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By Allen Garrison

IT is the purpose of this article to present. the results of an investiga-tion of certain clay and shale suspensions having viscosities that are materially influenced by fluid motion, and to discuss the bearing of these results, upon the choice of policy in the control of drilling fluids. A previous article described the design and the characteristics of an instru-ment adapted to measure the viscosity of plastic suspensions during continuous uniform motion and at a variety of speeds.1 It has long been recognized that the viscosity of a clay suspension depends on the past history of the fluid motion. Since an abundance of literature is available on this phenomenon,2 it is not necessary to describe it in more than general terms. It is usually observed that rapid motion reduces the viscosity of a clay suspension, and that some time is required for the viscosity to fall to its equilibrium value after the steady motion is started. On reducing the speed of motion to some lower value, the viscosity again rises, but it also requires some time to attain a steady viscosity value at the slower rate of motion. Thus clay suspensions are usually observed to be increasing in viscosity as time passes when the measurement has been immediately preceded by fluid motion that was more rapid than that employed in the measurement. And it is usually observed that the viscosity falls as time passes when the measurement has been preceded by more quiescent conditions. Reed,3 and Broughton and Hand4 have reported a condition of observa-tion of clay suspensions in which the viscosity was observed to fall during the first few moments of steady motion, and rise thereafter. The characteristics of the new instrument are particularly well adapted to studies of this kind. With it we have been able to observe all of the phenomena described above, and it is important to understand their nature because they all occur at some time during normal drill-

Jan 1, 1939

By W. B. Weeks, H. K. Shearer

The year 1937 brought to south Arkansas increased drilling activity and production. Oil production amounted to 12,159,440 bbl., an increase of 1,504,500 bbl., or 14.1 per cent over 1936. This was the largest production since 1931, and the first annual increase since 1925, when the deeper sands at Smackover were developed. There were 177 wells completed during the year, with 103 oil wells, 6 gas wells, and 68 dry holes, an increase of more than 100 per cent over 1936. Of the 56 wildcat wells drilled, 52 were dry and 4 produced oil. Two new fields, one important extension and three minor extensions were discovered. The trend toward deeper drilling is shown by the fact that 97 wells were more than 5000 ft. deep, including 80 over 6000 ft. and 13 over 7000 ft., although the depth record of 7973 ft., made in 1935, was not exceeded. Geological Section Deeper and more extensive drilling during the past few years, not only in south Arkansas but also in adjacent parts of north Louisiana and east Texas, has furnished much important geological information and has brought out some very unexpected facts in regard to structural and depositional conditions in the series of formations laid down in the interval between the end of the Pennsylvanian and early Cretaceous time. It is now evident that an important basin of salt deposition existed in the Arkansas-Louisiana-Texas area, but it is still an open question whether this salt basin was contemporaneous and continuous with the even larger Gulf Coast salt basin extending from Mississippi to Mexico. The accompanying columnar section (Fig. 1) shows the producing zones and names that have been applied to the several subsurface formations, most of which have no outcrop equivalents. This is for the convenience of readers unfamiliar with recent developments, but the correlations and nomenclature cannot yet be considered final. These formations will be discussed in more detail in various papers to be published in the near future.

Jan 1, 1938

By Robert Phelps

A STUDY of solid solutions has long been a source of interest because of the conditions -controlling their formation. X-ray investigations so far have been conducted with the idea that there were two types of solid solutions. In the first type, an atom of the solute was supposed to replace an atom of the solvent in the crystal lattice. In the second type, an atom of the solute was supposed to lie in one of the interstices between the atoms of the solvent. These pictures both require that the sizes of the atoms must play an important part in the process of solution. It is the purpose of the present investigation to study the mechanism of solid solution, using pure silver as the. solvent, and pure aluminum as the solute. X-ray measurements show that these elements have the same "shape" of atomic domains (they both crystallize as face-centered cubes) and that their atomic diameters differ by less than one per cent.1 The results of the present investigation point toward a chemical rather than a physical picture of the nature of solid solution, and make the older' pictures merely special cases of a more general picture. The new theory has the advantage, too, that it offers a rational explanation of certain phenomena which hitherto have been only interesting detached facts. The aluminum-silver system which was, chosen for this study has been studied by various methods by several workers. By means of thermal analysis Gautier2 and Petrenko3 have determined the phase diagram. Hansen4 studied the aluminum-rich alloys by means of thermal and microscopic analyses. , He showed that at high temperatures silver dissolved in aluminum to the extent of 47 per cent by weight at 5600 C. But this solubility decreased to 1 per cent at 200° C. Westgren and Bradley5made an extensive X-ray study of these alloys. They used the change in the lattice parameter of silver as a criterion of the solution

Jan 1, 1932

By C. H. Loux

This paper deals primarily with the advantages realized from the adoption of methods more suitable than those previously used. The improvements noted include: (1) modification of practice in shrinkage stoping, (2) use of sublevel caving over grizzlies, (3) improved haulage and loading, (4) use of contract wages wherever possible. The Washington mine is on Jonestown Hill, one mile south of Oxford, in northwestern New Jersey. It is producing 16,000 tons of concentrates a month, which are being shipped to the Alan Wood Steel Company's furnaces at Swedeland, Pennsylvania. History The first settlement in this region is reported to have been in 1735, and the magnetite ores were recognized immediately. The first furnace, built in 1741, began operation in 1743. During the Revolutionary War the output was chiefly used for making cannon balls, which, owing to the sympathies of the community, without doubt found their way into the hands of the British. This old furnace is still standing. Several important veins were soon developed, including the Martin, Strayley, McKinley, Adelaide, Welsh and Lanning. Mining was carried to a depth corresponding to the capacity of the pumps available. When these became inadequate, the workings were abandoned, and another vein was opened up. The Washington vein was probably discovered about 1850, and the first shaft started in 1854. In 1879, William H. Scranton made the first complete magnetic survey of the district and serious exploration of the deposit was begun. Rather indifferent success attended the earlier efforts of the many companies that attempted to mine and smelt the ore. In 1929 the property was leased by the Warren Foundry and Pipe Co. to the present operators, and the modification of practice then inaugurated is described in this paper. Geology These veins, like most eastern deposits of magnetite, are formed from, or are contemporaneous with, pegmatite intrusions into a gneissic country rock. The ore therefore follows the banded structure of the gneiss,

Jan 1, 1934

By N. E. Maccallum

Almost half a century has passed since the Siemens brothers, after tedious and costly experiments, finally began the manufacture of open-hearth steel. The furnace of that time was very small, having a hearth-capacity of from 3 to 4 tons, and we can appreciate the wonderful development that has taken place in those 50 years by the knowledge that to-day furnaces of 50 times the original capacity are in operation. As the new steel process assumed importance, and furnaces began to grow in number and in size, a question arose, to which no satisfactory answer has ever been given, and that was: aWhat is the safe and economical limit of the open-hearth furnace ?" Various stopping-places have been suggested, and 20, 30, 40, and 50 tons have each been advocated, but all such arbitrary restrictions have been passed, and 60 tons would probably represent the average furnace, although in a few instances from 70 to 80 tons are regularly tapped into one ladle. The furnaces which are the subject of the present paper have gone far beyond even these limits, and since, in my opinion, they mark another step in the progress of open-hearth steel, they will be considered fairly and frankly, in order that those to whom the matter may be of interest may be able to judge and form their own conclusions. Short accounts of the work of these furnaces have appeared from time to time in various technical journals, of which the following is a brief résumé. These furnaces are the property of the Phoenix Iron Go., of Phœnixville, Pa., and their distinctive and important feature is, that they charge to twice the capacitl of one ladle, and tap simultaneously into two ladles, with a device for controlling the flow into either. In this way the capacity of the furnace is not limited, as formerly, but heats of any size within the capacity of two ladles may be charged.

Jan 1, 1913

By W. H. Andrews

The constantly increasing consumption of Portland cement in the State makes the above subject of particular interest at this time. The increasing demand is due to the rapid settling of the country and the fact that new uses are being found frequently for the above named commercial article. The industry is one that is bound to grow as the population increases, and this being the case it may be well at this time to consider briefly the matter of the chemical and physical composition of proper raw materials. A cement mixture is one that contains approximately 75 per cent, carbonate of lime, 15 per cent. silica, and 5 to 7 per cent. alumina and iron oxides; the other elements being magnesium carbonate and mall quantities of the rarer elements generally associated with limestone deposits. It can be readily seen from the above composition that it is possible to build up this mixture from a number of different materials. First.—A rock high in carbonate of lime can be mixed with clay or shale in such proportions as to bring about the desired composition ; the chief difficulty in the building up of such a mixture is that it is hard to find a clay or shale in which the silica-alumina ratio lies between 4 to 1 and 3 to 1 and at the same time shows physical characteristics which will make certain its adaptability to the practical manufacture of Portland cement. Very often clays or shales are found which are right chemically but contain large quantities of grit or free silica. Such clays or shale must be ground to extreme fineness in the mixture in order to make the silica and alumina combine with the lime when the mixture is burned. On the other hand, clays or hales are often found that have the proper physical characteristics but in which the amount of alumina is too great. Second.—A mixture can be built up of different limestones some of which run above the 75 per cent. requirement and others below;

Jan 1, 1914

By John Garcia

THE presence of carbon de terre along the banks of the Illinois river was noted by the members of the Joliet and Marquette expeditions in 1673, and that may be referred to as the birthday of coal in the Middle West. The march of progress in the majority of indus-tries radiating from Chicago-one of the phenomena of history-is due in no small measure to this same carbon de terre and to the development and exploita-tion of the vast coal resources, which nature in a generous mood spread so lavishly over almost the en-tire state. The geological records indicate that coal-bearing rocks underlie three-quarters of Illinois, in-cluding 85 of the 102 counties and the entire area is estimated at from 36,000 to 42,000 square miles. Not all of the coal in this great area may be mined under the conditions existing today; producers are now taking the "cream" since industry demands the best quality and the lowest cost, thereby forcing competition among operators, which, in turn, com-pels the development of mines in those areas where the coal may be most readily .won, leaving the coal that is more difficult and expensive to mine to pos-terity. This is not such a bad arrangement, since the engineers of succeeding generations will enjoy the advantage of the experience of their ancestors, where-by they should profit and know how to mine a 2-ft. seam with as much economy and dispatch as we today work coal of thrice that thickness. During the period between 1830 and 1850, Illinois coal-mining progressed from the art of scratching along the outcrop to the development of small mines, mostly slopes, drifts and shallow shafts, but the real progress in the industry was coincident with the con-struction of railroads.

Jan 2, 1927

Lewis, B. LINDEMUTH, ?New York, N. Y.-I would like to confirm Dr. Howe's supposition that a process could be worked out for steel along similar lines. About 1 ½ years ago, F. D. Carney and myself were working on the elimination of columnar crystals which are particularly evident in nickel steel. We discussed rotation and varying speeds of rotation, but figured that with just rotation the steel would eventually catch-up to the motion of the mold and that the desired effect could not be obtained in that way, so we decided to alternate the direction of rotation. We rigged up in ordinary commercial turntable and on the same mounting attached a blast, furnace and mud gun, which is a simple steam cylinder, and mounted an 18-in. ingot mold on the turntable. The turntable had a stroke of about 10° to 12°, with stops at the ends. The steam cylinder would bang the table against the stops so that the stopping was so violent that it would tend to keep the metal in motion when the mold stopped and thus wash away any crystals that would form. We made quite a few interesting experiments; the results of which were that the columnar crystallization was entirely eliminated. At the same time we cast ingots in a similar mold, allowing the molds to remain stationary; these showed columnar crystals of from 2 to 4 in. in depth. The grain structure of the balance of the ingots, which were rotated, was very much finer than the grain structure of the ingots that were cast and allowed to cool slowly. The experiments were made on a 0.35 per cent. carbon nickel steel, which is probably more susceptible to columnar crystallization than any other. I think that the rolling properties and the forging properties of some alloy steels could be very much improved by a similar method, or some commercial method of casting ingots to eliminate this columnar crystallization.

Jan 5, 1919

By J. T. Hayward

Studies of the forces and conditions governing the recovery of petroleum from natural reservoirs indicate that a low gas-oil ratio increases ultimate recovery, retards the encroachment of water and tends to reduce lifting costs. Methods for controlling and reducing gas-oil ratios in producing wells consequently have been given considerable attention during the past few years. However, during this same period, the production from wells in nearly all fields has been fixed by proration agreements and it is the opinion of the writer that where a well is required to produce steadily at a predetermined rate, less than its "potential" or maximum capacity, the gas-oil ratio will depend only upon the rate of production, and will be independent of the method of production and of the design of equipment in the well. If no change in the rate of production is contemplated, efforts directed to improving the gas-oil ratio by altering the diameter of the flow string, changing the position of the choke, assisting the flow with gas-lift or pump, etc., will be unsuccessful. This viewpoint is not new. It was presented by H. N. Marsh and B. H. Robinson in 1929,' but it has not been generally accepted. Although engineers believe that the rate of withdrawal and not the equip ment used governs the water-oil ratio, a similar opinion regarding the gas-oil ratio is not so commonly admitted. The rates of flow of oil and gas into the base of an oil well depend upon the following conditions: 1. The characterist-ics of the oil and gas. 2. The characteristics of the underground reservoir. 3. Temperature and pressure conditions in the reservoir. 4. The back-pressure held against the face of the sand. In operating a well, the only one of these conditions over which control may be exercised through operating procedure and the use of equipment above the sand is the back-pressure at the face of the sand. Strictly speaking, the back-pressure varies over the face of the sand, owing

Jan 1, 1932

By A. B. Tanner

The effects of radon in drillholes on gamma-ray logs have been described by L. S. Hilpert and C. M. Bunker1 Since these effects may cause drastic error in the evaluation of uranium deposits, it is useful to know the conditions under which significant amounts of radon tend to accumulate in drillholes. In the studies described here, atmospheric conditions were found to dominate in the control of the behavior of radon in drillholes in the vicinity of a uranium orebody. The site of the investigation was in McKinley County, New Mexico, about 12 miles north of Grants. Drillholes of 4 1/4-in. diam, on 25-ft and 100-ft centers, penetrate ore in dry rock at a depth of about 100 ft. A geologic log of the drillhole of primary interest is shown in Fig. 1. Gamma-ray logs revealed three zones of ore-grade mineralization in the Todilto limestone. A 6-ft zone, the lowest of the three, assayed 0.20 pct U3O8 by chemical analysis. The limestone ores in this area contain disseminated uraninite and some yellow and orange secondary minerals. Only radon"", a member of the uranium'" series, was measured in this investigation. Radon is one of the chemically inert noble gases and is radioactive by alpha particle emission with a half life of about four days. In this discussion, amounts of radon are expressed in microcuries (1 microcurie equals 37,-000 disintegrations per sec) and concentrations of radon are expressed in microcuries per liter of drillhole air. Samples of air were obtained by lowering a sampling device (Fig. 2) into a drillhole and actuating the device at the desired depth. It was then raised to the surface and the sample was transferred to a storage tube. Within two days the sample was transferred to an ionization chamber, and the activ- ity of radon and its short-lived daughter products was measured at radioactive equilibrium with a vibrating-reed electrometer. The measurements were corrected back to the time of collection and involve errors estimated generally not to exceed + 5 pct to —15 pct. Radon Behavior in a Covered Hole: Fig. 3, a typical log of radon concentration vs depth in the covered drillhole, was made by using values of radon concentration at discrete depths. Continuous logs of alpha-particle radiation in the drillholes showed that such radon logs depict the continuous variation of radon concentration with depth quite accurately. Three features of radon logs were noted: 1) maximum

Jan 1, 1960

By H. W. Hitzrot

THE new 4800-ton fine-grinding plant at the Hollinger Consolidated Gold Mines property at Timmins, in the Porcupine district of northern Ontario, went into operation in November 1937, and represents the culmination of an experimental program. The plant is a moderately low rectangular building of hollow tile on a steel frame, large enough to house four 7 by 15-ft. ball mills, with a 12 by 27-ft. classifier beside each mill. At one end is space for the addi-tion of another mill and classifier or a mill and classifier for the regrinding of table concentrates. This regrinding is now done in the old grinding department of the main mill building. Also within the new building are the four 6-in. sand pumps for lifting the product from the low-dis-charge ball mills up to the classifier feed launders and the containers and appurtenances of a complete dust-collecting system. Together with the usual overhead crane, these constitute the major units of equipment within the new plant. The location is at the lower end of the main mill buildings toward the old tailings pond, now so neatly leveled off and sodded to rival the very best of our own W.P.A. projects. Close by the new grinding plant is a large dome-shaped structure-the new fine-ore bin designed and built by Mr. Longmore and the Hollinger milling and engineering staffs. There are four separate automatically loaded inclined belt conveyors leading up from the bottom of the bin to the grinding plant. Each belt is equipped with a recording weightometer, in the grinding building. The whole structure and the machinery within it give the impression of permanence and a carefully integrated design with close attention to details, giving the operators every advantage for consistently good work.

Jan 1, 1939

Crushed limestone is now being "de-dusted" at the Warner Co. plant in Bellefonte, Pa., by a new high-efficiency classifier utilizing aerodynamic principles not previously employed in classifiers. Crushed limestone for certain glass industry requirements must not have more than 10 pct fines in the overall aggregate, and it is the function of the new-type classifier to separate these fines from the coarse material. During the development of this classifier by the Buell Engineering Co. of New York, it was found to have possible applications for separating pulverized coal, sintered metals, ores, mineral flours, and fillers, among other items. Limestone from Warner's deep mine is initially crushed and particles larger than 3/8-in. mesh are burned in kilns to provide calcium oxide for the chemical industry. The 3/8-in. screenings are dried and crushed to -16 mesh for use by the glass industry. For those applications requiring a minimum of fines, no more than 10 pct -100 mesh material is allowable in the end product. Hence the need for high-efficiency separation.

Jan 11, 1960

By M. L. Hammond, G. M. Bowers

Silicon dioxide films have been prepared on silicon wafers by the oxidation of SiH, near 400°C. Results previously reported by Goldsmith and Kern7 have been qualitatively corrobovated using a system of different geometry, and significantly greater deposition rates have been achieved. The deposition rate is independent of thickness and nearly independent of the O2/SiH, ratio over a wide range; however, the rate is strongly temperature-dependent. The structure of the deposit depends upon the cleanliness of the substrate, and the electrical field strength of the deposited oxide depends upon the nature of the electrodes. MULTILEVEL interconnects in integrated circuits using aluminum metallization require an insulator that can be deposited at low temperature. Because the A1-Si eutectic is only 577°C, the maximum deposition temperature must be below about 500°C to prevent reaction of the aluminum with the silicon and with other materials in the integrated circuit. Many methods of depositing insulating films of SiO, and other dielectrics have been reported'-6 but the technique described by Goldsmith and Kern7 offers the simplest method of preparing SiO, films. The technique involves the reaction of SiH, and 0, to form SiO, films in the 300" to 500°C temperature range. Previous work using this gas system has been reported8 and the initial development work at Philco Microelectronics was done at the East Coast R&D Laboratories. 9 This paper corroborates some of the results of Goldsmith and Kern,7 shows that much higher deposition rates can be obtained than previously reported, and presents some observations on the structure of deposited SiO, films. EXPERIMENTAL CONDITIONS Fig. 1 is a schematic drawing of the apparatus used in this study. It differs from that of Goldsmith and Kern in that 1) the gases are mixed before they enter the reaction chamber, 2) there is no fritted glass diffuser, and 3) the wafers are stationary during deposition. The control thermocouple was in a well located 0.06-in. from the substrate, and three gas supplies were used: 1 pct SiH4 in N 2, O 2, and N 2. Water vapor must be excluded from the plumbing to prevent the formation of colloidal SiO, and the SiH4 must be diluted with an inert gas because SiH4-0, mixtures are extremely flammable above about 4 pct SiH The wafer temperature was determined by attaching a thermocouple to a test wafer and the temperature was maintained to +5 C. The conditions used in this investigation are listed in Table I. The temperature range was chosen for compatibility with the A1-Si system. The volume ratio of 0, to SiH4 is the actual volume of 0, delivered to that of SiH4, taking into account the initial dilution of the SiH4. This ratio, which was used by Goldsmith and Kern,7 is a useful indicator of the experimental conditions. The active/inactive ratio is the ratio of the volume of active gases, SiH4 and O2, delivered to the volume of dilution gas. The active/inactive ratio is an important parameter to specify for deposition rate determinations since it determines the amounts of reactants that arrive at the sample per unit time. Fairly high dilution ratios were necessary to achieve uniform deposits of SiO,. Most of the process characterizations were performed on the polished (111) face of 3 to 5 ohm-cm, n-type silicon wafers which were 0.009 in. thick; but the data approximately apply to deposition of SiO, on thin films of aluminum. It is difficult to obtain accurate deposition rate data over aluminum films because of coarsening the aluminum surface during exposure to 300" to 400°C. The deposited SiO, film fol-

Jan 1, 1969

By C.F. Pascoe, H.J. Roast

The object of this investigation was to compare the arsenical antimony-lead alloy with some of the regular bearing-metal alloys. With this end in view, the following tests were made: 1. Chemical analyses to show the composition. 2. Thermal analyses. 3. Macroscopic examination of fractures. 4.Microscopic examination. 5. Tensile tests. 6. Crushing tests. 7. Scleroscope tests.' 8. Brinell tests, at temperatures from 80' to 400' F. Tests 3 to 8 were conducted on both sand-cast and chill-cast specimens. For the purposes of this paper the alloys have been numbered from 1 to 6; their composition is as follows: Lead. ' Antimony, Tin, CoppeR ARSEnic, NumBeR PeR CENT. PER CENT. PeR Cent. PeR CeNt. PeR Cent. 1 82.64 12.95 4.40 0.01 none 2 27.54 9.04 59.87 2.65 none I 3 none- 0.13 ------------1.47 4 82.95 16.85 none 0.20 none 5 83.78 15.35 none 0.05 0.82 6 0.15 7.87 . 84.13 7.85 none The analysis, in the case of the antimony, was made by solution in sul-furic acid and titrated with permanganate. For tin, the ferric-chloride method was used; for copper, the alkaline separations, and the thio-cyanate methods; for arsenic, volatilization of arsenic and titration with iodine. The lead, with the exception of alloy 6, was taken by difference. With the exception of No. 5, the alloys were taken as received from the manufacturer. About 40 lb, were melted in a graphite crucible and recast into small ingots to insure uniformity of composition; samples

Jan 1, 1923

By C. F. Pascoe, H. J. Roast

The object of this investigation was to compare the arsenical antimony-lead alloy with some of the regular bearing-metal alloys. With this end in view, the following tests were made: 1. Chemical analyses to show the composition. 2. Thermal analyses. 3. Macroscopic examination of fractures. 4.Microscopic examination. 5. Tensile tests. 6. Crushing tests. 7. Scleroscope tests.' 8. Brinell tests, at temperatures from 80' to 400' F. Tests 3 to 8 were conducted on both sand-cast and chill-cast specimens. For the purposes of this paper the alloys have been numbered from 1 to 6; their composition is as follows: Lead. ' Antimony, Tin, CoppeR ARSEnic, NumBeR PeR CENT. PER CENT. PeR Cent. PeR CeNt. PeR Cent. 1 82.64 12.95 4.40 0.01 none 2 27.54 9.04 59.87 2.65 none I 3 none- 0.13 ------------1.47 4 82.95 16.85 none 0.20 none 5 83.78 15.35 none 0.05 0.82 6 0.15 7.87 . 84.13 7.85 none The analysis, in the case of the antimony, was made by solution in sul-furic acid and titrated with permanganate. For tin, the ferric-chloride method was used; for copper, the alkaline separations, and the thio-cyanate methods; for arsenic, volatilization of arsenic and titration with iodine. The lead, with the exception of alloy 6, was taken by difference. With the exception of No. 5, the alloys were taken as received from the manufacturer. About 40 lb, were melted in a graphite crucible and recast into small ingots to insure uniformity of composition; samples

Jan 1, 1923

By N. L. Hancox

Previous researchers have used the cutting and rejoining model to represent a porous body when attempting to place Archie's law on a theoretical basis and calculate rock permeabilities (F = Ø-m, where F = formation factor, = - porosity and m = a constant). In using the model, a porous solid is assumed to consist of sections with parallel sides containing straight. continuous pores of total porosity 4 (pore to total volume or, for a homogeneous body, pore to total area). The joining of pores at an interface between two sections is assumed to be random which results in a common pore area Ø2. This reduced area Ø2 is then taken as that area which limits electrical conduction or fluid flow in the body. Agreement between experimental results and results calculated using a model is not always good Because of this, various modifications of the model are presented — for instance, the random nature of the joining is questioned. Formation factor measurements on specially constructed porous specimens are described in this paper. it is concluded that the common pore area limits flow completely only if sections containing straight pores are very thin, and that, in most natural materials, the common pore area at an interface must be greater than that given by random joining. However, the model is still useful in permeability calculations, provided that the fractional area limiting flow is determined from formation factor measurements. INTRODUCTION Two important properties of porous media are permeability k, which describes the ease with which a fluid can flow through a porous medium, and formation factor F, defined as the ratio of the resistivity of a saturated specimen to the resistivity of the saturating liquid which describes the electrical properties of the saturated material. k is defined by Darcy's law,l k= µqL/P Ae . . . . . . . . . . . . . . . [1] where µ = liquid viscosity, q = flow rate, L = length of specimen, p = pressure across the specimen and = - the effective area over which flow occurs, F is given experimentally by Archie's law,2 F = Ø-m ,..............(2) where 4 is porosity defined as the pore to total volume or, for a homogeneous body, the pore to total area; and m lies between 1.3 for loose sand and 2 for cemented sand. Consider a porous body of total cross-sectional area A and length L, saturated with a liquid of resistivity R and with an effective area for conduction of Ae. Then, from the definition of F given previously, F=A/Ae , ................(3) or, from Eqs. 2 and 3, Ae = A Øm ..............(4) Thus, in any attempt to calculate k or F, some assumptions must be made concerning the pore structure of the body and a value derived for A,. To determine Ae, Childs and George3 and Wyllie and Gardner4 suggested an elementary statistical representation often referred to as the cutting and rejoining model of a porous body. The body is assumed to be composed of two or more parallel-sided sections of porosity 4, containing straight, continuous pores with a common pore area of Ø2 at an interface between two sections. The value is given by a random joining of the pores in either section. Two such sections,

Jan 1, 1969

By Arthur F. Taggart

The following conclusions on the work of the Hardinge mill are based on data furnished to the writer by the Hardinge Conical Mill Co. in the form of the mesh cards hereto appended. Energy units (E. U.) and relative mechanical efficiencies (R. M. E.) are computed by the "volume method" of Stadler.' Screen apertures used are the average apertures of testing screeps of the meshes given. i . Card 122. June 28, 1912. Vipond Porcupine Mines Co., Ltd., Schumacher, Ont., Canada. Ore from mill bin. Gangue, quartz and basalt. 4.5 ft. by 13 in. ball mill, Capacity, 48 tons per 24 hr. Charge, 4,000 lb. balls. Speed, 33 rev. per minute. Horsepower, 15 to 17. Water, 100 per cent. by weight. (50 per cent. ?) Product deslimed and oversise reground in pebble mill, see Card 113. Feed to mill through 2-in. mesh. Mesh Feed, Per Cent. Discharge, Per Cent.. + 1in. 5.50 ....... + 3/4. 28.00 + in. 30.00 ...... + 1/4in. 19.72 ....... + 10 10.87 2.10 + 20 2.42 8.00 -20 3.51 .....,. + 40 ....... 22.68 + 60 ...___ 10.50 4-80 ....... 11.80 + 100 ....... 3.90 -100 ....... 40.15

Jan 1, 1916

By A. J. Griest, A. P. Young, P. D. Frost

A study was made of the effect of ß grain size on the tensile ductility of a-ß titanium alloys haet treated to strengths in the range 165,000 to 180,000 psi. It was concluded that the primary cause of $ embrittlement is the large grain size which is obtained so rapidly in many a-ß titanium alloys when heated into the ß field. It was also found that grain-boundary a and acicular intragranular a in the microstructure are not necessarily detrimental to the tensile ductility if the prior ß grain size is sufficientlv fine. BETA embrittlement occurs in a-ß alloys when the finish hot-working or stages of the subsequent heat treatment have been done at temperatures in the ß field. In order to avoid this embrittlement, for-gings must be finished at temperatures under the ß transus. For better workability, it would be desirable to forge at temperatures in the ß field. For this reason, research has been conducted to determine the cause of ß embrittlement. Although ß grain size has been considered as a possible contributing factor to ß embrittlement, only limited research has been done to evaluate its effect. The effect of addition elements on ß grain growth in unalloyed titanium has been studied by Liu.' Complete mechanical property data, however, were not obtained for correlation with grain size. Ogden and coworkers2 have investigated the effect of both a and ß grain size and grain shape in Ti-Cr-Mo alloys. Their data indicated that tensile ductility was relatively insensitive to ß grain size at annealed strength levels (140,000 psi ultimate). No study has apparently been made to determine the relationship between ß grain size and ß embrittlement in a-ß alloys heat treated to high strength (180,000 psi ultimate). The high-strength condition is that in which ß embrittlement is particularly severe. Beta grain size is not easily varied through the use of a range of annealing times and temperatures in the ß field, because of the rapidity with which ß grain growth occurs. Short-time heating techniques are needed to obtain the smallest ß grains. EXPERIMENTAL PROCEDURE In this research, the experimental procedure was as follows: 1) Tensile and microimpact specimen blanks were resistance heated to produce a range of ß grain sizes. 2) The tensile and microimpact blanks were then solution-treated in the a-ß field and aged to produce predetermined ultimate tensile strengths in the range 165,000 to 180,000 psi. Tensile and impact ductility were then correlated with a grain size for constant strength levels. Materials—The alloys Ti-6A1-4V, Ti-4A1-4Mn, and Ti-16V-2.5Al are representative of the heat-treatable a-ß types in which ß embrittlement can be severe. The compositions and ß transi of the heats studied are given in Table I. The Ti-16V-2.5Al heat was melted and fabricated to 1/4 in. round at Battelle; the other alloys were obtained as 1/4 in. round rolled from commercial heats. The micro-structures of the as-rolled alloys were fine a-ß mixtures. This structure is typical of titanium alloys hot-worked extensively in the a-ß field. Resistance-Heating Treatments to Establish ß Grain Size—For direit resistance heating, a 1/4-in.-diam s~ecimen was heated with a 3000-watt transformer rated for 1000 amp with adjustable secondary voltage. The apparatus included a spray quench fixture. Both heating and quenching periods could be automatically controlled. For temperature measurements, 28-gage Chromel-Alumel wires were tack-welded to the specimen at its midpoint. A high-speed recorder-controller was used to control the heating cycle.

Jan 1, 1960

By Hans W. Schreiber, David W. Neuhaus

INTRODUCTION The Sunshine Mining Company's 16-to-1 silver deposit and mine project are located 384 kilometers (240 miles) southeast of Reno and 360 kilometers (225 miles northwest of Las Vegas, near Silver Peak in Esmeralda County, Nevada, at an elevation of about 2,300 meters (7,000 feet). The deposit was being developed, in 1980, with an anticipated mining and milling rate of 150,000 tons per year (500 tons per day). Mining is by underground, blast-hole open stoping with rubber-tire haul-age out of the mine to a straight cyanide plant about 5.5 kilometers (3.5 miles) from the mine. The product is a gold-silver dore which may be further refined at Sunshine's new refinery in Kellogg, Idaho. The cash required for investment was obtained through the sale of $25 million worth of 6 l/2h silver-indexed bonds. Some $15.0 million were directed toward development of the 16-to-1 Mine. These bonds, which were underwritten by Drexel Burnham Lambert of Chicago in April of 1980, are redeemable on or after April 15, 1985 or payable at maturity on April 15, 1995 at the greater of either $1,000 or the market price of 50 ounces of silver. Behre Dolbear acknowledges the kindness of the Sunshine Mining Company (Sunshine) for allowing the presentation of the subject material for this Case Study. APPLICABILITY AS CASE STUDY Reasons for Choosing 16-to-1 The reasons for choosing the 16-to-1 Mine as a case study follow: 1. The project is simple and compact. 2. The mine is small -- thus relevant to other contemplated precious metal operaions in the western states. 3. The areas of risk are readily identifiable. 4. A change to project financing was under consideration. 5. A substantial decline in the price of silver was experienced during development. 6. Behre Dolbear undertook one of the first feasibility studies of The 16-to-1 and thus has some familiarity with the project. Historical Summary The following history serves as a setting: 1. Late 1920s -- minor "production"(?) via shallow pitting. 2. Mid-1930s -- neighboring Nivlok Mine successfully put into production. 3. Late 1950s (?) -- Callahan Mining Company acquired rights and drilled -- results inconclusive; Callahan turned property back to Arthur Baker, who had originally interested Callahan in 16-to-1 on the basis of its similarity with Nivlok Mine.

Jan 1, 1985

By Jerry B. Newby

In the central Ohio area well completions and new production each increased 60 per cent. in 1928 over the previous year. Gas wells increased only 27 per cent. The ratio of dry holes to total completions was unchanged. Ashland County led with 113 completions; a new pool in the shallow Berea sand near Jeromesville stimulated activity. Licking County in the Clinton deep sand territory, however, lead in new production with 972 bbl. Two other deep sand counties followed closely, Coshocton with 831 bbl., and Muskingum with 718 barrels. The Trenton rock or Lima field of northwestern Ohio declined sharply in oil well completions to 130 for 1928 from 210 for the previous year. New production increased from 3000 to 6100 bbl., the increase coming from the Murphy pool in Liberty township, Seneca County. The total of gas wells was unchanged as compared with 1927. The ratio of dry holes to total completions rose from 13 per cent. in 1927 to 27 per cent, in 1928. The largest producer in the Murphy pool made 1200 bbl, in the first 24 hr. The total depth of the wells in this pool averages 1475 ft.; average initial production, 125 barrels.

Jan 1, 1929