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By D. Bienstock

In connection with air-pollution studies, the Bureau of Mines is cooperating with the U.S. Public Health Service in investigating the use of solids for removing sulfur dioxide in concentrations of less than 0.5 percent from combustion and waste gases. Removal of sulfur dioxide at flue-gas tempera¬tures would no longer result in the cooling of scrubbed gas, which is inherent to liquid scrubbing processes used exclusively in industry today. Results are reported of extensive investigation, using metallic oxides as absorbents, adsorbents, and oxidation catalysts at 130° and 330° C. (temperatures at which flue gas may be treated in powerplant practice). The most active absorbents tested were the oxides of manganese, cobalt, copper, and alkalized alumina; 23 to 33 grams of sulfur dioxidn were removed by 100 grams of absorbent at 130° C., while scrubbing more than 90 percent of the sulfur dioxide from a simulated flue gas, and 19 to 61 grams of sulfur dioxide were removed at 330° C. A more detailed study is reported on absorption and regeneration, using manganese oxides and alkalized alumina. Adsorption of sulfur dioxide on activated carbons and molecular sieves at elevated temperatures is considerably less efficient than removal by absorption--a maximum of 7 to 8 grams of sulfur dioxide could be removed with 100 grams of adsorbent at 130° C. A potash-promoted vanadium pentoxide is effective in converting sulfur dioxide to trioxide; complete conversion in a simulated flue gas containing 0.35 percent sulfur dioxide was obtained at 365° C. Pilot-plant and cost studies are being made by the Bureau to determine the economic feasibility of removing on an industrial scale the sulfur dioxide present in gases in low concentrations.

Jan 1, 1961

By Lloyd H. Banning

Crucible-smelting tests at the Northwest. Electrodevelopment Laboratory and a pilot-plant test on electric smelting of western phosphate rock for the Westvaco Chlorine Products by the Tennessee Valley Authority indicated that the small vanadium content of the rock is concentrated in the ferrophosphorus by-product of Phosphorus smelting. This research is concerned' mainly with recovering vanadium and phosphorus froth the ferrophosphorus produced from western phosphate rock. Exploratory tests were made of several methods of treating vanadiferous ferrophosphorus. Attempts to separate vanadium as a carbide dross by saturating molten ferrophosphorus with carbon were unsuccessful. Volatilization of phosphorus from ferrophosphorus was accomplished to some extent, both with and without addition of sulfur in several forms, but elimination of phosphorus was not complete. Brief testing in a small experimental converter on oxidation of vanadium and phosphorus; into a slag by blowing with air showed promise. A method that comprised fusing vanadiferous ferrophosphorus mixed with soda ash under oxidizing conditions gave encouraging results and was tested beyond the preliminary stage. A slag product of the fusion contained most of the phosphorus and vanadium as water-soluble sodium phosphate and. virtually water-insoluble sodium vanadate. After leaching the sodium phosphate froth the slag, the leach residue was reroasted with soda ash and salt. This roasted product was leached again with water to extract the vanadium.

Jan 1, 1951

By C. V. Davis

In the lnvestlg::ìt1on of mAthods for aSS8.7ing platin",. conducted by the Bureau ot MinAs, reoent experiments have d~velopad tha~ with ce..tain orei, especially when thr, quantity Of platinum 1s eonlidarablfl, nit'!le acid w111 not etfßct a iepard-Han of platinum and pa11adium. 'lhe following m;lthod has been found to be accurate and to reiu1 t in a complete S''lun''ation of' th~3:l metals. It is therefo 1" '!eeommei:ed that 1 t ba followed rath::r- than the method of separation with nitrio acid, givèn in Technical Pape'! 270.* At line 22, pagi 14, of that paper, bAglnnlng with ~tarm th,~ metals '.'ith dilute¡ nitrio acid," strikE out the rest of the paragraph, and substttutt~ the pro_t cedure g1 ven below. ?lunder and Thuringer.. have developed mnt¡iods for th"i sflparation of palladium from all the platinum metals exoept platinum bj m ,ans of dlmethy- 19lyoxlme. They state that the~ is no action for several hours if an excess of dimeth¡lglyoxime is added to an aqueous solution of ohloroplatinic acid in the cold, alio that only on boiling is the platinum pTecipi ated ¡~d than only PST't of the platinum i srenoved from the sUut1on. They found that palladium 1s p~ecipi tated quati tat! vely in the oold as (CaH 4N40 Pd) which is insoluble tn water, dilute hydroohlorio acid, dilute acetIc aofd or in 50~ ethyl alcbhol. All of their pT'90ipi tations we~p Carl". ied out ~hile the solutions were being heated. This caused a pal"tia~recipltation of the platinum along wi th the

May 1, 1922

By Rolland L. Blake

Petrographic and mineralogical studies were made on unoxidized samples from the Cuyuna and Mesabi districts to study occurrence and properties of the iron phyllosilicate minerals . Examination of 96 thin sections from the thinbedded facies of the main iron - formation of the Cuyuna district indicates that the most abundant minerals are Mn - Mg - siderite , stilpnome lane , and minnesotaite . Reconstitution and recrystallization of minerals has occurred along certain beds , and textures indicate that some minnesotaite apparently formed at expense of stilpnomelane . Three samples of stilpnome lane and one of minnesotaite were concentrated from fracture - fillings within iron- formation . Results of chemical , optical , spectrographic , X- ray diffraction , and differential thermal analyses on these samples are reported . The detection of ammonia in stilpnome lane samples is the first such occurrence reported , and its significance is discussed . New mineral data are presented on greenalite and probable septechamosite from the Mesabi district .

Jan 1, 1964

By Sidney Katell

The present report, a continuation of the series of Bibliography of Investment and Operating Costs for Chemical and Petroleum Plants, is concerned with articles published from January 1958 through December 1958. The periods covered in previous reports are as follows: January 1930 - August 1948 I. C. 7516 September 1948 - June 1952 I. C. 7705 July 1952 - June 1954 1. C. 7751 July 1954 - December 1956 I. C. 7847 January 1957 - December 1957 I. C. The following sources were used to obtain the references to and the abstracts of the published articles included in this report: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Reports of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Coal Age. 6. Coal Utilization. 7. Cost Engineering. 8. Industrial and Engineering Chemistry. 9. Nucleonics. 10. Oil and Gas Journal. 11. Petroleum Engineering. 12. Petroleum Refiner. 13. World Oil.

Jan 1, 1959

By R. H. Nafziger

Owing to the growth of alloy steel production and its influence on tramp element levels when recycled, foundries have expressed concern regarding the quality of scrap used to prepare iron castings. Reliable and current information was unavailable on the amount of tramp elements contained in iron castings over time. Accordingly, the U.S. Bureau of Mines, in cooperation with the American Foundrymen's Society (AFS), analyzed cast iron samples from participating foundries throughout the United States on a quarterly basis to ascertain possible trends. Each sample was analyzed for 28 elements to determine if changes had occurred as a function of several input variables. This bulletin describes the research and presents analytical results and evaluations over a 5-3/4-year period from January 1981 to September 1986. Results show that iron casting compositions are changing with respect to a few tramp elements such as arsenic, cobalt, chromium, tin, and zinc over the period. Changes in charge compositions probably are responsible. Significant variations between zones also were observed with aluminum, arsenic, cobalt, chromium, copper, and manganese.

Jan 1, 1990

By Oliver C. Ralston, Dorsey A. Lyon

Volatilization in retorts has been, until recently, the only commercial process of producing spelter, hence the zinc mine operators have had to meet the terms of the zinc smelters in regard to the following requirements: (1) Minimum percentage of zinc the ore must contain; (2) the chemical combination of the zinc in the ore; (3) the proportion present of those elements that interfere with the suceessful recovery of the zinc when the ore is retorted. In consequence of these requirements, only a comparatively small proportion of the zinc ores mined can be shipped directly to the smelters.

Jan 1, 1919

By Will H. Coghill, F. D. DeVaney

"Many of the iron ore deposits on the western end of the Mesabi Range Minnesota consist of the so-called ''wash ores."" Because of their high silica content these ores must be washed or concentrated to make them merchantable. Washing plants have been in operation for 20 years, during this period large quantities of tailings have accumulated in tailings ponds. These tailings contain the aggregate millions of tons of iron oxides which, if recovered, would greatly to the available tonnages and to the revenues of the mining companies. It the purpose of this paper to outline give results of concentration tests on tailings.In order that the reader may understand more clearly the type of material under consideration, a short description of the characteristics of the wash ores of the Western Mesabi Range and a brief resume a washing methods that have been are now being employed will be given. Appleby and Newton4 In their description of the district and of the ores say:The Western Mesabi district embraces the territory west of the town of Nashwauk in Itasca County. The territory to the east of this dividing line is known as the Central and Eastern Mesabi district. This subdivision is rot wholly arbitrary. While the ore bodies in the two districts resemble each other in. shape, size, and general structure, there is a marked and very important difference in the character of the respective ores. For purposes of comparison, the western deposits have been called washable ore bodies, and the central and eastern, standard ore bodies. The latter ores are the result of natural concentration processes which have teen carried far enough to produce a large proportion of high-grade ore Wet can be marketed direct; the Western Mesabi ores present a lesser degree of natural concentration and are as a rule of too low grade to admit of marketing without preliminary treatment. In many cases the grade can be improved by washing, hence the material is called washable ore. Exceptions to thin general rule may be noted in both districts. Many of the Western Mesabi ore bodies contain quite a proportion of merchantable ore. There are also portions of central and eastern Mesabi ore deposits which are of low grade and which can be improved by washing."

Nov 1, 1930

By R. T. MacMillan

Many bench-scale tests and studies have been conducted in developing and testing a chloride-volatilization procedure Ear treating low-grade manganese ore from the Maple Mountain-Hovey Mountain deposit of Aroostook County, Maine. The ore, averaging 10 to 12 percent Mn, contains manganese in several forms and is resistant to concentration or extraction by usual physical and chemical procedures. Over 90 percent of the manganese, content of the ore has been recovered using a chloridizing roast in which the ore was heated at 950°-9b0' C. in a circulating stream of hydrochloric acid gas. Chlorides of manganese and iron were volatilized and swept to a fume collector, where they were condensed and separated from the [as] stream. Operation of a small, 1-pound-per-hour shaft Furnace produced enough chlorides for studying other factors in an integrated process such as: (1) Conversion of the chlorides to oxides; (2) recovery of HC1 gas of suitable concentration Ear recycling to the chloridizer; and (3) control of the Mn-Fe ratio in the oxide product to produce a suitable feed for ferromanganese production.

Jan 1, 1956

By J. W. Paul

A study of mining methods and underground practices as they influence injury from falls of roof or coal reveals data as to the location in the mine where such injuries occur with the greatest frequency and as to some of the methods and practices which are in use for the prevention of injury. This paper, which presents statistics bearing on the frequency and place of occurrence of accidents and discusses regulations and practices which have resulted in a low-frequency rates from falls of roof and coal in a few representative mines, takes its information from mine-accident reports and from the results of studies conducted in a group of 80 mines in the bituminous coal fields of Western Pennsylvania, Ohio, and West Virginia. The statistics from this group of mines cover periods of one to four years but average 2 years and 7 months. During this time these mines produced over 110,400,000 tons of coal, equivalent to one-fifth of the annual production of all bituminous mines in the United States. The coal beds of the mines in the group studied are mostly flat, with local pitches of moderate degree. A number of mining plans are in use, each of which follows a general system of multiple entries, gross entries, and rooms. Room and pillar in panels either advancing, retreating, or half advance and half retreat, and the block system are employed. The methods of pillar extraction are by splitting, slabbing, pocket-and-stump, and open end. It is hoped that in presenting some of the details of the methods and practices at particular mines of this group which have commendable records in the prevention of injury some goad may accrue to many other bituminous mines which have similar natural conditions.

Jan 1, 1933

By R. L. Marek

"The number of persons fatally injured in the petroleum industry in California in 1930 was 50, a decrease of 20.6 per cent from 1929, when 63 men accidentally lost their lives. The decrease in the number of fatalities for 1930 has caused the first downward trend in the fatality curve of the California petroleum industry since 1927 and is coincident with a period of little active development in new fields, the shutting in of many wells, and reduced activity in the older fields of the State. That a direct relationship exists between the number of accidental deaths and the rapidity of new field development is particularly emphasized by the fact that in 1929, a year of intensive field development in California, 48 men were killed in the drilling and producing division, whereas in 1930, a year of less development work, only 25 men were killed in this division,The figures for the average number of drilling and producing wells in 1930 decreased appreciably from comparable figures for 1929 and a greater percentage of producing wells were shut—in in 1930 than in 1929."

Dec 1, 1931

By Carl W. Kelley

PRODUCTION in the United States of carbon black has increased from 20 million pounds per year in 1920 to over 2 billion pounds in 1964 valued at $156 million, mostly for consumption by the rubber-tire industry, which uses over 90 percent of total production. Production of over 2 billion pounds in 1964 is a 7.8-percent increase over 1963 and is the first time furnace black production has topped 2 billion pounds. Although 1964 channel black production dropped 6 percent below 1963, carbon black produced by the furnace process, which ac-counted for 92 percent of total production, increased 9 percent to 2,053 million pounds. Total shipments during 1964 amounted to 2,245 mil-lion pounds, a 7 percent increase. This growth parallels the expansion of the automotive and petroleum industries. Along with this expansion have been many advances, both in methods of manufacture and in the quality and variety of blacks available to industry. There are several kinds of carbon black, thermal, channel, furnace, lamp, and oil blacks. Until recently, channel has been the important black in rubber compounding. Following the introduction of the synthetic GR-S, and more recently of "cold rubber," it has been found that certain furnace blacks with particle size larger than that of the standard channel black give superior reinforcement. A great advantage of furnace black is that its yield per unit of gas feedstock is higher than that of channel black. The 184-million-pound increase in domestic carbon black sales was partially offset by a 37-million-pound decrease in exports. Decrease in exports especially to Europe, is expected to continue. In Europe, as in the United States, the major end use for carbon black is in the manufacture of automobile and truck tires. Although the number of automobiles in Europe is predicted to grow by about 7.5 percent per year, compounded until 1975, the increased demand will be met by a 20 percent increase in existing capacity and by the new plants being built in Europe by U.S. companies. Also) aromatic oils for producing furnace blacks are plentiful now that western Europe's chemical industry is switching to a petroleum base.

Jan 1, 1965

By Howard B. Hamilton

A switching system for high fault current 300 and 600 volt DC trolley and haulage systems, as used in the mining industry is presented. The system consists of paralleled main and auxiliary contactor circuits with a liquid metal current limiting device (CLD) in series with the auxiliary contact-or. Upon detection of a fault, the current is commutated into the CLD circuit. The liquid-metal vaporizes, increasing the CLD resistance and Considerably decreasing the actual current to be interrupted. This system will materially reduce the wear and tear on contactors because of the reduced interrupting requirement. the CLD is pressurized; when the current is interrupted, liquid metal flows back into the bore. Thus, it is resetting. Electrical and mechanical design principles are presented as well as materials for use, as found satisfactory in field tests on the device.

Jan 1, 1982

By F. P. Haver

The Bureau of Mines has investigated the electrochemical reduction of lead chloride as a method for producing lead without the pollution problems associated with smelting. It was determined that high-purity metal (>99.9 pct Pb) could be obtained, using PbC12 prepared by ferric chloride leaching of galena concentrate: PbS + 2FeCl3?PbCl2 + 2FeC12 + S°. Optimum results in small-scale electrolytic tests were achieved with a bath consisting of 40 to 70 wt-pct PbCl2 dissolved in KC1-LiCl eutectic, an operating temperature of 450° C, a current density of 2.5 amp/in2, and an electrode spacing of 0.5 inch. In large-scale tests made to develop a cell design for commercial application, the optimum electrode arrangement proved to be a bipolar configuration with horizontal plates. This gave a current efficiency of 86 pct with an energy requirement of 0.52 kwhr/lb lead. To determine the effect of impurity buildup in the bath, 1,200 lb of PbC12 prepared by ferric chloride leaching of galena concentrate was electrolyzed over a period of 2 months. Little deterioration of the metal quality occurred in that time; all of the lead produced had a purity equal to or better than corroding grade (>99.94 pct Pb).

Jan 1, 1976

By Chas. F. Jackson

This paper is one of a series dealing with special mining problems and forming part of a general study of mining, methods and costs being conducted under direction of the Bureau of Mines. A considerable part of the material assembled and discussed in this paper has been gathered from articles on individual mines written by consulting engineers to the bureau who are engaged in active mine operation at the properties described, while other data have been taken from the technical press or gathered from personal observations. OBJECT AND SCOPE OF PAPER C. F. Jackson4 ha[-] pointed out that underground transportation (tramming, haulage, and hoisting) absorbs an appreciable percentage of the total underground cost of most mines, averaging for different methods of mining 12.9 to 28.4 per cent of the total underground cost. In general the percentage of cost accounted for by transportation was shown to be highest for the low-cost mining methods.

Jan 1, 1931

By Walter E. Lewis

The Cuyuna iron range in Crow Wing County, Minn., is the principal producer of manganiferous iron ore in the United States. The ore is mined from a manganiferous iron formation in the bedrock of the Cuyuna district. This iron formation is divided into two general lithologic types-thin-bedded and thick-bedded. The unoxidized, thin-bedded iron formation is composed of iron silicate with associated fine-grained carbonates of iron and manganese. The thick-bedded iron formation carries iron and manganese oxides with intimately associated silica. Oxidation and leaching of the original iron formation have been the most influential factors in producing manganiferous iron-ore concentrations in quantities large enough to exploit on a commercial basis. The unoxidized and the partly oxidized and enriched iron-formation materials are suitable as a source of ferrograde manganese ore. These materials have been classified according to their amenability to mineral dressing and degree of oxidation and leaching.

Jan 1, 1958

By E. L. Singleton

The electrochemical reduction of aluminum chloride to aluminum was investigated in a closed, two-compartment cell utilizing a molten chloride electrolyte. The externally heated cell was divided into a reduction compartment and a combination AICl3 feed and metal removal compartment. Aluminum was deposited at 700° C on a molten aluminum catbode from a KCI-NaCI-AICI3 electrolyte. The AICl3 content of the electrolyte was replenished by either vapor or solid additions. The chlorine evolved was collected and measured to give a quantitative evaluation of AICl3 reduction. The effects of anode and cathode current densities and AIC13 concentration on anode current efficiencies were studiedo A range of 64 to 84 percent anode current efficiency was obtained with the 25-pound electrolyte capacity cell and related auxiliary equipment.

Jan 1, 1968

By Robert N. Roby

"The Moffet-Johnston property was investigated by the Bureau of Mines with the object of determining the presence of ore reserves that might be utilized during the war emergency. Preliminary examination was made during May and Juno 1943, as a result of which the Johnston 'tunnel was cleaned out and repaired, the .mime was surveyed, and a small program of exploration was undertaken. This report describes the work performed and presents the data obtained.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts prelimi¬nary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs benefication tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.The chemical and spectrographic analyses were made at Reno, Nov., under the direction of A. C. Rico, acting engineer in charge, Rare and Precious Metals Experiment Station, Bureau of Mines. The ore-dressing tests were under the direction of Rollien R. Wells, metallurgist, at the Salt Lake City laboratories of the Bureau of Mines.The author acknowledges the cooperation and assistance of the lessee of the property, H.R. Hakes, who furnished nine reports and other information.The Moffet-Johnston property is in secs. 2 and 3, T. 3 S., R. 5 W., in the Tidal Wave mining district of Madison County, Montana.The portal of the Johnston adit is near the mouth of Bear Gulch, 9 miles northeast of Twin Bridges, Mont. It is reached by an improved dirt road that serves mining properties farther up Bear Gulch. The Moffet mine and the Mountain View shaft are now accessible from the Bear Gulch road over an access road recently completed by the U. S. Grazing Service. The Grazing Service road has also been supplemented by bulldozer trails built by the Bureau of Mines.An electric-power line extends from the Montana Power Co's substation at Twin Bridges to mines at the head of Bear Gulch and passes within 200 feet of the Johnston portal.The claims of the Moffet-Johnston property were located about 1900. A report by H. V. Winchel, consulting geologist, in 1904 indicates that most of the development on the Johnston adit was completed by that date. At the time of the Winchel report, the Moffet workings had just penetrated the first ore shoot (fig. 4)."

Sep 1, 1946

By Ludwig Schmidt

"IntroductionThe evaporation losses of gasoline in the refinery, can be reduced by proper methods of refinery construction and operation. When gasoline evaporates slowly, as when stored in tanks that are not vapor tight, the most volatile part evaporates first, so that the remaining liquid in not only less in volume, but is also lower in quality. In some,evaporation changes the characteristics of the product so much that it must be reblended to meet trade specifications.Refiners are, therefore, greatly interested in the various appliances and methods used to reduce these losses. In the past this interest has been directed largely to storage tanks, probably because evaporation from tanks is more readily observed than losses during other refinery operations. As tests by the Bureau of Mines on evaporation of gasoline from small storage tanks had indicated that the losses during the various stages of refining might be equal to or greater than those of standing storage, a survey was during the spring and early summer months of 1924 in a large number of refineries in the Mid-Continent field. In order to enable the refiner to select the results of those tests that conform most nearly to the conditions that he has to meet, tests were conducted at various stages of refining, as follows: (1) Randown tanks, (2) (agitators), (3) filling tank cars, (4) storage of refined products, and (3) miscellaneous handling. The results are presented in this paper."

Nov 1, 1925

By Joan Weinberg

Real gross national product (GNP) grew at a seasonally adjusted annual rate of 2.2% in the third quarter, down from a revised 3.0% in the second quarter, according to preliminary data from the U.S. Department of Commerce (table 1). The slowdown in the rate of growth was attributed to the summer drought, a larger trade deficit, and a decline in Federal spending for defense. Exports slowed from the second quarter, as the dollar, compared with other industrial country currencies, edged up. Imports of both consumer goods and capital goods rose sharply, with consumers buying more foreign cars, computers, and electrical machinery. Although net exports of goods and services deteriorated slightly from the second quarter, the U.S. trade position continues to be much improved from 1987 and first quarter, 1988. Business spending for new plant and equipment rose at a 4.6% pace, well below that recorded earlier in the year. The 3.5% increase in consumer expenditure was accounted for mainly by nondurable goods and services; expenditure for durable goods--those products lasting more than 3 years--rose only 0.4%. Inflation, as measured by the fixed-weighted GNP price index, rose at an annual rate of 4.9% in the third quarter. Prices rose slightly less than they had in the second quarter, when inflation reached a 6-year high. In September, 1988, the President signed a U.S.-Canada free trade agreement (FTA) which will eliminate all tariffs and most nontariff barriers between the two countries by 1999, thereby creating the world's largest open market. In 1987, U.S.-Canadian bilateral trade totaled $161 billion. The expansion of trade is expected to generate 5% higher growth for Canada and up to 1 % higher growth for the United States by the end of the century. The higher growth for the United States translates into an estimated 750,000 jobs, and $2.4 billion in exports. Canadian parliamentary approval of the agreement is still required before the treaty can take effect. The debate in Parliament is continuing, and the issue is not expected to be resolved until after the November 21 election.

Jan 1, 1988