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By J. P. Harrison, K. Gao

It is well known that in situ stress measurements at a given site will generally display significant variability. However, it appears that a robust analysis of such measurements – i.e., one that is faithful to the tensorial nature of the data – is not available. Despite the fact that stress is a tensor, stress magnitude and orientation have long been analyzed separately using classical statistics. In earlier work we demonstrated the applicability of tensor statistics to the analysis of stress variability. Here, we investigate further the difference between tensor and classical statistics with respect to the stress tensor correlation matrix. Our analysis commences with the selection of a series of valid correlation matrices. Then, assuming that standardized tensor components follow the multivariate standard normal distribution, these correlation matrices are used to generate marginal probability distributions of the eigen-parameters (i.e., principal stress magnitude and rotation angle). From these, random stress tensors are generated, their eigenparameters determined, and the probability density distributions of these obtained using both classical and tensor statistics. Our results indicate that, for all correlation matrices, both methods give practically identical distributions for principal stress magnitude. However, the discrepancy between the two methods with regard to probability density distribution of rotation angle is highly dependent on stress component correlation. This discrepancy is usefully quantified in terms of the integral, with respect to orientation, of the difference between the two probability density distributions. This parameter, which we term Area Difference, is closely linked to the magnitude of the correlation matrix determinant, which itself is related to the normal stress correlation coefficient (i.e., ?x ,?y ??). Assuming that Area Difference should not exceed 0.1, we identify the critical determinant for any particular value of normal stress component correlation coefficient. Thus, using published in situ stress data and the obtained critical determinants, we show that for a specific normal stress component coefficient, when the correlation matrix determinant is less than its critical determinant, the more precise tensor statistics should be used to calculate the distribution of rotation angle. These results demonstrate that the customary analysis of stress measurement data may lead to erroneous results, and that tensor statistics appears to be preferred approach.

Jan 1, 2015

By E. P. Evoy, A. W. Jolliffe

"The Uranium deposit of Gunnar Mines, Limited, is on the south shore of Crackingstone peninsula in the Beaverlodge area of northern Saskatchewan.The ore consists of disseminated pitchblende and uranophane in brecciated syenite, and forms a tubular or pipelike body, outcropping at the surface and plunging southward at about 45 degrees for a known length of1,400 feet (see Figure I). The upper portion is being removed by open-pit mining to a depth of 300 feet below adjacent Lake Athabasca. The remainder will require underground mining methods (see Figure 2).The property was staked in July, I 952, and the orebody was subsequently defined by about 70,000 feet of diamond drilling. A 1,250-ton mill was completed in 1955, and production commenced in September of that year with ore from the open-pit operation. The mill is presently being increased to 1,650 tons capacity, and a three-compartment vertical shaft is being sunk to 1,250 feet in preparation for underground mining.GeologyThe mine property is underlain by an assemblage of Precambrian metasediments known locally as paragneiss, granite-gneiss, and syenite. These lie on the southeast limb of a southwest-plunging anticline, strike about north 75 degrees east, and dip southward at about 45 degrees. Para- gneiss outcrops in the northwestern half of the claim group, and again on the islands south of St. Mary's Channel. The granite-gneiss lies conform-ably within the paragneiss and makes up the southeastern part of the property. The syenite forms an irregular, triangular-shaped mass within, and near the footwall of, the granite-gneiss band. Small lenticular bodies of mafic rocks are also present, the former being most prevalent in the paragneiss.The granite-gneiss is coarse to medium-grained, pink to grey, well foliated, and composed of feldspar (65 per cent), quartz (20 per cent), chlorite, and minor mica. The general concordance of its contacts with paragneiss and the absence of intrusive relationships along these, the presence of uniformly oriented inclusions of obviously sedimentary origin within the granite-gneiss, and the variation in colour and texture across the strike all strongly suggest that this member represents a granitized sedimentary rock."

Jan 1, 1949

By C. Grisanti, E. Prina Howald

The major of Swiss territory is occupied by mountains. Natural events as floods, debris flows, landslides, rockfalls, and avalanches regularly threaten the safety of people and properties. On the one hand, extreme weather events cause great damages, on the other hand, the enhancement of territory’s exploitation increases the risk. The Swiss Government makes many efforts to deal with the prevention of natural hazards, especially through measures of land management. As stated by federal law, Swiss cantons are obliged to establish hazard maps and to take the risk into account in the land management. Hazard maps are based on the hazard matrix, whose abscissa and ordinate are probability and intensity of the event on site. This project focuses on rockfalls. It consists of three main parts: the creation of a database to collect data on site, the creation of a catalog with all type of measures, and the development of a methodology for the analysis of the effectiveness of protective measures. The creation of the database allows us to collect information: about the site, about protective structures implemented on it, and about failures. With many multiple choice fields and few free text fields, it can collect data in a homogeneous way, without redundancy. The catalog has to be a tool that gives a basis to make decisions. It collects information about all types of protective measures implemented on Canton Vaud’s territory or available on the Swiss market. Free text fields allow for data storage of specifics, to give a complete view of structure’s characteristics and potentials. Methodology consists of four steps. The core of the procedure is the structure’s evaluation following a score system; it allows for calculation of reduction factors that have to be applied to intensity and probability parameters of the structure. Then it is necessary to convert the reduced structure’s intensity value into a residual site’s intensity value. Although the first step enables us to choose suitable measure for a specific site, it is not necessary to perform it. Second step allows us to evaluate structures under scenario 0, where structures are in best conditions. Third step allows us to evaluate structures under six scenarios of possible failings. Fourth step allows us to convert structure’s reduced intensity into event’s residual intensity and to establish the new point on hazard matrix. While the procedure has already been defined, details of score system and conversion have to be developed during the second phase of the project.

Jan 1, 2015

By W. Harry Foster

"Asbestos Corporation Limited, incorporated in 1925, operates four asbestos mines and three asbestos mills in the Thetford Mines 1•egion of Quebec's Eastern Townships. A unique asbestos orebody, located in the Ungava Peninsula of Nouveau Quebec, was purchased by Asbestos Corporation Limited in 1964 and commenced production in 1972. As there were no existing facilities in the isolated, arctic region of Asbestos Hill, it was necessary for Asbestos Corporation Limited to construct at Deception Bay a deepsea wharf, a large ungraded fibre shed, a power plant and camp facilities. Forty-two miles of road were needed and were constructed from Deception Bay to Asbestos Hill. At Asbestos Hill, a complete crushing-drying-milling complex, a power plant, pe1•sonnel accommodations and open-pit facilities were provided. Unloading facilities and a fib1•e finishing mill we1l constructed at Nordenham, West Germany. The ""Asbestos Hill- Nordenham Story” is divided into individual papers covering all aspects of the engineering, construction and operation of this unique enterprise. Particular emphasis has been placed on those unusual aspects caused by the isolated location, arctic conditions, short shipping season and the deep permafrost."

Jan 1, 1976

By Donald A. Cranstone

Donald Cranstone holds B.Sc. (Honours) and M.Sc. degrees in Geology from the University of Manitoba and a Ph.D. in Economic Geology from Harvard University. He has worked as a mine geologist, a provincial geological survey geologist and as a senior exploration geologist. He joined what is now the Minerals and Metals Sector of Natural Resources Canada in 1971, where he has been a commodity specialist for gold, for copper and another 28 metals. He is a senior mineral economist, currently engaged in analysis of mineral exploration and discovery success in Canada and of the future of the Canadian mining industry. Abstract This paper examines the history of Canadian non-petroleum mineral production. The outlook over the next 25 years, for mining in Canada and in each province and territory, is reviewed. The outlook for mining in Canada and in most provinces/territories is favourable, but problems seem likely in a few jurisdictions unless new orebodies are brought into production. In terms of exploration potential, Canada consistently ranks among the top three countries in the world. Over the last eight years, Canada has consistently been second only to Australia as a destination for exploration investment. For the first time, Canada is ranked in terms of total mineral production, including coal and construction materials, relative to all the countries of the world including countries of the former communist bloc.

May 1, 2001

By Q. Jia, M. Rigaud, F. Ye, X. Zhong

In this work, the rheological behavior of ultra-low cement alumina-based castables with addition of flake graphite and extruded graphite pellets has been investigated. Emphasis has been laid on the influence of the type and amount of carbon additions and the results are compared with corresponding alumina castable samples without any carbon addition. It is found that alumina-based castables with extruded graphite pellets have good rheological behavior and flowability with lower water demand (< 6.3%), and no segregation during the shearing of castable.

Jan 1, 2004

By Horace Freeman

The sulphur consumed in Canadian pulp mills and acid plants is worth approximately three million dollars annually and amounts to one hundred and fifty thousand long tons, all of which is imported from the United States. Concurrently with a decline in the value of newsprint there has been a gradual increase in the price of this raw material. Most pulp mills in Canada are situated within reasonable distance of domestic pyrite deposits; nevertheless it has not yet been found possible to mine these deposits and utilize the contained sulphur in competition with the imported material. It is the purpose of this paper to elucidate the reasons therefor, and to describe? a commercial-scale experiment undertaken with the object of introducing a native raw material into the Canadian pulp industry on the purely economic basis. Reasons for the Preferred use of Sulphur The known sulphur deposits in the United States are very large, so that at least a twenty-year supply of this material is assured. It is recovered cheaply and in pure condition. Although large deposits of pyrite are known in Canada, nothing has yet been developed to compare in size, cost of mining, or purity with the United States material. It has been necessary to handle and transport more than two tons of pyrite to equal a ton of sulphur.

Jan 1, 1930

By H. R. Huffman

"This paper reviews the history of iron powder production, and outlines the varions production methods. The uses of iron powder and the reasons for its use are also covered. The paper concludes with a look at future trends in powder metallurgy.INTRODUCTION TO POWDERSTHE IRON POWDER INDUSTRY is enjoying a very rapid growth. The annual consumption of iron powder is now at the 100,000-ton level, twenty times higher than it was at the end of World War II, and the yearly in-crease bas been almost consistent at 20 per cent. This is expected to increase, bringing the tonnage to 200,-000, or even (according to some experts) to 270,000, in 1970. In any event, powder metallurgy is expanding at high speed and making an important impact on the production of iron and steel products. Some indication of the faith in the future market may be indicated by the commencement of three new powder production plants in Canada with a total capacity of 136,000 tons annually."

Jan 1, 1969

By Richard P. Taylor, Rod Henham

Abstract - Newly discovered pegmatites distributed throughout the sub-surface environs of the Musselwhite Archean gold deposit occur as narrow dikes that intrude most of the major lithological units. The mineralogy and textures of the pegmatite dikes are characteristic of granitic pegmatites of the "Rare-Element Class"; more specifically, they closely resemble varieties of the "Complex-type" granitic pegmatites that are commonly associated with zones of tantalum mineralization. The essential minerals in the dikes comprise albite, quartz, and K-feldspar, together with lesser amounts of mica (including lepidolite), spessartine, tourmaline, and locally, spodumene. Fine-grained (30 µm to 300 µm), tantalum-bearing minerals occur in the quartzo-feldspathic matrix of the dikes as disseminations, in interstices, and in small vugs. The nature of the tantalum-bearing mineral assemblage present in individual pegmatite dikes varies from a simple mineral assemblage composed of ferrocolumbite (with around 39 wt% Ta2O5) in the most northerly dike, to more complex assemblages comprised of manganotantalite (with up to 75 wt% Ta2O5), ferrotapiolite (with up to 79 wt% Ta2O5), and microlite (with up to 76 wt% Ta2O5) that are present in dikes located several kilometers to the south and southwest. The compositional characteristics and textural relationships of the tantalum-bearing minerals in the dikes provide evidence of igneous fractionation trends that are typical of rare-element granitic pegmatites. Such trends suggest that the newly discovered pegmatites represent part of a more extensive group of cogenetic, tantalum-mineralized dikes.

Jan 1, 2001

By Liu Tao, Wang Wei, Liao Wenjiang, Yang Weiyan, Tang Bin

Side-blown Furnace technology is a developing technology and was developed very quickly in China in recent years, dozens of reference smelters can be found for the treatment of copper concentrate, copper slag, Lead slag, zinc leaching slag and different kinds of slurry. This paper introduces the working principle of the technology, displays the innovations and specifications of China Nerin's SBF technology, gives examples of the typical reference smelters, and looks ahead to future applications. INTRODUCTION Side-blowing furnace smelting process The side-blowing furnace smelting process (SBF process) is one of the bath smelting process with independent intellectual property rights of China Nerin. This process was originally applied to treat copper concentrate and high-lead slag. The SBF process includes two categories, i.e. to treat copper concentrate and to treat industrial solid waste. Up to now, the SBF process has been applied in around 5 million tons of copper concentrate processing capacity and 20+ plants with high-lead slag reduction process. In recent years, SBF process has been gradually used in zinc leaching slag, electroplating sludge, industrial solid waste (e.g., various metallurgical slag), and electronic waste disposal. The basic principle of SBF process is that the material to be treated is directly charged to bath through charging hole with crushed coal and flux, then, enriched oxygen air would be sent to slag level (Vanyukov/Jifeng style furnaces)or matte level (Baiyin style furnaces) via primary tuyere. In this case, the material completes matte/slag metallurgical reaction of gas-liquid-solid interaction under vigorous mixing, and separate matte and slag at the bottom of furnace hearth. With the help of secondary tuyere, the low-pressure air or enriched oxygen would be provided for secondary combustion in the freeboard. The core of SBF process is process parameter control and engineering design of SBF. Presented as a fixed rectangular type, the SBF is a metallurgical furnace consisting of copper water jackets and refractory material. The SBF is consisting of hearth, middle of furnace and furnace top with the sequence from bottom to top. The middle of furnace itself can be further divided into bath area and post-combustion area with primary tuyere and secondary tuyere at both sides. The furnace hearth is made of refractory bricks, which are fused and rebonded Mg-Cr brick, Mg-Cr brick and clay brick from inside to outside. The furnace top adopts a steel water jacket with charging hole and uptake shaft. The water-cooled partition wall is placed at uptake shaft and near charging hole.

Jan 1, 2019

By H. L. Cameron

General Statement In July, 1948, experimental aerial photography o shallow water zones on Northumberland strait was carried out by the Nova Scotia Research Foundation. This work was designed to test the feasibility of aerial photography for coastal surveys o various types, including seaweed and bottom detail surveys. In the course of the work at Lismore, undersea faulting was noted visually and was later clearly apparent in the photographs. In order to prove beyond doubt that the lineations photographed are actually faults, a ground check was made, and terrestrial stereoscopic photographs were obtained of these features where they intersect the shore line. There can be no doubt of their nature, and the type of faulting is probably thrusting due to compressive forces. This is indicated by the successive right- and left-hand displacements on intersecting faults. The age of the fracturing is post Lower-Pennsylvanian (Lismore) and is correlated with similar compression faulting in western Cape Breton. As far as can be ascertained, this is the first time that subsea faulting has been photographed, though it is quite possible that similar structures have been observed elsewhere. Location and Area Lismore is on Northumberland strait, approximately thirty-five miles east of Pictou (see index map, Figure 1). The area mapped from aerial photographs (Figure 2) is a strip approximately two miles long by a quarter of a mile wide. Figure 3 shows a stereo-pair of the aerial photographs used to construct this map. The terrestrial stereoscopic photographs (Figure 4) show one of the faults.

Jan 1, 1949

By Jian-bin Xie, Lin-fang Shen, Zhi-liang Wang

"In order to research temperature field for construction of connecting passage in Metro using artificial freezing method, the finite difference software FLAC3D is employed to numerically simulate construction process of connecting passage. During construction, the overall distribution of temperature field around connecting passage, the relationship between soil temperature and freezing time, the distribution and variation for the thickness of freezing wall are studied from the perspective of numerical analysis. The results show as follows: after 55 days’ freezing, the soil temperature surrounding connecting passage is about -24 oC ~ -28 oC, and the minimum thickness of freezing wall is about 4.0m, which is larger than the design value 3.1m. So construction conditions have satisfied to the excavation of connecting passage and pumping station. During the excavation of connecting passage, soil temperature has almost no obvious change and the thickness of freezing wall remains constant mainly. After 45 days’ normal thawing, the temperature of freezing wall rises 12 oC approximately. And the soil temperature rises faster at the beginning of the normal thawing stage. In the whole process of construction, the frozen area is about 5m outside the edge of connecting passage, and the cooling area is about 10m outside the edge of connecting passage. INTRODUCTIONThe first recorded application of the artificial freezing method is on a mineshaft project in 1862, and it has been widely used in foundation pit engineering, subway tunnels, mine shaft engineering and so on (Wang Zhiliang, 2010; Zhang Juanxia, 2012; Qiu Fan, 2007; Zhou Xiaomin, 1999). This method has many advantages of enhancing soil strength; decreasing permeability and adopting various unstable soils (silt clay, sand, gravel, etc.). It has been applied successfully in metro engineering construction in Beijing, Shanghai and Nanjing. According to incomplete statistics, the construction of connecting passage using artificial freezing method accounted for 98% in Shanghai metro (Qiu Fan, 2007)."

Jan 1, 2015

By E. Heikkinen, J. Suikkanen, T. Siren, J. Valli, M. Hakala

Diametrically faced borehole breakout observations are a fairly good indication of magnitude of the secondary stresses acting perpendicular to the borehole. In cases of low in situ stresses, where borehole breakouts are not observed naturally, it is possible to increase the prevailing stress state around the borehole by increasing the rock temperature. When the temperature is increased sufficiently, thermally induced borehole breakouts will occur. By implementing the temperature increase in boreholes located at excavated tunnels, it is also possible to study the effect of the near-field stresses caused by the excavation. The near-field stress state changes as a function of borehole depth, thus increasing the information available from experiment. To study the feasibility of this proposed low cost method, a Borehole Thermal Spalling (BTS) experiment was executed in ONKALO Underground Rock Characterization Facility, in Western Finland in 2014. The first borehole pilot test with the method was conducted in ONKALO at the POSE niche in already at May 2010, with the second pilot test following in August 2010 at Äspö HRL. The major objective of the experiments was to define the trend of the maximum in situ stress component, while also providing knowledge of the in situ spalling strength of the ONKALO rock mass. The stress state in ONKALO is nearly isotropic in horizontal layer, causing problems for the use of more traditional stress measurement methods. With boreholes heated over long interval, the weakest rock parts are observed to fail, thus providing statistical confidence. For these reasons, continuous test sections have an advantage in ONKALO, compared to spatially limited stress measurement methods such as overcoring and hydraulic fracturing. The BTS experiment is conducted in 9 meter deep vertical boreholes located at the POSE niche, situated -345 m depth below the ground surface. The boreholes used within the BTS experiment are located in migmatitic granite, in an experiment area where the surrounding stress state and the rock strength are fairly well known. The prior knowledge of the stresses is favourable for the experiment, as it requires careful planning and iterations to determine the appropriate heating power domain. Too low heating power will not be sufficient to cause borehole breakout, while too high heating power causes breakout in all directions thus making determination of stress direction hard or impossible. The initial state of the borehole and induced borehole breakouts will be monitored using acoustic televiewer logging (ABI) and optical borehole logging (OBI) imaging techniques. Fracture mechanics modelling is used in planning of the experiment, also in back-analysis to link the observed breakout angle to stress state. Both the pilot test in 2010 and BTS test in 2014 resulted in similar borehole breakout direction. The results are in line with so called EDZ & VT1 stress interpretation, revealed the maximum horizontal component bearing the magnitude of 21.5 MPa, with the trend of 166°.

Jan 1, 2015

By Sean Junor

Cameco Corporation ?One of the world?s largest producers of uranium ?Operations in Saskatchewan, Ontario, the United States and Kazakhstan ?Development projects in Australia ?One of the best employers for Aboriginal Canadians Geographic location ?Remote or northern operations ?Northern Saskatchewan ?Residents of Saskatchewan?s north (RSN) ?Wyoming ?Nebraska

May 1, 2010

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005

By P. Henry

Hydrometal provides an adequate technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy, while keeping the environment cleaner. Two case studies of our integrated hydrometallurgical recycling facility (Hydrométal) in Belgium are discussed.(I) Recycling of Cu-Co cement generated at the second purification step of zinc sulfate solution. (II) Recycling of lead complex materials from the lead industry.

Jan 1, 2008

By C. J. Havard, G. C. Taylor, D. G. Cook, N. C. Ollerenshaw, D. K. Norris

"The area encompassed by this report is the eastern and northern Cordillera, shown on the composite map accompanying these background papers. It extends from the 49th pm•allel to the Arctic Ocean and from the Rocky Mountain and Tintina trenches to the Interior Plains. The Mackenzie delta is included in the discussions because of the implications of the bedrock geology of the Arctic Plateau and Coastal Plain on the hydrocarbon and mineral potential beneath it.The eastern and northern Cordillera forms the back-bone of the Western Canada sedimentary basin and from it most of the principles of orogenesis and epeirogenesis relating to the understanding of the structural, depositional and fossil record of the basin have been derived. It may be divided roughly into two parts, reflecting basic differences not only in structural style but also in mineral potential. The more easterly and younger rocks generally contain hydro-carbons, coal and non-metallic minerals; the more westerly and older rocks contain metallic and industrial minerals."

Jan 1, 1970

By Art Hamilton

The Zn-Pb-Cu-Ag ore deposits of the Boundary and N-5 zones near Bathurst, New Brunswick, occur in a polydeforrned volcano-sedimentary sequence that is part of the Ordovician Tetagouche Group. Massive and disseminated sulfides are hosted by an argillaceous to cherty sedimentary sequence that is stratigraphically Wlderlain by a siliceous fragmental unit and is overlain by a feldspar-rich crystal tuff and related tuffaceous rocks. The deposits have a low iron sulfide content relative to that of most stratabound sulfide deposits of the Bathurst-Newcastle mining district. The ore is commonly associated with chlorite- and talc-rich sediments. The N-5 deposit is considered to be the fault-displaced extension of the Boundary deposit. The Boundary deposit is estimated to contain 891 000 t grading 3.31% Pb, 7.96% Zn, 0.32% Cu and 44 g/t Ag; the estimate for the N-5 zone is 330 000 t grading 3.24% Pb, 7.15% Zn, 0.33% Cu, and 37 g/t Ag. The ore is processed at 1000 tpd at the Heath Steele mill.

Jan 1, 1992

By Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

A thermodynamic description of the equilibrium in liquid and gas phases under specific conditions of refractory gold pressure oxidation was generated using the HKF theory. The gold behavior was considered at 190-225°C in the presence of 1-100 mg/L of chloride ion, and under oxidationreduction potential (ORP) of +700 to +1030 mV. The calculations show that the predominant form of gold(I) occurrence is [AuOH]° compared to [AuCl2]?. High ORP favors the formation of [AuCl4]? as a predominant form of gold(III). It is noted that this complex is responsible for the gold losses buildup during POX. Laboratory test results for double refractory concentrate POX are shown. The combined negative effect of (i) organic carbon of the concentrate and (ii) dissolved chlorides in POX slurry on gold recovery is demonstrated. The effects of carbonate blending to the POX feed concentrate and incomplete oxidation of sulfides on POX performance were studied. The pilot tests results of continuous pressure oxidation are also shown and generally confirm the laboratory results and theoretic dependencies. A comparison of the experimental data with the results of thermodynamic calculations is made. As a result of current research, an effective process for POX treatment of carbonaceous sulfide concentrates in the presence of chlorides was developed.

Jan 1, 2014