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Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By Irving Hartmann

As part of the continuing effort by the Bureau of Mines to promote mine safety, research work is being conducted at the Experimental coal mine, Bruceton, Pa., on the prevention of coal-mine explosions and on other mine-safety problems. The principal subjects studied during the past 2 years are briefly described in this paper. Although at present these problems are relevant particularly to the mine layout and to high-speed mining practices in numerous American coal mines, it is hoped that the findings will prove interesting and useful also to our European research colleagues. Some of the investigations treated here will be presented in greater detail in forthcoming Bureau of Mines reports. 1. UNDERGROUND STORAGE OF COAL CUTTINGS The seams in mist American bituminous-coal mines are undercut, shear-cut, or top-cut before blasting. The cuttings arc generally loaded out with the balance of the coal. However, in some mines it is not economical to load and remove cuttings from the mine. This applies especially if the cut section of the seam is of appreciably lower grade than the rest of the coal, or if the cut is made partly into an adjacent stratum that is high in incombustible content. In such mines the cuttings are sometimes stored in random heaps in rooms or other areas, along the ribs of mine entries, or in layers on the floor of rooms or entries.

Jan 1, 1956

By N. S. Dalal, Xianglin Shi

"INTRODUCTIONEpidemiologic studies of workers in chromate-ore related industries, 1-3 and stainless steel welding and related occupations4 have shown that they have about 20-40 times higher risk of throat or respiratory track cancer than controls. Although the actual carcinogenic substances were not identified in these statistical studies, Cr(VI) compounds (for example, calcium chromate, zinc chromate, and lead chromate) were implicated as the causative agents, whereas Cr(III) compounds were not suspected as carcinogens. s These suggestions were supporte4 by laboratory studies wherein many Cr(VI) compounds produced sarcomas at the implant or injection sites.1,5 Squamous cell carcinomas and adenocarcinomas closely resembling human lung cancer were induced by intrabronchial implants of calcium chromate in rats, 6·7 whereas Cr(DI) oxide and Cr(lll) sulfate did not induce any tumor formation.6,7While the mechanism of the chromate-induced carcinogenicity is not fully understood, it is generally thought8 that it involves some damage to DNA. Specifically, it has been reported that: a) the chromate ion, henceforth referred to as chromate, can pass through the cell membrane and enter the cell while CR(DI) does not, 9 b) chromate does not interact with either native or denatured DNA 10 while Cr(III) does, 11 and c) the final Cr-DNA complex isolated from cellular reactions of chromate is Cr(III)-DNA, with Cr(III) binding to the phosphate groups.12,13 Thus the important question is: since Cr(DI) cannot pass through the membranes, how does Cr(III)-DNA complex form? For this to happen, Cr(VI) must be reduced to its lower oxidation states, 14 ultimately to Cr(III), by some reductants in the cellular environment. Unless this reduction occurs, the DNA would not be damaged and therefore no chromate carcinogenicity would ensue. Thus the reduction of chromate to its lower oxidation states seems to be a key step in the chromate carcinogenicity .1s One of the major reductants in cellular environments is thought to be glutathione (GSH), both outside and inside the cells.16-lB Some evidence for the role of GSH in the chromate toxicity was provided by recent studies showing that exposure of hamster cells to non-toxic levels of added selemite increases the levels of GSH as well as the Cr(VI)-induced DNA strand breaks,19 and that such DNA strand breaks in hepatocytes also change in direct proportion to the GSH content. 20,21 These observations were interpreted as implying that the reduction of chromate by GSH to some reactive intennediate is an important step in the chromate carcinogenicity. 20.21 In · the present undenaking22 we have used electron spin resonance (ESR) and spin-trap methodology to investigate the reduction of chromate by GSH and find evidence for the involvement of the glutathionyl radical (GS ·) as well as Cr(V)-intermediates."

Jan 1, 1990

By Frank B. Fulkerson

This is the second of two interrelated studies of waterborne transportation. The first study discussed transportation of mineral commodities on the inland waterways of the South-Central States.2 Together, the two surveys describe and analyze the flow of foreign and inland waterborne commerce of the gulf coast. All the principal mineral-industry imports and exports of the gulf coast are mentioned in the report, including metals, nonmetals, and mineral fuel products, The gulf coast foreign trade in mineral industry products was determined to be composed of a small number of commodities.

Jan 1, 1971

According to contemporary psychophysical theory, the relationship between the strength of a perceived sensation (S) and the intensity of a physical stimulus (1) is best expressed by a power relationship.(1) S=kln (1) This psychophysical principle has been applied to many practical problems, including the development of scales or guidelines for effective temperature, loudness, brightness, and ratings of perceived exertion. Based on the results of a number of experiments using a variety of scaling methods and a number of different muscle groups, the pooled estimate of the exponent for muscular effort and force is 1.7.(2) When applying this principle to work situations, it is assumed that individuals are capable and willing to consistently identify a specified level of perceived sensation (S). For manual materials handling tasks, this specified level is usually the maximum acceptable weight or maximum acceptable force. These phrases are defined by the instructions given to the test subject:(3) You are to work on an incentive basis, working as hard as you can without straining yourself or becoming unusually tired, weakened, overheated, or out of breath. If the task involves lifting, the experiment measures the maximum acceptable weight of lift. Similarly, there are maximum acceptable weights for lowering and carrying. Such tests are isoinertial in nature; however, in contrast to the tests described in Chapter 3, they are typically used to test submaximal, repetitive handling capabilities. Data are also available for pushing and pulling. These are reported as maximum acceptable forces and include data for initial as well as sustained pulling or pushing. Why Use Psychophysical Methods? Snook identified several advantages and disadvantages to using psychophysical methods for determining maximum acceptable weights.(4) The advantages include: • Realistic simulation of industrial work (face validity); • Ability to study intermittent tasks (physiological steady state not required); • Results are consistent with the industrial engineering concept of "a fair day's work for a fair day's pay"; • Results are reproducible; and • Results appear to be related to low-back pain (content validity).

Jan 1, 1998

By Michael Rieber

This study is an extension of our previous work in the area of coal transportation Its subject is the comparative costing of competing transport erodes. A wide range of costs and aspects of costs are dealt with in terms of engineering - economic analyses of the cost of the components which make up the facility and operating system descriptions of each coal transport mode. The cost comparisons, though analyzed, are not meant to be statements of policy but, rather, an input to decision making. The technical material presented in the succeeding volumes, alone with the earlier work cited above, forms the basis for the analyses. This material may also broaden the general understanding of coal transportation issues and problems. The project is divided into two main sections: (1) lone distance coal transport and (2) gathering and distribution systems. Within each section economic and technological comparisons are made of the available modes. These are used as the basis for comparisons among the modes. Inter-modal compatibility is studied with respect to both mixed trunk line shipment anti with respect to feeder to trunk line and trunk line to distribution systems. The engineering and technological data form the bases for the costing and economic analyses.

Jan 1, 1977

This report is the 23d in a series summarizing research and technologic work by the Federal Bureau of Mines on coal and related investigations; it is the fifth report to be issued on a calendar-year basis.2/ Publications by Bureau personnel in 1958 are cited;3/ in addition work in progress during the year is briefly described. To conserve our reserves of coal the Bureau of Mines conducts a program concerned with the development of fundamental information on coal characteristics and behavior, and the improvement of technology related to its production and utilization. The ability to anticipate and meet future demands for coal depends on a number of factors: (1) Knowledge of reserves from a stand- point of both quantity and quality; (2) the development of improved mining methods, health and safety measures, and preparation techniques that will insure its most efficient exploitation; and (3) knowledge of the controlling factors in efficient use of coal in combustion, carbonization, gasification, direct and indirect hydrogenation, and other new processes. The Bureau is concerned with each of these areas.4/,5/

Jan 1, 1960

By Oliver C. Ralston

[This paper is an expanded revision of a report entitled "Froth Flotation and Agglomerate Tabling of Nonmetallic Minerals, " published in Transactions of the Canadian Institute of Mining and Metallurgy (vol. 40, November 1937, pp- 691-726) and prepared a year previously. Revisions embodied herein brine the data up to January 1, 1938. References have also been added to make the earlier paper more complete for the period it covered.]

Jan 1, 1938

By George A. Morrison

This paper describing the methods of mining and crushing limestone at the West Winfield, Pa., limestone mine of the West Penn Cement Co., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and coats in the various nonmetallic mining districts. HISTORY The limestone deposits of western Pennsylvania have been exploited for many years and have been quarried extensively at West Winfield in Winfield. Township, which lies in the southeastern corner of Butler County.

Jan 1, 1931

By Doerner H. A.

From thermodynamic calculations Maier predicted that zinc oxide and methane would react at specified temperatures substantially according to equation (1). (1.) ZnO + CH4 = Zn (gas) + CO + 2H2. Other reactions that may take place are (2.) CH4 = C + 2H2. (3.) ZnO + CO = Zn (gas) + CO2. (4.) ZnO + H2 = Zn (gas) + H2O. Maier predicted that 870°C would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1), at equilibrium, would be substantially complete at or above 927°C. Theoretical considerations indicate that reaction (1) is reversible: this is supported, but not proved, by experimental data. The other reactions are known to be reversible. At low temperatures reaction (2) requires a catalyst and it is slow below 1000°C. Reactions (3) and (4) are rapid, but the equilibrium constants are such that only small concentrations of CO2 or H2O can be produced below 1000°C. Maier calculated that CO2 should not exceed 0.5 per cent at 870°C., and the calculation for water vapor gives a still smaller order of magnitude.

Jan 1, 1931

This manual provides instructions for installing, operating, and maintaining a protective canopy on the Joy Mfg. Co. loader. These instructions are based upon two actual install .at ions: one made in a mine on loader, model 14BU10-11AH, and one in the factory on model 14BU10- 11AH. The parts list and engineering drawings for the protective canopy are included at the end of the manual. And a discussion of some alternative design concepts is also included. The manual can also be used for retrofitting other loaders with similar protective canopies. Skilled mechanics can determine if the instructions herein would be applicable to the other loaders and can determine any necessary modifications if they are not.

Jan 1, 1973

By R. R. Wells

This report summarizes the results of preliminary mineral-dressing studies by the Bureau of Mines on five samples of copper-bearing ore from various Alaska de-posits. The work on each sample was not extensive enough to warrant individual publication. The results, however, indicate the possibilities and limitations of concentration of the respective ores. The information therefore may be helpful in future development of these ore bodies. Four of the five samples tested were submitted to the laboratory by engineers of the Bureau of Mines as part of the examinations and survey investigations of strategic-mineral deposits in Alaska. This program is conducted to assist development of mineral resources in the Territory and particularly to aid economic exploitation of marginal or complex ores. The fifth sample was submitted by engineers of the Defense Minerals Exploration Administration.

Jan 1, 1956

By W. L. Dare

This report is one of a series published by the Federal Bureau of Mines to describe methods and costs of mining uranium on the Colorado Plateau. The Navajo Uranium Division of Kerr-McGee Oil Industries, Inc., mines uranium from several deposits of carnotite-type ores, which lie buried in the Lukachukai Mountains on the Navajo Indian Reservation, Apache County, Ariz. The country is rugged and isolated Constructing and maintaining roads has been a continuous task. The ore bodies occur within the Salt Wash member of the Jurassic Morrison formation and are similar to other such deposits on the plateau. The current mining activity in the Lukachukai Mountains is a result of uranium-ore discoveries in 1949, although the Navajos undoubtedly knew of the outcrops of yellow uranium minerals long before that time. The ruggedness of the country and the heavy soil cover over much of the surface hampered prospecting, but probably the main reason the ore was not found sooner is that no one took the trouble to look for it in the Lukachukai Mountains.

Jan 1, 1961

By Richard P. Walters

This Bureau of Mines report reviews and assesses the technology for preparing electrodeposited coatings of the platinum-group metals from molten alkali metal cyanide baths. Methods are described for the preparation and purification of the cyanide electrolyte. Vacuum drying, fusion, and purity of the cyanide salts are discussed. Use of a sodium borosilicate test tube as a sodium-ion-conducting membrane for the addition of the desired platinum-group metal is described. The optimum plating parameters of potential and current density for Pt, Pd, Rh, Ru, and Ir coatings that result in the best deposits are given. A method for producing platinum-rhodium alloy coatings of predetermined composition is also described. The importance of careful substrate surface preparation is illustrated. While problems still remain with respect to coating porosity, careful application of the methods described permits the preparation of adherent, coherent electrodeposited coatings of the platinum-group metals.

Jan 1, 1984

By Ralph Husack

The Bureau of Mines investigated the effect of gamma radiation on reactions between Pennsylvania anthracite and fluorine and chlorine. In the tests with fluorine about 90 percent of the coal reacted at 350° C to form volatile products whether or not irradiation was employed. Up to 0.8 ml of liquid products per gram of anthracite was collected. Among the 25 com-pounds indicated by gas chromatography, fluoroform and l,l-difluoroethylene were tentatively identified from their relative retention times and perfluoro-cyclopentane from its infrared spectrum. In addition, a clear, hard, wax, probably a fluorocarbon, was formed at 45° C in both the presence and absence of radiation. With chlorine there was no significant difference due to radiation, and preliminary tests indicated that the chlorine reacted more with the organic matter of anthracite at 200° C than with inorganic matter. At 400° C the results were inconclusive because of excessive corrosion in the reaction vessel.

Jan 1, 1966

By H. E. Harris

It has long been recognized that one of the principal ways of combating dust in coal mines is by means of water sprays. However, spray systems, currently in use, clog or plug frequently, thereby reducing the effectiveness of dust control aid, in turn, possibly increasing the health hazard to mining personnel. Moreover, the maintenance and replacement of spray system components, e.g., nozzles and filters, can be expensive in terms of direct costs of labor and material, and the consequent loss of production. Recognizing these problems, the Bureau of Mines sponsored a research project on the "Development of a Non-Clogging Water Spray System"; this project was carried out by Eastern Associated Coal Corp. The overall objective of this project was to develop a non-clogging water spray system suitable for use in underground coal mines. Since most of the dust formed is at or near the working coal face, emphasis was placed on face equipment such as a continuous mining machine. To accomplish this objective, a two-phase project was carried out. The first phase involved determining the causes of spray nozzle and spray system clogging, determining the availability of spray nozzles or systems that could be modified to be non-clogging, and developing a non-clogging water spray system. Phase two was concerned with the fabrication and the laboratory and field testing of a non-clogging system. In each phase, there were both laboratory and field investigations, and the results of these investigations are presented in this report.

Jan 1, 1975

During the interval 1929-41, geophysical exploration in Russia made considerable progress, as reflected in publications. The greater part of these publications was available during the preparation of Geophysical Abstracts and Ms been abstracted in them. The rest was not received and remained unaccounted for. A considerable portion of these lading publications are now listed in bibliographic form, in view of their interest to geophysicists. All publications entered in the bibliography are in Russian. 1. GRAVITATIONAL METHODS 1. Abakelia, M. S. The Organization of Gravitational Observatories in Transcaucasia. Problemy Sovetskoi Geologi, Moscow, vol. 6, No. 5, 1936, pp. 452-454.

Jan 1, 1945

By John P. McDonnell

Cable supports offer several advantages over traditional secondary support methods by enhancing stress redistribution to pillars and gob areas, minimizing or eliminating timbers and cribs that reduce ventilation, eradicating material-handling injuries related to placement of crib supports, and providing a cost-effective alternative to secondary support. The U.S. Bureau of Mines, in researching alternatives to traditional roof support methods, designed and installed high-strength cable supports to improve the stability of longwall gate road and bleeder entries in a Western U.S. coal mine. With the cooperation of industry, methods were developed to install cable supports in a tailgate and bleeder entry test area using traditional resin cartridges. Resin-grouted cable bolts were also installed and evaluated in additional longwall gate road and bleeder entry systems at the study mine. The cable-bolted areas successfully maintained roof support throughout the tailgate and bleeder entries. Cable supports replaced wood cribbing as secondary support in the bleeder entry system and minimized the use of cribbing in the longwall tailgate entries. This report describes the theory, application, and advantages of cable supports and presents mine measurements made to assess the cable performance during the retreat process of longwall mining.

Jan 1, 2010

By L. A. Haas

S02 reduction with CO was studied in an integral flow reactor at a nominal flow of 0.5 liter per minute. Reactant gas contained 3 percent SO2, 6 percent CO, and the balance He. SO2 conversion was determined for three different types of catalysts. The first consisted of 16 commercial catalysts used for various chemical syntheses. Only the commercial catalysts which contained transition metals in alumina removed more than 30 percent 80a at temperatures below 510° C. Two other types of catalysts were prepared in the laboratory either by pelletizing equal amounts of powdered alumina and transition metal oxides or by impregnating commercial alumina tablets with transition metal ions. Regardless of preparation techniques, Cr and Fe in alumina were the two best catalysts. The observed results suggest that an intermediate (SCO) is formed by the interaction of surface metal sulfides and carbonyls. Alumina then catalyzes the interaction of SCO with S02 to form the end products (sulfur and carbon dioxide). Over 80 percent S02 was removed at 460° C with 2 grams alumina impregnated with 2.5 percent iron.

Jan 1, 1972

By James A. Wasson

Because of the danger to life and property in a coal mine if an oil or natural gas well should be accidentally intersected during mining operations, certain precautionary measures should be carried out prior to entering previously unmined areas. The locations of all wells both at the surface and at the depth of the coalbed should be accurately determined. The condition of the well should be learned from surface observations, and more importantly, from subsurface examination by geophysical logging devices where possible. It is also desirable to learn the physical properties of the hydrocarbon-bearing rock formation and the hydrocarbon fluids. The major hazard presented by oil or natural gas wells to mining operations is that of explosion and fire due to the rapid release of gas into the mine atmosphere. Wellbore pressure, the principal index of danger, should be determined by one or more of the methods described and by a service company such as those listed in the appendix. Because of high pressures involved and the consequent hazard, much emphasis has been placed on underground storage of natural gas in areas containing minable coalbeds. Maps are shown of the principal coal producing areas and the locations of currently active gas storage reservoirs. A checklist has been included of factors to be considered when mining coal in an area where oil or gas wells exist.

Jan 1, 1973