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By Charles Dr. Li, John Dr. Box

Selective flotation and adsorption behavior of zircon and rutile under hot soap conditions have been examined. Conditioning temperature, pH and washing steps were shown to control the flotation selectivity. The adsorption of the sodium soap of oleic acid at zircon- water and rutile-water interfaces was investigated through micro- electrophoresis and adsorption density measurements. The soap adsorption on the zircon surface increased markedly with increasing temperature due to a strong chemisorption/surface reaction, and was almost independent of pH. In contrast, the soap adsorption on rutile decreased at high pH values. A simple physisorption plus hydrophobic interaction appeared to be the principal mechanism for the soap adsorption on rutile at moderate temperatures (below ~70(C), beyond which it may change to chemisorption through an activation process. Water wash, particularly under acidic conditions (pH 2-3), of the rutile particles treated with soap, will lead to a desorption of the soap from the rutile surface by forming an acid salt precipitate.

Jan 1, 1995

By A. Marabini, G. Belardi, N. Sheau, F. Veglio

The present paper deals with the modelling of a Multi-gravity separator in the treatment of chromite fines. A first screening study was carried out by 2" full-factorial experiments in order to check the main effects and interactions among the investigated factors: shake frequency, shake amplitude, tilt angle and washwater flowrate were taken in consideration in the study. Two size fractions were employed in the experimental tests. Successively, considering the factor with larger influence on the Cr203 and SiO2 grade and Cr203 recovery in the concentrate, a further improvement of the experimental design was performed to determine empirical models to describe the behaviour of the MGS in the mineral treatment. The results show how intrinsic interaction among the factors take place, highlighting that an optimization study must be carried out considering all the MGS setting parameters.

Jan 1, 1995

By John W. Kelse

What happens when the skull and crossbones goes on a product? In the case of cancer warnings, the consequences can be severe. If the label contains the term "lung carcinogen", you might expect to compensate a lot of smokers, meet a lot of expensive lawyers, be counseled by equally expensive consultants and pay sharply elevated insurance premiums, if you are able to obtain coverage at all. At the extreme, you may face plant shutdowns, job losses or even Chapter 11 bankruptcy. Regardless of how you fare, you are likely to learn some very disconcerting things about the risk evaluation and regulatory system which required you to label in the first place. If a particular material or product does pose a health risk, you are obliged both legally and morally to warn those potentially exposed. Once that warning appears on the label, however, the consequences are often beyond your control. You and your embattled product become part of a legal/regulatory system which has a life of its own. Therefore, the issue of health labeling is not so much whether one warns but rather whether the warning itself is justified and the reasonableness of what happens afterwards. It is this matter of justification and reasonableness, particularly of cancer warnings, which this paper addresses. Until, as they say, your ox has been gored, we tend to believe that risk is determined by the best available technology and expertise We expect that risk evaluators appreciate the ramifications of their work and place things in proper perspective; that risk has been appropriately demonstrated before it is publicized and regulated; that the time-honored concept of prudence, to err on the side of safety, has not been excessively stretched. Unfortunately, the risk evaluation process is rarely, if ever, this

Jan 1, 1991

By Harold D. Taylor

Cone fitting is a procedure which can be used to estimate the short range, linear portion of a variogram. Rather than combining data over windows In different directions and fitting by hand, cone fitting estimates the variogram in all directions at once using a multiple regression approach. The method automatically provides estimates of nugget effect, anisotropy, and initial slope of the variogram. This paper presents the results of simulation studies which have been carried out. These studies Indicate that the method works well and that it may be particularly useful for small data sets. The simulation studies also indicate that the local variogram may differ greatly from the theoretical variogram.

Jan 1, 1986

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By A. A. Peshkov, N. A. Matsko, K. N. Trubetskoy

It is possible to divide the general objectives of a company into two components: maximum expected profits and viability over time. These components are designed to maximize the companies value over time. The evaluation of a project includes both a discounted cash flow (DCF) analysis and a risk analysis. The DCF analysis determines whether the project should be accepted or rejected, and the risk analysis helps to forecast possible deviations from the original estimates. However, the results of both methods do not allow for a quantitative comparison between the main objectives of the venture, and they do not resolve the issue of whether it is advisable to sacrifice immediate profits for future profits. This paper attempts to resolve this issue. The present research was carried out on mining projects with different waste-extraction schedules. Calculations were made using the US Bureau of Mines' usage-of-costs model. Russian experience in open-pit mining is reflected in this paper.

Jan 1, 1996

By S. Shrivastava, R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner(SPL) is obtained at the end of the pot's life. The SPL contains small amounts of cyanide and fluoride, which present environmental problems. Spent potliner could possibly be used as a fluidizer to replace calcium fluoride (CaF2) in the iron- and steelmaking industry and in the glass industry. A low viscosity and a low melting point are prime requirements for such an application. In the present study, viscosity measurements were performed. The effects of various additives, such as sand, limestone, dicalcium silicate dust and MgO baghouse dust, on the viscosity of SPL were studied. The results showed that the addition of sand and limestone can produce a very high fluidity SPL melt at significantly lower temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 2002

By J. Loredo

Wastes related to abandoned mine sites can constitute important potential pollution sources, depending on their mineralogical and geochemical characteristics and volume. Mine waste disposal sites contain a diverse variety of wastes including overburden material and waste rocks, the ore which cannot be economically removed and wastes from the smelting processes when they are accomplished at the mine site. These materials are usually heterogeneous in size, mineralogy and metal concentrations. Asturias, in northern Spain, has an extensive mining history and, in consequence, there are abundant unreclaimed and derelict mine sites with abandoned mines and spoil heaps of different age, morphology, content and dimensions. In these spoil heaps, waste materials are subjected to the intense action of a humid environment, so the instability of sulphides and sulpharsenides results in the production of acid and metal-rich leachates, which are incorporated to surface water or infiltrated through the land reaching groundwater bodies. The mineralogical and geochemical characteristics of the stored materials are key data to evaluate if they represent an environmental risk. Mineralogy and geochemistry of wastes and the particular specific environmental conditions of each site affect the rate of weathering and therefore the metal release. The characterisation of mine wastes is a necessary step in order to establish suitable assessment strategies with the aim of reducing the leaching, transport and widespread of ecotoxic elements from mining wastes to the environment (surface water, sediments, soils and air). As a consequence of the weathering of As-rich mineral phases, high arsenic contents are commonly detected in effluents from mine voids and spoil heap leachates.

Jan 1, 2006

By V. Rastogi

Surfactant-based bactericides are able to control acid formation in sulfidic materials such as pyrite and sulfidic ores, thereby helping to abate acid rock drainage. Bactericides are used in the following two ways: as periodic or continuous spray treatments for the prevention of acidification of material actively handled and moved and in controlled-release form for reclamation. Site-specific bactericide treatments are designed for active sites and reclamation. Results from two active coal refuse sites show that acid production can be reduced by 88% or more. Results from reclaimed sites show that bactericide treatment can be more effective than the addition of alkaline materials such as limestone and can reduce acid production from 3,500 to <30 ppm. The controlled-release-pellets treatment outlasts the life of the pellets, as shown by a study of a site now 10 years old A single treatment sets up a change in site microbiology to replace acid-producing Thiobacillus ferrooxidans bacteria with heterotrophic bacteria and creates a stable site without the need for further treatments. A secondary beneficial effect of bactericides is on revegetation, and biomass from treated areas is almost 10 times that from areas not treated with bactericide. Depending on the application, bactericide treatment can be cost effective upfront and certainly long-term, compared to the perpetual water treatment that could be required, even after productive use of the site is completed

Jan 1, 1997

By Stephen R. Pogorski, Nicholas Busigin, Colin R. Phillips

The movement of radon away from its source in porous media is determined by two key parameters: the fraction of the total radon formed which enters the intergranular pore spaces, termed the emanation coefficient, and the transport processes which exist in these pores such as diffusion and convection. The first parameter, the emanation coefficient, is of primary importance since it is a measure of the actual amount of radon which is free to migrate within the media. The effects of particle size and radium concentration on the emanation coefficient were examined using a quartz-pebble conglomerate ore from the Elliot Lake mining district of Ontario. It was found that the smallest particle size examined (<74 µm) had the highest radium concentration and contributed the most to the radon emanation. A one-to-one correspondence between radium concentrations for the various particle size fractions and radon emanation was not observed. Samples were examined using scanning electron microscopy and very small particulates were observed to be present on the particle surfaces. When these very small particulates were removed from the host particle surfaces by rinsing, the radon emanation decreased by a factor of 17. This result indicates that most of the emanation comes from the very small particles. The effect of moisture on the emanation coefficient was examined qualitatively and a trend of increased radon release with moisture content was noted.

Jan 1, 1981

By A. C. T. Bigg, A. F. Colombo, A. R. MacPherson

The step-by-step study of the Stronsay ores follows the testwork through the initial determination of Bond Rod and Ball mill work indices, the MacPherson Autogenous work indices and the production of a preliminary flowsheet. These results are then used to design a pilot plant program to test the effectiveness of fully autogenous primary and secondary grinding and to determine the feasibility of controlling feed rate by the use of variable speed mill drive and/or varying the mill load. A final flowsheet is recommended with mill sizes and power requirements.

Jan 1, 1992

By M. S. Seehra, V. Suresh Babu, R. S. Pandurangi

Different mixtures of the three polymorphs of silica viz. quartz, cristobalite and tridymite are analyzed by x-ray diffraction (XRD) and their IR spectra are investigated by photoacoustic spectroscopy. It is observed that XRD provides a higher resolution to distinguish between the three polymorphs in a sample than IR spectroscopy. In the latter, a sharp band near 617 cm-1 is characteristic of both cristobalite and tridymite. A mine dust sample is quantitatively analyzed by XRD and it is shown to contain illite, quartz, kaolinite and calcite.

Jan 1, 1991

By P. H. Williams

Experiences gained using computers in the mining and geological environment have shown that it is quite rare for a system or the data it stores to be truly stand alone. Just as the mining enterprise aims to have a smooth integration of operations from exploration through mining and extraction to sales, so it should develop all its information systems within an overall framework or architecture which covers the applications and data as well as the computer hardware and communications. This paper discusses methods of achieving such an architecture, and describes some of the benefits it can have on the development and implementation of information systems. The key aspects are the identification of the business functions and the data that they use, and ensuring that the IS plan supports the overall objectives of the enterprise. Hardware and communications policies should be based on the plans for the applications and data, rather than the reverse.

Jan 1, 1986

By Fernando Concha, Arturo Barrientos

The flow in a hydrocyclone is divided into a boundary layer around the walls, an exterior inviscid flow and an air core in the center of the equipment. The boundary layer flow over the lateral walls is associated with the short circuit of particles to the underflow, while the boundary layer over the top of the hydrocyclone and the outer part of the vortex finder tube is related to the short circuit of particles to the overflow. Classification takes place in the exterior flow. The model can be validated with pilot or industrial data and simulates the performance of hydrocyclones in a wide range of design and operating variables.

Jan 1, 1992

By J. J. Carlson

Studies were carried out to determine whether filtration rate changes observed in an iron ore concentrator were due to variations in particle shape. It was confirmed that ores mined from different locations differed in filtration rates by as much as 60%. However, when image analysis was used to quantify the shapes of the individual particles in the filtration feed, it was found that the particle shapes showed almost no variation, and the shapes did not correlate with the filtration rate. It was also determined that the filtration rate variations were not caused by changes in particle size distribution. These results suggest that the differences in filtration rate are due to factors other than size and shape, such as surface chemistry.

Jan 1, 2008

By Lynn B. Hales, Randy A. Ynchausti, Robert W. Colby

Process control systems have evolved from single loop control to distributed control with computer based expert control strategies. The next step is to add adaptive control to the expert control strategies. An object-oriented intelligent adaptive optimization approach is defined and simulated results are presented.

Jan 1, 1995

By Robert W. Bartlett

Pretreatment of sulfidic refractory gold ore by biooxidation in coarse-crushed ore heaps is a promising new technology, especially for low-grade ores that cannot afford pressure leaching or roasting. An algebraic equation for determining the economically optimum biooxidation of the sulfide minerals in the ore is provided that is based on the empirical biooxidation rate constant for the ore, the project&apos;s financial discount rate, the ore grades of both refractory and non-refractory gold, and the gold price. Then, the economically optimum duration of bioheap pretreatment, t$, is determined from its logarithmic relation to the optimum fractional extent of ore biooxidation, F$, through the ore&apos;s biooxidation rate constant. In doing so, it is assumed that the ore is adequately crushed and amenable to bioheap pretreatment and that the cumulative oxidation of the ore with time is known from ore testing so that the rate constant can be determined.

Jan 1, 1995

By J. M. Mutmansky

Introduction Since the Hardy Cross numerical algorithm was applied to the solution of mine ventilation networks, numerous developments have taken place in ventilation network analysis procedures. The Newton-Raphson method, the linear theory method and the second-order approximation method are three of the additional approaches that have been applied. The efficiency of a ventilation network analysis procedure depends not only on the method of solving the system of equations derived from ventilation networks but also on the method of deriving the equations through selection of the meshes. This paper investigates the impacts of three mesh selection methods on the efficiencies of four ventilation network procedures. The minimum-resistance spanning tree method is the most popular procedure for selecting meshes. The shortest-path method was suggested by Epp and Fowler (1970) for improvement of the Newton-Raphson method. The minimum-resistance-path method is suggested here as the third method of selecting meshes. The effects of these three methods on the Hardy Cross method, the Newton-Raphson method, the linear theory method and the second-order approximation method are analyzed in this paper. These network analysis methods have been summarized in the paper by Kim and Mutmansky (1991). Mesh selection methods A procedure for mine ventilation network solution based on mesh equations typically consists of two steps: • the mesh selection step and • the network solution step. The mesh selection step establishes a set of independent equations to solve the network. The resulting equations are nonlinear. One method of solving nonlinear equations is to linearize the equations and iteratively solve these linear equations. The four analysis methods previously discussed in this paper use this approach. The linear equations required for solution can be written in matrix form as: P•dQ = dF (1) where P is the pseudo-resistance matrix, Q is the quantity matrix, and F is the Jacobian matrix (Kim and Mutmansky, 1991). The efficiency of the solution method depends on the characteristics of the P matrix, which in turn depend on the method of selecting meshes. To understand the impacts of the mesh selection methods on the efficiency of the ventilation network analysis procedures, the characteristics of the P matrix must be understood first. The diagonal elements of the P matrix, m in number, are the sums of the pseudo-resistances of the branches contained in the m meshes necessary for solution. The off-diagonal elements are the sums of the pseudo-resistances of the branches shared by two meshes. For example, P12 (first row, second column element of the P matrix) is the sum of the pseudo-resistances of the branches common to mesh 1 and mesh 2. When solving the system of equations expressed in Eq. (1), three of the iterative procedures (the Newton-Raphson, the linear theory and the second-order approximation methods) use the direct factorization method (Burden and Faires, 1985) on the P matrix. When the direct factorization method is used, the computational efficiency is enhanced by larger diagonal elements and a sparser P matrix. Generally, the sparsity of the P matrix is more important than the size of the diagonal elements. There is no known mathematical method of predicting the efficiency of these procedures, but heuristic methods can be used to study the efficiency. The Hardy Cross algorithm applies the Gauss-Seidel method of splitting the P matrix and applies the Newton-Raphson procedure. The efficiency of the Hardy Cross method depends on the spectral radius of the matrix[[D-L]-1U], where D is the diagonal, L is the lower triangle and U is the upper triangle of the P matrix for the Newton-Raphson method (Ortega, 1972). The smaller the value of the spectral radius, the faster the convergence. As with the other three methods, larger diagonal elements and a sparser matrix aid in faster convergence. With the Hardy Cross method, however, the size of the diagonal elements is more important than the sparsity of the matrix. Remembering that each of the diagonal elements of the P matrix is the sum of the pseudo-resistances of the branches in a mesh and that each off-diagonal element is the sum of the pseudo-resistances of the branches shared by two different meshes, the following strategies can be used: • Avoid having branches with larger resistance values shared by multiple meshes. This increases the size of the diagonal elements and reduces the chance of off-diagonal elements being large.

Jan 1, 1993

By Guido Deissnann, Jennifer L. Kirkaldy, Stephan Kistinger, Carol M. Pettit

Contaminated mine drainage presents a potential hazard for aquatic ecosystems and groundwater resources. Reliable predictions of long-term developments in seepage quality are necessary to select reasonable decommissioning options and remediation measures for waste-rock heaps during mine closure and/or mining site rehabilitation to minimize future risks and environmental hazards. Extensive geochemical modeling work was used to assess the consequences of various remediation options for waste rock heaps at a former uranium mine in Eastern Germany. The predicted contaminant discharges are used for an assessment of long- term benefits of decommissioning alternatives to derive conclusions for sustainable remediation measures using risk-based cost/benefit analyses.

Jan 1, 2000

By Stanley Ferguson

Since 1978, the Colorado Department of Health has become involved in specific investigations of possible radiation hazards among nonminers in Colorado communities. In each instance, the improper disposal of mill tailings has precipitated concerns and allegations of radiation hazards. This presentation is a brief summary of the findings, to date, of 4 such investigations involving tailings disposal problems in Canon City, Denver, Durango and Grand Junction, Colorado. Canon City In the summer of 1979, allegations of excessive cancer incidence were made at public hearings concerning an application for a Radioactive Materials License submitted to the Colorado Department of Health by the Cotter Corporation for a uranium mill at Canon City. Canon City is the site of a uranium mill operated since 1958 by Commonwealth Edison. Local residents accumulated figures and calculated rates suggesting a 2-fold excess in total cancer mortality. These rates were not adjusted or standardized for demographic varibles. A review of cancer mortality data and computation of age standardized rates for years 1950 through 1977 showed that Canon City&apos;s cancer mortality rates were within expected limits, actually lower than rates for the State of Colorado or the United States. The first slide shows rates for every fifth year, 1950 through 1975. Further, an analysis of Canon City cancer incidence data from the Colorado Central Cancer Registry revealed that 1979 incidence rates were not significantly different from Colorado rates, with the exception of prostate cancer. The next slide shows age standardized incidence rates for lung, colon, breast and prostate cancer. Data were also reviewed for leukemia, myeloma, lymphoma and cancers of the thyroid stomach, uterine certix, ovary, kidney, bladder-and brain, however, small numbers of cases prevented meaningful rate calculation. 1980 data are presently being analyzed. None of the data yet examined support allegations of radiation-associated cancer in Canon City. Denver In February of 1979, the Department of Health became aware of a number of radium mill tailing deposits in the Denver metropolitan area, remnants of the radium milling industry of the early 1900&apos;s. Several of the deposits were situated so as to possibly contribute significantly to radiation exposure of a small number of people over a period of several decades. The Department developed protocols for radiation surveys, dosage estimates and, for a small number of persons, body burdens determinations and peripheral blood lymphocyte cytogenetic studies. The results of this investigation suggested no measurable biomedical impact as a result of the radium deposits. Durango In October of 1979, a physician residing in Durango, Colorado released information from a preliminary analysis of lung cancer data suggesting an incidence rate several times expected in that city. The data were presented at a meeting of a citizen&apos;s group concerned about the possible health hazards of 2 uranium mill tailing deposits located in the south end of the city. Since cancer incidence data generally do not exist in most of western Colorado, a team of epidemiologists was dispatched to Durango to work with local physicians and hospitals in conducting an epidemiologic study of selected cancers for the period 1969 through 1978. After case-finding and record abstracting were completed, it was determined that sufficient data were available for study of only 3 sites: lung cancer, breast cancer and leukemia. The next slide shows age standardized incidence rates for these 3 sites for 1969-1978 for Durango and the State of Colorado. There are no significant differences in these rates. The data did show a geographic peculiarity with regards to the relative proportion of tumor types near the tailings deposits as opposed to away from the deposits, however, this finding is based upon very small numbers of cases and may represent only the random excursion of rates based upon small observations. This investigation suggests that if a carcinogenic hazard is present, it is too small to be detected by the study method employed. Grand Junction The Department of Health has been involved in the Grand Junction mill tailings problem for several years. In 1966, the Department issued an order terminating the practice of free public access to a 55-acre pile of uranium mill tailings. Prior to this order, an estimated 300,000 tons of material was removed. Of this amount, an estimated 50,000 tons was presumably used in residential and commercial construction. Despite many allegations of cancer and birth defects excesses in Grant Junction since the mid 1960s, the first epidemiologic study of cancer was conducted in the spring of 1977. Data from the Colorado Central Cancer Registry were analyzed and reported to the Executive Director of the Department of Health in June of that year. The findings of the first and preliminary study were an unexplained excess of acute leukemia and chronic myelocytic leukemia. The excess was based upon small numbers but was present across all age groups. No increase in chronic lymphocytic leukemia was evident.

Jan 1, 1981