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By Jean Scott, G. A. Collins, G. W. Hodgson

WHILE it is well known that trace metals in crude •oils and distillates have been a matter of deep concern to refining engineers because of the damage done .by the metals to cracking catalysts and refractories (8, 5), the trace metals in crude oils may be of great benefit in correlation studies and in origin studies. During the geological processes in which the oil is formed from •animal and vegetable life, the hydrocarbons are subjected to a host of inter-related reactions, both physical and chemical. It has been well demonstrated that the lighter materials, certainly the short-chain paraffin hydrocarbons, are degradation products of the heavier molecules, and it might be concluded that for correlation studies it would be advisable to direct attention as much as possible not to the degradation products of the large molecules but to the large molecules themselves. Be this as it may, the methods at •hand to conduct the study are not particularly precise and, in the past, attention has centred on the simpler small molecules, as evidenced by the great mass of work involving distillation and chromatography with painstaking separation of the simpler 'front-end' hydrocarbons.

Jan 1, 1954

By J. Nsasi Bakambu

This paper describes an autonomous platform for exploration and navigation within networks of tunnels, as those typically found in underground mines and caves. In the exploration mode, a remotely located supervisor instructs the platform to move through successive sections of the network, gathering range data that is, then, concatenated into 2D/3D survey maps of the environment. In the navigation mode, the supervisor specifies high-level missions on the previously acquired survey maps. A motion planner, then, translates each mission into a set of consecutive navigation actions, separated by natural landmarks. Mission execution consists of detecting landmarks, self-localizing and performing the planned navigation actions.

May 1, 2003

By J. D. T. Steyl

Anglo American Corporation and the University of British Columbia have developed a medium-temperature oxygen pressure leaching process for the extraction of copper from chalcopyrite concentrates in an acid-sulphate system (AAC/UBC process). Leaching is performed at 150°C and surfactants are added to disperse molten elemental sulphur from the unreacted sulphide surface to prevent liquid sulphur occlusion. Copper extractions of over 95% and elemental sulphur yields of around 60% were observed over a 2-hour average residence time in a continuous pilot autoclave. Sporadic blockages occurring under continuous conditions were found to be caused by the accumulation of molten elemental sulphur mixed with unreacted sulphide mineral. A batch programme of experimentation was undertaken to establish the reason for this phenomenon. Batch experiments were conducted at low pulp densities on concentrate samples with narrow size distributions and at similar solution compositions to those experienced in the pilot autoclave. The overall rate of chalcopyrite oxidation was shown, under approximately constant solution composition, to be a strong function of the total available mineral surface area. Initial copper extraction rates followed the shrinking particle kinetic model under intrinsic surface control. Deviation from shrinking particle kinetics was however observed after a certain oxidation time. Secondary electron images identified small (typically less than 20 µm) sulphur conglomerates at the point of deviation, which 'collected' unreacted chalcopyrite mineral particles and lowered the total mineral surface area available for oxidation. These sulphur clusters are thought to be the precursor for blockages experienced in the continuous pilot autoclave. These results emphasised the importance of fine grinding (P80 5-20 µm) and suggest that shorter residence times may minimise the formation of sulphur conglomerates in a continuous autoclave operating at medium temperature.

Jan 1, 2004

By John D. Godfrey

A brief account of economic developments in and around northeastern Alberta is presented and mention is made of mining and industrial developments currently of interest in the area. Planned and projected operations are briefly discussed for this region. The history of geological surveys and mining activities in the Shield area of Alberta and the adjoining parts of Northwest Territories and Saskatchewan is traced. Reassessment of the presently-known economic picture of northwestern Canada in conjunction with some recent information on Precambrian structures of northeastern Alberta points to some interesting mining possibilities, particularly in and around that province.

Jan 1, 1960

By D. M. Morrison

"The most important factor in Canadian mining is not the operating cost of current projects but the availability of capital for future projects. The future of mining at depth will be producing ore from the top of the orebody working downward with very effective, tightly controlled mining methods, i.e. either selective mining or bulk mining with well controlled dilution and fragmentation. The key characteristics of future mines will be smaller access excavations, more effective ground support, very precise blasting techniques and more efficient and reliable materials handling systems. Equipment will be smaller and designed for high efficiency and low maintenance, reducing both the capital and operating cost. This means there will be fewer scoops, more continuous mucking machines and conveyor belts, both lateral and vertical.Orepass failures have become accepted and the resultant redevelopment and retramming has become common. The capital investment in so-called permanent ore passes and crusher stations becomes questionable, particularly when crushers are only necessary for less than 10% of the ore going through the system. The best way to solve the chronic instability of ore passes is, as with all of the stability problems at depth, by reducing the excavation size rather than increasing ground support. Smaller access drifts would reduce the capital cost and increase the rate of development as well as reduce the amount of waste to be handled, reducing the ground support and the ventilation requirements. Large drifts and ore passes are essential only for the equipment needed to handle large pieces of ore and the productivity of scoops is very expensive when the requirements for ventilation and large access drifts are taken into account. The key issue is the fragmentation generated by primary blasting.The future of mining in Canada will depend on simple and robust technology geared to the environment in which it will have to operate. Its survival will depend on some-thing much more fundamental and difficult to accomplish than a technological advance — it will require a dramatic change in the way the mining process is managed, how work is organized, how effort is rewarded and how costs are measured — a complete change in mind-set."

Jan 1, 1996

By L. D. Snyder, J. K. Russell

"The Lower Jurassic Iron Mask batholith intrudes Upper Triassic Nicola Group volcanic rocks in the Quesnellia terrane of southcentral British Columbia and hosts Cu-Au mineralization. The batholith comprises three mappable intrusive phases, including: Pothook gabbro to diorite, Cherry Creek monzodiorite to monzonite and Sugarloaf diorite. The Iron Mask hybrid forms a fourth mappable unit that makes up to 45% of the areal exposure in the batholith. It is highly variable in texture and composition and subdivided into three types; Type I and II have abundant (partially digested) xenoliths, many of which are derived from the Nicola Group, whereas Type III is xenolith-poor and shows extreme outcrop-scale textural diversity.Pothook and Cherry Creek rocks are similar in texture, mineralogy, whole rock and mineral composition and style of alteration. Contacts between the two can be intrusive or gradational. Rocks collected from these two suites have compositions that are permissive of a single magma batch, although simple crystal fractionation does not explain all chemical variations within and between the two suites. The Sugarloaf unit comprises a diverse group of amphibole-phyric rock types and is texturally and mineralogically distinct from Pothook and Cherry Creek suites.The Iron Mask hybrid represents progressive stages of physical and chemical interaction between Nicola Group country rocks and Pothook magma. Magmatic assimilation (selective or partial) is supparted on the basis of field relationships, petrographic observations, and REB compositional data. Thermal dehydration and partial assimilation of Nicola Group rocks by Pothook magma is shown to be a valid means of promoting early and extensive volatile saturation in the Iron Mask batholith."

Jan 1, 1995

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By T. Patching

"A GLANCE BACK AT what has happened in the past is often a useful guide to the future, although it should be used mainly to provide a sense of direction rather than a map that must be followed. As a preamble to discussing some of the questions posed by the organizing committee it may be appropriate to briefly review the distribution and careers of the graduates of our Department since the first degree in mining engineering was awarded in 1916. An attempt has been made to keep a record of the locations and careers of the Department's 540 graduates in mining and metallurgical engineering. Almost all of those who graduated before 1930 have now retired, but a very large proportion held positions as senior executives prior to retirement. A major proportion of those who graduated before 1950 are now in what might be considered senior management positions. Those who have 10 to 20 years of experience are generally in work of senior engineering responsibility or in supervisory or junior management ranks, while those who graduated in the last ten years appear to be generally in staff engineering or junior supervisory positions. This classification is admittedly imprecise because it is difficult to determine from a job description whether duties should be considered of an engineering or management nature - a distinction between the two terms is often over-emphasized. Nevertheless, the trend from technical engineering to management responsibilities with seniority and years of experience is clear in the careers that we have been able to follow."

Jan 1, 1972

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, David Grimsey, Denis Shishin

"An integrated nickel flash smelter is operated with Peirce-Smith converters at the Kalgoorlie Nickel Smelter. To improve the partitioning of arsenic between slag waste and matte product, an option to modify the slag–matte chemistry by addition of CaO was analysed. A combination of plant sample analysis, high-temperature laboratory experiments and thermodynamic modeling was carried out to evaluate the process options. The high-temperature experiments involved the re-equilibration of industrial matte-slag samples at 1225 °C and P(SO2) = 0.12 atm, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LAICPMS). A private thermodynamic database for nickel sulfide smelting and converting was used together with the FactSage thermochemical software package to assist in the analysis of the distribution of elements between slag and matte as a function of CaO addition. The thermodynamic predictions combined with experimental data obtained in this study can be used to characterise the effect of CaO fluxing on the slag–matte thermochemistry during the nickel sulfide converting.INTRODUCTION At the Kalgoorlie Nickel Smelter (KNS), nickel sulfide concentrate is processed in an Outotec-type flash furnace to produce nickel matte containing +47 wt% Ni. Separation of nickel matte and waste slag from the flash smelting is enhanced through settling in the electric arc -heated zone attached to the flash furnace. The flash furnace matte is further processed in a Peirce-Smith converter to produce Ni-rich matte containing +66 wt% Ni (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011). Iron silicate-based slag is used in the converting process at KNS. Most of the arsenic is contained in the final matte and very little of the arsenic partitions into the slag. Previous work by Font et al (Font, Hino, & Itagaki, 2003) shows that the distribution ratio of arsenic between calcium ferrite slag and nickel-matte (LAsslag/matte) is significantly higher than that between iron silicate slag and nickel-matte, where LAsslag/matte = (wt pct As in slag)/{wt pct As in matte} (1)"

Jan 1, 2017

"IntroductionThe Chairman, in his speech to this body last year in Montreal, stated that the Dominion Coal Board looked to and depended upon the Bureau of Statistics for statistical material, and the Bureau does collect and publish monthly and annual data on coal. It may therefore be asked why an officer of the Dominion Coal Board should prepare and give a talk on statistics.I would explain that it has been our experience in the Board that, since the supply and consumption of coal in Canada is subject to a seasonal ebb and flow, it can be more profitably studied on the basis of a twelve-month period ending on March 31st than of a calendar year, since the end of March does represent a fairly stable end point in this ebb and flow. The figures are not prepared or published by the Bureau on that basis and it has therefore been thought that a presentation on this fiscal-year period would be of interest. The Bureau of Statistics has agreed that this may be valuable and all the data here presented are based on the reports secured from various sources by the Mining, Metallurgical and Chemical Division, Dominion Bureau of Statistics. The only contribution by either myself or the staff of the Dominion Coal Board has been the tabulation in a different twelve month period, and the comments upon the picture presented.It should be noted that the data for the month of March, 1950, are not available in all cases and consequently the figures for that year contain an estimate for this month."

Jan 1, 1950

By Jonathan Ruiz Lizardo, Met-Chem Canada Inc., Flavio Ccuno, Constante Umipig, Ewald Pengel, José Ruiz

"Cerro de Maimón is located in the Dominican Republic on the island of Hispaniola approximately 75 kilometers northwest of the capital city, Santo Domingo. The processing facility consisted of two separate processing plants for oxide and sulphide ores. The oxide plant processed oxide ore bearing gold and silver ore using cyanide leaching and Merrill Crowe processes, while the sulphide plant produced a copper concentrate using conventional flotation. Cormidom is a commendatory example how mineral processing facilities can co-exist in balance with the environment. In 2014, natural occurring copper oxide contamination with finer grained copper-zinc sulphide mineralisation was expected to dominate the sulphide ore body. In anticipation Cormidom contacted the original plant designer Met-Chem to assist in overcoming this challenge. Test work indicated that increased flotation time and subsequent very fine grinding were required. Met-Chem provided the detailed engineering and Cormidom proceeded with the expansion project internally. Currently Cormidom has processed the sulphide ore successfully by implementing flotation modifications. This paper describes the history of Cormidom, test work on the “new” ore body, modification in process design in the Cu-Zn sulphide flotation circuit, construction and implementation.INTRODUCTIONCorporación Minera Dominicana (CORMIDOM) was a wholly owned subsidiary of GlobeStar Mining Corporation (a Canadian based minerals exploration company) with extensive exploration of base and precious metals in the Dominican Republic. In 2007-2008 CORMIDOM constructed the Cerro de Maimom project. The company was subsequently sold and purchased by Perilya Limited from Australia in 2013. Cerro de Maimón is located in the Dominican Republic on the island of Hispaniola approximately 75 kilometers northwest of the capital city, Santo Domingo. It is near the town of Maimón in Monsenor, Nouel Province (see Figure 1)."

Jan 1, 2016

By D. S. Case

"Following a brief explanation of the land arrangements under the Alaska Native Claims Settlement Act, this paper will examine both a mineral exploration agreement and a mining development agreement negotiated between two large mining companies and two different Alaska Native institutions. One of the institutions is a village corporation involved with an exploration agreement and the other is one of the Alaska Native regional corporations, which is party to a mining and development agreement with Cominco Alaska for the development of the Red Dog lead and zinc mine.Special attention will be given to the factors to be considered when dealing with small aboriginal owners with few resources in the context of an exploration agreement, including development issues which must be considered early in the process. The paper will also discuss the unique royalty and taxation structures developed for the Red Dog Mine Agreement as well as environmental issues. The paper will also consider the ways in which the cultural and differing economic interests of an aboriginal owner and a large mining company have been accommodated in the both the exploration and development agreements"

Jan 1, 1998

By G. Guiglionda, A. Deschamps, F. De Geuser, M. Langille, B. J. Diak

"Increased demand for light-weighting in passenger vehicles has created a need for strong, light, ductile materials to be used in body-in-white applications. The AA6xxx-series of aluminum alloys are suitable candidates meeting most requirements but can fall short of the formability demands of designers, necessitating an understanding of what controls the formability in this alloy series. This work examines the effect of copper alloying in AA6xxx on the pre-ageing and natural ageing responses of the microstructure and mechanical properties. The changes in microstructure observed by differential scanning calorimetry and hardness testing are related to the work-hardening and strain-rate sensitivity parameters for these alloys measured by tensile testing. An observed asymmetry in the measured strain-rate sensitivity associated with increasing versus decreasing strain rate changes suggests that a different mechanism operates for the two conditions. It is postulated how this asymmetry in strain-rate sensitivity will impact the necking and ductility behaviour of these alloys.INTRODUCTION The widespread use of AA6xxx series alloys in the form of sheets has provided the need for a more thorough understanding of the complex interactions between composition, processing, resulting microstructure and ultimately, the mechanical properties of the alloys. Conventional industrial practices involve the production of rolled AA6xxx sheet (typically 1 mm thick) to be used for body-in-white (BIW) applications for auto body panels (Hirsch, 2004, 2014). The final metallurgical step prior to the shipment of these panels to manufacturers involves a solution heat treatment (SHT) reverting the ageing products of the alloys into solid solution and the product is then shipped to the customer. During this shipping time and while sheets are waiting to be used, the natural ageing (NA) process occurs whereby the strength of the alloys increases resulting in reduced formability. This can result in a product that is unable to meet the formability demands of the automotive manufacturer. As a result, industry has moved towards performing pre-ageing (PA) treatments to prolong the “shelf-life” of the material prior to it having insufficient formability. Once formed into BIW panels, the parts are then painted and subsequently undergo the paint curing heat treatment which consists of a short period of time at medium temperature, typically 20 minutes at 170–190°C. This short artificial ageing (AA) treatment, known as the paint bake (PB), provides additional strength and improved dent resistance for the material, but reduced formability. The PB result is strongly dependent on the PA treatment performed prior to the forming operation. Furthermore, the addition of copper (Cu) to a base Al-Mg-Si composition is known to increase the alloy’s strength. The goal of this work is to study the effect of Cu on strength, strain hardening, and strain-rate sensitivity (SRS) of these alloys, to understand the strength-formability compromise, for two separate heat treatment schedules; one including and one excluding the PA treatment, both followed by NA."

Jan 1, 2018

By Stefan Boshkov

THE ADVENT of mining at great depth has brought to the fore the question of stresses around mine openings. The many-pronged attack on this problem is certified by the accelerated appearance, in the mining literature, of articles on various topics related to this subject (1). Whereas it may be agreed that we, of the mining profession, have fallen woefully behind in research and the development of an understanding of this important facet of the general problem of mining, it must also be accepted that the analysis of the stresses in a mine structure is usually more complex than is the case in the majority of structures encountered and dealt with in civil engineering. Whereas homogeneity and isotropy are readily acceptable for most metals, such properties are but crudely approximated in rocks. Whereas the external loads on a structure in civil engineering may be readily determined, those on a mining structure are subject to ?conjecture. Whereas the limits of the structure may readily be defined in civil engineering, the boundaries of the mining structure are, in most cases, indeterminate, and subject to intelligent guesswork, at best.

Jan 1, 1956

By K. K. Dehn

This study focused on determining the stability of thin shotcrete fill fences at a hard rock mine in northwestern Ontario during increased pour rates of paste backfill. Determination of the stability of the fence is needed for both personnel safety and to avoid failure of a fence. Failure of a fill fence during backfill activities would have severe impacts on production and potential hazards to nearby workers. Approved fill fences at the mine are a slender design of 10.5 centimeters of shotcrete applied to a rebar framework with burlap lined ?bedspring? backing. Approved mine standards dictate that fill rates may not exceed 1.5 meters of paste depth per 10-hour shift when pouring behind a flat fill fence. To decrease the backfill cycle time the study looked at fence stability during increased pour rates of 2.5 meters paste depth poured within a 10-hour shift. An instrumentation design was developed including pressure cells, strain gauges, and tilt-meters that were built into experimental fences to observe the effects of increased pour rates on lateral wall pressures, strain development in the rebar and shotcrete reinforcement, and physical deformation patterns along the face of the fence. The data was analyzed for overall stability.

May 1, 2007

By R. A. May, P. J. Brooks, W. M. Smith

"Neill and Gunter Limited (NGL) has prepared a preliminary design and a cost estimate for a ferric chloride leach plant to recover copper, lead, zinc, and silver from a typical complex sulphide ore. This plant design is specifically intended to treat unconcentrated ground ore (flotation feed), but can be readily adapted to treat bulk concentrates. Samples of ground ore and bulk concentrate were obtained from Heath Steele Mines, Miramichi, New Brunswick, laboratory testing, and preliminary process flow sheet preparation was carried out by the Research and Productivity Council in Fredericton, New Brunswick. Approximately thirty drawings have been produced, including process and equipment flowsheets, process piping and instrumentation drawings, and preliminary general arrangements. Preliminary capital and operating cost estimates were prepared for a plant that would treat 1000 t/d of crushed and ground ore to produce about 30 000 tpy of zinc. Capital and operating cost estimates were also projected for plants up to 4000 t/d of processed ore. Recoveries of 99% for zinc, 98% for lead, and 96% for copper were achieved in laboratory tests on unconcentrated ore. These recoveries were higher than the overall recoveries obtained from bulk concentrate, yielding approximately 10% more revenue.A 1000 tonne per day plant was determined to have a low return on investment, however, depending on the size and type of mining operations employed and the FCL plant throughput. DCF-ROI projections of 20% to over 30% were calculated for 100% equity financed “green field” mine, mill and FCL plant operations of 2000 t/d and higher"

Jan 1, 1997

By R. M. BUCHANAN

The segment of Canadian industry based on smelting of alum in um and manufacture of consumer products is based entirely on imported alumina and bauxite. In the absence of Canadian bauxite deposits, consideration of anorthosite, a less desirable aluminous rock, is being undertaken as one alternative in maintaining assurance of supply. Anorthosites in Canada cover many thousands of square kilometres of the Precambrian Shield. Although compositions vary widely among Canadian anorthosites, many appear to exceed the specified minimum of 25% A I 20 3 in bodies containing more than the required JOO million tonnes. A lthough most Canadian anorthosites are of Precambrian age, one located in British Columbia has been identified as being Middle _Cretaceous.

Jan 1, 1984

By C. J. Simensen, R. Østhus, H. J. Roven, K. G. Skorpen, H. Kalager

"This work encompasses co-extrusion of alloy Al4.5Mg at the core and rapidly solidified Al4.5Mg1Ag forming the surface layer. The goal is to produce a multi-material by co-extrusion having a relatively hard surface as compared to a softer core. At the same time, work hardening in both alloys is expected to be significant due to Mg in solid solution. Precipitation hardening at 160°C is studied by applying solution heat treatments at 560°C. The hardness increased from 80 to 130 VH in the surface material after 236 h. Surprisingly, the Al4.5Mg alloy also shows pronounced aging at this temperature, i.e. from 70 to 90 VH. The relatively high solution heat treatment temperature introduces grain growth in the core, but this is insignificant for the RS surface alloy. Blisters forms at the surface and cracks follows large portions of the interface. However, the tensile ductility is significant in all conditions due to very pronounced work hardening, i.e. for the as co-extruded, T6, under- and over-aged. The elongation at fracture ranges between 40–45% and the tensile strengths 240–275 MPa. The tensile properties increase linearly with the thickness of the RS alloy, i.e. following the rule of mixtures.INTRODUCTION Al-Mg alloys in 5xxx-series are classified as non-heat treatable wrought alloys (Polmear, StJohn, Nie, & Ma, 2017). The formation of the binary ß-Al8Mg5 does not give a substantial increase in the strength of the alloys (Mondolfo, 1976). When a third element like Ag, Cu or Zn are added, G.P.?zones are formed at low temperatures and intermediate, partial coherent phases are nucleated somewhat higher temperatures and finally a ternary, equilibrium phase is formed (Auld, 1968; Cousland & Tate, 1986; Mondolfo, 1976). Both the formation of G.P.?zones and intermediate phases increase the hardness and strength of the materials. An intermediate, hexagonal T´?phase is formed in Al-5 wt%Mg-1wt%Ag, and finally the equilibrium, cubic phase (Al,Ag)9Mg5 is nucleated (Cousland & Tate, 1986; Mondolfo, 1976)."

Jan 1, 2018

By E. Ghali, W. Zhang, G. Gabra, N. Sorour, G. Houlachi

The additives polyacrylamide, 1-Butyl-3-methylimidazolium chloride, Tetra-butylammonium bromide, Benzalkonium chloride and chitin are evaluated during zinc electrolysis from synthetic acidic sulphate electrolyte containing Mn2+ ions, in absence and in presence of 0.0055 mg dm-3 of Sb3+ ions. Galvanostatic polarization tests for 2 hours at 50 mA cm-2 and 38oC were carried out to determine the cathodic and anodic potentials, and current efficiency of the deposited zinc. Potentiodynamic polarization and cyclic voltammetry tests have also been employed to study the electrochemical behavior of each additive on the zinc deposit on aluminum electrode. Results showed that, in presence of Sb3+, adding 1 to 3 mg of 1-Butyl-3-methylimidazolium chloride increases the cell voltage by ˜0-7 mV. Current efficiency is increased by ˜4.90-6.40%; power consumption is reduced by ˜147-173 kWh t-1 by adding 1-3 mg, respectively. However, in absence of Sb3+, cell voltage is decreased by ˜7-28 mV, current efficiency is increased by ˜0.70-1.50%; power consumption is reduced by ˜41-47 kWh t-1 by adding 1-3 mg. The effect of the other additives on cell voltage, current efficiency, lead content and morphology of zinc deposit has also been examined. Surface morphology and crystallographic orientation of the deposit was studied using scanning electron microscopic (SEM) and X-ray diffraction (XRD), respectively. The content of lead in the deposit has also been measured using inductively coupled plasma spectroscopy (ICP).

Jan 1, 2015

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a' very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948