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By Charles D. Litton

This U.S. Bureau of Mines report details the results of a series of large-scale experiments where small coal fires were used to ignite the conveyor belt at air velocities ranging from 0.76 to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited the conveyor belt located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flaming coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two nomographs are presented, which define sensor alarm levels and sensor spacings as a function of belt entry cross-sectional area and belt entry air velocity.

Jan 1, 2010

By L. B. Pankratz

Thermodynamic data on the elements, oxides, sulfides, halides, and selected hydrides, carbides, nitrides, carbonates, sulfates, silicates, and miscellaneous compounds were reviewed, evaluated, and compiled at the Bureau of Mines. Values for CP°, S°, H° -H°298, ?Hf°, and ?Gf° are given in tabular form. A brief thermodynamic background and a number of examples and applications are presented.

Jan 1, 1984

By D. E. Wolfson

As a part of its overall program of coal carbonization, the Bureau of Mines is studying the coking properties of coals that may be used for metallurgical purposes. The objectives of this study were given in detail in a previous report.2/ The inherent suitability of coal for metallurgical use depends primarily on (1) chemical composition, (2) preparation characteristics, and (3) carbonization behavior. The first two factors, as well as the available reserves, are considered in selecting coals for carbonization tests.

Jan 1, 1957

By G. R. Fitterer

In the manufacture of steel by any process the refining period involves the partial elimination of the metalloids carbon, manganese, phosphorus, and silicon, by virtue of their reactions with ferrous oxide. At the end of this refining stage the metal consists chiefly of iron in which small amounts of these materials are dissolved. Unless some deoxidizer is added to the steel at this time, the reaction between carbon and ferrous oxide will continue with such force that it is impossible to form sound steel in the ingot molds. Instead, the product will exhibit a marked porosity due to the formation and trapping of carbon monoxide-the product of the reaction mentioned. However, if deoxidizers are added, steel may be obtained which is dense and free from gas bubbles. At the same time the deoxidation products will remain in the steel as impurities. For example, silicon additions form SiO2 or combinations of SiO2 and FeO. Additions of manganese form deoxidation products consisting of various proportions of MnO and FeO. It is also quite obvious that simultaneous additions of manganese and silicon will form oxide combinations either in the binary system MnO-SiO2 or in the ternary system FeO-MnO-SiO2. Work at the Pittsburgh Experiment Station of the United States Bureau of Mines, in cooperation with the Carnegie Institute of Technology and the Metallurgical Advisory Board, involved the study of such deoxidizing reactions and their products. In this connection considerable information is necessary concerning FeO, MnO, SiO2, and Al2O3, and their various combinations. Some of the most needed data are the melting points of all of these materials. At the outset of this work ordinary methods of melting point determinations were found to be inadequate for various reasons, and the procedure finally selected involved the use of the micropyrometer with occasional corroboration by quenching methods. The reasons for this selection, together with a description of the apparatus, are given in the following pages.

Jan 1, 1932

By Lloyd A. Morley, Robert Stefanko

1 Abaibanel, S , "Deflection of Confining Walls by Explosive Loads," Israel Jour. Technology, vol. 4, n. 1, Feb 1966. 2 Albertoni, S and others, "Numerical Computation Methods for Implosion Processes," EURATOM Proc. of the Conf. on Megagauss Magnetic Field Generation by Explosives and Related Experiments, Milan (Italy), July, 1966. 3 Alexander, S. J , and Hambly, E. C., "Design of Structures to Withstand Gaseous Explosions," Concrete, vol. 4, n 2, Feb. and March, 1970. 4 Anonymous (Belgium Institute of Extractive Industries), "Report for 1968 (covering approved equipment for Belgiums gassy coal mines)," (in French and Flemish), Amales des Mines de Belgigue, n. 6, June, 1969. 5. Anonymous (Ghent Univ., Belgium), "The Welding of Very Thick Steels. Margin of Uncertainty of the Robertson Test," EURATOM Contract 042-61-9-RDB, May 20, 1965. 6. Anonymous, "Inportance of the Nature and Size of Weld Defects with Regard to the Mechanical Strength of Pressure Vessels, (in Flemish), A. Sys. Rev. Soudure, vol. 27, n. 3, 1971. 7. Anonymous (Raentgen Technische Dienst N V., Rotterdam), "Non¬Destructive Welding," Quarterly Report No 13, EURAEC - 1342, March 30, 1965. 8. Anonymous (Staff, USBM Safety Research Center), "Research and Technologic Work on Explosives, Explosions, and Flames: Fiscal year 1969," USBM IC8492, 1970. 9. Anonymous, "Symposium on Flameproofing Intrinsic Safety and Other Safeguards in Electrical Instrument Practice, April 27, 1962," IEEE Conf. Report Ser. 3, 1963. 10. Anonymous, "Unfired Pressure Vessels," ASME Pressure Vessel Code, Sec. 8, 1965. 11. Anonymous, "Unusual Pressure Relief Devices," Industrial and Engineering Chemistry, vol 54, n. 1, Jan., 1962. 12. Archer, G. L., "Design to Avoid Brittle Fracture in Welded Structures," Paper No. 4, Improving Welded Prod Design, vol. 1, Welding Inst., Cambridge, England, 1971. 13. Bailey, F. C., "Buckling and Failure Strength of Plating Panels Loaded in Shear," Final Report NASA Contract NObs-72290, Lessels and Assoc., Inc., Waltham, Mass., Sept. 20, 1963.

Jan 1, 1974

By Irving Hartman

The results of the first experimental study by the Bureau of Mines on the explosive properties of metal powders were published in 1945. Since that time the explosibility of numerous other industrial dusts and powders has been investigated. Part of this information has been published, but most of the data has not been released to date. This paper summarizes the results of experiments on 22 samples of titanium, zirconium, thorium, uranium, and hydrides of these metals. The major part of the investigation was made under cooperative agreement with the Atomic Energy Commission.

Jan 1, 1951

By A. J. Kraemer

The twenty-fourth of a series of semiannual surveys pertaining to motor gasoline marketed in the United States was made by the Bureau of Mines in August, 1931. The first part of a report giving the results of that survey as they pertain to specification data is given in this paper. A companion report, Part II, is in preparation and will discuss the results of other determinations made on the samples, including octane number ratings on the individual samples (to be made by the Bureau of Standards) and results of the determination of gravity, color, doctor test, and "gum" content by the copper dish method and the Bureau of Mines steam-oven method. The retail price and the tax at the time each sample was taken will also be reported.

Jan 1, 1932

By S. J. Pearce

The Bureau of Mines has prepared, as circumstances have dictated, a series of Schedules setting forth the minimum requirements that various types of equipment should meet to be considered safe and satisfactory for use in certain hazardous or unhealthful conditions. These Schedules cover a wide variety of devices ranging from explosives to electrically operated mine locomotives. This paper deals with those Bureau of Mines Schedules under which respiratory protective devices are tested and approved, and its purpose is to explain the function and operation of these Schedules. Provisions have been made for testing and approval of the following types of respiratory protective devices: Self-contained breathing apparatus,2/ supplied-air respirators,3/ gas masks,4/ dispersoid respirators,5/ and chemical cartridge respirators.6 These devices are tested at the Central Experiment Station of the Bureau of Mines in Pittsburgh, Pa. Self-contained breathing apparatus is tested by the Safety Branch, and the other types of respirators are tested by the Health Branch.

Jan 1, 1951

By X. Shi, K. S. Kaspnak

"The generation of free radicals from reactions of nickel (Il)-thiol complexes with molecular oxygen and model lipid hydroperoxides was investigated by electron spin resonance (ESR) utilizing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. Incubation of nickel (II) [Ni(II)) with cysteine in an aerobic environment generated hydroxyl (·OH) radical, which then reacted with cysteine to generate a carbon-centered alkyl ( · R) radical. Radical generation was inhibited under a nitrogen atmosphere. Model lipid hydroperoxides, cumene hydroperoxide, and I-butyl hydroperoxide enhanced the yield of these radicals and also generated an alkoxyl (·OR) radical. Radical yield decreased by approximately half under a nitrogen atmosphere. Although histidine did not cause radical formation in the reaction between Ni(II) and cumene hydroperoxide under aerobic conditions, the addition of histidine to a mixture containing Ni(ll), cysteine, and cumene hydroperoxide under the same experimental conditions increased the yield of · R radical but lowered the yield of ·OR and ·OH radical adducts. It thus appears that histidine caused the ·OH attack to be more site-specific. Similar results were obtained utilizing 1-butyl hydroperoxide. Penicillamine or N-acetylcysteine yielded similar results except that under aerobic conditions, reaction between Ni(ll) and N-acetylcysteine without hydroperoxide did not generate a significant concentration of free radicals. Under the same experimental conditions, cystine did not generate any detectable free radicals, suggesting an important role of the -SH group in Ni(II)-mediated free radical generation. The results indicate that free radical generation from the reaction of Ni(Il)-thiol complexes and molecular oxygen, and/or lipid hydroperoxides, may play an important role in the mechanism(s) of Ni(II) toxicity and carcinogenesis. INTRODUCTIONWhile nickel is a well-recognized carcinogen [l, 2]. the underlying biochemical mechanisms remain unclear (3, 4). Recent studies suggest that these mechanisms may involve oxidative DNA damage through free radicals, especially the hydroxyl (•OH) radical [5-13]. The mechanisms of nickel carcinogenicity and toxicity may also involve lipid peroxidation [14-21]. Unlike ferrous ion [Fe(II)], the Ni(II) cation itself does not directly react with 02, H2O2, or lipid hydroperoxides to generate free radicals [12, 21]. However, it has been reported that Ni(II) complexes with certain synthetic oligopeptides, e.g., tetraglycine or glycylglycylhistidine, make Ni(II) reactive with 02. This reaction results in transitory formation of Ni(III) and degradation of the organic ligand via free radical reactions [22]. Such Ni(II)-peptide complexes are also capable of reacting with H2O2 to produce oxygen free radicals [11, 12]. Although the cellular environ¬ment may not contain these particular peptide ligands that are known to render Ni(II) redox active in vitro, it does contain a variety of oligopeptides that are capable of forming Ni(II) complexes at physiological pH, and thus may facilitate Ni(II) redox activity in vivo. These oligopeptides include glutathione (y-L glutamylycysteinylglycine), carnosine (homocarnosine (y aminobutyryl-L-histidine), and anserine ( B-alany1-3-methyl-L-histidine)."

Nov 1, 1995

By Daniel G. Di Canio

A computer based accident cost indicator model (ACIM) for estimating tangible costs of occupational injuries, illnesses, and fatalities in the U.S. mining industry is described. Studies performed to expand the scope of the ACIM to all mining sectors are presented. Validation of ACIM cost element estimation algorithms with actual costs of mining-related injuries and illnesses are presented. A study of the effect of a fatal accident on production in surface coal and metal/nonmetal mines is presented. The study is based on a sample of 15 fatalities in underground and surface mines. Evidence of significant long- term decline in postfatality production at 6 of 8 underground samples is presented. The average loss is shown to be 1.8% of annual mine production. A study of accident costs in U.S. mining from 1975 through 1981 using the ACIM is presented. The study shows that total annual costs increased from $180,000,000 in 1975 to $379,000,000 in 1981, a 15% annual increase after adjusting for inflation, with mining companies bearing 45% of the total and expected wage losses to mining families accounting for 42%. The study shows total costs of $12,400 per accident and $674,000 per fatal accident for 1981.

Jan 1, 1983

By Joseph Grumer

Reported fiscal year 1973 studies of fires and explosions seek to develop capabilities during mining operations to detect and quench ignitions of gas in the face area, to detect and quench by means of passive or triggered barriers explosions propagating in rock-dusted coal dust, and to detect incipient fires early enough for easy extinguishment. Research discussed includes minimum air velocities to lift coal or rock dusts, surveys to determine adequacy of rock dusting, chemical agents to quench gas or coal dust explosions and their relative efficacies, spectra radiated by explosions, and nozzle sprays of extinguishants.

Jan 1, 1973

By Seth T. Reese

THE INJURY DATA and experience at coal mines in the United States for 1951 are presented in this bulletin under the following general heads: (A) General injury experience: Tables 1 to 18: Contain current data on number of fatalities and nonfatal injuries, frequency and severity rates, average severity, major and detailed injury agencies, and distribution of injuries by part of body and days of disability. (B) Selected injury data: Tables 19 to 43: Contain current data on various selected factors of operating and physical conditions that contributed to the occurrence of injuries at bituminous-coal, lignite, and anthracite mines. These factors include extent of hand and machine loading, size of mine by employment and production groups, thickness of bed or vein, duration and number of work shifts, rating of mine as gassy or nongassy, types of cap lamps, explosives, and combination of factors that influence mine safety. (C) Injury experience by States: Tables 44 to 50: Contain current data on number of fatalities and nonfatal injuries, frequency and severity rates, average severity, major causes and principal agencies, injury records of all coal-producing States, and the relative standing by States according to injury-frequency rates. (D) Major disasters: Table 51: Lists the coal-mine disasters that occurred during 1951, giving location, source, and cause. A major disaster in coal mining is defined as a single accident in which or as a result of which five or more men lost their lives. (E) Historical coal-mine injury experience: Tables 52 to 86: Contain data on injuries, injury-frequency rates, employment, and production at bituminous-coal, lignite, and anthracite mines from the earliest records through 1951.

Jan 1, 1955

By John C. Hartley

Three systems that monitor ventilating fans are described. These electronic monitoring systems automatically perform most of the operations required to conform with the provisions of the Federal Mine Safety Code in the event of fan failure or slowdown.

Jan 1, 1964

By C. J. Chindgren, L. C. Bauerle, J. B. Rosenbaum

Modifications of the conventional method of preparing ductile vanadium metal by calcium reduction of V2 05 in a bomb were explored for clues to a more economical procedure . The modifications examined included ( 1 ) omitting the gas purge of the bomb ordinarily used for eliminating atmospheric nitrogen , (2 ) using low- grade vanadium feed materials , ( 3 ) using alternative reductants , such as aluminum , magnesium , and silicon , and reductant mixtures , and ( 4 ) bomb refining of aluminothermic metal produced in open- vessel reductions . The most promising modification appeared to be bomb refining , using calcium to purify vanadium metal -- of low aluminum but high oxygen content-- prepared by open- vessel aluminothermic reduction of vanadium pentoxide .

Jul 1, 1960

By C. W. Smith

The U.S. Bureau of Mines conducted research to determine the effect of ground water control on the dewatering of phosphatic clay wastes. Two storage impoundments were constructed. One impoundment was surrounded on three sides with a series of well points (shallow vertical wells) to lower the ambient water table and the second impoundment served as a control. Ground water was pumped from the area surrounding the test impoundment for a period of 490 days. A constant pumping rate of 60 gal/min resulted in a water table drawdown of 13 ft, approximating the bottom of the impoundment. At the end of the test period percent solids in the test impoundment was 35 pct, while in the control impoundment percent solids was only 26.8 pct. Percent solids of greater than 30 pct is required for capping and final reclamation using fertile overburden.

Jan 1, 1989

By Todd M. Ruff

Researchers at the National Institute for Occupational Safety and Health (NIOSH), Spokane Research Laboratory, are investigating technology and methods to monitor the blind areas around large haulage equipment used in surface mines. On average, six fatalities a year can be attributed to equipment colliding with other vehicles or pedestrian workers, or backing over the edge of a dump point. Several off-the-shelf technologies exist for monitoring areas that an equipment operator cannot see from the cab, including radar, video cameras, and radio signal detection systems. NIOSH researchers have tested many of these systems on large dump trucks both at their test facility and at surface mines. This article discusses the technologies available for this application and their effectiveness in detecting objects near an off-highway dump truck. Also, guidance is presented for mine safety personnel who are planning to evaluate collision warning systems or cameras on their haulage equipment. Available Technology Over the past few years, the number and types of systems available for monitoring the blind areas around heavy equipment have increased. Systems marketed for the automotive and recreational vehicle industries have been around for a while. Small video cameras can be found

By John C. Hartley

Three systems that monitor ventilating fans are described. These electronic monitoring systems automatically perform most of the operations required to conform with the provisions of the Federal Mine Safety Code in the event of fan failure or slowdown.

Jan 1, 1964

By R. V. Ramani, K. Bode

"IntroductionThe theory of particle dispersion and deposition in turbulent flow is important to many fields of science and engineering. Dispersion has been studied in some detail since the early fifties (Taylor, 1954; Fischer, 1967; Osipov and Grekov, 1968; Skobunov, 1970 and 1973; Klebanov and Martynyuk, 1974). A broad research effort has also been underway in studying the mechanics of dry particle deposition. Friedlander and Johnstone (1957) proposed a theory, according to which particle deposition from vertical pipe flow could be described by an eddy diffusion transport followed by a final flight to the surface. There have been numerous revisions and additions to this original theory (Owen, 1960; Liu and Agarwal, 1974; Liu and llori, 1974; El-Shobokshy and Ismael, 1980) The mining process essentially consists of breaking in situ materials and transporting them out of the mine. An inherent characteristic of this process is the generation of fine particles. Fine airborne particulates are associated with a number of threats to the health of the miners; fine coal dust can also result in mine-wide catastrophic incidents such as dust explosions. For these and other reasons, it is important to understand the behaviour of airborne dust particulates, particularly their generation, entrainment, transport, dispersion, and deposition in the mine environment for their control.Mine related studies on dispersion and deposition have been few. Yet, several studies of gas and dust dispersion, diesel exhaust contamination, and methane ingress into mine workings have recognized the need for developing reliable parameter values for fundamental understanding of the phenomena (Da""Yes and Slack, 1954; Hodkinson, 1957; Hodkinson and leach, 1958; Mass and Wildschut, 1966; Airey, 1969; Courtney et al., 1986; Stefanko, Ramani, and Thakur, 1974; Stefanko, Ramani and Kenzy, 1977; Bhaskar, 1987, Bhaskar and Ramani 1990; Qin and Ramani, 1989; Shankar and Ramani, 1990)."

Dec 1, 1995

By D. H. Carlson, J. H. Johnson

"The U.S. Bureau of Mines and Michigan Technological University (MTU) are collaborating to develop an apparatus for measuring diesel tailpipe emissions in underground mines. A tailpipe emissions measurement apparatus (EMA) is described that dilutes diesel exhaust and measures the concentrations of diesel particulate matter (DPM), CO, CO2, NO, and NO2 at known dilution ratios.The EMA was evaluated by side-by-side comparison of its measurements with those by laboratory grade instruments. Concentrations of CO and C02 measured by the EMA were usually within ± 14 pct of concentrations measured by laboratory-grade instruments for CO and ±20 pct for C02• EMA measured DPM concentrations were, on average, 29 pct lower than those measured by laboratory-grade instruments, with the differences being fairly consistent. The CO and C02 differences are related to the method of calculating the EMA's dilution ratio, and the difference in DPM concentrations is attributed to thermophoretic and/or condensation losses related to the EMA's unheated sample probe. Preliminary analysis of data obtained with a heated sampling probe and modifications in the sampling procedures have indicated reduced variability in DPM and in the calculated dilution ratios."

Mar 1, 1992

By E. D. Gardner, Edmund Stein

"IntroductionMassive sulphides occurring in metal mines are inflammable and furnish the fuel for many mine fires. Actual sampling has shown that dangerous amounts of sulphur dioxide and hydrogen sulphide may occur in mine atmospheres after blasting in massive sulphides. Probably some .of the finer sulphide in the material being blasted burns while it is in contact with the flame from the explosion. It’s also possible that oxygen of the explosive enters into the reaction.That sulphide dusts are explosive under some conditions has long been suspected, but the theory has not been generally accepted as having been proved. Evidence now at hand appears to be conclusive that such explosions do occasionally occur in mine workings in massive sulphides. Information from several mines working in heavy sulphides shows that occasionally, sulphur dioxide in larger amounts than could be expected from the blasting alone are occasionally thrown out into the mine atmosphere during blasting. Accidents have occurred and lives have been lost by men being caught in such gases. Also it appears in a few cases that damage done to timber in stopes by concussions has been greater than could 112.ve been expected from the regular blasts. In most of these cases the unusually large amounts of Sulphur dioxide could only be accounted for by an explosion or by an ignition of sulphide dusts. When this occurs it is probable that the settled dust is stirred up by the first shot of a round, then the dust cloud is ignited by this or a succeeding shot.In one instance, the senior author, while wearing breathing apparatus, returned to a station to take a gas sample immediately after a raise round had been blasted, and encountered a heavy white fume or smoke that was corrosive to the skin and which forced a retreat. The sample, which was taken farther back in a greatly diluted atmosphere, showed a high percentage (0.18) of sulphur dioxide. The station and the raise which was just being started were very dry and the walls and floor of the station contained settled sulphide dust which apparently was ignited by the blast."

Mar 1, 1928