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By Martin Langenderfer, Sergii Chertopalov, Catherine Johnson, Vadym Mochalin, William Fahrenholtz

The high temperature and high pressure of an explosive detonation can be used for the production of nanomaterials. The controlled detonation of explosive compositions along with the collection and characterization of reaction products encompasses a process known as detonation synthesis. The primary advantage of the method of detonation synthesis is the possibility for producing monocrystalline nanoparticles with diameters of less than 10 nm. In order to successfully synthesize nanomaterials via the detonation process, it is necessary that the explosive detonation is conducted in a sealed environment. This environment when pulled to a vacuum or purged with inert gas such as argon will reduce the oxidation of detonation reaction products. Detonation synthesis testing is currently being conducted in a 1.8 cubic meters (m3) (64.3 cubic feet (ft3)) ellipsoidal pressure vessel consisting of two interlocking half shells. The testing involves the controlled detonation of cast mixtures of Cyclotrimethylene-trinitramine (RDX) and 2,4,6-Trinitrotoluene (TNT) in conjunction with siliceous compounds to produce nanocrystalline diamond and silicon carbide. Alternative detonation environments including the presence of a cooling medium such as water or dry ice to absorb residual, post detonation, thermal energy and enhance the stability of the materials being produced have improved yield. Modifications to the explosive charge composition have an effect on the type and quantity of materials that can be produced. Doping of explosive charges with various organic and inorganic compounds has shown promise in the synthesis of materials that are difficult or uneconomical to produce through other methods. This paper outlines the process development of detonation synthesis facilities. Preparation of the pressure vessel to create a suitable detonation environment for the production of nanomaterials is examined. Formulation of explosive charge compositions and considerations involving test charge initiation are discussed in detail. Experimental results and analysis from initial testing as well as plans for future research are also evaluated.

Jan 1, 2018

By Michael S. Wieland

This report discusses measurement techniques utilized in and trend results obtained from research on delay blasting malfunctions in underground coal shots at the U.S. Bureau of Mines. Charge malfunctions occur during delay blasting in underground or surface mines, rendering the explosive operations more hazardous and less productive. Modern instrumentation techniques reveal several types of reduced charge performance, resulting from cross-hole interactions. Two receptor (wave-target) charge malfunctions were detected in fourteen shots that were undeniable. There were other receptor charges that exhibited under-performance by registering out-of-tolerance or noticeably reduced detonation rates. Delay blasting generates tremendous shock waves and rifting forces that fracture and heave the surrounding stratum and unfortunately damage remaining unfired charges. This report contains two graphs, representing roughly 1% of total records, that show donor (wave-source) charge shock waves and rift (reaction-to-heave) compressions. These debilitating wave impacts precipitate modes of reduced charge performance ranging from weak detonations or misfires to sympathetic detonations. As recognized from previous research, impaired charges react poorly, perform less useful work, and yield fumes with atypical higher toxicity.

Jan 1, 1995

By Francisco Sena Leite, Raquel Sobral, Vinicius Gouveia de Miranda, Céu Jesus

"This document investigates a newly developed technique with the objective of improving terrain triangulation models (horizontal/sub-horizontal and vertical/sub-vertical terrains), mainly blast free faces. The algorithm uses multi-linear regressions to generate the best point cloud projection plane by applying the residues modulus minimization so as to create the finest 3D triangulation model. A change of base is required to create a new set of coordinate axis and generate completely new projection planes. The projection plane residue analysis is inferred in order to avoid or reduce the outlier points. The dataset is composed of 12 terrain models obtained from photogrammetry and a 3D Laser equipment thatgenerates georeferenced cloud points. This new technique is validated by the analysis of the obtainedcritical burden by the improvement of the general aspect view of the terrains and the capacity of outlier’s detection. The result and the quality of the algorithm demonstrates the improvement in the triangulation mesh, reducing errors in the calculation of over/under burden, free face volumes, cavities and, therefore, in the estimations of clearance/safety distances."

Jan 1, 2017

By D Larson, M Finger

Chemical explosives may become a key element in many of the in situ energy and mineral recovery methods under development. This paper discusses the potential role of explosives in deep rock mining for resource recovery. Several energy and mineral recovery programs described are an outgrowth of the Plowshare Program and Explosives R&D conducted as part of the AEC/ERDA mission at Lawrence Livermore Laboratory. Several important aspects of the use of explosives in deep rock mining are reviewed. First, the status of knowledge of deep rock fracturing to create permeability underground is discussed. Completely contained blasting has not been a widely applied tool used in the mining industry. We conclude that data available on deep rock fracture is minimal and that the mechanisms that control the processes must be understood before technical and economic feasibility can be established. We also discuss the unusual problems in the selection of an explosive or blasting agent for deep rock applications including emphasis on the functioning at depth and safety aspects. Finally, a brief review of similar activities within the U.S. is given.

Jan 1, 1976

By Sergio Segovia Parra, Victor Hernan Sheen Uriol

This contribution of the concept of mass blasting both closing and production allows breaking paradigms, to limit the number of tons to thunder. The areas of geotechnical different mining large mining companies worldwide and especially from the National Copper Corporation (CODELCO, Chile) has been declining volumes closing blasting and production, with the misconception to protect the end walls of the pit, before any geotechnical risks caused by various types of faults; especially the circular faults. A blasting of small tonnage can do more damage to a wall when it is not properly sequenced, leading to the coupling of the wave train and therefore the exponential damage in/s (peak particle velocity, PPV) on the wall of the Tagus. Blasting closing mass production and contribute technically and operationally in the dynamics of the following operations: loading, hauling, crushing, processing and preparation of the final product; eliminating delays to return to thunder small volumes where one must stop all mine equipment, incurring high costs and especially losing valuable time in the continuity of the following unit activities.

Jan 1, 2015

By Daniel Haines, Benjamin Konshak, Michelle Crull

American Technologies Incorporated Group (ATI) is the prime contractor with U.S. Army Corps of Engineers, Huntsville Center (CEHNC) in the Honolulu District for the removal of munitions and explosives of concern (MEC) at the Former Waikoloa Maneuver Area. The site is approximately 123,000 acres on the Big Island of Hawaii, which was used as an artillery firing range with live ammunition and other explosives deployed. ATI utilizes state of the art metal detection equipment to find and excavate metallic anomalies that have hazard potential. Both the investigation and disposal procedures present challenges due to residential communities and archeological sites that are located in and around the site. In order to excavate metallic anomalies safely and without adverse impact, ATI utilizes CEHNC-designed, open front barricades constructed of sandwiched sheets of aluminum with a support structure. When munitions or explosives are located, ATI is responsible for safe disposal using shape charge perforators to detonate the item where found. Sandbags are used for mitigating the effects of all detonations.

Jan 1, 2008

By Scott G. Giltner, Paul N. Worsey

During the short duration of an explosive blast, many events occur which are too quick to be detected or observed in detail with the naked eye or by normal photographic techniques. Through the use of "hightech", high speed video, many of these events can be observed, instantly played back and recorded for later use. The use of a Spin Physics SP 2000 Motion Analysis System at a blast casting operation is presented. The variable range of recording speeds offered by the SP 2000 allowed it to be used for examination of different areas of blasts. At its maximum full frame rate of 2000 frames per second the SP 2000 can easily pick up the flame front as it travels down a nonel tube and the flash from the surface delays as they fire. The system was used for a variety of tasks including, but not limited to,the determination of delay accuracy to within 0.5 ms, the velocity and trajectory of the faces during blasts, and pinpointing geological problem areas. The effectiveness of the system as used on site is discussed along with detailed method of set up, recording, playback and data processing. Other details including site specific environmental and lighting problems are also covered.

Jan 1, 1986

By David Siskind, Mark Stagg

Vibrations from Dade County (Miami area) quarry blasting and structure responses were measured at 11 locations between February and April, 2000, and 10 homes were inspected to analyze the characteristics of their cracking and other damages. These results were combined with information collected by the County and other studies done in south Florida for a blasting impact assessment specific to this area. In addition over 40 quarry blasts in the nine-week monitoring period, about 800 measurements were available from previous monitoring in Dade and neighboring Broward counties. An overall worst-case analyses based on the highest individual amplitudes suggested that vibrations in some areas could have been as high as 0.35 in/s. While amplitudes in the study period were below this value, they were found to be relatively high for the distances and charge sizes. Attenuation with distance is less in Dade County than found elsewhere with quarries having to use scaled distances several times higher than similar sites in the north. Consequently, the vibrations are perceptible at very large distances.

Jan 1, 2001

By Claude Cunningham

AEL’s Electronic Delay Detonators are in routine use and growing in both volume and breadth of application in Africa. This trend will continue and grow internationally owing to increasing pressure on rockbreaking operations to conform to sustainable development principles. A fundamental breakthrough has been achieved, bringing production blasting into line with technologies, which leverage performance through tight monitoring and control. When moving from pyrotechnic systems, benefits are normally realized without having to adopt different timing patterns, but significant additional benefits are realisable by using the flexibility and precision of the electronic units to enter windows of timing previously closed. The higher price and increased care needed are a worthwhile investment, enabling operations to cross the chasm to stronger revenues, but the system must be robust and suited to the application and personnel. Economic models are vital for keeping track of the potential and achieved benefits of these systems. Some resistance can be expected from those who stand to lose income as a result of the improved efficiencies.

Jan 1, 2004

By Norman Paley, Zachary Pickett

The Red Dog Mine is a high-grade zinc-lead mine located in northwest Alaska which began operations in November 1989. In June 2014 the upper half of a charge in a trim shot in the Aqqaluk pit deflagrated. No other holes in the area were observed to react and the remainder of the pattern was shot without incident. This was the only known case of a deflagration in the 25 years of operations. As part of the investigation into the cause of this incident rock samples were obtained from the area of this hole and from other areas in this pit. The samples were assayed and tested for reactivity using the Reactive Ground Catalyzed Adiabatic test. Approximately half of the samples were found to be reactive with standard blasting agents. Unexpectedly, some of these were found to be reactive with blasting agents doped with urea to act as an inhibiter. Relationships between element grades and reactivity and between Specific Heating Capacity and reactivity were developed; however, the small sample size led to these models having an unrealistically large number of geological model blocks tagged as reactive. A program to better understand the behavior by testing more samples was initiated. Drill core was selected based on the predicted level of reactivity using the aforementioned relationships. The samples covered a greater range of grades and lithologies and included rock from the soon to be developed Qanaiyaq pit. The samples were dry pulverized then split for elemental assay, Reactive Ground Catalyzed Adiabatic testing, Specific Heating Capacity (SHC) determination, and X-ray Diffraction (XRD) mineralogical analysis. From this data, a Red Dog Mine specific assay based classification for separating reactive from non-reactive ground was developed. Furthermore, it was possible to divide the reactive ground into two subgroups: i) rock which reacts with ANFO-emulsion blends even when manufactured specifically with a reactivity suppression agent like urea and ii) rock which reacts with ordinary ANFO-emulsion blends only when a reactivity suppression agent like urea is absent.

By David Leidel, James Stuart

The 50 ohm resistorized electric detonator is commonly used in the oilfield for initiation of wireline conveyed perforating guns and other downhole explosive tools. This type of electric detonator provides some degree of safety above that of the conventional one ohm electric detonator, since a higher current level is required to initiate the device. In order to obtain the necessary data to develop safe distance tables from RF sources for the 50 ohm electric detonator, laboratory tests were conducted to determine the detonator’s “no-fire” current, AC impedance, and its susceptibility to ESD. The results were surprising as two types of failure modes were observed. The “no-fire’ current levels determined from Langlie “One-Shot” Test Methods were determined for the devices tested providing values for the 0.999 probability “no-fire” power level at a 95% confidence level. This data will serve as the basis for sets of safe distance tables from RF sources that will appear in the forthcoming edition of the Institute of Makers of Explosives Safety Library Publication 20, “Safety Guide for the Prevention of Radio Frequency Radiation Hazards in the Use of Commercial Electric Detonators, (Blasting Caps)”.

Jan 1, 2010

According to the Directive 93/15/EEC, given on 5th of April 1993, all the commercial explosives placed on the market and transfered in European Union and EFTA countries have to be certified and contain the CE-marking. Before the products can be awarded by the CE-marking they have to fulfil the Essential Safety Requirements (ESR) of Appendix 1 of the Directive. From the beginning of last year the commercial explosives could not have been be sold in Europian Union countries without the CE-marking. The legitimacy of the Directive 93/15/EEC encompasses High Explosives, Detonating Cords, Safety Fuses, Gun Propellants and Detonators. At the moment in Europe, there are seven Notified Bodies (NB) working in the field of commercial explosives. They are in Spain (LOM), Germany (BAM), France (INERES), England (HSL), Netherlands (TNO-PML), Sweden (SP) and in Finland (PvTT). The Swedish SP has qualifications only for the detonators and the Finnish PvTT for High explosives, Detonating cords, Safety Fuses and Gun Propellants, but not for the detonators. The role of the NB is to work as a third independent body between the client and the manufacturer testing, studying and certifying explosives by the commission of the manufacturer. The Notified Bodies are operating independently competing the clients, the explosives manufactures.

Jan 1, 2004

By Qi Jinduo, Gong Min

On the basis of actual parameter of wall control blast in Nanfeng mine, China, the process of dynamic stress changing between two column charges was studied recently for a presplit-cushion blast by holographic photoelasticity. In the experimental model, two holes were simultaneously detonated from both ends (four ignition points). The bottom of the holes were loaded more than other parts (heavy charge). Under these conditions, four consecutive isochromatic fringe patterns at different times were acquired in one loading run, and the characteristics of the stress distributions were compared at different places and times in the holes. It was found that interaction types of stress waves vary along the holes. The theory is posed that the stress wave which is formed by the interaction of earlier producing P wave and later S wave along a distributed line charge is the most important part in all stress waves. Research indicates that a heavy charge in the bottom of the holes is crucial to producing a presplit-cushion effect at the bottom. "End Effect" doesn't affect the magnitude of stress along linking lines between the bottoms. The chief fields of the "End Effect" are also explained in the paper.

Jan 1, 1998

By Thomas M. Keevin, Gregory L. Hempen

A study was conducted to measure underwater pressures associated with confined borehole shooting used to remove rock for The Kill Van Kull Deepening Project, U.S. Army Corps of Engineers, New York District. A major natural-resource-agency concern was the potential for fish mortality during explosive rock removal. Currently, fish mortality models are based on testing programs that exposed captured organisms to open-water blasts. Natural resource agencies, without in-house explosive engineering expertise, generally are not familiar with the physical properties of blasting underwater. Confined shots are most often used for demolition and rock removal underwater. Pressure amplitudes from confined blasts are significantly reduced as compared to open-water blasts that, are commonly used for fish testing The duties of natural resource agencies are made even more difficult by the lack of published data on pressures associated with confined blasting. As a result, explosive weights for confined shots mistakenly have been used to run mortality models that were developed using open-water blast pressure data. This study was conducted to collect pressure measurements during rock removal for the KVK deepening project and compare those data with computed peak pressures for open-water explosions.

Jan 1, 2005

By D. Fry, S. Hunsaker

Ammonium nitrate in explosives and sulfides in reactive ground have the potential to react at ambient and elevated temperatures resulting in premature detonations. The Australasian Explosives Industry Safety Group (AEISG) published, in 2006, a Code of Practice1 for elevated temperature and reactive ground. This paper reviews the chemistry, general reactivity of various ground types, elevated temperature hazards, and testing protocols contained in the code, that are industry best practices for managing ammonium nitrate-based explosives in elevated temperature and reactive ground conditions. In addition to reviewing the 5th edition AEISG Code of Practice, data is presented validating the recommended sampling guidelines within the code. Dyno Nobel has been screening reactive ground samples and performing sleep time testing since the code of practice was first released. Test results demonstrate the effects of samples that are allowed to oxidize before testing and are shown to be subsequently less reactive and not representative of the actual hazards facing mining blasting operations. Results also show that for a given reactive ground sample, reaction times decrease with increasing temperature. Data also quantify the delay in reaction time given by inhibited products. These results emphasize the importance of proper sampling and preparation of samples to accurately characterize elevated temperature and reactive ground hazards. They also demonstrate the efficacy of inhibited products in managing these hazards

Jan 1, 2024

By Jim Hall, Denis Rickman, Jon Windham, John Ehrgott, Stephen Akers, Byron Armstrong

With the growing concerns about terrorism world-wide, numerous agencies conduct experiments to investigate the effects of terrorist vehicle bombs. In many cases, the vehicle bomb of interest utilizes some form of ammonium nitrate/fuel oil (ANFO) as the explosive source. Due to the high cost of fullscale testing, it is advantageous to conduct at least some vehicle bomb experiments at reduced scale. Extensive testing has shown that ANFO is a non-ideal explosive, and its explosive output does not scale reliably at explosive masses below approximately 400 lb (182 kg). Most scale-model testing requires explosive masses 1 to 5 orders of magnitude smaller. Thus, scale-model testing is typically conducted with “ideal” explosives, such as composition C-4, which perform in a scalable manner at virtually any charge mass. The utilization of an ideal explosive to model ANFO requires the existence of an accurate means of equating the performance of the two explosives. The airblast equivalence of C-4 and ANFO has been well established. However, the cratering equivalence of these explosives is not thoroughly quantified. This is especially true for the case of an above-ground detonation, which is precisely the scenario of interest in vehicle bomb studies. A study has been conducted to better define the cratering equivalence of C-4 and ANFO for above-ground detonations. This paper presents a discussion of results from this research.

Jan 1, 2008

By Brian Lewis, Reinhold Daykin Schnell

Blasting specifications and guidelines are very important aspects of detailed project specifications covering any scope of work (SOW) that involves explosives and blasting procedures. A lot of larger construction or tunneling projects require some degree of project specifications for the entire scope of work on such project, including blasting specifications. It is important that all blasting specifications effectively and accurately address all explosives and blasting concerns associated with the SOW for such project. This includes safety and security, required personnel and their associated responsibilities, procedures and applications involving explosives, blast design and planning, blast monitoring and reporting, quality assurance and quality control, and local, state, and federal regulations and limitations. With the of wide range of information required in blasting and overall project specifications along with the risks associated with work involving explosives, it is also important to ensure qualified personnel are involved in interpreting or compiling and approving any blasting specifications and guidelines. The purpose of the following paper is to explore and present the basic information, as summarized above, that should be included and considered in the creation of detailed blasting specifications and guidelines. Detailed information is presented in specific relation to a potential bid package that would be compiled for a construction or tunneling project requiring protective or high-profile blasting.

Feb 6, 2023

By Hans-Peter Rossmanith

Fracture mechanics (Atkinson 1987, Broek 1988, Rossmanith 1978-2002, 1983, 1997, Kanninen & Popelar 1985) and wave propagation (Graf 1975, Rinehart 1975) form the main ingredients in the new electronic detonator based blasting technology. The full potential of using short delay initiation timing in bench and underground blasting can only be exploited if the underlying physical processes are properly understood. From a structural geology point of view, in many open pit mine operations, blasting is performed in incompetent and/or loose rock. Under such conditions the stress waves produced by blasting very quickly dissipate in the rock mass and often their energy cannot effectively be put to work. This contribution shows the effect of open and closed joints – and to some degree also faulting – on the blast wave field and shows the influence of structural geology on the blasting result. A simple engineering method which combines wave propagation and impact mechanics is developed in order to assist the non-scientifically trained blaster in understanding blasting in blocky rock formations. Extensive use will be made of the so-called Lagrange diagram which was introduced in detail in the author’s previous lecture at ISEE 2003 (Rossmanith 2003). This presentation can be considered a continuation of the 2003 presentation.

Jan 1, 2004

By Tristan Worsey, Nathan Rouse, Daykin Schnell

The authors were retained by a proposed underground metals mine operation to evaluate the potential blast vibration amplitudes that could be generated at surface structures above the proposed mine. Literature reviews of published blasting documentation gave little information, data, or models on surface blast vibrations produced by underground mines. At the client’s request, the authors contacted a number of underground mining operations to evaluate interest in sharing blast vibration data with the authors so that the authors could develop an underground-to-surface blast vibration regression equation. The authors worked with three underground metals mining operations to collect surface blast vibration data produced by heading blasts and stope blasts. The data included blast vibration amplitude values, seismograph records, blast design geometry, charge weights, and detonator delay and sequence designs. The total amount of information was used to produce a regression equation and summary dataset that could be used by the proposed underground mining operation to evaluate blast vibration amplitudes that will be generated on the surface. This work is published and presented so that operations with proposed underground mines or proposed underground mine extensions can use these equations to predict vibration amplitudes on the surface above the mine workings before any blasting occurs.

By Ashlin Pillay, Osamu Iwata

Hong Kong is ranked as the world’s third most important international financial hub and attracts significant growth and development annually. The city is also known as the world's most vertical city, the most common view from your window in Hong Kong city centre is probably the window of another 30 storey skyscraper. The increasing demand for real estate in this bustling Metropolis has placed immense pressures on its transportation infrastructure because whilst the construction continuously grows upward with larger and larger skyscrapers, it leaves the transportation planners with very little choice but to go underground. As a first world city, interrupting daily business operations is simply not an option; however, of even greater concern is the safety of these 8 million residents. Blasting Regulations are under the strict control of the Mines Division showing zero tolerance to the breaching of safety standards. The Ho Man Tin Station (HOM) excavation, a part of the Kwun Tong Line Extension (KTE) project situated in Hong Kong began in June 2012 and is one such project that is under strict regulations from the Mines Division. The HOM project is a cross cut interchange station between the Kwun Tong Line Extension (KTE) and Shatin Central Link (SCL).

Jan 1, 2015