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"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By R. Vergunst, E. A. Devuyst, G. Robbins

"INTRODUCTIONThe Inca process for continuous cyanide removal from industrial wastewaters was patented in 1984 by G.J. Borbely, et.al. (1). The process requires SO2, air, lime and a copper catalyst. Both free and complexed cyanide are oxidized to cyanate in the pH range 8 to 10. Cyanide bound to iron is removed by precipitation as a ferrocyanide insoluble salt and other base metals are removed as hydroxides.The process was piloted in 1982 on barren bleed solution at Campbell Red Lake Mines Ltd., Ontario (2). Since 1982, the Inca SO2-air cyanide removal technology has been applied in twelve commercial installations. The process has significant advantages over other commercial processes in the completeness of cyanide removal and lower reagent requirements and costs.COMMERCIAL INSTALLATIONSBy the end of 1988 Inca will have applied its patented cyanide removal technology to twelve commercial operations. Three of these, namely Scottie Gold Mines, Dupont of Canada Expl. Baker mill and Carolin, all in British Columbia, Canada, have ceased cyanidation operations but SO2-air cyanide destruction results were good for all mills, particularly so for over two years for the Scottie mill.Removal of cyanide from CIL slurry tailings is applied at Equity Silver (9,500 tpd) and Inca's new 1,200 tpd mill at Inca/Golden Knight. Detoxification of CIP tailings is carried out by Colosseum California (3,600 tpd) and Canamax's Ketza River operation (360 tpd). Repulped tailings from Merril-Crowe flowsheets are treated at Total Erickson's Mount Skukum mill (300 tpd) and Skyline's Johnny Mountain mill (200 tpd) and barren bleed at Inco/Queenston's McBean mill (500 tpd). Lynngold's MacLellan mill (1,800 tpd) treats pond supernatant water. Plating shop cyanide effluents are decyanized at Kuntz Electroplating in Kitchener, Ontario. Many of the above commercial operations were described in some detail in previous publications (3,4). Typical installations are described in this paper. A summary of operating results is given in Table 1."

Jan 1, 1989

By C. E. Smith, R. J. Inglis, M. I. Brittan, J. H. Schoeman

"AbstractA number of plant-scale cyanidation tests were carried out in an attempt to uncover the causes of fluctuations in gold recovery efficiency. Computer analysis of the results verified that the treatment of reclaimed waste rock material along with normal run-of-mine ore was having an adverse effect on metallurgical efficiency. Mineralogical examinations showed that the free gold particles in the dump material were heavily tarnished or coated (predominantly by hydrated iron oxide), accounting for the lower recoveries. The indications were that the effect could be counteracted somewhat by using higher than normal cyanide and lime reagent concentrations and adequate leaching times. Analysis of the results showed further that leach pulp density was an important operating parameter affecting extraction efficiency. A variable activation energy leaching model provided an extremely good characterization of individual batch leach runs.IntroductionFLUCTUATING METALLURGICAL EFFICIENCY at the gold concentrator of the S.A. Land and Exploration Company Limited (""Sallies"") prompted some plant-scale cyanide leach studies in an endeavour to uncover the causes of the variations in gold recovery."

Jan 1, 1977

By G. A. Gross

"Nearly 90 per cent of the iron ore produced in Canada is derived from iron-formation or bedded iron deposits. About 70 per cent of this consists of concentrates obtained from iron-formation; another 20 per cent was formed by natural enrichment processes.Four principal varieties of iron-formation are recognized -the Algoma, Superior, Clinton and Minette types. Differences in their geology, mineralogy, chemical com-position and environment of deposition are of special significance in their evaluation as ore.The properties of the ores, including grade, beneficiation qualities and minor element content in taconites, metataconites and naturally enriched ores, reflect characteristics of the primary stratigraphie units from which they are derived. A detailed description of the stratigraphie facies is essential for efficient utilization of these source beds."

Jan 1, 1966

By China University of Mining and Technology, P. Zhang, C. Zhou, C. Duan

"Recovering pyrite from the gangue with high sulfur content is of great significance for both economic development and environment protection in China. Due to the global water shortage and high cost in wet separation processes, it is urgent to explore more efficient energy and water conservation method in mineral processing field. This study has proposed an innovative method based on density difference for fine pyrite enrichment by vibration fluidized bed. In this study, the total sulfur content (TSC) of the gangue sample is 19.18%, and the pyrite is disseminated with fine granularity in the gangue which should be crushed for dissociation. The combination and dissociation experiment of -6mm gangue shows that the dominant density of -6+3mm, -3+1mm and -1+0.5mm comminuted material is +2.9g/cm3. Based on the analysis of characteristic, the effects of various factors on the separation performance were experimental studied. The results show that gas velocity, vibration intensity and bed height all have the significant effects. With the increases of superficial gas velocity, vibration intensity and bed height, the separation performance all presents a decreasing tendency. Additionally, the TSC of -6+3mm, -3+1mm and -1+0.5mm materials are respectively up to 37.94% , 35.43% and 30.61% at the optimum conditions, which are the 1.72?1.90 and 2.29 times as much as the TSC of raw material, respectively. This study demonstrates the vibrated fluidized bed can recovery pyrite from the gangue effectively.INTRODUCTIONWith the increasing mining and separation of coal, the yield of gangue has a further growth tendency, which has become one of the largest reserves of industrial waste (Querol et al., 2008). However, many harmful elements, such as S?NOx and Hg, is existed in the gangue leading the serious damage to the soil and environment (Hao, Yun, Zhanyuan, Sen, & Song, 2013). In addition, the economic would be suffered from the loss resulting in the occupied of arable land caused by the accumulation of gangue (Yeheyis, Shang, & Yanful, 2009; Zhou, Liu, Yan, Fang, & Wang, 2012). Therefore, the government has put forward the policies of ""green mining"" in China (Xing & Gao, 2009; R. Zhang, Ai, Zhou, Ju, & Zhang, 2015; Zheng, Du, Li, Qiu, & Yang, 2015). Among different research areas of coal utilization, extracting the useful minerals has become one of hot topics (Ledin & Pedersen, 1996; P. Patra & Natarajan, 2003; Partha Patra & Natarajan, 2004). At present, many researchers has devoted to the desulfurization of coal all over the world. As result, the sulfur element, which is mainly existed in the presence of pyrite, would transferred in the tailings, namely the gangue. Meanwhile, the pyrite is important raw materials to produce rubber, paper, textile and match. Consequently, recovering the pyrite from the gangue is not only suitable to the requirement of ""green mining"", but it could turn the waste into the treasure having the important significance."

Jan 1, 2016

By S. D. Graham

"The extractive metallurgy of gold is largely controlled by mineralogical factors such as the presence of refractory gold, particle size, gangue mineral associations, presence of preg-robbers, oxygen and cyanide consumers, and locking characteristics in base metal sulphides. Light microscopy and automated mineralogy techniques are regularly used to characterise the effect of these variables on gold recovery. However, despite their widespread application there are a range of limitations when grades are low. Typically, the analysis of low-grade samples requires the preparation and analysis of numerous polished blocks. This is often costly and time consuming, with complexities regarding analysing statistically representative particle quantities and problems overcoming stereological bias. This is compounded by the “nugget” effect and high tenor nature of gold mineralisation. X-ray Microscopy techniques have the potential to overcome many of these problems, in particular the statistical representivity of analysis, removing stereological bias and effectively locating phases that are present in ultra-trace proportions. In this paper we outline the potential benefits of employing X-ray Microscopy (XRM) in characterising gold losses from a typical Cu-Au porphyry project, which were illusive in 2D based analysis. The talk will also outline additional application areas of XRM within the extractive value chain."

Jan 1, 2017

By lchimura. R. .

Japan Oil, Gas and Metals National Corporation (JOGMEC) and Centro de Investigation Minera y Metalurgica (CIMM) commenced a five year project from 2001 to modify the treatment of the furnace dust from Teniente converter containing harmful elements like arsenic and lead. The project was supported by Japanese and Chilean governments, and a demonstration plant was installed and operated at Las Ventanas Smelter and Refinery (Division Ventanas CODELCO). The basic and detailed engineering was made by Mitsui Mining and Smelting Co., Ltd (MMS) based on the joint study among JOGMEC, CIMM and Division Ventanas CODELCO. Arsenic in flue dust is lixiviated by sulfuric acid and fixed as crystalline ferric arsenate, where leachability of arsenic will be lower enough than the regulation, 5mg/I by TCLP (Toxicity Charactaristic Leaching Procedure) of USEPA. On the other hand, the recovered copper from the dust will be fed to the copper production process at Las Ventanas Smelter and Refinery, while zinc will be recovered as the exportable product. As introducing the crystallization and growing stage, the stable crystalline ferric arsenate formation can be achieved under the normal pressure.

Jan 1, 2007

By Peter A. Hacquebard

Recent drilling programs have shown that the in-situ coal resources of Nova Scotia are very substantial. The grand totals of the measured, indicated and inferred categories amount to 232 m, 646m and 993 m tons, respectively. This vast quantity of coal occurs essentially in five main fields: Sydney, Mabou, Port Hood, Pictou and Springhill. The largest resources (84% of the total) occur in the submarine area of the Sydney coalfield. With a 65% recovery rate, there are at present 150m tons of proven, recoverable coal in Nova Scotia. At a predicted maximum annual production of 5 m tons, this amount equals a lifespan of 30 years. However, additional drilling, particularly in the Sydney offshore area, holds promise of increasing the recoverable reserve tonnage to at least 350 m tons. This figure may be compared with the 484 m tons production obtained during 191 years of mining (from 1785-1976). The geological appraisal of the remaining coal resources in the five fields mentioned is presented in three-dimensional diagrams, per individual seam and corresponding reserve area. In addition, the submarine extensions of the Sydney and Mabou coalfields are discussed in light of results obtained from off shore oil exploration wells. The terminology and standards of coal resource calculations are pointed out, and the phenomenon of seam splitting and its prediction from geological data is illustrated. The availability in Nova Scotia of either thermal or metallurgical coal is considered in relation to rank and sulphur content. This paper was presented in June 1977 at the 90th Annual Meeting of the Mining Society of Nova Scotia. The coal resource estimates, however, have been updated to include the results obtained with the offshore drilling in the Sydney Coalfield to November 1977.

Jan 1, 1979

By M. A. Hardie

"CASES and mixtures of them are so common and so much a part of everyday existence that they become so taken for granted that their individual characteristics and idiosyncrasies rarely become of curiosity to others than those involved in tl1eir production, processing, treatment, transportation, and for utilization. The use of the most common and universal mixture of gases -air -is begun at birth by ail living creatures and their discontinuation of its use terminates existence. Modern man rides on air in his tires, rides through it for high-speed transportation, and uses it for his comfort in the heating and air conditioning of his domicile. It is neither the aim nor the in-tent, in the next few moments, to provide a panacea for even a portion of the problems inherent in the gas industry nor to delve deeply into any particular facet of its diversities. The purpose is primarily to touch upon some of the peculiarities and generally to consider approaches to employ in the pursuit of solutions."

Jan 1, 1959

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By Yann Sivry, S. Subramanian, Divyasree C. Prabhakaran, Jean Riotte

The potential of a bacterial strain isolated from water samples collected from a chromite mine in Odisha, India has been assessed for the bioremediation of hexavalent chromium, a toxic environmental pollutant. The isolate was identified as Sphingopyxis sp., a Gram negative bacterium, adopting molecular biological protocols and biochemical characterization techniques. Detailed investigations on the bioremoval of Cr(VI) were carried out using Sphingopyxis sp. cells and the various parameters affecting the biosorption process were evaluated. About 55 % biosorption of Cr(VI) was obtained using Sphingopyxis sp. bacterial cells and the residual chromium in solution was found to be bio-reduced to the trivalent form, namely Cr(III). Thus, complete bioremediation of Cr(VI) could be achieved using the mine isolate, with contributions from both biosorption and bioreduction mechanisms. The Cr(VI) biosorption isotherm obtained for the isolate was found to follow a typical Langmuirian behavior and the free energy value of biosorption was determined to be ~-25 kJ/mol, indicative of involvement of chemical binding forces in the bioremediation process. The chromium biosorption kinetics by the isolate followed a pseudo second order reaction. The FTIR spectral studies revealed that carboxyl, hydroxyl, amino and phosphate groups were involved in the biosorption process. X-ray photoelectron spectroscopic studies on the bacterial cells interacted with Cr(VI) confirmed the presence of both Cr(VI) and Cr(III) on the cell surface. The electrokinetic studies revealed that the surface potential of the bacterial cells were less electronegative subsequent to interaction with Cr(VI), compared to the cells alone, which further testified to the binding of positively charged Cr(III) ions, formed by bioreduction of Cr(VI), to the bacterial cell surface. A marginal shift in the iso-electric point obtained for the bacterial cells interacted with Cr(VI), corroborated the involvement of chemical binding forces in the bioremediation process.

Jan 1, 2016

By S. U. Baltuch, E. G. Baltuch

"Ventilation in process buildings is key to proper mill function. Correctly engineered systems to evacuate surplus thermal energy from process areas allow optimized rates of air change, thus assuring the good functioning for the lifecycle of the process while demonstrating conformity with occupational hygiene standards. Computational fluid dynamic simulations, coupled with traditional calculations and physical modeling, can demonstrate to end users and assist engineers in the optimization of mill ventilation, reducing total installation costs while assuring that the proper solution is in place for the complete lifecycle of the process equipment. Results have been fully implemented on a number of steel mill and aluminium smelter applications and we continue to study, optimize, and innovate as new tools become available to provide the best possible engineered solutions for particular applications. INTRODUCTIONThe objective of this research project is the development and implementation of modern approaches and computational fluid dynamics (CFD) simulation in the engineering of green ventilation of hot process buildings. This will assure the predictive performance and improve the quality and ease of construction of industrial gravity ventilation equipment, along with the adjunct hot process buildings, while lowering the overall project costs and time to completion.In order for a hot process building, such as a steel mill, to properly function, heat must be extracted from within. This is accomplished by having air inlets at the bottom of the building and outlets at its apex. The reason for this is to maximize the potential chimney effect. When using stack (buoyancy) effect ventilation, the process heat becomes the driver. Therefore, increasing this distance (height) improves the ability of the heated airstream to utilize basic gravity for acceleration of the heat/air flow, allowing a regular number of air changes per hour while ensuring that the process environment remains weather resistant under normal operating conditions.This process has been understood since the time of King Charles I of England, who decreed in 1600 that buildings should have 10 foot ceilings and that windows should be made taller rather than wider to allow better smoke extraction.Figure 1 is a painting of the Bethlehem Steel Works in the 1860s, where the concept of air inlets and penthouses on the roofs for air outlet was already being put into practice. Figure 2 is an early photograph of the Pittsburgh Steel Works."

Jan 1, 2012

By M. Massinaei

Recently constructed circuits have included multiple stages of columns in a variety of applications, from roughing to cleaning. The Miduk copper concentrator (in south-eastern Iran) is one of the unique mineral processing plants which use column flotation cells as rougher. As the bulk of final concentrate is produced by rougher columns, optimized metallurgical performance of these cells is crucial. This paper will present the study and optimization of, a froth washing system of columns. For this purpose, the cross-sectional area of orifices was increased and their orientation altered. Concentrate assay for copper and silica, in addition to bias rate were found to be the assessment criteria. Modification of the wash water system resulted in increasing the purity of rougher and final concentrate. Negative bias and short-circuiting of wash water into the concentrate launder were the main causes of improper froth zone washing in the former system.

Jan 1, 2007

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By Geology Staff, C. H. Stockwell

"The Flin Flon base metal mine, owned and operated by the Hudson Bay Mining and Smelting Company, is on the Manitoba-Saskatchewan interprovincial boundary at a point 400 miles north of the International boundary. The deposit was discovered in 1914 by Thomas Creighton and the Mosher and Dion brothers. Since production commenced in 1930, 25,000,000 tons of ore have been mined. On January 1st, 1946, reserves were estimated to be 26,000,000 tons, averaging 2.99 per cent copper, 4.i4 per cent zinc, and 0.089 oz. gold and 1.25 oz. silver per ton. In addition to the four metals named, others recovered from the ore include- cadmium, selenium, and tellurium. The mine workings extend to the 3,750-foot level, but little development work has yet been carried on below 3,250 feet.The known ore occurs in six lenticular to irregular bodies within a zone 500 feet wide. These bodies average 900 feet long, 70 feet wide, 1,500 feet in vertical depth, and 2,500 feet in length along the plunge. They were formed by replacement of the country rock and include ore of two types, solid sulphides and disseminated sulphides. Seventy per cent of the total known ore is of the solid sulphide type. This consists essentially of metallic sulphides- chiefly pyrite- with included remnants of the host rock, and additional quartz and carbonate. In places, the ore exhibits banding, inherited from pre-existing structures. The disseminated ore occurs usually on the footwall side, and along the bottom of the plunge, of the solid sulphide bodies."

Jan 1, 1954

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By D. D. Hogarth

"IntroductionThe Hull iron range, comprising the Forsyth, Scott , Baldwin and Lawless properties (Fig. I), is in Gatineau Park, on the outskirt s o f the city of Hull , and about 6 miles (10 kilometres) northwest of the Federal Parliament Buildings.The deposits have been known many years and described numerous times, although the history has been treated lightly in former publications. Total ore shipments have been calculated at 122,700 long tons, of which over 80% were mined before 1900 and 74% in two brief periods: 1870-74 and 1880-82. It is surprising that the period 1870-74 has been overlooked by most authors and 1880-82 ignored altogether. More surprising, the essential data for these two periods are contained in manuscripts of the Robert Bell collection, which must have been available to officers of the Geological Survey o f Canada.The period 1801-1874 ha s already been covered by the writer in ""Pioneer mines”, but much information has come to light since publication. The present paper is therefore based o n new data and a fresh appraisal. However, little additional data were found for the early history (1801-1854) or for the legal cases involving A.H. Baldwin, and these parts were mainly summarized from the relevant sections of the above-mentioned publication.GeologyThe ore deposits are all situated somewhat below the middle of a graphitic, calcitic marble horizon, here folded into a northeast-plunging synform. The Forsyth, Scott and Baldwin deposits are on the south limb of the synform; the Lawless is on the north limb. The marble is underlain by three non-carbonate groups: biotite gneiss with interlayered quartzite (top), granite gneiss and skarn (middle), and biotite-garnet gneiss (bottom). Below these groups is a lower horizon of graphitic, calcitic marble. The whole sequence is Precambrian and has been subjected to high-grade (Grenvillian) metamorphism, but, in the north, is cut by an unmetamorphosed Cambro-Ordovician diabase dyke. For further information, the reader is referred to the summary by Baird."

Jan 1, 1983

By Michio Okada

Dissociative adsorption of hydrogen (deuterium) on thin gold films grown on Ir{111} surface has been studied with temperature-programmed desorption using a quadrupole mass spectrometer and nuclear reaction analysis. Thin Au{111} films are epitaxially grown on Ir{111}. Surprisingly, H2 (D2) can dissociatively adsorb on these Au{111} films, although it is well known that Au surfaces are noble enough not to dissociate hydrogen molecules [B. Hammer and J.K. Nørskov, Nature 376, (1995) 238]. We attribute this to the sensitivity of hydrogen to changes in the local surface properties, e.g., electron localization (the narrowing of the s-band, the s-band center model), which could explain the upto now unexpected high for the reactivity of a thin Au{111} surface. Moreover, we found that H (D) atoms can be confined into a Au thin film and/or the interface between an Ir surface and the thin Au film. We demonstrate how anomalously reactive thin Au films grown on an Ir surface are, and also compare the Au films with Ag films grown on Ir to test the validity/generality of our proposed s-band center model.

Oct 1, 2003

By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By Arthur Dubé

An account is given of the developments brought about in the last fifteen years by metallurgical research in the field of heat treatment of steels. The practical aspects of these developments are especially emphasized. Methods of representation of the phase-change during austenitizing and sub-critical transformation of austenite are described and the importance of time-temperature-transformation charts for the planning of heat treatment cycles is shown. Special copies such as retained austenite and internal stresses developed on quenching are also discussed in some detail. Due to the interest shown currently in these problems, it has been thought advisable to describe briefly the underlying principles and present some of the results already available.

Jan 1, 1945