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Thermal Processing of Petroleum Fly Ash for Vanadium Recovery

Sep 13, 2010

By Patridge A. C

Observations of coal stockpiles subject to unusual levels of instability showed that the particular coals exhibited 'gap grading', a relative lack of intermediate size particles. This led to a suggestion that fine coal particles within the pile might have been induced to migrate under the influence of water flow and to concentrate in relatively impervious layers, resulting in local water saturation and reduction of shear strength. To investigate this suggestion, a large test column has been constructed and washed coals with various levels of fines content have been subjected to a downward flow of water. Subsequent examination of the bed of coal within the column confirmed the percolation of fines and their concentration into horizontal layers, and showed the development of zones of saturation above those layers. Shear box tests showed differences in cohesion and internal friction angle between coals with different percentages of fines, supporting the hypothesis that fines percolation may lead to decreased stability.

Jan 1, 1995

The Hunter Valley Rail Project (HVRP) represents most of the coal producers using the Hunter Valley Rail System in NSW to haul coal to the port of Newcastle. This system carries over 70 per cent of NSW's coal exports, comprising over 30 per cent of total Australian coal exports. Hunter Valley coal is the largest export industry in NSW, and one of its largest export growth opportunities. However, the industry is under intense pressure in international markets from existing and new coal producers and from other energy sources. Whilst potential growth in demand is substantial, particularly for thermal coal in Asia, excess world supply has pushed prices down, and this underlying trend may well continue. The industry has lost international competitiveness and as a result, investment has dropped 44 per cent over the last two years. The industry must be rapidly structured to compete and attract investment on the basis that these pressures will continue. Substantial productivity improvement and cost reductions must be made for the industry to regain competitiveness, otherwise growth will not occur and the industry will decline, with serious implications for the Australian and NSW communities. The introduction of internationally competitive rail freight rates is an urgent and essential part of this process. It is the key objective of the HVRP.

Jan 1, 1995

By Pradhan GK

Blasting is one of the most important operations involved in surface coal mining. The removal of over-burden waste in surface coal mines of India had experienced many improvements in terms of blasting, explosives selection, blast design, equipment selection, deployment. etc. Two case studies of very large surface coal mines have particular importance in their blasting operations. Both these units have been equipped with large capacity excavating machines, hauling units and also have some difficult mining situations. Blasting is done in benches in close proximity to human dwellings and over coal seams developed by underground methods with problems of high wall stability etc, as well. The various steps taken to improve the blasting operations ensure smooth operation of the equipment to meet the targetted coal production.

Jan 1, 1991

A review of ground control procedures in Western Australian underground mines is presented. Geotechnical input into initial mine design and methods of ground control is rare. As a result, the frequency of unexpected rockfalls is comparatively high, with over three quarters of the mines adopting non-specialist ground control designs experiencing unexpected falls-of-ground. In contrast, mines that provide some level of specialist input into initial ground control design experience decreased rockfall frequencies.

Jan 1, 1992

This paper reviews the issues of mining machinery automation with special emphasis on underground applications. Automation is desirable because it offers the following advantages: ò increased safety by reducing human exposure to hazards of underground mining; ò higher productivity; and ò reduced wear of equipment. In spite of these advantages and in spite of numerous attempts over the past several decades, mining automation has been a difficult proposition, partly because no two mining operations are exactly alike and these operations are carried out in an unpredictable environment. This is the main difference between automation in factories and in mines and that is why mining automation has been lagging so far behind factory automation. Automation is possible only when the machine 'knows' its workspace. In a factory, this workspace can be 'described' to the machine because it is sufficiently controlled. In a mine, the environment undergoes continuous change and the only way the machine can 'know' its workspace is through real-time sensing.

Jan 1, 1995

By Kubo H, Ninomiya R, Ojiro T, Sato T

New high-strength Zn alloys for moulds are demanded from the automobile and electric industries in Japan, because the s rength of Zn moulds is still not high enough for the mass production. There are two approaches to improve the strength of Zn alloys. One is to increase the Al content. ZA alloys (ZA-8, ZA-12, ZA-27) were developed through this approach. The other is to increase the Cu content. But it is known that an increase in Cu generally depresses the castability of Zn alloys, so that the alloys with increased Cu have been rarely studied until now. In this study a reconciliation between the strengthening and the castability of Zn alloys by enriching both with Al and Cu has been attempted. Accordingly we have studied on the Zn alloys containing 4 to 25 mass per cent Al and to 24 mass per cent Cu have been studied. Their fluidity, which primarily corresponds to the castability of the alloy, were measured first and 19 alloys were selected based upon their fluidities and casting temperatures. Mainly the mechanical properties of all 19 alloys were tested and some were found to be excellent in both strength and castability. Z1009 (Zn-IOAI-9Cu-0.02Mg alloy) cast in a sand mould has the tensile strength of 360 MPa while ZAS (Zn-4AI-3Cu-0.04Mg alloy), which is the most popular alloy for moulds, is 215 MPa. Z2520 (Zn-25AI-20Cu-0.02Mg alloy) cast in a sand mould has a Vickers hardness of 178, compared to 107 for ZAS and 104 for ZA-27 (Zn-27AI-2Cu-0.02Mg). Furthermore the castability of Z1009 is as good as that of ZAS. The underside shrinkage occuring in casting ZA-27 is restrained in Z2520.

Jan 1, 1993

By Ho E

Analyses of several nickel mattes from around the world show a significant variation in their copper content. Typically, matte contains an alloy, heazlewoodite and a copper sulphide phase. The various commercial methods of processing these mattes are reviewed and some of the fundamental factors which determine the choice of leaching system are discussed. Electrochemical studies on pure heazlewoodite and millerite in sulphate and chloride media are compared which show that nickel sulphides react via a series of nickel deficient sulphides and exhibit passivation as nickel is removed. Differences in the electrochemical behaviour of nickel sulphides in chloride media are attributed to greater crystallinity of sulphur and less formation of'NiS2. The electrochemistry of mattes differs because of the presence of alloy and copper. Copper in the matte modifies the potential for alloy dissolution and the rate of anodic dissolution of nickel. At elevated temperatures, Cu(II) in solution exchanges with NiS and completes the leaching of nickel at relatively low potentials without significant oxidation of sulphur to sulphate. It is concluded that there are fundamental advantages to leaching nickel matte in chloride media using Cu(II)/Clz as the oxidant.

Jan 1, 1996

Methane is present in varying degrees in nearly all underground coal mining operations. At mixtures with air near 5-15% it is explosive and consequently since it is not usual for these levels of contamination to be reached in the general body of a mine ventilation system it is not unusual to experience it in specific places. On longwall faces the most used power loader is the shearer machine and because of its general shape, situation and operation it is likely that all the factors which are required to cause a frictional ignition can be present. This paper makes a general appreciation of the causes of these ignitions and methods which are and have been used to control these situations on and around these machines.

Jan 1, 1981

By Clarke RG

Renison Mine was developed as the first all diesel mine in Australia. The foresight of the early planners in committing the Mine to Decline access has paid dividends in the past two decades with Renison Mine establishing itself as one of the most productive underground mines in the world. The excellent productivity has also resulted from the development of mining equipment technology, both on the part of the equipment suppliers and through the coordination of the Mining, Automotive and Technical Design Sections at Renison Mine. Constant improvements in truck and loader design, the design of specific equipment to carry out specialized tasks such as installation of services, scaling and ground support and the conversion to electrically powered equipment have been ongoing at Renison. Currently, larger scale trucks are being investigated for ore and waste haulage due to increased haulage distances and production requirements. It appears as though an articulated low profile truck of around 50 tonnes capacity may provide the short term solution based on the performance data available.

Jan 1, 1982

By Schofield D, Denby B, Stout F, Moli A

This paper documents the development of a user-friendly computational program, which has been constructed to assist the mine ventilation engineer in the optimal design and operation of methane drainage ranges. In the past, many computer tools for ventilation engineers led to the development of `research systems'. These computer systems, although developed with the needs of the industry in mind were due to a combination of inexperienced programming methods and the availability of suitable user interface software not easily accessible to the practising engineer. Recent developments in computer hardware and software (particularly windows based graphical user interfaces) mean that engineers no longer need to dedicate large amounts of valuable time to become familiar with often complex items of software. The authors of this paper intend to demonstrate a practical system which successfully integrates complex mathematical models, an easy to use interface and knowledge based techniques. The graphical interface guides the user to draw on the screen a mimic diagram representation of the methane drainage network. The user is prompted, during the construction of the drawing, to input the information and data required by the calculation and knowledge based procedures. The computer program then calculates all of the flows, purities and pressures throughout the network. Given reliable measured data from an existing range a comparative analysis can be performed between the predicted and measured network flow data. A knowledge-based system may utilise this analysis to either update the operational status of the network or suggest either a reasoned maintenance or remedial strategy to improve the performance of the drainage system. The development of the OMEN project has been carried out at the request of the Midlands Group, British Coal Corporation, Edwinstowe. The system is about to be field tested at a number of mines. It is hoped that when this paper is presented that the system will be used at both Group and mine level.

Jan 1, 1995

By Torabi S. R, Daly C. R

Wind blast is the sudden movement of air displaced by the massive collapse of roof rock in underground openings and is experienced as a high velocity flow of air through adjacent workings. The initial flow in the outbye direction is often followed by 'suck back', that is a reverse flow of air towards the newly created void. As part of the Wind Blast Project, undertaken by The University of New South Wales, Department of Mining Engineering, a physical model was constructed. One of the functions of the laboratory wind blast model is to provide insight into the dynamics of the interaction between the falling strata and the air being compressed below. During a collapse, some air is expelled into the surrounding roadways while the remainder penetrates towards the top of the roof elements. In this paper two aspects of the rock mass properties which influence the phenomenon are considered: - Flow paths through the falling roof element, ie the permeability of the roof element; - Bed separation prior to the fall which introduces a void above the roof element. A series of tests was carried out utilising the physical model in order to investigate the relationships between the flow of air through the simulated roadways, the variations in gauge pressure above and below the falling roof element, and the acceleration and terminal velocity of the latter, all as a function of the flow paths through the roof element and of the extent of the void above. The results of comprehensive tests using the wind blast physical model suggested that the time history of outbye air flow in the simulated roadway comprises two distinct phases. a) A primary phase, characterised by a high velocity flow of air which exhibits a peak and corresponds to the period during which the roof element is accelerating. The peak air velocity is related to the acceleration of the roof element. b) A secondary phase, characterised by a residual air flow of a lesser velocity than in the primary phase and corresponding to the period during which the roof element is falling at its terminal velocity. The velocity of the residual air flow is directly proportional to the terminal velocity of the roof element. In a monolithic collapse of a roof element it was shown that the presence of flow paths in the roof element increased the air velocity in the roadway in both the primary and the secondary phases. The presence of an air-filled void above the roof element, on the other hand, influenced the air velocity only in the primary phase by increasing the peak air velocity. The overall duration of the process was however decreased as a result. 'plug type' collapses, where roof failure extends to the ground surface, potentially generate the highest peak air velocities likely to be encountered during wind blasts.

Jan 1, 1995

By Baczynski NR, Fagan MJ

A 3050m long section of a 1.65m internal diameter tunnel is presently under construction in the Brisbane area by means of the pipe-jacking method. The soils along the alignment had been deposited in a deltaic/estaurine environment and rapid changes in soil type occur. The tunnel passes beneath several extensive bodies of surface water. Groundwater problems have been experienced with tunnelling through alluvial sands and gravels. Details of the ground conditions, the pipe-jacking method used and tunnelling experience are discussed in this Paper.

Jan 1, 1987

By Albinson T

Mexican epithermal deposits can be broadly grouped into two types based on their contained metals, distribution, associated igneous rocks and fluid inclusion compositions. Silver-gold deposits (e.g. Tayoltita) mostly occur in the western part of northern Mexico where host rocks consist of Eocene, intermediate composition volcanic and intrusive rocks; fluid inclusion studies indicate that mineralizing fluids were _10 eq. wt. % NaCl). The distribution of these two deposit types, crosscutting major major crustal sutures, and the close spatial-temporal relationships between mineralization and magmatism, together suggest that magmatic processes were more important in the formation of mineralizing solutions, as a source of both ligands and metals, than the segments of crust hosting deposits.

Jan 1, 1995

By Scales PJ

Fatigue is the primary cause of failure of structural and mechanical components subject to dynamic loading. Recognition of this basic fact and the development of appropriate techniques and details are important in the design and repair of off highway trucks (OHTs). The frames and appendages of OHTs and other mobile plant used in the Pilbara are subject to tough operating conditions. Any fatigue-prone details quickly show up and become a maintenance liability of considerable concern. Much of this equipment is approaching the limit of its fatigue life and maintenance managers face decisions on whether to repair or replace. Even new equipment often contains some poor details which suffer distress soon after commissioning. In those cases a repair is required which will reinstate the detail to its original intended design life. Repair details must be practical and cost effective. They must also be tailored to the capability and expertise available in the field or in local manufacturers' establishments. This is particularly important where original equipment was manufactured overseas and long delivery times are involved. Lessons are drawn from components which have failed, using the evidence constructively, to provide an upgraded part or an improved substitute. With the experience now available it is relatively easy to extrapolate to cover new problem areas. This paper describes specialised techniques of mechanical fastening and detailing for low fatigue susceptibility, built up over many years of experience with OHTs and other mining plant and equipment in the Pilbara.

Jan 1, 1982

By Fiedler VA, Threadingham GM, Leckenby DF, Clarkson CJ

The Utah Development Company Research and Development Laboratory has embarked upon a programme of optimisation of the company's coal preparation plants. This goal is being accomplished in a three-fold manner - use of pilot plant equipment for optimisation and modelling of the various unit operations, evaluation or development of on-stream ash analysis for process control, and evaluation or development of alternative processes. In each of these areas, digital data acquisition- and at a later stage, process control feedback, is being extensively utilised, based largely upon the use of the HP85 and HP9915 desktop computers. A variety of input/output configurations such as HPIB, BCD, GPIO are used, and at times supplemented by microprocessors such as the Intel 80/05 to assist in data transfer. This paper will discuss a number of specific projects, especially in relation to the manner in which the variables are monitored, and the data later retrieved and analysed.

Jan 1, 1983

By P J. Clark, A W. Fisher, R G. Ford

Site characterisation of subsurface contaminant transport is often hampered by a lack of knowledge of site heterogeneity and temporal variations in hydrogeochemistry. The use of a regional-scale data compilation derived from satellite imaging is discussed with respect to directing design of site characterisation to monitor the fate of a Dense Non-Aqueous Phase Liquid (DNAPL) plume in Nevada. Evaluation of the drainage basin contributing to the groundwater flux into the study site was used to re-assess the site conceptual model and re-direct the characterisation effort. The use of highly resolved measurements of subsurface hydrogeochemistry in space and time were employed to identify the predominant biogeochemical processes controlling arsenic transport during discharge of groundwater into a pond at a site in Massachusetts. Direct-push conductivity measurements coupled with vertically-resolved sampling within the pond and adjoining aquifer demonstrated spatial and temporal variations in dissolved arsenic within groundwater and the pond water column and sediment pore water. Spatial variability was observed over the scale of centimetres to metres, and temporal variations were observed over the scales of days (following storm events) to seasons. Microbially-driven redox processes maintained anoxic conditions in groundwater and at the sediment-water interface (iron and sulfate reduction) and exerted both a direct and indirect influence on arsenic solution speciation and partitioning to surface water sediments.

Jan 1, 2004

Drag pick roadheaders and continuous miners have been applied in the coal mining industry for several decades, having replaced drill-blast methods as the primary means of excavating coal and coal-measures strata. The generally harder rock types associated with metalliferous mining have precluded the use of such machines in the past, however, developments in machine technology and increasing labour costs and environmental constraints suggest that there are now likely to be applications suited to the method. Metalliferous mining engineers are generally unfamiliar with the machines themselves and with the fundamental criteria controlling rock cuttability. This paper gives an introduction to the machines and the controlling factors.

Jan 1, 1987

By Mathew P. J

The CSIRO Division of Mineral and Process Engineering in Melbourne has been developing on-stream analysis sensors based on neutron and gamma radiation for better control of quality and process operations. This has resulted in the development of Ironscan, an on-stream analyser that measures the iron content of both lump and fine iron ore on conveyor belts. It can be mounted under existing conveyors with minimal modifications to the conveyor structure and can cope with steel cables in the belt. An interface gauge and an on-stream coal ash analyser have also been developed, both based on measurement of natural radioactivity. The interface gauge monitors the interface between liquor and mud in thickeners and washers, provided the natural radioactivity of the mud is sufficiently high to detect it above background. The natural-gamma ash gauge is a valuable addition to the Coalscan range of ash gauges. It is applicable to heavily laden coal conveyors or bins where the coal bed thickness exceeds 30 cm, and also to lightly laden conveyors, provided the coal is profiled on the conveyor.

Jan 1, 1991

The mineralogy of regolith material for which whole rock geochemistry has already been done can be used to better understand/rank the significance of geochemical anomalies. Case studies show that the secondary minerals of the regolith environment have quite different capacities to incorporate pathfinder and target elements, eg hematite appears to be a better host to Pb than goethite and Pb rich alunite-jarosite minerals are a better Ag host than mimetite. Thus correlations between elements in regolith material may be strongly affected by mineralogy. Understanding of the significance of a geochemical anomaly is frequently enhanced by knowledge of the weathering susceptibility of different minerals. For example, when a mineralogical sequence which does not correspond to the expected order is found (eg feldspar overlying weathered material without feldspars) it is possible that transported material is present in the profile. Such mineralogical information is particularly relevant as exploration continues into areas of thick regolith.

Jan 1, 1997