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By S. Foged

Umicore and MWH jointly demonstrated that mechanical dewatering of goethite and neutralised tailings significantly increased the life of a 30 ha tailings pond and improved the operation of the pond. Umicore operates one of its zinc production plants in Balen, Belgium. As part of its production process, an excess of neutralised and goethite¬containing tailings is generated. These have historically been stored inside large lined ponds. As the storage area of the current goethite pond was nearing its capacity, Umicore studied the potential for an extension to the existing embankment. However, this extension would face intense regulatory scrutiny, because the environmental and safety impacts were considered important. Together with Umicore, MWH suggested and investigated an alternative treatment approach consisting of mechanical dewatering prior to storage. A feasibility study was prepared where wet storage was compared to dry storage. Differences in safety risks, environmental impacts and economic costs were outlined. The study demonstrated that the life of the tailings pond could be increased from 6 to 22 years, seriously reducing the environmental impacts and safety risks at no significantly higher cost than would have been incurred with the continued operation of the existing pond. The results of the study are presented in this paper.

Jan 1, 2006

By G. B. Harris

In recent years, increasing attention has been focused on the hydrometallurgical treatment of base metals feeds, especially nickel laterites and polymetallic sulphides. One approach that has received some attention is the use of high?concentration chloride solutions (brines), which are now showing some promise after initial setbacks. Iron is usually the major component in the base metal feed to such processes, and if physical means cannot be used to remove it, then the iron concentration in the pregnant leach solution is always significant. This paper presents some of the background theory on the hydrolysis of iron in high-strength (>3M) chloride brines, and discusses the roles of temperature, solution concentration and free acidity. It is shown that the system is complex, but that crystalline and readily-filterable hematite can be generated, and that the system has a low energy requirement.

Jan 1, 2006

By V. A. Preto

The Rexspar uranium deposit is located approximately 5 kilometres south of Birch Island, B.C. Three separate zones of commercial-grade uranium mineralization mineable by open pit have been outlined. Uranium and fluorite-celestite mineralization occur in a trachytic member of alkali-feldspar porphyry, lithic tuff, tuff breccias and pyritic schist conformably interlayered with a succession of strongly deformed greenschists and fragmental rocks that are, in large part at least, of volcanic origin. The age of these strata is not precisely known, but they are considered as part of the possibly Mississippian Eagle Bay Formation. Commercial-grade uranium mineralization is always associated with fluorphlogopite-pyrite replacement of the trachytic unit and is contiguous to, but separate from , a zone of ore-grade fluorite mineralization. In all zones, ore occurs in lenses of variable thickness and lateral extent, which lie parallel to the schistosity of the trachytic rocks and surrounding greenschists. The principal radioactive minerals at Rexspar have been identified by other workers as uraninite, uranothorite, bastnaesite, torbernite and metatorbernite. Considerable amounts of thorium oxide and widespread rare earths have been reported from all three radioactive zones. The geology of the deposit suggests that the trachytic rocks represent a highly differentiated intrusive-extrusive system in which fluorphlogopite, pyrite, fluorite and uranium-bearing minerals were deposited late in the evolution of the system by deuteric, volatile-rich fluids. The considerable amounts of thorium and widespread rare earths associated with the uranium tend to support the thesis that this element is of primary origin rather than secondary.

Jan 1, 1978

By A. Eslami

When producing high grade mattes in smelter plants, copper losses in the slag are inevitable. Hence, the recovery of copper from slag has been the focus of many research projects, copper flotation being a widely used process. In the Khatoonabad converter, 200 t/d of slag are presently produced with a grade of 2.3% Cu. Assuming a 85% recovery by flotation, about 3.9 t/d copper could be produced, which is of prime importance economically. In the present work, a sample of this slag was crushed and ground in the laboratory to liberate the copper-bearing minerals. Following mineralogical studies, optimum laboratory flotation parameters were obtained, resulting in 90.27 % recovery and 9.42% of copper grade for the rougher stage. At pilot scale, a pulp of 28% solids was floated at ph 10.5 using 40 git of Z6, 25 git of R407 and 20 git of MIBC and A65. A recovery of 83.52% was obtained for a concentrate grade of 28.36% Cu. In the rougher cells, the feed consisted of particles 94% finer than 74 microns whereas in the cleaning stage, particles were 95% finer than 44 microns. Based on the obtained results, the Sarcheshmeh Khatoonabad converter slag is presently being fed to the Chargonbad flotation plant, where a concentrate of 32% copper at 86% recovery is being produced.

Jan 1, 2007

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT: As part of an overall study of properties and processes influencing consolidation of oil sands fine tailings resulting from different extraction processes, self-weight consolidation tests were per-formed. Fourteen 2 m and 1 m high standpipe tests were instrumented to monitor the rate and magnitude of consolidation of seven fine tailings materials. Tests provided valuable information about the variation of consolidation related to differences in fine tailings material properties that result from a change in bitu-men extraction process (caustic versus non-caustic). In addition, the effect of adding a coagulant to caustic fine tailings was measured. Test results are presented and discussed in terms of consolidation rate long-term volume decrease, compressibility, and downward drainage. Non-caustic fine tailings had fasterinitial consolidation, which is important in tailings ponds for reducing storage capacity and returning decant water at a faster rate to the extraction plant. Similar results were obtained for caustic fine tailings with a coagulant addition. However, long-term settlement of the different fine tailings appears to con-verge to a similar value over time because it is then governed by effective stress.

Jan 1, 2011

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By J. E. Ryan

General Description Due to the extreme cold weather experienced in Flin Flon during the winter months, thought and precaution were necessary in the design of the plant buildings. The machine shop, carpenter shop, drill shop, and coal plant buildings are similar in the building materials used in their construction. They are sided with two-inch shiplap, insulated with celotex and asbestos paper, and covered with corrugated iron on all side-walls. Roofing consists of 2 by 4 lumber on edge, laminated, and further covered by celotex and three-ply roofing. These buildings are heated by means of unit heaters. The heaters are primarily steam-heated radiators, through which the air of the buildings is circulated by electrically-driven fans. Our machine shop is located to the east of, but central to, the main operating buildings of the mine and plant, and is so connected by a net work of tracks as to be able to serve all portions of the entire plant conveniently. The building is divided into two bays, the main bay 53 ft. by 340 ft., and the east bay 24 ft. by 340 ft. The shop office and drafting room, a two-story annex 24 ft. by 30 ft., is located on the west side of the shop. The arrangement within the shop is such as to house conveniently the several departments, namely, heavy machine tool section, repair floor section, boiler shop heavy tool and floor section, blacksmith heavy tool and forge section, tool room, electric welding rooms, stock room, tin and copper shop, and electrical parts and armature winding and repair shop (see Figure 1). All the heavy tools, the repair floor section, and railway tracks are so located in the large open bay as to be fully serviced by an electrically operated 15-ton bridge crane, with a span of 50 feet and a travel the full length of the shop. A standard-gauge railway track, branched off the main line, penetrates the full depth of the building. This track lies along the extreme east side of the main bay, allowing easy entrance and movement of rolling stock and heavy machinery, loaded on standard flat-cars, to the repair floors in the main bay. Eight jib cranes, affixed to building columns, further facilitate the heavy repair work throughout the various shop divisions. Our light and heavy machine tools are standard equipment, not unlike tools used in mine, mill, and railway shops.

Jan 1, 1935

By D. Hodouin

Jan 1, 1978

By G. J. Hawkes

"We all know that every man who works for us should have a thorough knowledge and understanding of his responsibilities. But how about ourselves? Du we have a thorough knowledge and understanding of our own responsibilities as Mill Superintendents?I once had an occasion to say to a Manager that I did not know something was my responsibility and he replied with suitable emphasis ""Everything inside those four walls is your responsibility"". That makes the extent of our responsibilities clear but does not give us a check list to keep an eye on as we do our job from day to day.What are our responsibilities? I suggest they are the following:1. Developing and maintaining efficient operating and maintenance crews.2. Milling the required tonnage.3. Recovering the economical maximum amount of gold.4. Keeping costs at the economical minimum.5. Seeing that the figures are reasonably accurate for tonnages, assays, production, losses, and costs.6. Preventing accidents.7. Preventing fires.8. Maintaining the equipment and building and keeping them clean and tidy.9. Enforcing company rules and regulations."

Jan 1, 1965

By Norman R. Ball

"Many people in the mining and metallurgical industries were brought up to embrace Henry Ford&apos;s pronouncement that ""History is bunk"" but it is not generally known that the same Henry Ford created and paid for one of the finest technological museums in the Western World. I am aware that many people feel that industry history is something you ask aging executives to do or that history is a clip-andpaste compendium of pictures re-discovered every 25 years or on the occasion of issuing a press release on plant expansion. Moreover, there are many who fear historians as somewhat deranged individuals interested only in corruption, injustice and sensational labour strife. Good history lies somewhere between the controlled P.R. handout and the hysterical attack. Writing good history is a difficult creative act based on the application of experience, insight, wide knowledge and careful reasoning to available evidence. To date, the Canadian mining and metallurgical industries have achieved a great deal but left too little evidence and it is this lack of evidence which must be corrected before it is too late. It is the purpose of this article to stimulate thoughts with regard to archives, one of the more important vehicles for the preservation of such evidence."

Jan 1, 1999

By H. W. Parsons

Several low-temperature, dry chlorination processes for the treatment of sulphide minerals are reviewed, in a chronological order. These processes include the following: the Swinburne-Ashcroft, Baker-Burwell, Maim, Comstock-Wescott (Aldermac) and the Mitterburg Mining Process. Dry chlorination investigations at the Canadian Mines Branch (now CANMET) and the U.S. Bureau of Mines are discussed, as is a proposed process by the South Africa National Institute for Metallurgy. The techniques used in the process are discussed, as are the shortcomings, problems and failures of the methods.

Jan 1, 1978

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By W. Petruk

"D. Doyle How large is the beam to which you referred? Are we considering Watts, Griffis the probe of a 1 micron sized particle?& McOuatReply Yes. The beam would be about 1 micron. We could enlarge or reduce it depending on the current in-put.D. Doyle Then chemically bound material we might not see. If you are restricted to 1 micron then you would not be able to separate things smaller than this. Is this not so?Reply We won't be able to analyse it but we will see it as the scanning electron microscope has a resolution down to about 0.1 microns. We should be able to get the general composition of such a grain plus its surrounding grains. We feel we can then make a reasonable estimate if it were as small as 0.1 microns. An accurate analysis would be achieved with grains of 3 and 4 microns.D. Doyle Would this have an application in the hydrocarbon field?Reply The lowest atomic number would be sodium. We wouldn't be able to go below that atomic number. Anything with sodiumor a larger atomic number would enable us to analyse the carbon.M. Fairwether Do you have any policy relating to priorities. For instance areCominco companies going to be limited in the amout of samples permitted to give everyone a chance because quite frankly our company, and I'm sure all base metals companies can hardly wait for the installation of this equipment. I can forsee two years back-log of work in the first month.Reply Quite frankly, I haven't looked at this. At the present time the work is under the START program but I suppose we will have to look at possible changes. Anything under the START program has first line priority.B. Thorndycraft Will the briquetting of samples be automated as well? Pinson MiningReply No, not at this point. Our polish section laboratory is first-class and can turn out 18 polish sections a day which is more thar we can handle.B. Thorndycraft With the capability of this machine to operate in a hands-off manner perhaps it could start to look for the 5 micron gold particle in tailings?Reply I have such a program using a wave-length spectrometer rather than the energy dispersive. The wave-length spectometer is about 10 times as sensitive and would scan the section much faster. A one inch diameter polished section would be scanned in about 7 hours for anything 1 micron or larger."

Jan 1, 1984

By M. Dupuis

It has been previously demonstrated [1,2] that using selective collector bar rodding has a big impact on the uniformity of the current density at the top surface of the cathode block and hence on the intensity of the horizontal current in the metal pad, The present study investigates the impact of using selective collector bar rodding on the MHD stability of a 500 kA aluminium electrolysis cell, For this purpose the recently developed MHD package for the aluminium reduction cell time dependent behavior is used.

Jan 1, 2005

By A. Holland, T. Krumins, E. Olin, J. F. M. Castilleja, J. Geldart, C. Fleming, I. Jackman

A flowsheet has been developed to treat the flotation tailings from a copper mine in Mexico to recover gold and silver by cyanidation and carbon-in-pulp (CIP). The plant will treat ~15,000 t/day of a 60:40 blend of current flotation tailings and the mine’s historic tailings. The tailings also contain a significant amount of cyanide-soluble copper, and the economic viability of the project is strengthened by recovering most of the copper and cyanide associated with this process. The solution and solid phases in the CIP tailings will be separated in a counter current decantation (CCD) circuit and the CCD solution overflow will be treated by a SART Process. Copper precipitates as a salable copper sulphide product in the SART Process and the cyanide that is associated with the copper complex is regenerated as free cyanide. After SART, a portion of the SART product solution will be recycled to leach to reuse the free cyanide, while the remaining solution will be used as wash water in the CCD circuit. Incorporation of the SART Process in the flowsheet allows the CIP circuit to be operated aggressively as a gold plant, which means most of the silver in solution passes through CIP to SART. Silver co-precipitates with copper in SART and is recovered very efficiently with the copper sulphide by-product. Incorporation of SART also allows the leach and CIP circuits to be operated with relatively high levels of free cyanide, which enhances silver leach kinetics and helps keep copper from loading onto the carbon in CIP. The flowsheet was developed in the laboratory and successfully demonstrated in a fully-integrated pilot plant in 2018.

Jan 1, 2019

By D. A. Temple, G. O. John

Until recently, the approach to the problem of treating complex ores bas been to produce, insofar as is possible, mono-metal concentrates which are treated in traditional zinc, lead and copper smelting circuits, with the residues and by-products from some of these circuits being retreated for the recovery of contained values either by a separate residue treatment process or along with the primary feed to the appropriate circuit. The continued development of the Imperial Smelting Process, with its ability to treat poly-metal concentrates, calls for a re-examination of the traditional approach to this problem, and this the paper attempts to do. A survey of recent progress in the technical development of the process is made and a summary of current operational performance is included.

Jan 1, 1971

By P. H. Jennings

Commercial tellurium commonly contains heavy basemetal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities (~ 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too s low to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Feb 1, 1966

By J. F. Wright

The cold, or Kississing, Lake area in northwestern Manitoba was the scene of considerable prospecting and mining activity last summer. At the Sherritt-Gordon property, four diamond drills were at work exploring a large deposit of copper and zinc ore, and underground work was in progress on this deposit from two shafts. Some preliminary diamond drilling was completed in five other deposits, and surface exploration work was in progress at a dozen or more additional localities where copper and zinc sulphides were known to be present. Many prospectors visited the area and spent some time in search for new deposits, but apparently few discoveries were made; consequently, last autumn some returned a little disappointed in the area as a prospecting field. Although many visited Cold Lake area last summer in the search for mineral deposits, it should be emphasized that this new prospecting field is a very large one, and that to date only a small proportion of the ground has been examined, except in a very general way. Within the past 18 months, a village of several dozen cabins, and with a population of l00 or more persons, has sprung up on the shore of Cold lake, just west of the Sherritt-Gordon mine. This at present is the business centre of the area, and two banks, a post office - named Kississing by the Postal authorities - a Mining Recorder&apos;s office, as well as several restaurants and stores carrying a fairly complete stock of groceries, dry-goods, and general prospecting equipment, are already established.

Jan 1, 1929

By Y. Wang, S. Liu, K. Jiang

China is the world’s largest producer and consumer of non-ferrous metals. In recent years, significant progress has been made in research and commercial application of pressure leaching technology to produce some nonferrous metals. Research and development activities include a low-pressure, low-temperature leaching technology for complex copper concentrates, a hematite process to treat pressure leach solutions from zinc concentrates, and a pressure leaching - solvent extraction process for molybdenum and rhenium. Examples of commercial practices include a two-stage pressure leach technology in a zinc plant in Danxia, a direct leaching technology in a zinc plant in Zhuzhou, a high pressure acid leaching process for a nickel laterite project in RAMU, and a pressure leaching technology to treat arsenic sulfides in a plant in Guixi. The development of pressure leaching technology for the recovery of lead, vanadium, gallium, germanium, and precious metals in China will also be described in this paper.

Jan 1, 2015