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By R. F. Chaiken

The Bureau of Mines has carried out experimental and theoretical studies with prilled and pulverized ammonium nitrate-fuel oil (AN-FO) mixtures containing varying amounts of fuel oil in an attempt to quantify the effects of stoichiometric composition, nonideal detonation behavior, and expansion volume on the production of CO, NO, and N02 fumes. Experimental fume measurements were obtained in the Bureau's large closed gallery facility (7.2 X 104 liter expansion chamber) and in the standard Crawshaw-Jones apparatus (90--liter expansion shamber) using a prepackaged charge configuration containing about 450 g of explosive.4 The theoretical calculation of toxic fumes was achieved with an equilibrium detonation code called "TIGER,," Contrary to initial expectations, the NOx (= NO + N02) fumes from the large gallery test were found to be in essential agreement with the Crawshaw-Jones results. It was also concluded that (1) "TIGER" calculations offer a good approach to the prediction of toxic fumes; (2) there is a basic problem in extrapolating laboratory measurements of CO fumes to mine conditions--this being due to postdetonation oxidation of CO to CO2; and (3) the detonation velocity decay rate of an explosive is a useful experimental parameter for correlating toxic fumes production with nonideal detonation behavior.

Jan 1, 1974

By R. Banda

This paper describes the decision to implement and then the implementation itself, through trials, of electronic ?Smartdets? over previously used shock tubes. It concludes that Mufulira Mine has become the first mine in Zambia to convert 100% of its stoping to ?Smartdets?, because the Mine?s management was prepared to look beyond the unit cost of product and were ready to look at the broader picture of cost effectiveness and increased productivity.

Jan 1, 2005

By D Chappell

Coromandel Peninsula gold mineralisation has an epithermal style which involves extensive alteration of host rocks and addition of pyrite over large volumes of rock. These altered rocks therefore have high potential for generating acid rock drainage. Natural acid groundwater discharges occur in altered rocks, but not in propylitically altered rock. There is little calcite available in mineralised rocks to neutralise this acid. In contrast, the mesothermal veins of the Otago Schist cause little alteration of the host rock, and that alteration has similar mineralogy to the host rock. Calcite is a common mineral in host and mineralised zones, and sulphides are generally subordinate. Hence acidification of Otago rocks is unlikely. This lack of acidification in Otago facilitates arsenic mobility in solution, up to hundreds of ppm. Arsenic is insoluble under acidic conditions in the Coromandel. Base metals are soluble under acidic conditions of the Coromandel, but they are immobilised by adsorption on to the widespread clay minerals where the solutions are neutralised. Base metals are generally immobile in Otago, but when they are mobilised, adsorption is less effectiveas an attenuation mechanism because clay minerals are rare.

Jan 1, 1998

By Francisco Sena Leite, Pedro Brito, Auã Kiahla, Raquel Carvalhinha, Tomi Kouvonen, Vinicius Miranda

Shockwaves that generate vibration in the surrounding environment of a blast, are one of the most important factors to control drill & blasting works near delicate buildings as well as in sensitive structures (wall control). On top of the damage to the buildings themselves, sensitive equipment such as computers, measurement apparatus and medical devices can be also compromised. The most commonly measured values from vibration are PPV (peak particle velocity), acceleration and displacement. Some devices and techniques have been developed in the last decades to measure the impacts of these vibratory phenomena. This information can be used to predict levels of vibration for future blasts and improve their quality of design using the attenuation law. From traditional studies to modern seismographs, a range of solutions are used for this propose. The main problem of applying this kind of technology is the high cost associated with each measurement device. In order to measure the ground vibration using new technologies while lowering the cost, a device has been developed using a microcontroller and electronic sensors commonly found on the market. This new equipment was tested side by side with traditional seismographs and the results were sent to a server for analysis. After several blasts, the necessary data was generated for the validation of the prototype. Through numerical mathematical processing (Taylor’s approach and numerical derivation) the original data supplied by the accelerometer’s sensors was transformed into velocity and, after the data mining, a statistics residue analysis was applied in order to evaluate if the data from the prototype and from the traditional seismographs were similar. The data from each system was used to estimate the attenuation law and the results are shown in this paper.

By K. V. Konigsmann

"Mattagami Lake Mines Ltd operate a zinc-copper mine with an annual output of about 200,000 tons of zinc and 30,000 tons of copper concentrates. Zinc concentrates arc shipped to a company owned smelter in Valleyfield (a distance of 690 miles), for Export to Quebec City and also to Josephtown, Pennsylvania (1,060 miles, Figure 1.)The protection of concentrates in open gondola rail shipments has been a matter of concern since operations commenced. Considerable financial losses did occur at times because of wind erosion. Operating difficulties were also encountered by customers because of excessive moisture accummulation in the concentrates. Test shipments made in 1969 established the magnitude of losses in open cars. The results and subsequent investigations at our mines and elsewhere confirmed that load protection is an economic necessity.Many types of covers were experimented with, more or less successfully. In 1972 we agreed on a joint program with Dupont of Canada Limited. A new type of cover was developed by early 1973. It has been in use since, undergoing several improvements as experience accumulates."

Jan 1, 1975

By H. Hamma, R. Fehrmann, M. Gaune-Escard, G. Hatem, S. B. Rasmussen, K. M. Eriksen

The molten salts M2S2O7and MHSO4, the binary molten salt systems M2S2O7-MHSO4and the molten salt-gas systems M2S2O7-V2O5and M2S2O7-M2SO4-V2O5(M = Na, K, Rb, Cs) in O2, SO2and Ar atmospheres have been investigated by thermal methods like calorimetry, Differential Enthalpic Analysis (DEA) and Differential Scanning Calorimetry (DSC). Fundamental thermodynamic data like temperatures and molar heats of solid-solid transition and fusion, phase diagrams, heat capacities of solids and liquids, heat of mixing, and heats of complex formation have been obtained and are reviewed here. Also EPR spectroscopic evidence of V(IV) complexes and their structure are reported and the results are discussed in relation to the mechanism of SO2oxidation by V2O5based industrial catalysts. Keywords: Alkali pyrosulfates, alkali hydrogen sulfates, vanadium pentoxide, EPR spectroscopy, complex formation

Jan 1, 2004

The 8 ft by 91/2 ft drive which joined No. 7 Shaft with Browne Shaft on the 1,480 ft level was extended from both ends and met at a point approximately 12,000 ft from No. 7 (2,000 ft from Browne).The surveying required for this 2 1/2 mile haulage drive called for greater accuracy than was obtainable from South Mine standard methods. Procedures and devices from published information were tried and modified as required to suit local conditions. Several new methods were applied and improved as the drive advanced. The control of angular, linear and level measurements was perhaps considerably in excess of the requirements, but this was offset by abnormally large discrepancies resulting from shaft plumbing. The accuracy of the final breakthrough, although not to the standard desired, was sufficient to complete the connection without inconvenience and added cost.INTRODUCTIONThe acquisition of the Browne Shaft leases in January 1962 presented the management of Broken Hill South Limited with the problem of transporting ore from these leases to its mill. It was eventually decided that diesel locomotivehaulage through a 2t mile drive on the 1,480 ft level between the two mines was the best solution. The drive was advanced from both ends after Browne Shaft was deepened by 80 ft to reach the 1,480 ft level horizon. Each end advancedabout 15 ft/day with the miners working three 7 hr shifts. Blasting was restricted to the end of the shift.The survey work involved five shaft plumbings and 78 theodolite stations in a traverse, underground and surface,of more than 5 miles. Because of the exceptional length of the drive, an unusually high degree of reliability was required.The aim was for a maximum error at breakthrough of 1 ft 1 in 30,000, and to secure this, precise methods of linear measurement were necessary. Shaft plumbing in particular posed special difficulties.

Jan 1, 1965

By T. E. Wakefield

Over several decades in Southern Africa the advance rates when sinking vertical shafts have declined significantly. The upside has been a substantial improvement in shaft bottom conditions and a commensurately improved safety performance, with an increasing number of shafts being sunk without fatalities and disabling injuries. This paper briefly reviews historical sinking rates and matches changed sinking productivity to the introduction of new sinking methods that have been adopted to eliminate/mitigate safety risks. Meeting the challenge of returning to historical advance rates whilst progressing in the quest for zero harm by utilizing three dimensional animated computer modelling is described. Making use of commercial modelling software makes it easier to evaluate different methods, sequencing, in shaft barrel ergonomics, and stage and shaft bottom layouts before procuring project plant and equipment. Benefits accrue not only in better communicating methods and configurations for detailed planning and design, but also during crew training. The traditional engineering ?as-built? drawing practice has been extended to the concept of an ?as executed? sinking model which seeks to capture operational experience and learning for future best practice. The paper concludes with some of the organizational culture challenges being overcome as this non traditional approach to shaft sinking optimization is being introduced.

Jan 1, 2009

By Steve Dillingham

In every aspect of conduct, on the blast site or off, the issue of credibility is raised. Promises are made, commitments are satisfied, safe practices are obeyed, communication is maintained, and proven procedures followed. Only by fulfilling these objectives, are we deemed trustworthy and reliable - in other words - credible. Unfortunately, at times, we fall short of achieving our goals. Whether intentionally or accidentally, everything is not completed according to plan or accuracy. On the blast site, falling short of achieving such goals may contribute significantly to a chain of events that can potentially produce accidents. At the very least, a blaster’s credibility will be jeopardized. The fact remains that the blaster that continuously conducts business in a professional manner will less likely find him or herself as a defendant in future claims.

Jan 1, 2003

The compilation of the sampling nomogram is an essential tool in the optimization of a sampling protocol and allows the operator to track the change in relative variance of the sampling error (the Fundamental sampling error) during steps of comminution and mass reduction in the process of recovery of the aliquot for analysis. The data required for the compilation of the nomogram are centred on the sampling constant K and the exponent, alpha (a) of the nominal fragment size. Five methods for establishing K have been identified, but two of them, the duplicate sampling analysis method and the heterogeneity test method purport to provide such constant. The step by step procedure for each of these two methods was examined using broken ores from three mines, Mponeng mine, Kloof mine, and Lily mine. Two of these mines (Mponeng and Kloof) are typical Witwatersrand-type gold mines, and the third is an Archaean-type shear related gold deposit situated in the Barberton Greenstone belt. The results suggest that the factor K derived using the heterogeneity test is very accurate, but applies only to a single size fraction in the spectrum of comminuted materials. The calculation of gold grain sizes using this method appear to be too small and do not conform with the results from detailed mineralogical studies. The factors K and alpha derived using the duplicate series analysis are appropriate for use across a wide spectrum of comminution sizes and also provide realistic gold grain sizes, comparable with the equivalent circular diameter of gold grains identified in mineralogical studies of the ores.

Jan 1, 2010

By M. G. Zabetakis

This publication contains highlights of a 4-hour lecture and demonstration by the Bureau of Mines on the fire and explosion hazards of flammable liquids and solids, oxidizing materials, corrosive liquids, and compressed gases. The authors first presented this material as part of a 2-week course given to officers and enlisted men at the U.S. Coast Guard's Dangerous-Cargo Handling School, established at Fort Eustis, Va., in 1959. The Bureau was asked to present the lecture and demonstration because of the extensive experience of its researchers in handling certain harardous commodities.

Jan 1, 1961

By M. Radwan, S. Shimada, S. Z. El-Tawil, K. A. El-Barawy, Y. Miyamoto

This study presents the results of synthesizing monolithic siliconoxynitride, Si2N2O, ceramic from a mixture composed of reclaimed silicon and natural desert sand by using the nitriding combustion synthesis method. Single-phase Si2N2O powder was prepared by the combustion of a mixture composed of silicon and pulverized sand in 3 MPa nitrogen gas. The combustion reaction completed in 2 min and the combustion temperature reached 1577°C.The as-synthesized Si2N2O powder is agglomerate of fine particles with sizes < 5 µm and has various morphologies; rod-like and irregular crystals, irregular kinking, hollow crystals and grown pseudo-hexagonal prismatic crystals. Porous Si2N2O compacts (24.5–47.1% porosities) were fabricated from the synthesized Si2N2O powder at different calcia-alumina additives (5–20 wt%) by normal sintering at 1500°C for 1 hr in N2atmosphere.They showed superior oxidation-resistance at high temperatures up to 1500°C in an oxidizing atmosphere of Ar/O2/H2O(70/20/10 kPa).Near-full dense Si2N2O compacts were also successfully fabricated from the synthesized Si2N2O powder with 5 wt% oxide additives by using the spark plasma sintering at 1600°C.DenseSi2N2O had good mechanical properties (18.7 GPa Vickers hardness, 3.3 MPa.m1/2fracture toughness and 363 MPa strength) and excellent chemical and oxidation resistance.

Jan 1, 2004

By Marshal Scherba

Coal seams approximately 7 feet, 9 feet and 20 feet thick at depths of 250, 600 and 1,000 feet respectively were detected using high resolution seismic reflection techniques. Investigation of seismic profiles indicates that good data are required to delineate faulting with only 20 feet of throw but that faulting with 50 feet of vertical displacement can be detected with poor data. Data acquired from dynamite charges fired in water saturated media were clearly superior to that acquired using charges dry tamped in 10 and 20 foot holes.

Jan 1, 1977

By K. Y. Haramy, R. O. Kneisley

This U.S. Bureau of Mines report summarizes a study of large-scale strata response to longwall mining at a western U.S. coal mine. This study utilized surface and subsurface measurements, geologic mapping, in situ stress measurements, and pressure cell readings to characterize strata behavior. Preliminary analysis of surface subsidence and time-domain reflectometry (TDR) was used to determine a suggested main roof caving sequence. Coal ejected from the face apparently resulted from brittle failures that occurred because of lack of significant yield zone development. The combination of a strong coal with pronounced directional behavior, low overburden pressures, a good caving roof, and a high-production environment that minimized time-dependent loading apparently reduced yielding of the longwall face. The panel 1 headgate-entry design appears adequate; however, the abutment pillar and adjacent panel tailgate rib are highly stressed and may contribute to problems during second panel mining. The small chain pillar yielded after passage of the face, but the pillar width may be near maximum since evidence of a stressed core exists.

Jan 1, 1992

By Lucia Kuizon

The Cactus Springs Roadless Area Review and Evaluation (RARE II) study area (No. A5188) comprises 12,800 net acres (5,180 ha) in San Bernardino National Forest in west central Riverside County, California, about 20 air miles (32 km) southeast of Palm Springs. Mineral investigations are made by the U.S. Bureau of Mines on National Forest lands identified as Further Planning Areas in the RARE II program. The Bureau of Mines reviewed literature, mining claim records, and production files; examined the study area; and mapped and sampled mineral properties where appropriate.

Jan 1, 1983

By Phillip R. Moyle

A cobalt/manganese occurrence in Clark County, Nevada was the subject of a site-specific mineral investigation by the U.S. Bureau of Mines in 1988-90. The study site is in the northern part of the Million Hills (wilderness) study area which is administered by the Bureau of Land Management. Field work during a period of one week consisted of geological mapping and sampling of workings and outcrops, and geochemical and geophysical surveys conducted on four transects totalling 7,600 ft. Although the concentrations of cobalt (0.1 to 0.5 percent) detected in samples from the fissure zones are within the range of grades associated with world-class economic deposits, the volume of material enriched in cobalt at the study site is insufficient to warrant consideration as a potential resource. Concentrations of manganese, nickel, copper, lead, zinc, barium, and thallium, although anomalous, are too low for economic consideration. At the study site, workings consist of three trenches and nine pits. The exploration history is unknown, and no production is reported.

Jan 1, 1990

By A. Boominathan

The behaviour of single piles under lateral dynamic loading is very critical and the study is still a current field of research since 1950&apos;s. Though many methods have been developed analytically to estimate the dynamic lateral stiffness, very limited dynamic testing on full scale piles were carried out to study the response of piles under lateral dynamic loading. Hence, field lateral dynamic vibration tests are conducted on driven precast concrete square pile of 400mm size and driven cast in-situ concrete piles of 400mm and 500 mm diameter at a petrochemical complexes site at Haldia (India). The results of steady state and free vibrations tests are discussed herein and compared with the response of the piles estimated from PILAY.

Jan 1, 2002

By Daniel Mallette, Richard Goodridge, C M. Lownds

Despite a world of mobile devices that has many of us taking the ability to communicate wirelessly for granted, an in-hole wireless initiation system was thought to be not viable. The known and common wireless communication techniques are not suited to this application. To overcome this, we have developed cutting edge technology to communicate to our initiating devices more than 1km through solid rock.

Jan 1, 2016

By Russell Griffin

The current state of the art of fire and smoke detection technology is reviewed from the standpoint of suitability for use in under- ground metal and nonmetal mines. Detection modes, fire signatures, and environmental considerations are included. Preliminary results of long- term, in-mine tests are presented.

By Brock Wallis, Steve Davidow

The following text will present the concept of rock socketed drilled shafts used to support electrical substation structures, and discuss the cost and schedule risks that traditional design responses to unforeseen shallow rock can pose to a project. Design considerations will be detailed, including rock characterization, shear strength of drilled shafts, and modeling lateral resistance of the shaft and surrounding rock. The specific case of drilled shafts installed for heavily loaded structures at the Moxie Freedom Substation will provide an example of how close collaboration between the engineer and contractor to refine designs based on site-specific feedback can provide tangible benefits to the project. In this example, value engineered designs resulted in an approximate 40% reduction in shaft/concrete volume and a 60% reduction in total rock socket depth. PROJECT OVERVIEW The Moxie Freedom Project included the construction of a new 500 kV switchyard in Berwick, Pennsylvania. The foundation contractor was selected to install both small and large diameter drilled shaft foundations to support the structures within the switchyard. The small diameter shafts were utilized to support transformers, switches, bus supports and a static mast, while the large diameter shafts were used to support one 180-foot monopole and six H-Frame structures. CHALLENGES: ROCK SOCKETED DRILLED SHAFTS Available geotechnical data at the time of bid included limited borings and seismic refraction. The borings were not located at every structure, and the contractor and design engineer were left to interpret desktop studies and geophysics to determine the probable site-specific conditions at each foundation. The data suggested substantial variability in the quality and depth to bedrock across the project area, indicating significant risk of deep embedment into bedrock at all seven large diameter shaft locations. Rock socketed drilled shafts pose unique challenges for both designers and contractors, and the topic has become a focus of national foundation organizations. Traditional design models result in deeper and/or larger diameter shafts where rock is encountered. In the case where site-specific geotechnical conditions are not clearly understood and rock is encountered at shallow depths, this can lead to significant additional rock drilling, impacting overall project cost and schedule. Rock drilling can result in more than ten times the cost of soil drilling and can easily take in excess of ten times longer to excavate.

Jan 1, 2018