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By Fidelis T. Suorineni

The Ashanti mine, located in Obusai, Ghana, West Africa, has been in production for over 100 years, and is currently the second largest single gold producer in Africa. The mine covers a concession area of 434 square kilometers with four main ore types: the quartz vein type, disseminated sulphide type, supergene sulphides and transition ore, and granitoids stock works (visible gold and quartz veinlets). Various mining strategies and methods have been employed for the mining of the narrow-vein ore at Ashanti. In recent years, the mine owner: Ashanti Goldfields Company Ltd. has embarked on a mine-wide expansion program to boost production to a target of one million ounces per annum. With the rapid depletion of its high-grade ore, a suitable mining method was required to produce a high tonnage at low cost to meet production objectives. This paper discusses how the Ashanti mine applied Canada experiences in mining technology to boost production, and the impact that the differing geological settings between the two countries had on the stope performance at the Ashanti operations. Experience developed at the Ashanti mine led to innovative modifications for stope layout and design methods in relatively poor ground conditions.

Oct 1, 2001

DynoMiner APS Delivery Systems Overview ? New Design of DynoMiner APS-M2 ? Stand alone or attach to Cargo type 10,000 lb (4536 kg) emulsion bins. ? Hose reel w/200-ft (61-m) by 1-inch I.D (25-mm) hose capacity, power rewind. ? Increased water and trace capacity. ? Hose reel and gassing offered as options. ? New Flow Meter ? DN-100: aluminum body, UHMWPE rotors. ? Will be offered as an option. ? APS Nomenclature ? Proposed changes ? DynoMiner APS and APS-M1 to become DynoMiner APS Drifter ? DynoMiner APS-M2 to become DynoMiner APS Stoper. ? Both to have optional gassing / flow metering.

May 1, 2004

Reliable estimation of in situ stress is a major step in the analysis and design of underground excavations in rock, particularly for evaluating the stability of underground structures to prevent failure or collapse. In the last ten years, the Western Australian School of Mines (WASM) has studied and developed an AE stress measurement technique using orientated core named the WASM AE method. It allows the determination of a representative and detailed knowledge of the in situ stress field during the early stages of a project (such as mine feasibility studies), even in areas where development access is not yet available. The method has been used for in situ stress measurement at more than 80 mine sites worldwide with over 200 individual stress measurements carried out to date. This paper describes the sample collection, sample testing and reconciliation of results for very deep measurements carried out at the Craig-Onaping mine complex in Sudbury Canada. The results constitute the deepest measurements undertaken to date at the WA School of Mines and indicate that the main principal stress is horizontal and oriented parallel to a common regional sub trend in a NE/SW direction.

May 1, 2009

By J. A. Meech, R. J. Tucker

"Since the establishment of froth flotation as an effective method of mineral beneficiation there has been both academic and industrial interest in the levels of the various reagents required to perform the desired separations. Academic interest was spurred by a desire to understand the mechanisms involved - industrial interest by a need to improve the efficiency of the process. These efficiency improvements can take two forms: cost reductions due to reduced reagent consumption and/or improved separation efficiencies. The latter are indicated by either improved grade-recovery relationships for removal of a valuable mineral from gangue, or improved separation of two similar valuable minerals.The processing of lower grade ore bodies at higher tonnage rates has necessitated increased interest in both reagent consumption and metal recovery. Furthermore, the development of accurate and functional on-stream analysis equipment in the 1960's and 1970's has allowed for a better understanding of the dynamic processes involved in a flotation circuit and has required a more concrete statement of the relationships and reactions between the minerals and chemicals in the flotation pulp. Development of these relationships is necessary in order to make use of on-stream analysis to control the process at, or near its more efficient level."

Jan 1, 1984

By T. Gerritsen, T. Plikas, K. Ochoa, M. Loveless, R. MacRosty, J. Reichart, R. Pula

Sidewall accretion in a smelting furnace plays an important role in furnace integrity as it provides protection to the sidewall cooling elements and thereby extends the furnace campaign life. The extreme thermal and mechanical stresses in the furnace and changes in the slag chemistry can cause the sidewall accretion to melt or break away decreasing the lining protecting the cooling elements. Thin accretion is highly undesirable as it increases the risk of exposing the cooling elements to the molten bath and in the worst case may lead to a failure. Therefore, monitoring the sidewall accretion on an operating furnace is extremely important to manage furnace integrity and to support safe furnace operation. Operators often generate estimates for sidewall accretion and refractory thickness using either copper cooler temperatures or heat load into the cooling water circuits. Multivariate statistical models, on the other hand, have the capability to consider all the process measurements simultaneously to provide a more reliable estimate. This paper describes the application of multivariate statistical models for sidewall integrity monitoring on a Flash Converting Furnace (FCF) and also discusses the online implementation of these models as the Sidewall Accretion Monitoring System. INTRODUCTION Rio Tinto’s Kennecott Utah Copper (KUC) smelter located near Salt Lake city, Utah operates a Flash Smelting Furnace (FSF) and a Flash Converting Furnace (FCF) to produce high-grade matte and blister copper respectively. Since the commissioning of smelter in 1995, several improvements were made to these furnaces to increase their efficiency and operational safety. At present, Kennecott smelter is known to be among the lowest-emission and highest energy recovery copper smelters in the world. Since the smelter start-up, Kennecott has invested in several advanced furnace monitoring practices to evaluate the integrity of the furnaces and improve their campaign life. An example is their temperature monitoring system installed for the smelting and converting furnaces, which continuously monitors the furnace sidewall temperatures and notifies the operators during temperature excursions. During an investigation on the converting furnace, it was revealed that there were frequent temperature excursions in the settler sidewall area towards the reaction shaft end of the furnace that caused significant furnace downtime. The reason for the sidewall temperature excursions was not clearly known.

Jan 1, 2019

By Ken Wood

"A reliable source of water of an acceptable quality is vital to the success of any mineral processing plant using wet methods. For Cerro Verde, a new 108,000 t/d copper mill in southern Peru, the main source of raw water is the Chili River. The Chili River is heavily contaminated with raw sewage, industrial wastewater and agricultural runoff, and can also receive high sediment loads during the rainy season. The initial water treatment plant could not supply design flows of water due to the exceptionally poor water quality. Problems with treated water quality caused significant difficulties with water consuming equipment, such as the plant cooling systems. This paper details the Cerro Verde water system and changes from design through to start up from a mineral processing perspective.INTRODUCTIONMining, and mineral processing in particular, is a water intensive activity. Improving water system design and practice are key strategic requirements in moving toward a more sustainable mining industry. This case study forms a basis for ongoing research into water use and reuse at mines and mineral process plants, conducted by AJ Gunson, under the supervision of Dr. Bern Klein and Dr. Marcello Veiga at the University of British Columbia. The case study material was gathered through involvement with the design, startup, and redesign of the Cerro Verde water system.Cerro Verde is a low-grade copper porphyry mine, located near the city of Arequipa in southern Peru, at an elevation approaching 2,800 m. In 1972, one of the world’s first copper Solvent Extraction – Electrowinning (SX/EW) facilities was built on the site, processing oxide ore from two main open pits. In 2004, the operator, Sociedad Minera Cerro Verde S.A.A. (SMCV), approved a 108,000 t/d expansion project to process sulfide ore reserves through a new concentrator plant. The plant was designed under extremely tight schedule and capital constraints, with a mandate to intentionally avoid any overdesign."

Jan 1, 2008

By Norman A. Jull

"Factors which affect the separation achieved in a hydrocyclone are discussed and illustrated with graphs of some mathematical relationships.Definitions of separation and sharpness include comment on use of elutriation devices.A plea is made for better evaluation of field data prior to their reporting or use in calculations. Methods of evaluation are suggested, with samples of the relevant calculations.An example of the effect of percent solids errors is given, with computer printout and plotted corrected recoveries.INTRODUCTIONThe range of interest in cyclones runs from a simple demand for classification results to a detailed study of published equations defining cyclone characteristics. Probably this group covers as broad a range and, in an attempt to offer something for everyone, I will begin with general operating comments, then move on to more analytical topics. Ideally, an author would compose his paper after the discussion period, when he would have a better idea of the areas of special interest to his audience.Sor'1e of you may share our incurable fascination with classification, especially as performed in cyclones. It is amazing that such a simple device could be in use for more than 20 years and retain as much mystery as it does. Substantial parts of the mystery have been solved but some remains, to keep up our curiosity. There is at least one valid reason: the unusual compactness of this device, which makes internal observation very difficult. What other unit can you think of which performs such a complex separation between particle sizes, shapes and specific gravities at such high capacity? Retention time in a cyclone is typically 3 seconds!Mutual Agreement - In a cyclone, every parameter of geometry and of operation interacts with every other. In an orderly discussion of individual parameters it would be necessary to repeat, in every section, 11 if all other factors are equal"". Could we agree now, for our mutual convenience, that that phrase is clearly understood between us during the remainder of this paper?"

Jan 1, 1972

By R. Sharon, P. M. Hawley, X. Ochoa

"Development of Barrick Gold’s Pierina gold mine in north-central Peru requires construction of a waste dump for disposal of nonore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low-quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high-quality, hard, durable, blocky waste rock.A hybrid dump design concept was developed that requires in-pit segregation of highand low-quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included.This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems."

Jan 1, 2003

By Robert J. Maron, Mark Fernald, Alex Van der Spek, O’Keefe. Christian, Tim Bailey

"Sonar array-based non-invasive flow measurement technology is becoming an accepted and many times a preferred method of measuring challenging single and multi-phase flows in the mineral processing industry. This fundamental sensor and measurement technology has been extended to two developments that provide new measurement capabilities useful for monitoring and managing slurry flows and pipes.The first development is the non-invasive measurement of real-time velocity profile of slurry flow in horizontal pipes. Multiple non-invasive passive sensors measure localized velocities and are combined to provide a velocity profile measurement. This information can be used to determine the approach and onset of solid deposition on the bottom of the pipe. Having this information in real time can enable operation at lower velocities and/or higher solids concentration while avoiding solids deposition or plugging and its associated operational costs.The second development is the non-invasive measurement of pipe wear on slurry lines. Presently, such measurements are made by hand-held portable ultrasonic thickness gages. The numerous shortfalls associated with the manual method are overcome with a set of permanently or semi-permanently installed transducers clamped onto the outside of the pipe. This ring of sensors contains a series of conformable ultrasonic transducers spaced around the circumference, which are used to measure the thickness of the pipe under their respective locations. Compared to manual methods, this system and approach results in better repeatability and accuracy. It also decreases inspection labor costs and pipe access requirements. The minimal accuracy variations in the presence of varying environmental temperatures will be shown. Trending of pipe wall thicknesses in high wear pipelines will be illustrated. The benefits of significantly improved pipe wear monitoring in hydrotransport lines with abrasive solids, and associated improvement in the ability to insure safe operation and avoidance of costly environmental damage due to leaks caused by pipe wear will be discussed."

Jan 1, 2009

By James R. Lang

The Xietongmen deposit is located 350 km west of Lhasa, Tibet. It is a new, high-grade porphyry copper-gold discovery and the first deposit to be systematically explored by a western company in southern Tibet. In 2005, Continental Minerals Corporation drilled 21,332 m of core in 63 holes and demonstrated excellent lateral and vertical continuity of high-grade copper-gold mineralization over an area 750 m by up to 350 m in size which remains open in all lateral directions. Drill intersections repeatedly yield grades >1% Cu equivalent (based on gold and copper prices) and include 308.5 m at 0.87% Cu and 1.25 g/T Au (1.60 CuEQ%), and 315.6 metres at 0.61% Cu and 1.11 g/T Au (1.26 CuEQ%). Extensive drilling in 2006 will expand and delineate the deposit, and metallurgical, engineering, environmental and socio-economic evaluations will begin. Xietongmen is hosted by volcanic and intrusive rocks of the Gangdese belt, a magmatic arc active between 120 and 30 Ma along the southern margin of Eurasia. Pervasive alteration is dominated by a well-mineralized K-feldspar and biotite assemblage, and by a more peripheral sericitic assemblage also with strong chalcopyrite. Major vein stages include chalcopyrite-bearing quartz, biotite, magnetite and pyrite-pyrrhotite types.

May 1, 2006

By Derek H. C. Wilton, David T. W. Evans

"Abstract - The Midas Pond gold prospect, central Newfoundland, is hosted by sheared and altered felsic and mafic pyroclastic rocks of the Tulks Hill volcanics, Victoria Lake Group, and has been trenched and tested by 19 diamond-drill holes. Gold values are sporadic, with the best diamond-drill intersection assaying 7.3 g/t over 0.9 m, and the highest grade channel sample containing 14.7 g/t over 1.15 m. Alteration and mineralization are confined to a 200 m wide brittle-ductile shear zone. This shear zone formed in response to regional D1 deformation, and the shear zone fabric parallels the regional S1 foliation. D2 deformation resulted in broad Z-shaped flexuring of the shear zone. The deformation was probably related to the ca. 396 Ma to 420 Ma Salinic Orogeny.Advanced argillic alteration and an extensive halo of Fe-carbonate and pyrite surround the gold mineralization. Alteration minerals include pyrophyllite, paragonite, quartz, plagioclase, chlorite, fluorite, Fe-carbonate, and pyrite. As such, the alteration seems to reflect combined epithermal (argillic) and mesothermal (carbonate) mineralizing environments. The argillic alteration and fluorite represent a regional hydrothermal effect on the felsic volcanic rocks; whereas, the Fe-carbonate and pyrite represent a mesothermal alteration associated with auriferous quartz veins. The Au, which is spatially associated with pyrite, occurs in three structurally-controlled vein sets. These veins are confined to the contact between a highly deformed breccia (the banded mafic tuff) and structurally overlying, altered felsic tuffaceous rocks. The vein sets include: V1 boudinage veins that parallel the shear-zone fabric (C-shear veins), and V2 and V3 extensional fracture veins which are controlled by an S2 fracture cleavage. V1 veins are the earliest and contain the lowest concentrations of Au. V2 and V3 veins are concentrated within the hinges of the D2 flexures.Pb isotope data for galena separates indicate that the Pb in the vein systems was probably of local derivation. Sulfur, C, and O isotope data for mineral separates are similar to data for typical mesothermal lode gold deposits. Fluid inclusion data suggest the presence of at least three hydrothermal fluid types in the region, viz., (1) an early saline fluid which produced the argillic alteration, (2) a CO2-bearing fluid directly related to the auriferous mineralization, and (3) H2O-NaCl fluids which flowed through the Midas Pond shear zone at a lateral distance from the zone of mineralization. The mineralizing fluids are interpreted to have been CO3 -2-rich types which originated through metamorphic dehydration and decarbonation of mixed island-arc and continental crustal rocks. Gold precipitation resulted from the reaction of these fluids with the Fe-rich breccia unit. Pre-existing and simultaneously crystallizing pyrite served as loci for Au precipitation."

Jan 1, 2000

By M. Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

Jan 1, 2005

By R. Mckinstry, M. Rantapaa, T. Bolles

"Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput.Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore.Barrick Goldstrike’s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs."

Jan 1, 2005

By M. A. Upham

"MINING is Canada's second largest basic industry, producing material with a gross value of 2.5 billion dollars, led only by agriculture with 2.9 billion dollars. It pro-vides employment, directly and in-directly, for three quarters of a million people. Since the Second War, the value of mineral production in Canada has tripled. Economists forecast that over the next 15 years its value will triple again. Canada is a basic and leading supplier of nickel, iron, copper, zinc, lead and uranium. It is also a major oil producer, leads the world in the production of asbestos and in five years will be the leading producer of potash, a basic constituent of fertilizer.It can be seen that Canada's wealth and economic progress lies in being a primary producer of economic minerals and in building secondary industries to manufacture finished products from these raw materials. Canada's future in the field of mineral production looks bright, with our resources just starting to be tapped. Outside of the large expanse of Soviet Russia, we are by far the world's most fertile mineral exploration area."

Jan 1, 1967

By V. I. Lakshmanan

Process Research ORTECH Inc. (PRO), with its in-depth knowledge on cobalt behaviour in nickel matte smelters and its novel mixed chloride hydrometallurgical processing, is developing a hybrid process to enhance cobalt recovery. PRO’s experimental data is compared with plant information on cobalt behaviour in smelters. In final stages of iron rejection in the converters, the thermodynamics of the matte-slag system dictates the undesirable transfer of the cobalt to the final converter slags. This results in much lower cobalt recovery in the product Copper/Nickel matte (<60%) in present copper and nickel smelters. This information is used to transfer cobalt into desired quantity of converter slag. The enriched cobalt slag is subjected to PRO mixed chloride process to recover nickel, and cobalt as high value salts of importance in lithium ion batteries. From a typical converter slag containing 3.5% Ni, 1.5% Co, and 1.0% Cu, PRO leach process extracts 98 % Ni, and 98 % Co, and 99% Cu. Application of this process to enhance cobalt recovery in typical Copper/Nickel smelters is presented. In addition, this will also enhance the Copper and Nickel recovery. Both these aspects are of interest to the Copper, Nickel, and cobalt producers. INTRODUCTION In pyrometallurgical extraction of copper and nickel from sulphide ores cobalt often occurs with copper and nickel. The requirement of cobalt is increasing due to its need in lithium ion cells used in electric vehicles. Therefore its efficient and economical extraction in a form suitable for use in lithium batteries is of great interest at present. In the pyrometallurgical processing of copper and nickel sulphide concentrates the concentrate is smelted to produce a furnace matte, which is then sent for converting to remove the iron to produce iron free (~1% Fe) matte for further processing to copper or nickel matte. The copper/nickel matte is processed for metals recovery by hydrometallurgical or vapo-metallurgical or oxidation – reduction routes to make market products. As shown in Figures 1 and 2 the slags are produced in the smelting step and in the converting steps. The metal losses in smelting are controlled by the oxygen pressure in that step and slag production which is controlled by concentrate grade. The slag produced in the converting step which is carried out at a higher oxygen pressure contains higher level of metals is often returned to the smelting step to increase value metals recovery.

Jan 1, 2019

By D. Fleury

"This paper describes the challenges of mining a sill pillar under various types of paste backfill quality. From 1994 to 2002, Louvicourt mine produced approximately 12,600,000 t grading 3.5% Cu, 1.5% Zn, 27 g/mt Ag, and 0.85 g/mt Au. The mining method is transverse blasthole stoping, mining primary and secondary stopes. The production of this 4,300 t/d operation was accomplished using two mining horizons; from the 655 m level to the 415 m level and from the 860 m level to the 680 m level. The main sill pillar is between the 680 m level and the 655 m level. The second sill pillar is between the 885 m level and the 860 m level representing a quarter of the main sill pillar in size. Since 2002, production has gradually decreased and mining activities are expected to end in mid-2005. The sill pillar production will represent almost 25% of the total mine production. The overall recovery of the sill pillars stopes will be discussed in this paper. To recover the sill pillars, more than 1,500 m of development was planned in or under paste backfill. The first sill pillar stopes under paste backfill were mined out in 2002 with excellent results."

Jan 1, 2005

By Brian Hart, Roger St. C. Smart, James Francis, Mark Biesinger

"There are a number of challenges involved with the surface analyses of different mineral phases from process streams in a flotation facility. The first of course is to collect samples that are representative of the process and to ensure that they remain in a pristine condition prior to introduction into the instrument. In mineral processing, sample collection from the different streams is done on site and preservation involves simply removing oxygen from the sample by bubbling nitrogen or argon gas through the sample and snap freezing with dry ice.The second challenge in studying the surface chemistry of specific minerals is to find reliable methods of mineral phase recognition. In surface analysis of mineral particles confident mineral selection can be difficult with many multi-metal minerals (e.g. chalcopyrite, pyrite, sphalerite) and with precipitated, adsorbed, reacted and contaminant species in the outermost molecular layers.In this paper we show that principal components analysis (PCA) of ToF-SIMS data provides improvement in phase recognition, particle selection and associated variations in surface species. We will demonstrate, with specific examples, that this technique can be utilized to differentiate surface chemical factors promoting (hydrophobic species) or inhibiting (hydrophilic species) flotation.Species recognition based on the PCA method in a study of Cu transfer between chalcopyrite, pyrite and sphalerite mineral mixture clearly identified a statistical difference in copper intensities between the sphalerite and pyrite phases. A similar ToF-SIMS/PCA based study applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrated extensive CuOH and NiOH transfer between the chalcocite and heazlewoodite minerals. The statistical analysis has been able to confirm some mechanisms and deny others proposed to control recovery and selectivity giving more focus on the control factors.The ToF-SIMS PCA statistical analysis has elucidated differences in surface chemistries which illustrate the discriminating depressant action of adherent aluminosilicate (gangue) fine particles and adsorbed ions on the surface of sphalerite grains. In the flotation test concentrates, HIC conditioning resulted in the removal of these gangue fines thereby improving surface collector attachment efficiency, promoting a greater recovery of sphalerite."

Jan 1, 2007

By J. I. Mathis

"The failure that was utilized for developing this model was a double bench-scale failure, approximately 20 m in height, in the Misery pit at BHP Billiton’s EKATI mine site. The bench that failed was excavated in biotite schist. Due to previous problems with bench-scale toppling failures, this bench was excavated with a 70° inclined, 30 m deep preshear. Upon exposure, the wall was very clean with half-barrels commonly observed from the pre-shear operation.In August 2003, a bench failure of about 1000 t occurred in this pre-sheared biotite schist (Fig. 1). Upon examination it was noted that the foliation that paralleled and dipped at 70° into the face when excavated was approximately horizontal at the top of the failure (Fig. 2). While the failure mode itself appears complex, the failure was apparently driven by three factors:• a low-angle, low-frictional strength fault or discontinuity at the base of the failure area;• water either contributed meteorically from precipitation and/or from permafrost melt; and• foliation planes providing a viable toppling geometry once toe block motion began to occur.The above details are illustrated in Figure 3.After considerable thought and analysis, a model was postulated for the failure.It is thought that the entire failure had been triggered by displacement of a toe block (Fig. 4). This toe block is bounded on the back by foliation, the bottom by a low-angle, lowstrength fault, and the front by the bench face. Water pressures behind the bench face developed forces on the block as can be seen in Figure 5. These forces were sufficient to induce block motion. As can be seen in the relative shear strength diagram in Figure 6, only a small amount of water is necessary in the face to initiate block displacement. Note that in this figure, a simplistic piezometric pressure distribution was assumed."

Jan 1, 2004

By Hannu J. Häkkinen

Metal clusters exhibit unique size-dependent physical and chemical properties that differ from those of bulk materials or large particles. Here we discuss recent theoretical investigations of the catalytic properties of free and MgO-supported gold clusters. The catalytic activity of gold clusters depends sensitively on the environment, charge state, and chemical composition of the catalyst. Relativistic bonding effects stabilize large planar structures for gas-phase gold clusters, and non-compact ?quasiplanar? structures are present as important isomers also for surface-supported clusters. The hybridization of the atomic 5d and 6s states is significantly enhanced by the relativistic effects, and large spatial variations in the nature of the local electronic structure make the low-coordinated gold atoms preferable adsorption sites for oxygen molecules. The adsorbed oxygen molecules are activated to superoxo- and peroxo-states via charge-transfer from gold, and Eley-Rideal and Langmuir-Hinshelwood reactions with CO proceed via low-barrier formation of intermediates, which do not require O-O dissociation as precursors. This facilitates the low-temperature (below 300 K) activity of gold nanocatalysts in CO oxidation. Other gold nanostructures, such as mono-atomic gold nanowires, may also become important prototype systems in chemical sensing and nanocatalysis; here we show that they are active promoters of hydrogen dissociation.

Oct 1, 2003

By M. Sturzenegger

This paper documents a field survey using long-range terrestrial digital photogrammetry at the Palabora open-pit mine, South Africa, for multi-scale characterization of rock mass discontinuities. Stereomodels covering the entire mine were generated based on photographs taken from a distance of 1600m across the pit, using a series of f=20-400mm lenses. Details on the methodology used and its accuracy are discussed. Preliminary results on discontinuity orientation, persistence and intensity are presented, highlighting the effect of observation scale. The potential uses of long-range terrestrial digital photogrammetry in open-pit mine and large natural rock slope environments is emphasized. The use of an f=400mm lens from distances larger than 1.5km may represent an important step forward in the geotechnical characterization of inaccessible remote rock faces.

May 1, 2009