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By Scott Honan, Tassos Grammatikopoulos, Mike Johnson, Kelton Smith, Niels Verbaan, Ernesto Bourricaudy, Eric Larochelle, Rick Sixberry

"NioCorp is developing the niobium/scandium/titanium Elk Creek carbonatite resource deposit. The carbonatite phase contains significant niobium (0.71% Nb2O5), titanium (2.68% TiO2) and scandium (72 g/t) and is composed predominantly of calcite, dolomite and ankerite. Niobium is mostly (80%) contained in the pyrochlore and the balance in various Fe-Nb-Ti oxides, which also host most of the titanium. Scandium is distributed homogeneously throughout the ore mineral assemblage. The process flowsheet recovers separate niobium, titanium and scandium products. Scandium is extracted from whole ore hydrochloric acid leach solutions through solvent extraction, and is further refined through a re-leach and precipitation process. Scandium leach residues are treated with sulphuric acid to recover separate niobium and titanium precipitates. Both hydrochloric acid and sulphuric acid reagents are recycled within the flowsheet. This paper will discuss key bench and pilot test results (focusing on the scandium flowsheet) and will present a conceptual flowsheet developed by the project team for NioCorp at SGS Minerals.INTRODUCTION NioCorp is developing North America's only niobium/scandium/titanium project. The Elk Creek project is located near Elk Creek, Nebraska, and is the highest grade niobium project in North America and the largest prospective producer of scandium in the world. These elements are unique and valuable superalloy materials that are strategic and critical to many industries and national defense technologies. The project includes the Elk Creek Carbonatite (the Carbonatite) that intruded older Precambrian granitic and low to medium grade metamorphic basement rocks. Both the carbonatite and Precambrian rocks are interpreted to be unconformably overlain by approximately 200 meters (m) of Paleozoic marine sedimentary rocks of Pennsylvanian age. As a result of this thick cover, there is no surface outcrop within the Project area of the carbonatite, which was identified and targeted through magnetic surveys and confirmed through subsequent drilling. The available magnetic data indicate dominant northeast, west-northwest striking lineaments, and secondary northwest and north oriented features that mimic the position of regional faults parallel and/or perpendicular to the Nemaha Uplift."

Jan 1, 2017

By E. M. De Souza, J. F. Archibald

This paper examines aspects of Canadian mine backfilling operations that may be implemented to assist in reducing solid waste production, lowering energy costs, and restricting Greenhouse Gas emissions. Many Canadian underground mines use backfill to mitigate environmental effects associated with tailings disposal. Backfill production and disposal are energy intensive processes that require an average energy cost of 37.7 MJ/tonne of backfill to complete. Mine backfills, in engineering applications, also commonly make use of cement as a stabilizing agent. Cement requires an additional energy cost ranging between 4,637 and 6,600 MJ/tonne to produce. The large energy needs associated with mine backfilling and cement production operations create significant CO2 and Greenhouse Gas emissions. Approximately 1 tonne of CO2 and Greenhouse Gas is emitted for each tonne of Normal Portland Cement produced. For single mines producing 3,000 tonnes of backfill per day, considering both backfill and cement emission source terms, total emissions of CO2 ranging between 120.36 tonnes and 169.44 tonnes/day are anticipated. In Ontario, mining operations contribute 700,000 - 840,000 tonnes/year of CO2 and Greenhouse Gas emissions to satisfy backfill cement consumption needs alone. Potential reductions of cement in backfill would significantly reduce emission of these gases and lower their adverse environmental impacts. This paper identifies alternate, equally effective and lower cost binder agent strategies for cement in backfill that may lead to cement consumption reductions. Post-consumer glass represents one such potential alternative backfill binder. Over 950,000 tonnes of glass are disposed of annually in Canada, two-thirds of which exists in the form of easily recoverable glass packaging that is not currently recycled or reused. The partial replacement of cement by waste glass may address goals for reducing non-recyclable glass waste disposal; enhancing mine back filling operations; reducing total backfill energy costs; and ultimately reducing Greenhouse Gas emissions levels currently generated by the Canadian mining industry.

Jan 1, 2004

By Glen A. White

The level of impact and mitigating measures that are forecast in an environmental assessment (EA) for a new, or significantly modified, metallurgical processing facility or mine are taking on increasing importance during the subsequent life of the facility. The basic premise is that one is authorized to operate within the envelope defined by the approved EA. Operations inevitably change as they develop and mature, and at some point, one is faced with the prospect of re-doing the original EA work. This can lead to significant development delays. Cameco Corporation (Cameco) has played a major role in developing the northern Saskatchewan uranium mining industry over the past decade. Through the EA process, the company has developed ideas on what works well in generating approvals that give the operator some future flexibility. Early introduction of concepts for potentially different mining and processing methods, as well as contingency plans if things do not work out exactly as predicted in the original EA, can make subsequent regulatory approval for change a more efficient process. One must also preserve the principles of open consultation upon which the EA process was originally based. As such, involvement and support from local communities and other stakeholders is required to ensure the long-term success of the EA process.

May 1, 2004

By F. McGravie, S. T. Solinski, W. W. Robertson

During this, the Centennial year of the discovery of the Hall-Heroult process, it seems appropriate to review some of the developments which have taken place in Canada and to explain why it has become an important world centre for the production of primary aluminum. For many years after it was recognized that the element aluminum existed, scientists were frustrated in their efforts to isolate it. In the early 1800s H. C. Oersted and Frederick Woehler prepared small quantities sufficient to measure some of the physical properties. A quasi-commercial process involving reduction with metallic sodium was developed by the French scientist H. St. Claire Deville in 1855 but the cost was very high ($30. 00 per kg). It was not until 1886 that Charles Martin Hall in the United States and P.L.T. Heroult in France, more or less simultaneously but completely independently, discovered the process which is essentially that in use today. Some of the early pioneers in the industry quickly recognized the potential of the hydro-electric resources in Canada as economic energy suppliers for aluminum production. The first commercial production in Canada was in Shawinigan, Quebec in 1901, only 15 years after the process was discovered. Subsequently operating plants were established at nine different locations in Canada (Quebec and British Columbia) (Table 1). Operations continue today in all locations except one (La Tuque). The table shows present plant capacity which for the older plants was reached in an evolutionary manner including replacement of obsolete capacity or upgrading and modernization of existing designs.

Jan 1, 1999

By J. R. Giegerich

"IntroductionMINING operators in common with other operators are confronted today with two serious problems, shortage of experienced workmen and rising costs. The following review of practices at the Sullivan mine of The Consolidated Mining and Smelting Company of Canada, Limited, outlines certain measures that have been responsible, during recent years, for minimizing the effect of these two problems. The paper is divided into three main sections:( 1) Training programmes and job studies( 2) Improved mechanization and equipment( 3) Large-scale methods of operationTraining Programmes and Job StudiesJob TrainingJob training courses were introduced at Cominco immediately after the last war and proved to be a great benefit to the operations. There were three courses given, Job Instruction Training, Job Safety Training, and .Job Relations Training. These were spread over a period of two years and were taken by all operating supervisors and some key operators.The courses were introduced by a trained instructor from the British Columbia Department of Labour. This man trained twelve of our employees as instructors by giving them an intensive one-week course. Similarity between the three courses was such that the instructors trained in the first one were very readily trained for instruction in the two succeeding courses."

Jan 1, 1952

By Christoph Mueller

Broad band mine communication today is characterized mainly by individual solutions, which have in common their long development phases and their high cost for development, operation and service. The use of Ethernet and TCP/IP on the other side provides an uniquely price efficient combination of high bandwidth open networking, universal use and accessibility of cheap development tools, especially because it forms the technical infrastructure for the worldwide Internet. TCP/IP and Ethernet assures reliable networking however it is not able to guarantee the latency timing of forwarding network information. Therefor, the network design requires strict load limitation and application level traffic control especially if moving equipment has to be manually remotely controlled via the network. To optimize the use of bandwidth on mining networks using load limited, ?bandwidth wasting? local Ethernet segments, long distance broadband traffic should be carried out using more efficient, deterministic communication backbones providing a guaranteed quality of service for each of the physically separated networks. Open networking and broadband systems however may lead to the anticipation that any demands on bulk data or multimedia traffic can be fulfilled in the future. This definitely will not be the case as the bandwidth demands of applications will be growing as least as fast as the bandwidth provided by communication systems. Looking on those problems from an overall system integration perspective, machines and equipment in the future have to be equipped with intelligent computing devices capable of an intelligent local data preprocessing. Such ?Embedded Machine Information Servers? running commercial computing power in the future will be the intelligent bridge between open networking and a secured, high safety local automation system. These ?Embedded Machine Information Servers? then also can make advantage of intelligent video and audio data preprocessing to store and transmit multimedia information ?on demand? or when the application requires it. Summarizing the potential for the future Ethernet based networking together with powerful communication backbones and intelligent local data preprocessing on the machines in the future will lead the way to integrative, reliable and cost efficient mine automation solutions.

May 1, 2002

By J. E. Nesset, W. Zhang, J. A. Finch

Frother influences water recovery through control of bubble size and a chemical effect. De-coupling the two is necessary to establish the extent of the chemistry effect. A setup is described to give steady state water overflow rate (Jwo) along with measurements of bubble size into and on top of the froth. Arguing neither bubble size correlates directly with water overflow, a frother mass balance is solved to estimate the bubble surface area flux in the overflow (Sb0 ). The solution required measurement of frother concentration using TOC analysis and frother adsorption density using surface tension data. The relationship between Jwo and Sbo reveals the frother chemistry effect, quantified for discussion purposes by an equivalent water layer thickness.

Jan 1, 2009

By Stephan I. Zajac, Roger A. Blais, John B. Stubbins

THE iron deposits of central Labrador occur within a relatively small area, herein called the Knob Lake Iron Range, in which a northwest-trending series of low hills and ridges defines the height-of-land at the boundary between provinces of Quebec and Newfound-land. Approximately two-thirds of the deposits are in Quebec and the remainder in Labrador, with several deposits straddling the inter-provincial boundary. These deposits are being exploited in open-pit mines by the Iron Ore Company of Canada centered at Schefferville, Quebec. Since 1954 this company has produced more than 56 million tons of iron ore to become Canada's leading iron ore producer. With indicated reserves of more than 375 million tons of direct-shipping ore and large tonnages of iron formation amenable to beneficiation, this mining district is assured of a long life. This paper describes the Knob Lake iron ores and their geological settings and stresses the features that lead to a better understanding of their origin. The

Jan 1, 1961

By Jiuhua Xu, Yuling Xie, Fenglei Bie, Neng Jiang

"Abstract - The Xiaoqingling Mt. area is one of the most productive gold districts in China. The gold-bearing quartz veins are controlled by a series of east-west shear zones within the Archean Taihua Group, and related to the late Yanshanian (Cretaceous) granite. The major metallic minerals are native gold, electrum, pyrite, galena, chalcopyrite and sphalerite, with gangue minerals dominated by quartz, sericite, ankerite, and calcite. The host rocks are mainly amphibolite, plagioclase gneiss, and migmatites. Principal alteration is sericitization, silicification, pyritization, and carbonization.There are four generations of hydrothermal quartz in altered rocks of gold deposits. The earliest generation of quartz, (Q1), occurs in altered amphibolite gneiss and migmatite, and typically contains fluid inclusions with halite crystals (type A) and two phases, (L+V), of fluid inclusions (type B). The salinities of type A inclusions are 32 wt% to 52 wt%, with dissolution temperatures of halite crystals being from 155°C to 465°C. The second generation of quartz, (Q2), occurs as a fine-grained aggregate associated with sericite, and has small (less than 3 µm) type B inclusions. The third generation of quartz, (Q3), occurs in mylonitic, intensively altered rocks and specially beresite (a type of rock composed of quartz, sericite, and pyrite) near the veins, and contains large amounts of CO2-rich fluid inclusions (type C-fluid inclusions with liquid CO2 and type D-fluid inclusion with high density CO2). The CO2 contents of type C range from 72.6 to 87.4 mol% in gas phases, and 35.7 to 68.3 mol% in liquid phases, based on Laser Raman analysis. The homogenization temperatures of fluid inclusion type A and C are from 215°C to 380°C, and from 210°C to 325°C, respectively. The minimum trapping pressure of fluid inclusions is estimated as 80 MPa to 170 MPa for type A, and from 57 MPa to 190 MPa for type C, which approximate to those of fluid inclusions in vein quartz.The ?18O of quartz are from 10.4‰ to 11.0‰ for Q3 of altered rocks, and from 10.7‰ to 12.8‰ for stage I quartz. The calculated ?18O of fluid inclusions varies from -1.3‰ to 6.0‰. The ?D of fluid inclusions ranges from -67‰ to -59‰ and from -81‰ to -48 ‰, respectively. It is concluded that the water in the hydrothermal fluids both reacting with wallrocks and precipitating orebodies could have been mainly of magmatic and/or metamorphic nature. However, local meteoric water might have been important in late mineralization, because of a distinct oxygen-shift toward the meteoric water. The ?34S values for pyrite of the ores range from -7.1‰ to +7.1‰, with an average of +2.9‰. Those of other sulfides (chalcopyrite, galena, and sphalerite, range from -12.5‰ to 8.3‰. The ratios of lead isotopes for galena of the ores are: 17.06 to 17.31 (206Pb/204Pb), 15.43 to 15.74 (207Pb/204Pb) and 37.58 to 38.45 (208Pb/204Pb). In summary, ore-forming fluids in the Wenyu-Dongchuang gold deposits may have originated from a mantle and/or lower crust source, and ore materials were derived from the Precambrian basement, the Taihua Group."

Jan 1, 1998

By A. Djebara

Today, indoor air quality, especially in manufacturing industries, is of great interest due to the use of new processes and advanced materials such as those containing nanoparticles. Manufacturing processes generate aerosols (dry or wet) which can be detrimental to occupational health and safety and to the environment. Controlling metallic particle emissions during machining processes should limit their formation at the source, and thus minimize the risk of exposure; this at-source reduction requires the characterization of the particle emitted (size, nature, concentration, etc). The metrics normally used in characterizing fine and ultrafine particles include the mass concentration, the specific surface and the number concentration. Most of these metrics are affected by the size, the geometry and the density of the measured particles. Information about the form and the real size of the particles is thus very important. A procedure for collecting and characterizing fine and ultrafine metallic particles was developed and applied to the study of particles emission during the machining of aluminum alloys. It was found that metallic particles emitted during the machining of aluminum alloys are of various shapes and sizes, and this information must be taken into account when characterizing these particles.

Jan 1, 2011

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By R. B. Paine, B. M. Wright

"Syncrude has entered a new era involving the use of pipeline slurries to convey oil sand to the extraction plant. Hydrotransport operations and base plant operations encounter vast performance differences when processing different types of oil sand. This paper describes the hydrotransport process, its history at Syncrude, methods of describing the source ore characteristic and plant performance. The use of this information within Syncrude and how it will be managed on an ongoing basis will also be described. IntroductionThe Syncrude Canada Ltd. site is located 43 km north of Fort McMurray, Alberta, on the Athabasca oil sand deposit. The Syncrude operation consists of mining, extraction, upgrading, utilities and other support facilities. The mined ore is sent to the extraction plant where water and solids are removed from the bitumen. The bitumen is then sent to the upgrading plants to be further processed into Syncrude Sweet Blend (a light sweet crude oil). Syncrude produced 73.5 Mbbls of Syncrude Sweet Blend in 1996 and produced 75.7 Mbbls in 1997. Prior to 1993, Syncrude moved ore from the pit to the extraction plant via four dragline / bucketwheel/ conveyor systems. These systems, supplemented by auxiliary ore crushers, satisfied the feed requirements of the extraction plant. Ore was conveyed to the control tower area and placed in the dump pocket via four radial stackers. Various blending scenarios occurred at this point, using feed from the four mining quadrants and from auxiliary feed crushers. Upon entering the extraction plant from the base mine, the oil sand passed through a series of tumblers where it was mixed with hot water and caustic. It then proceeded to one of four primary separation vessels where bitumen froth was floated off and the middlings and coarse fractions were recombined and sent to the tail oil recovery vessels, or TORs, for further processing."

Jan 1, 1999

By N. Wachgama, J. P. T. Kapusta, R. U. Pagador

The Thai Copper Industries smelter (Thai Copper) is located some 200 km southeast of Bangkok near the MapTaPhut deep sea port in one of the industrial centres of Thailand. Although construction of the complex started in the mid 1990s, the smelter, acid plant and refinery were completed in 2004. Thai Copper is a state-of-the-art copper smelter processing imported concentrates with a total yearly capacity of 165,000 tonnes of cathodes. It employs the El Teniente Technology where concentrates are blended and smelted continuously in a primary smelting reactor to produce high grade matte or white metal. The white metal is converted in batches to blister copper in Hoboken siphon converters equipped with Air Liquide Shrouded Injector (ALS I) Technology for sonic injection of oxygen enriched air. Final refining is carried out in two anode furnaces prior to anode casting and electrorefining. Thai Copper and Air Liquide Canada executed a technical assistance agreement in late 2005. Pre-commissioning of the shrouded injectors took place in July and November 2006 while hot commissioning occurred in December 2006. This paper presents the major technical aspects of the joint commissioning, including the establishment of operating practices specific to shrouded injection converting. Preliminary results of this first commercial implementation of ALSI Technology in copper converting are also provided.

Jan 1, 2007

By J. C. Beidelman

One of the oldest settled portions of Canada is that "strip of land" extending into the Gulf of St. Lawrence, known as the Gaspe peninsula, with the Bay of Chaleur on its southern boundary. This "strip of land" is still so very sparcely populated that only at a few places does settlement extend more than a few miles from the coast. ? The peninsula is 160 miles long, 75 miles wide and with the exception of the above mentioned settlements is a mountainous wildness-void of all roads or inhabitants. Developments in the interior, of all nature, out-side of the cutting of timber by limit holders, was entirely lacking until the year 1915, when mining was first commenced. In the summer of 1844 Sir William Logan made a preliminary survey across the peninsula, from Cape Chat on the Gulf of St. Lawrence to Cascapedia on the Bay of Chaleur, passing through a country ?of which very little was known at that time. After a rather rough trip to the headwaters of the Grand Cascapedia river, Logan's party descended this river to its mouth, passing ten miles west of what is now known as the Federal mines. There is no record of Logan, or of any of his party, finding zinc or lead ores of any character on their journey across the peninsula, and until 1909 no precious or base metals were discovered within reasonable distance of Logan's survey.

Jan 1, 1924

By L. V. Chugaev, Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

"Pressure oxidation (POX) is one of the most common and reliable methods of processing gold-bearing sulfide concentrates. However, when processing concentrates that contain natural carbonaceous matter, substantial gold losses occur due to autoclave preg-robbing. The latter involves formation of gold chloride complexes under typical POX conditions (high temperatures, high acidity and high ORP) and subsequent sorption of these complexes by carbonaceous matter. Naturally, chloride ion plays a significant role in the process of autoclave preg-robbing; its concentration in POX solution has a well-marked effect on subsequent gold recovery during cyanidation of POX residue. The previous research done by SRC Hydrometallurgy showed that autoclave preg-robbing of gold could be significantly inhibited by the addition of mercury(II) compounds to POX slurry. The positive effect of mercury(II) was well pronounced both at high (>20 mg/L) and low (<5 mg/L) Cl concentrations in POX solution. The successful bench-scale laboratory testing was followed by pilot plant trials at Ore Test Facility in Blagoveshchensk, Russia. The present paper provides the results of these trials. The bench-scale testing results were verified; the optimum oxidizing parameters and reagent dosage were specified. The behavior of mercury (II) at POX pilot plant was found to be in good consistency with industrial practice described in the literature.INTRODUCTION Pressure oxidation (POX) is one of the most common, reliable, and commercially proven methods of processing gold-bearing sulfide ores and concentrates. However, when processing double refractory materials that contain natural carbonaceous matter, POX technology advantages are compromised by autoclave preg-robbing of gold. The latter occurs when natural organic carbon and soluble halides are both present in autoclave feed. Strongly oxidizing conditions of POX (high temperature, oxidation-reduction potential or ORP, and acidity) favor formation of gold-halide (mostly, gold-chloride) complexes, which tend to bond with carbonaceous matter. The exact nature and mechanism of this bonding is unknown, but as the result of this, cyanide is unable to leach gold from POX residue and the precious metal is lost to the tails (Axenov et al., 2014; Dimov, Chryssoulis, & Sodhi, 2003; Fomenko, Zaytsev, Pleshkov, Chugaev, & Shneerson, 2013)."

Jan 1, 2017

By Lawrence D. Meinert

Most large skarn deposits are zoned in both space and time relative to associated intrusions. Zonation occurs on scales from kilometers to micrometers, and re?ects in?ltrative ?uid ?ow, wall rock reaction, temperature variations, and ?uid mixing. The most spectacular examples of skarn zonationusually occur at the skarn-marble contact, where transitions between monomineralic bands can be knifesharp. Other small-scale examples occur in zoned veins and individual mineral crystals. Although,visually striking and scienti?cally interesting, in mineral exploration these small-scale variations areless useful than deposit- or district-scale zonation. In most skarn systems there is a general zonationpattern of proximal garnet, distal pyroxene, and vesuvianite (or a pyroxenoid such as wollastonite, bustamite, or rhodonite) at the marble front. As well, individual skarn minerals may display systematic color or compositional variations within the larger zonation pattern. Such patterns are reviewed for 14well-studied examples of Cu, W, Sn, Au, and Zn-Pb skarns. In addition, many deposits have endoskarnor other alteration of the associated intrusion, and recrystallization or other subtle changes have occurred in the surrounding wall rocks. Copper skarns, such as Mines Gaspé in Quebec and Big Gos-san in Irian Jaya, have high ratios of garnet:pyroxene and are zoned outward from the intrusion, to gar-net, to pyroxene, to massive-sul?de replacement and vein deposits. Garnets in Cu skarn are Fe-rich and change from dark red-brown near the intrusive contact to paler brown, green, or yellow in distal loca-tions. Pyroxenes in Cu skarns are pale and diopsidic near the intrusion, and become darker and more Fe- and Mn-rich away from the intrusion. Tungsten skarns, such as Salau and Costabonne in France and Pine Creek and Garnet Dike in California, have intermediate ratios of garnet: pyroxene, are more extensive vertically and along strike than perpendicular to the intrusive contact, and have zonation pat-terns commonly complicated by overprinting of metamorphic lithologies. In W skarns, garnet is com-monly subcalcic and the pyroxene is Fe-rich, re?ecting particularly reducing wall rocks or great depth of formation. Tin skarns, such as Dachang in China and Moina in Australia, also can have subcalcicgarnet and Fe-rich pyroxene, but this reduced mineral assemblage typically is due to an association with reduced S-type granites. Tin skarns differ from most other skarn types in having a late greisens stage that may replace earlier Sn-bearing calc-silicate minerals, thus liberating Sn to form cassiterite.Many high-grade Au skarns, such as Hedley in British Columbia and Fortitude in Nevada, have low ratios of garnet: pyroxene and are associated both with reduced plutons and reduced wall rocks. Gold-rich zones occur in Fe-rich, pyroxene-dominant, distal skarn. Zn-Pb skarns, such as the Yeonhwa-Ulchin district in Korea and Groundhog in New Mexico, have low ratios of garnet: pyroxene and generally form distal to associated intrusions. These skarns also are zoned from proximal garnet to distal pyroxene and pyroxenoid (bustamite-rhodonite), with signi?cant zones of massive sul?des within and beyond skarn. Manganese enrichment of most mineral phases, particularly pyroxene, is characteristic of distal zones. Fundamental controls on skarn zonation include temperature, depth of formation, composition and oxidation state of associated plutons and wall rocks, and tectonic setting. Most W skarns form at relatively great depth, 5 km to 20 km, with extensive high-temperature metamorphic and meta-somatic mineral assemblages. In contrast, most other skarn types are relatively shallow, <10 km and mostly <5 km, with limited, lower temperature metamorphic aureoles. Differences in oxidation state correlate well with different skarn zonation patterns, particularly garnet: pyroxene ratios and compositions, and can be used in both classi?cation of and exploration for skarn deposits

Jan 1, 1997

By R. A. L. Drew, G. Mendoza-Suarez, J. Filipi, R. Vintila, J. A. Kozinski

Economics and environmental considerations along with the increasing demand of hydrogen encourage development of novel technologies such as plasma processing of hydrocarbons and thermal cracking of natural gas. Plasma discharges, either in thermal or non-thermal regimes are expected to allow low temperature and fuel flexible on-site hydrogen generation. The main drawback of thermal plasma reformers is the high-energy consumption resulting from high-temperature operation. On the other hand, non-thermal plasma, generated by dielectric barrier discharge (DBD), is able to simulate the chemical reactions employing much lower energies than those required by thermal treatment processes. The non-thermal plasma process allows for instance, a direct conversion of methane into hydrogen and carbon black with no CO2 release. The focus of this research was on the GHG-free method of H2 generation in compact non-thermal plasma reactors using low, medium and high permittivity dielectric ceramics. A stable, non-thermal plasma was generated by placing a dielectric ceramic between two electrodes with a 25 thou gap and applying an alternating current of 1-5kHz and voltages of 4-8kV. In order to ensure energetic efficient plasmas, experiments were conducted to analyze the behaviour of different permittivity ceramics. It was found that the dielectric properties of a ceramic, when used in a DBD reactor, have a strong influence on the discharge characteristics, which in turn influence the power consumption. Higher dielectric constant resulted in higher conversion rates of methane (higher yield of hydrogen and carbon). At the same time, the mechanical properties of the dielectric material, which are closely associated with its processability, influenced its resistance to electron bombardment, as well as thermal and mechanical damage. Therefore a reliable ceramic should have good dielectric properties, in addition to good thermo-mechanical stability.

Jan 1, 2004

In this study, we develop a detailed model of the likely future carbon footprint of primary copper supply. We develop a peak copper production model, based on a detailed copper resource data set, and combine this with a comprehensive life cycle assessment model of copper mining and milling to predict greenhouse gas emission rates and intensities of Australian and global copper production up to 2100. By establishing a quantitative prediction of both copper production and corresponding greenhouse gas emissions of Australian and global copper industry, we then analysed the emissions intensity of various energy input scenarios, such as business-as-usual, solar thermal electricity and solar thermal electricity with biodiesel. The Australian Government has an aspirational goal for long-term greenhouse gas emissions of an 80% reduction from the 2000 level by 2050. For the copper sector, this means moving from about 12.6 Mt CO2e in 2000 to a goal of some 2.52 Mt CO2e in 2050 (assuming equal emissions reductions across the economy). Based on the energy sources modelled, only the solar thermal plus biodiesel scenario was capable of achieving this goal at about 0.15 Mt CO2e, since the solar thermal alone scenario still includes normal petro-diesel as a major source of emissions. Overall, it is clear that there are abundant resources which can meet expected long-term copper demands, the critical issue is more the carbon (and environmental) footprint of different copper supplies and use rather than how much is available for mining. It is clear that the switch to renewable energy can have a profound impact on the carbon intensity of copper supply, even allowing for increased energy intensity as ore grades decline, and a complete conversion to renewable energy will position the copper sector to meet existing annual greenhouse gas emissions targets and goals.

Aug 1, 2013

By A. A. Rafiei, J. A. Finch

A previous study comparing n-pentanol and the polyglycol Fl50 showed that the two reagents could give the same gas holdup but with different size bubbles. The finding implies that bubble rise velocity depends on the surfactant (frother) type. A study using bubble swarms supported the frother type effect but bubble interactions were a possible confounding factor. This study resolves the question by measuring the rise velocity of single bubbles of 0.8-2.5mm diameter over a distance :::: 300cm in n-pentanol and F 150. It is shown that at typical frother concentrations used in flotation that the rise velocity in n-pentanol remains comparable to that in water alone while in Fl50 the velocity is significantly reduced. The results confirm the suspected impact of frother type. It is illustrated that in n-pentanol the rise velocity does not reached terminal; while in Fl50 it does and this is the source of the velocity difference. Advances

Jan 1, 2009

By C. S. Parsons

Introductory The steady advance in the price of lead and zinc in the metal markets of the world during the past few years has resulted in an active search for new deposits of these metals, and to the re-examination of known properties that are now idle. There are a number of deposits of these metals in eastern Canada, the best known of which are the Tetreault mine at Notre Dame des Anges, Que.; the Reader mine on Calumet island, Que.; the Stirling property in Cape Breton, and the Federal mine in Gaspe district, Que. . The author has run concentration tests on the ores from the first three mentioned properties. The ores from Notre Dame des Anges and Calumet island presented problems in concentration which were not successfully solved until the past year. Although considerable experimental work has been done by the Ore Testing Laboratories on the ore from the Stirling mine we have not been successful in developing a satisfactory method of treatment. Character and Types of Ores Metallurgically the lead-zinc ores of eastern Canada may be classified into three distinct types as follows: First: - Ore in which the sulphide minerals are fairly coarsely crystalline and can be freed by crushing to 40 or 60 mesh. The zinc blend has a high iron content (not marmatite) and gives a dark brown colour on grinding. The ores of Notre Dame des Anges and Calumet island, Que., may be cited as examples.

Jan 1, 1925