems. These metal oxides represent a large class of semiconductor materials suitable for photocatalytic processes. In recent years, new materials of this class such as TiO2 and ZnO have been developed due to their photo-catalytic abilities to degrade various environmental pollutants. This work aimed to evaluate the photocatalytic activity of zinc oxide previously synthesized by combustion synthesis in solution using citric acid as fuel and different reasons fuel/oxidant. After synthesis, the powders were subjected to heat treatments at different temperatures and photo-catalysis. The photocatalytic activity was evaluated by the degradation of a solution of methyl orange in a photochemical reactor of UV illumination, after which the transmittance of the samples measured with the assistance of a spectrophotometer. To analyze the results, a commercial zinc oxide was used as standard. The products of combustion synthesis in solution showed that photocatalytic activity varied according to the ratio fuel/oxidant and as a function of heat treatment. The results showed a higher photocatalytic activity for the products obtained with disabilities fuel in the reaction and heat treated.

Aug 8, 2018

By Paulo Rodrigues dos Santos Junior, Luciano Passos de Jesus, Vagno Dordenoni Beltrame, Vinicius Antonio Ramos Pin

Faced with an increasingly demanding and selective market, a thorough analysis of each step of the processes is required in order to achieve high levels of performance. In addition to a major factor of importance in the rolling process, due to its high price, the rolls represent one of the main items in the cost of hot coils production. Using the 6 sigma methodology, there were opportunities for improvement in the grinding process, fatigue analysis, improvement in NDT in rolls, as well as means to guarantee operational stability, which allowed the reduction of roll’s consumption and consequently the cost of production.

Oct 11, 2019

By Aline Lima da Silva

The reduction in SOFC operating temperature due to recent development in materials and fabrication techniques enables the use of ferritic stainless steels as interconnects for SOFCs. Ferritic stainless steels offer many advantages over traditional ceramic interconnects, such as higher thermal and electronic conductivity, as well as relative ease of fabrication. However, the formation of chromium oxide on ferritic stainless steel results in an increase in ohmic resistance and can lead to the loss of cathode catalytic activity (due to Cr volatilization, with cathode poisoning). The oxide growth depends on several factors, such as steel composition, temperature, oxygen partial pressure. In this way, knowing the phase stability, the oxidation behavior of the material and the oxidation kinetics is of great interest. In this context, a thermodynamic study of the oxidation of ferritic stainless steel 430 under oxidizing atmosphere (cathode), at the temperature of 750ºC, is carried out. As one can see, the thermodynamic system can be very complex, involving several phases (chromium oxide, (Fe,Cr,Mn)3O4 Spinel, iron-chromium oxides, etc.). The effect of oxygen partial pressure and alloying elements on phase distribution is evaluated. Thermodynamic modeling is compared with experimental results from literature.

Aug 8, 2018

By Jônatas Venancio Barbosa, Dagoberto Brandão Santos, Túlio Magno Füzessy de Melo

In this work, the mechanical and metallurgical behavior of titanium added ultra-low carbon (ULC-Ti) steel under hot and warm working conditions was studied by means of dilatometer compression tests. Double compression schedules were performed at temperatures between 700°C and 1000°C, inter-pass times of 0.5-100 s, and deformations of 0.5 and 0.3 in the first and second stages, respectively, with strain rate of 1 s-1. The analysis of the flow curves obtained allowed the evaluation of the softening characteristics of the steel. The softening and microstructure features indicate different restoration mechanisms depending on the temperature range. Static recrystallization with rapid microstructure restoration is observed at temperatures within the austenitic and intercritical field. Strain induced boundary motion and recovery mechanisms apparently control the restoration process in the ferrite region. In general, flow stress curves showed dynamic recovery behavior. Only the deformation in the intercritical region produced a peak in the flow stress curves. Isothermal holding tests associated with single hit compression indicated the presence of dynamic strain induced transformation, accelerating the softening kinetics at the intercritical region.

Oct 1, 2019

By Luiz Henrique Accorsi Gans

First, this works carries an experimental evaluation for austempered ductile iron (ADI) as a gear material. And second, in order to provide a better understanding of the microstructural effect on the stress state of subsurface regions, a finite element method approach was considered using the submodeling tool in ANSYS 11.0. For this, ADI gears were produced from continuous cast iron bars, heat and thermochemical treated and tested in FZG test rig. The results were compared to those of carburized steel AISI 8620 and induction hardened steel AISI 4140 gears. The wear experiments were performed at the temperature of 90ºC with two torque stages: 135 N.m (running-in) and 302 N.m (steady-state). The time for pitting and spalling on the gears surfaces were measured using image analysis. The results showed a very good potential of using ADI for manufacturing gears, replacing induction hardened steels. Also, the ADI gear with smaller nodules showed higher life for pitting. In contact fatigue tests with severe load, the carburized AISI 8620 steel proved more adequate than the austempered ductile iron, showing that the mechanical properties are critical in the resistance to damage in gear contact. The austempered ductile iron with smaller nodule size showed to be very competitive with wear resistance similar to AISI 4140 steel induction hardened. With ANSYS, it was verified that the nodule size affects the gears life independently of the mechanical properties of the matrix. The results showed that the nodules indicate the presence of a concentration stress, but their size doesn’t affect the contact fatigue life as much as the total amount of nodules, regardless of the ductile iron microstructure. The size and number of nodules affects both the nucleation and the propagation stage of cracks. ADIs with higher amount of nodules have a greater wear resistance. Also, compared to the Hertz contact theory (isotropic material), the presence of graphite nodules indicates a non-isotropic material and made the maximum shear stress point moves toward the surface.

Jul 31, 2018

By Nishit Patel

Development work on the use of plasma torches in blast furnace ironmaking was completed in the 1980s. The technology developers planned to reduce blast furnace coke consumption using electrical energy and large scale coal injection through the tuyeres. Since this time, Westinghouse Plasma Corporation has improved torch reliability with industrial experience in solid-waste-to-energy facilities, as well as metallurgical applications. As coke makes up one-third of the hot metal cost, savings efforts frequently seek to lower coke consumption by increasing process efficiency or replacing coke with cheaper fuels. Alter NRG and Hatch assessed the merits of using plasma torch technology to superheat the hot blast. Coke rate savings, electrical purchase requirements, and a financial analysis to implement the torches are presented.

Aug 17, 2017

By Luis Armando Espitia

AISI 410 martensitic stainless steel specimens were low temperature plasma nitrided at 400°C in a mixture of 75%N2:25%H2, during 20 h. Active screen technic was used to avoid any edge effect The nitrided case is composed of expanded martensite (a’N) and e-Fe3N iron nitride, whilst chromium nitride precipitation was avoided. Surface hardness reached 1275 HV0.01. The transverse microhardness profile shows a gentle hardness gradient with a NHT nitrided case depth of 28 µm. Nanoindentation tests were carried out in order to assess the hardness (H), the Young modulus (E), the H/E and H3/E2 ratios and the elastic recovery (We) of both nitrided and non-nitrided specimens. The cavitation erosion mass losses were measured as a function of exposure time. The results showed a decrease of 27 times of the mass loss compared to the non-nitride specimens. Wear rate decreased from 2.56 mg/h for the non-nitrided condition to 0.085 mg/h after nitriding. The increment in the elastic recovery and the higher hardness values are responsible for the greater cavitation erosion resistance exhibited by the expanded martensite. Such results showed that low temperature plasma nitriding and the formation of expanded martensite are effective to increase cavitation erosion resistance of AISI 410 stainless steel.

Jul 31, 2018

By Maciej Korecki

Pyrowear®Alloy 53 steel is an excellent material for the construction of drive transmission components (gears, shafts, etc.) which have to operate in difficult conditions primarily in the aviation industry (Fig. 1.). Among the properties of such items is a high case hardness and abrasion-resistance, while the core remains flexible and is capable of carrying large impact loads. They can work at elevated temperatures with limited lubrication. The thermal treatment of such materials is based on case hardening by means of carburizing. This paper presents the technology of vacuum carburizing of Pyrowear® Alloy 53 steel. It discusses the methods of establishing different profiles of carbon concentration in a layer and their influence on the hardness profile. The effects of sub-zero treatment and tempering on the properties of the hardened case are also considered. It also presents a SimVaC® simulator of vacuum carburizing, designed especially for Pyrowear® Alloy 53 steel, which provides highly accurate predictions of the outcome of the process as the profile of carbon concentration in the layer, or vice versa: establishes the process parameters which will guarantee the required profile.

Aug 16, 2017

By Liao Jianfeng

The Baosteel Zhanjiang 5,050m3 blast furnaces have been built with highly independent integration and innovation technologies and represented the state of the art of the world’s huge BFs. The proper of BF1 and BF2 is designed with long-campaign technology; both BFs share the same set of stockhouse, water and PCI systems; the BCQS serial-hopper no-bell top, TRT and blower are all local equipment as applied; four top-combustion stoves systems are matched; the BFG is cleaned by fully dry process; and the automation control system for the main process is self integrated. The BFs have been started up and performing with sound indicators. Their smooth proceedings symbolize China’s huge blast furnace ironmaking technology ascending a new high.

Oct 30, 2017