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By Hojong Kim, Isehaq Al-Nafai, Kwadwo Osseo-Asare

The standard Gibbs free energy of formation (ΔGo f, 298) of bastnasite, (Ce, La, Nd, Pr)FCO3, was estimated using four different methods. The obtained average values were − 1589.5 kJ/mol for CeFCO3, − 1599.5 kJ/mol for LaFCO3, − 1589.1 kJ/mol for NdFCO3, and − 1595.4 kJ/mol for PrFCO3. The value for cerium bastnasite, CeFCO3, was used to construct a potential vs. pH (Eh-pH) diagram to investigate the stability relations of cerium bastnasite. The diagram shows that CeFCO3 is stable in neutral to basic conditions (pH ~ 6.5–11).

By Raymond Philippe

Background ?Hatch Water has worked with most major mining companies in Chile on water supply and optimization projects ?Many(copper) mining projects are located in Northern Chile, which hosts the driest desert on earth Water supply options in Northern Chile ?River ?Availability/Rights ?Well(Brackish) Water ?Availability/Rights ?Municipal Wastewater ?Water rights ?Volume ?(Desalinated) Seawater ?Infinite source ?Cost depends on distance and altitude ?Recycling/Reutilization ?Water losses All these options present water quality issues

May 1, 2009

By Thiago Pinto Silva

A Usiminas implementou dois ensaios para caracterização de minérios de ferro na sinterização, intitulados assimilação e penetração de fase líquida. O primeiro tem como objetivo avaliar as fases mineralógicas, a formação de poros e a resistência mecânica de partículas nucleantes e aderentes por meio da reação do minério com o calcário. O segundo objetiva medir o comprimento da penetração da fase líquida formada entre a calcioferrita e o minério. No presente trabalho, são descritas as principais características e potencialidades desses novos testes, os quais foram utilizados para a avaliação do comportamento metalúrgico de seis minérios distintos. Os resultados obtidos de assimilação e de penetração da fase líquida foram comparados com as características mineralógicas e químicas dos minérios, sendo observada uma boa correlação entre essas características e os resultados dos novos testes. Verificou-se também que a análise tradicional do minério não é suficiente para estimar seu comportamento metalúrgico na sinterização, o que reforça a importância da utilização dos novos testes implementados. Além disso, permitem avaliar o comportamento dos minérios em altas temperaturas, auxiliando na escolha da carga de minérios mais adequada para a sinterização.

Aug 1, 2018

By R Stimpson, B Johnson, B Hesse

During a period of twelve months between FY18-19, a series of trials were conducted to compare production drilling accuracy using two different methodologies, and the subsequent impact this had on stope performance (dilution and recovery). Testing was conducted at a series of underground mines in Australia. The drill rig’s existing alignment processes were compared to a new technology system, with the following observations: • The new technology was proven to limit rig alignment error, thereby reducing average blasthole deviation, resulting in an increase in the number of holes drilled within tolerance by up to 160%. • The increased accuracy reduced stope dilution significantly by reducing over-break of subgrade ore, whilst also increasing drilled meters (faster stope-cycle time), reducing the bridged tonnes ratio, and facilitating the capture of previously uneconomical stopes. A cost-benefit analysis extrapolated from each of the trials showed the extent to which the new technology, when applied to production data, reduced average dilution, increased ore recovery as well as general drill and blast productivity. In one such trial, the new technology was proven to have reduced average dilution by net 45.4%, which if applied to a full year’s production data, would result in AUD8.2M additional ore recovered, with AUD4.5M less spent on wasted cost of haulage and processing of diluted ore. As a result, return per tonne would increase 22%, from AUD87 to AUD106. This improvement was maintained over the following 12 months – reducing average dilution from 22% in FY17 to 12.1% in FY19.

Mar 15, 2021

By Wesley, Worner H

During the meeting of the Institute last year at Port Pirie, the opportunity was taken to sample the lead bullion coming from the blast furnace and various stages during the refining process. Also, in the desilverising section, the upper zinc rich phase was sampled as the silver content built up and in the cupellation operation a series of samples was taken as the silver content of the bullion increased. In these two cases, the samples were taken under the supervision of a member of the staff of the Broken Hill AssociatedSmelters.In the following account of the microstructure of the samples taken, only the main phases present have received attention. In this connection deduction from phase diagrams of binary alloys has been used in conjunction with the assays carried out on duplicate samples taken at the same time as those for micro examination.

Jan 1, 1938

By Günter Huber, Bruno Mattle, Helmut Westermayr, Daniel Spöndlin, Max John, Nejad Ayaydin

PROJECT DESCRIPTION Alignment The Strenger Tunnel forms part of the S16 four-lane expressway between Landeckand Bludenz. The construction of this important East-West connection started in 1973with the Arlberg Road Tunnel as its key constituent. Beginning in 1992, solutions for the section between Pians and Flirsch were investigated. Efforts to conserve nature and to avoid potential avalanche and landslide areas led to a solution detouring the villages in the Stanz valley. The starting points were predetermind by the intersections at Pians in the East and at Flirsch in the West. As a result of the expected traffic load and the comparatively high gradient of 2.9%, both one-way, two-lane tubes were constructed at once. The north tube is 5.851 m long, the south tube 5.775 m, see Figure 1. Layout of Tunnel Cross-Section The tunnel cross-section was determined by 2 × 3.75 m wide, 4.70 m high roadways, two sidewalks and sufficient space for two fans above the clearance

Jan 1, 2005

By S. V. Burr

"A 28-year study of cross folds leads to the conclusion that the northwest-southeast folds recognized in many areas of North America are part of a regional pattern. Detailed examination of over 650 geological maps and reports of Ontario indicates that this folding can be traced across the province. Evidence is presented that this fold pattern played an important part in determining the pattern and scale of intrusion, that its recognition in the field can aid in defining stratigraphy, folding and faulting, and that it may have played an important role in channeling hydrothermal or magmatic mineralization. IntroductionThe concept of regional cross folding in Ontario is not new. W.H. Gross (1955) discussed regional cross folds in the Archean of Northwestern Ontario, and A.M. Goodwin (1961) referred to regional cross folds in the Archean of Ontario and Quebec. However, the interpretation in this paper is new.The writer saw a cross fold for the first time, underground, at Little Long Lac Gold Mines in Geraldton, Ontario, in 1951. This recalled the ""transverse folds"" on E.R. Faribault's classical maps of Nova Scotia, published by the Geological Survey around the turn of the century; M.E. Hurst's cross fold(s) at Timmins, Ontario (Figure I); and the cross folds mapped by A.W. Jolliffe in the Yellowknife area of the Northwest Territories. All these mapped cross folds had one thing in common with the fold at Little Long Lac: A northwest-southeast axial trend. Were such cross folds of purely local extent, or might they be indicative of a widespread regional fold pattern? If so, has such folding any significance for mineral exploration or potential?By 1959, based on a study of about 1000 Canadian geological maps and reports, including 291 in Ontario, the writer reached the conclusion that cross folding trending northwest-southeast is so widespread as to constitute a pattern of folding, and that such cross folding should produce changes in plunge along pre-existing greenstone fold belts."

Jan 1, 1980

By M. J. Howes

The high degree of mechanisation, which is mainly diesel-powered, has a significant effect on heat loads; heat output from this source often exceeds the heat flow from the surrounding rock. The extensive use of diesel-powered equipment also influences ventilation rates and minimum values are necessary to ensure that emissions of diesel exhaust are adequately diluted. Many Australian mines are in subtropical or tropical areas with high ambient wet- and dry-bulb temperatures on surface. This, coupled with the large amount of heat from mechanisation, usually means that refrigeration is required at much shallower depths. A secondary problem is associated with the definition of acceptable thermal environment conditions, which are sometimes based on the assumption of no air movement. This gives rise to very stringent thermal environment acceptance criteria, which, in some areas, would prohibit work on surface, let alone underground

Jun 12, 1905

By R. Pretorius, N. Mautsa

In a cobalt precipitation plant, phosphoric acid is used to eliminate excess uranium from the pregnant leach solution, resulting in a cobalt hydroxide product that has little uranium contamination. However, the amount of phosphoric acid added must be monitored and controlled to avoid financial and sustainability impacts and to prevent negative impacts on the final product quality. One possible solution to this problem is the use of online residual phosphorus measurement techniques to regulate the addition. By continuously monitoring the residual phosphorus levels in the solution, the plant can adjust dosing in real time to maintain the target residual phosphorus level. As a result, the cobalt precipitation plant can improve phosphorus level control, lowering the risk of overdosing, and ensuring consistent product quality. This approach can also improve process efficiency, reduce operational costs, and have a positive environmental impact

Jan 1, 2023

By D. Imeson, T. Grammatikopoulos, M. Aghamirian, M. Oliazadeh

"More than 70% of potash is produced worldwide by froth flotation. Flotation of potash was developed in the early 1930s. Amines are widely used for flotation of sylvite (KCl) from halite (NaCl) and insoluble materials such as clays. Amine collector is also absorbed by clays. Therefore, clays are usually separated by scrubbing and de-sliming prior to flotation. Alternatively, slimes can be floated ahead of potash flotation. Flotation recoveries of sylvite are commonly in the range of 85%, while losses can occur in slimes, flotation tailings and make-up of process brine. Ores containing free coarse-grained sylvite are generally screened, whereas both fine and coarse fractions are conditioned and floated separately. The unique features of potash flotation include solubility of sylvite in water, the size of particles floated and fast kinetics. Particles up to 2.3 mm can be floated and about 50% of flotation feed can be removed in the rougher stage in few minutes. The main challenges in potash flotation are the recovery of potash from slimes, flotation efficiency in the presence of carnallite and recovery of coarse potash grains. A review of potash flotation shows that there is still room for improvement in both coarse and fine potash flotation. The present paper reviews the most significant flotation parameters including reagent type and dosage, flotation circuits, flotation equipment size and new developments in potash flotation. The latter include new reagents, flotation technologies (Hydrofloat, Jameson and column cells) larger flotation cells and slimes flotation.INTRODUCTION Potash is the common industrial term for potassium in various chemical combinations and minerals soluble in water. About 90% of potash produced worldwide is used as agricultural fertilizers. Flotation is the main treatment process of sylvinite (KCl-NaCl) ores for recovery of sylvite (KCl). Potash concentrate should contain a minimum of 95% KCl and be relatively free from 0.2 mm KCl fines. The flotation process for beneficiation of potash ores was developed in United States and Russia concurrently in the early 1930s. In 1934, Potash Corporation of America applied flotation process in a commercial scale (Tippin R.B. and Huiatt J.L). In the initial application, halite (NaCl) was selectively floated by employing lead chloride as an activator and soap as collector. The sylvite concentrate was reported in the cell underflow."

Jan 1, 2012

By C. W. Davie

"This paper is the second of a series of progress reports4 on a study of the hydrometallurgy of manganese which is being conducted in an endeavor to make possible utilization of the large deposits of low-grade domestic manganese ores that occur in several States.There are at least four processes in which a knowledge of the action of SO2 gas on manganese oxides at elevated temperatures may prove of value.One of these involves dissolution of manganese from ores. The Bureau of Mines has investigated the hydrometallurgy of manganese by a process in which SO2 gas, a waste product at many smelters, is passed into water to form a solvent for manganese. Although several manganese minerals were readily dissolved, rhodochrosite (MnCO3) was attacked but superficially.5 Recent experiments have shown that a roast at 650 to 9000 C. converts the manganese of rhodochrosite to a form that is quickly dissolved by a weak SO2 solution.6 Introduction of smelter gases containing much as 5 per cent SO2 during such a roast would not add much to the cost of the operation, and might result in the formation of considerable water-soluble manganese sulpate.Another case involves a subsequent step in the hydrometallurgical process, namely, the formation of oxides of manganese with simultaneous evolution of SO2 by the heating of the MnSO4 produced by evaporating its solution.A third has to do with the roasting of zinc sulphide ores containing manganese as a preliminary to leaching. During purification of the solutions to be used for the electrolytic deposition of zinc the iron must be oxidized to make possible its removal. Manganese dioxide has been used for this purpose,7 and since manganese compounds are present in some zinc concentrates,8 it is of interest to learn what happens to the manganese in a zinc sulphide or on roasting, and what portion of the manganese in the roasted product might be available for oxidation."

Oct 1, 1930

By R. A. Gee, G. B. Ashton, S. T. Warren, P. N. Groves

Northside Storage Tunnel provides 500 megalitres (Ml) (130 million gallons) of storage capacity to capture stormwater/sewage overflows into Sydney Harbour. The6.6 m diameter TBM driven tunnel traverses Middle Harbour 85 m (280 ft) below sea level and through a sandstone/shale rock mass, highly disturbed by stress relief, 20 m(65 ft) beneath the base of the sediment filled palaeochannel. Target limits for inflow, groundwater drawdown and settlement of the valley beaches were achieved by systematic forward grouting from the TBM. Support included rockbolts, sets and shotcrete to carry rock loads, control block instability and spalling and to provide durability and serviceability. This paper describes the tunnelling and grouting works and their effectiveness.

Jan 1, 2001

By A. Nieto

A vehicle proximity warning–collision avoidance system is being developed using GPS and wireless local area networks to improve safety of off-highway trucks in open pit mines. After two-and a-half years of research, software development, and laboratory testing, field tests were carried out at operating limestone quarries and open pit mining operations to evaluate GPS accuracy and overall system effectiveness under rugged operating conditions. This article describes the progress made on this NIOSH-funded project and discusses the GPS accuracy tests and overall system tests that were carried out during the year 2001 at the Colorado School of Mines Survey Field and at the Morenci open pit copper mine in Arizona. Keywords: GPS, Advanced Mining, Virtual Reality, Wireless Networks, Proximity Warning

Jan 1, 2003

By D. B. Lovett

The work described in this report was directed toward identifying and devising methods to minimize the previously observed variability between working level hour exposures and the alpha particle track densities resulting on Track Etch films exposed to mine atmospheres containing radon and radon daughters. The disequilibrium between radon and its daughters was shown to directly affect this Track Etch film calibration factor. The wide range of disequilibrium states possible in mine situations amply explains the variability in the previous tests. A file of published mine atmosphere composition data was compiled and was used, along with atmospheric compositions derived from several theoretical models ref the atmospheric behavior, to evaluate the variability of several dosimeter configurations and concepts. A nonlinear, iterative regression analyse; was formulated that successfully predicted working levels to within 8 to 10% from only the alpha particle activities (Rn, RA, and RaC') data such as are obtainable from Track Etch films over a wide range of disequrlibrium conditions. A model expressing atmospheric concentrations as a function of radon source strength, plate out rate factor, ventilation rate and the fractional re-entry by recoil of previously platted-out daughters was derived and used in the regression program in addition to preparing a set of reference tables and graphs showing the disequilibrium behavior of the atmosphere. Other factors that can affect the Track Etch Film response writ considered and shown to he less crutial than the disequilibrium state. The results of a series of exposures of a dosimeter concept fixture in the Denver Mining Research Center radon chamber air presented and discussed.

Jan 1, 1976

Digital Simulation of Particulate Processes The inherent complexity of mineral particulates (shape, size and mineralogical texture) has challenged conventional simulation model approaches for decades. Much effort was expedited in using mathematical assumptions to accommodate stereological effect. With the advance of instrumental methods such as x-ray microtomography 3D structure can, in many cases, be measured directly. The information derived from such measurements provides direct input to building the structural digital model. In addition digital simulation methods that enable creation of process realistic particulate properties in an efficient digital computer space have demonstrated their effectiveness to model a variety of realistic packing, sorting and multi-phase processes. The paper reviews recent advances in the use of information derived from 3D micro-tomographic imaging and laser scanning technology can be coupled with digital methods to enable simulation of tablet compaction and dissolution, filtration and permeability, column packing and leaching kinetics, packing and cementation of nuclear waste. By assigning 'properties' to a digital zone (voxel) in the computational space it is possible to mimic the realistic characteristics of quite complex particulate mineral processing systems. The system self-adapts to correct the coherent particle characteristics (shape, size, compound, porosity) with time. Such simulations are useful to elucidate the sensitivity of system performance to variations in process parameters. Dimensional scaling of the approach is also possible, as the case studies will illustrate, in deploying the method to both small (micron) and large (m) features. The use of process realistic simulations presents experimental challenges in code validation. It is in this context that other tomographic methods play a role in direct 3D measurement of system behaviour such as electrical and optical sensors.

Sep 13, 2010

By C. F., Christopher

The purpose of any steel-making process is to convert the two raw materials iron and scrap into steel. The chemical analysis of the steel is set within certain limits which involve the physical proper- ties desired by the consumer. In addition to tensile properties a large number of other properties are at the present time desired, such as impact resistance, grain size regulation, specific degrees of hardenability, resistance to creep at high temperatures, resistance to expansion on heat treatment, the ability of the product to undergo extreme amounts of cold deformation without failure, and many other properties which are not directly related to the specified chemical analysis. Variations in many of the properties of plain-carbon steels are due to elements and compounds not included in the ordinary "five element"§ composition. Such variations result primarily from variations in oxidation of the metal in the furnace and from the deoxidation method employed. The steel-making problem therefore resolves itself into two distinct sections: (I) the elimination of certain elements from the charge (the iron and scrap entering the furnace) and the addition of materials to meet the chemical specifications for the heat; (2) the manipulation of the slag and metal and the process of deoxidation to give certain desired properties in the steel entirely apart from the chemical analysis specified. Each of 'these two ends must be attained

Jan 1, 1957

By J. C. van Dyk

The objectives of this study were firstly to characterize and quantify the inorganic material in the Secunda gasification feedstock. Secondly, the effect of washing on coal properties and sulphur content was investigated. Coal from a single source and a coal blend from 6 different mines were tested. Composite samples were visually sorted by a geologist in the groups containing roof, floor, C-shale, pyrite, carbonates and siltstone material. Inorganic mineral types from the single source and coal blends were characterized separately. Characterization results indicate that the average mineral matter distribution (mass %) of the coal tested was as follows: carbonates (6%), carbon-shale (19%), pyrite (12%), roof (18%), floor (46%) and siltstone (22%). The roof, floor, pyrite, carbon-shale, carbonates and siltstone in the single source and coal blend have similar chemical properties and characteristics, except for the ash melting temperatures of pyrite and kaolinite in the siltstone. By implementing selective mining and increasing mining management practices, the percentage discard in the run of mine coal can be significantly reduced, by up to 45%, if the mining of roof and floor material can be avoided. No significant impact of mining practices on sulphur content is expected in this case due to the low concentrations of sulphur in the roof and floor material. In summary, selective mining practices will probably result in almost45% decrease in the discard content in the run of mine to gasification, an increase in the carbon content from 55.0% to 58% (air dry basis) and a decrease in sulphur content from 1.1% to 0.9% (air dry basis). It is clear from this study that the main source of sulphur is not in the high ash-content mineral types (e.g. floor and roof), but in situ in the coal structure. Keywords: inorganic material, effect of washing, roof, floor, pyrite, C-shale, carbonates and siltstone

Jan 1, 2005

By I. A. Costa, Y. Fouquet, F. Barriga

"Lucky Strike and Menez Gwen are two hydrothermally active sites located along the border of the Azorean plateau, southwest of the Azores islands where the alteration processes affecting basaltic rocks are prominent (Costa et al., 2003). Here we report on a slabby brecciated rock, abundant at both Lucky Strike and Menez Gwen, composed mainly of basaltic fragments cemented by hydrothermal precipitates from warm fluid circulation system. Research reveals that hydrothermal alteration takes place mainly by replacement processes, in which silicification is dominant (Costa et al., 1997 and Costa, 2014).Petrographic observations, including scanning electron microscopy (SEM), microprobe analysis, and mass balance studies made on basaltic fragments within the breccia show that silicification is one of the main processes resulting from hydrothermal fluid circulation. This alteration process leads to complete replacement by silica, in extreme cases, forming an impermeable cap that may contribute to the formation of sub-seafloor sulphide deposits, including examples in the geological past."

Sep 1, 2014

By Donald E. Ralston

The Huntsville study area in northeastern Alabama consists of Jackson, Limestone, Madison, and Marshall Counties. Major emphasis was placed on the Huntsville urban area in Madison County to analyze the relationship of urban growth and the minerals industry. Huntsville was delineated into its component urban, suburban, and rural parts for 1964, and the primary area of growth was predicted for 1990. Population estimates were made for the four-county area as a unit and Madison County separately, and projected to 1990. Demand estimates for crushed stone and sand and gravel were made for the same area units and projected to 1990. Analysis of quarry sites in the Huntsville area was made for the present and for the future. The mineral operations of the study area are all located in rural areas; in the case of Huntsville, the mineral sites are located in areas defined as "rural" in the component urban-suburban-rural system. The operations outside Madison County can expect to have minor problems with urban encroachment, while those operations in Madison County can expect major problems associated with urban growth and development. Some of the problems associated with limes tone production can be reduced if producers invest in capital equipment that will reduce the nuisances inherent in this activity. Although urban expansion endangers some quarry operations in Huntsville, topographic and political restrictions which prevent urban expansion can effectively shield quarry operations for some time.

Jan 1, 1970

By George A. Page, Hewitt Wilson, Vance S. Cartwright

"Purpose of InvestigationThe process of removing solid material from liquid suspensions has been studied at the Northwest Experiment Station, United States Bureau of Mines, in cooperation with the University of Washington, as part of a general program to investigate the dewatering of Pacific Northwest plastic kaolins, which is difficult by ordinary filter-pressing methods. The present paper is a progress report of the work began by Vance S. Cartwright in 1928 and continued in 1931 and 1932. Spray evaporation is believed to be valuable for the following classes or grades of clay and clay mixtures:(1) Highly colloidal, plastic-type clays, which release their mechanically attached water with difficulty; (2) clays prepared for shipment in pulverized or powdered condition; and (3) synthetic, ceramic, porcelain, and tile mixtures prepared as aqueons suspension, dried and pulverized before molding. Dilute suspensions can be dewatered by spray evaporation to produce concen-trated casting slip or plastic clay with a lower water content.The most common dewatering method used in preparing powdered kaolin for the market comprises the following steps: Reduction of the water content by filter-pressing from approximately 75 percent in the thick ""slip"" condition to about 30 percent in the condition; further reduction of the water in the filter-press cakes by heat to about 5 percent; and pulverization of the dried cakes in hammer or dust. These three steps can be simplified to a single process by spray evaporation."

Jan 1, 1935