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Just as Australia is part of the Pacific Rim, so the Pacific Rim should be viewed as part of the whole world. That applies in particular to that scarce commodity û money. There are five main factors of production in any mining development û mineralisation, materials, manpower, management and money. LetÆs focus on the upstream input û mineralisation, and the downstream input û money, especially in the area of communications. Unknown to many, the Competent Person reporting on Mineral Resources and Mineral Reserves has a direct and unavoidable impact on the companyÆs financial statements û the profit and loss account and balance sheet. With respect to reporting of the major asset of most mining companies û the resources/reserves û investors are getting a better deal now than at any time in memory as regards flow and adequacy of information. Australia has been a world leader in this regard. The outlook is for even more informative and useful reporting. The more rigorous reporting requirements for Exploration Results and Mineral Resources/Reserves, which have become a worldwide phenomenon over the last five years, will continue. This will be positive for the mining industry as a whole and for Australia in particular. However competition for the scarce investment dollar will also increase. Put simply, mining has many competitors, unconnected with mining, for the capture of the investment dollar. It behoves all participants to recognise that there are three investment factors which influence strongly the willingness of investors to put money into mining. These are Confidence, Credibility and Consistency. AustraliaÆs investment image stands high in these three respects, but the competition will continue to grow. AustraliaÆs lead must be maintained. However, some investment decisions should not necessarily be based on fundamental, quantifiable facors. Some of these are outlined.

Jan 1, 2004

The recent trend of installing flotation cells with volumes as large as 200 m3 in concentrators is driven mainly by economic considerations such as lower capital, operating and maintenance costs. Despite the economic advantages, the metallurgical benefits from these large cells have not yet been fully realised by the industry. This is mainly due to the lack of understanding of cell operation, viz cell mixing and hydrodynamics, gas dispersion and froth transportation behaviour in large cells. There is still no rational basis for selecting optimum cell operating conditions and down-the-bank operating profiles. The relationship between cell operating conditions and metallurgy is not well established. This has resulted in poor utilisation of cell capacity in many operations. The present trend of installation of fewer cells in a bank requires each cell to be operated very efficiently. Optimisation of cell operation provides an opportunity for significant metallurgical improvements in a flotation circuit with minimal capital expenditure. Extensive work on optimising of cell performance has been carried out at various Teck Cominco operations in Canada, Peru and USA. Three different levels were involved in this work. The first level was aimed at identification of cell operating conditions for optimum mixing and hydrodynamics, gas dispersion, entrainment and froth flow behaviour in individual cells. The objective of the second level was to identify the optimum bank operating profile for cells down the bank in a circuit. The third level then focused on controlling these cell operating conditions and bank operating profiles for tighter control of concentrate grade and recovery for optimum bank metallurgy. This paper presents some of the major findings at all three levels and demonstrates the importance of each level in optimising the performance of flotation banks installed with large cells.

Jan 1, 2005

The reasons for using SFRS, including the way a SFRS performs in comparison to plain shotcrete as a support element in mining tunnels, are discussed. The mechanisms by which steel fibres reinforce shotcrete and the need for specifying performance criteria are highlighted. A description of current testing procedures, including an overview of æquantitativeÆ design recommendations provided from various international authorities, is provided. A summary of international recommendations on suitable æqualitativeÆ performance classifications is also reviewed, including a critique of their suitability. Finally recommendations on the practical considerations necessary to ensure good quality, in-place SFRS, are made, including a calculation method for determining minimum steel fibre dosages.

Jan 1, 1999

By N Voller, A Ishmurzin, G Hackl, M Wu, A Kharicha, M Chintinne, C M. G Rodrigues, A Ludwig

Slag fuming (SF) is a critical process for recycling zinc-containing slags, but the corrosive nature of molten slag poses challenges to the reactor durability. The freeze-lining (FL) technique offers a solution by forming a protective layer on the reactor wall. It requires intensive cooling using watercooled jackets, which can stabilise the FL while compromising the energy efficiency of the process. This study presents a computational fluid dynamic (CFD)-based model to optimise the SF process by considering FL formation and its impact on heat transfer and reactor wall temperature. A volumeof- fluid (VOF) model is coupled with a mixture continuum (MC) solidification model to capture the intricate multiphase flow dynamics within the SF furnace. Two FL types are considered: FL solidifying on the reactor wall in the slag bath region; and FL solidifying on the reactor wall in the freeboard region. The FL of the first type forms when the slag temperature drops below liquidus temperature. The FL of the second type only forms when a splash-induced slag droplet collides with the freeboard wall and solidifies. A series of splashing events are necessary to coat the freeboard wall. The simulation was run until a global energy balance was reached. This means that the heat losses from the water-cooled jacket, bottom wall, outlet and fuming balance the heat gains from the hot gas injected through the submerged plasma torches. The increase in FL thickness, due to its low thermal conductivity, reduces the heat losses through the reactor walls. The calculated FL thickness and heat fluxes were in good agreement with industrial data, validating the model’s credibility. The simulation results provided valuable insights into the fuming process, including slag bath temperature evolution, slag splashing dynamics, FL formation patterns, local heat fluxes through the reactor wall and overall energy balance. These findings can inform process optimisation strategies to enhance the energy efficiency and sustainability of SF operations. The authors have built a prior version of the model framework and applied it to simulate FL formation in an electric smelting furnace (ESF). The results from both the ESF and the current SF highlight the applicability of such model framework to a range of industrial processes involving FL formation. This model framework can ultimately contribute to more energy-efficient and sustainable industrial operations.

Aug 21, 2024

By Rashchenko AF, Voiloshnikov GI, Elshin VV, Khomutov VV

The sorption method for the precious metals recovery fromsolutions and pulps are a perspective trend of modernhydrometallurgy. Russian gold mining industry uses thesemethods, anion-exchange resins being applied as sorbents. Theanion exchange resins allow effective recovery of preciousmetals, however, they have several drawbacks as compared withactivated carbons: high cost of sorbents; difficulties arisingduring treatment of pulps with complex ion composition;necessity of using titanic equipment and thiourea for gold elutionfrom loaded anion-exchange resin and its regeneration.

Jan 1, 1993

By P Kumar, J Safarian

Understanding how ore interacts with flux particles at elevated temperatures to create molten slag is crucial since it governs the dynamics of a chemical reaction. This study explores the smelting behaviour of pre-reduced Nchwaning manganese ore when combined with lime, with the objective of examining the evolving interaction between pre-reduced ore particles and lime over time. The research sheds light on the interaction between solid and liquid and the phases that emerge during this process. To achieve this, a sessile drop furnace was employed to rapidly heat the materials positioned adjacent to each other on an alumina substrate and to observe the smelting process as it unfolded over time. This method allowed for the direct observation of the melting temperatures and the flux-ore reaction progression rate, and the potential disruptive events that might occur. By comparing the molten interfaces of the fluxed materials at various time intervals, this study provides insights into the relative rate of slag formation from the two materials. The results indicate that the main slag formation initiated at approximately 1400°C and continued to advance with time, with complete mixing occurring around 1500°C. The possible phases formed were identified using Scanning Electron Microscopy and modelled using Fact Sage thermodynamic software. In addition, the iron particles in the pre-reduced Mn ore were separated and settled from a rich MnO-containing slag. It was found that the separation of molten iron droplets from the slag depends on the rate of solid MnO particles dissolution into the adjacent slag phase.

Jun 19, 2024

By P Ireland, S Mitra, G Evans, A Wang, M M. Hoque

This work presents an experimental study of flow dynamics in a bubble column system (crosssection: 100 mm × 100 mm) using a non-intrusive optical technique with targeted application in a novel REFLUX™ Flotation Cell. The study had two aims – measurement of the bubble size distribution (BSD) and local energy dissipation rate in the system due to bubble motions over a low range of gas flux varied from 0.02 to 0.08 cm/s without impairing the visibility of the system. A central bubble plume was generated by injecting compressed air through a sintered glass distributor in quiescent liquid. Highspeed shadowgraphy imaging was performed to determine the BSD in the presence of surfactant (Sodium Dodecyl Sulfate (SDS) concentration ~ 10 ppm). The BSD exhibited a unimodal shape at different locations of the column for all gas flux cases. A non-intrusive particle image velocimetry (PIV) technique was used to quantify the flow field generated by the bubble motions, which was used to estimate the local energy dissipation rate. The local energy dissipation rate exhibited an increasing power-law dependency on the gas flux.

Aug 24, 2022

By R L. Verburg, R Johnstone

DeBeers Canada Mining Inc (DeBeers) recently submitted an Environmental Assessment (EA) for its proposed Snap Lake Diamond Mine located in Northwest Territories, Canada. As part of the EA process, a site water quality management plan must be developed. Plan development requires an integrated approach such that the key factors influencing water quality can be identified and managed to minimise potential impact. A system model was therefore developed to simulate the site-wide water quality conditions and mass loadings to the principal environmental receptor of concern, Snap Lake, during operations and post-closure. Requirements of the simulation included integrating hydrology, geochemistry, hydrogeology and site management practices in a dynamic way. A unique feature of the site was the need to accommodate a complex flow system that included a feedback loop between lake water and mine water. A system model was constructed using the GoldSim software package that integrated on-site water quality and flow measurements, as well as results from independent groundwater flow and geochemical modelling efforts. The GoldSim model simulated concurrently the movement of 39 solutes through the subsurface mine and surface facilities. Solute sources considered included four different waste rock and tailings types, explosives use in the mine, treatment plant discharge, and recycled process water for dust suppression. Separate solubility constraints were identified for different regions of the flow system (eg underground mine; treatment facility; surface water bodies). Kinetic test data were used to derive temperature-dependent rate constants for use in calculating mass inputs from surface sources such as waste rock piles. The model generated water quality estimates over time for a variety of management scenarios at several potential discharge locations. The integrated approach used by the model was effective in identifying the significance of key factors influencing overall water quality such as explosives use, mine water inflow rates, waste rock reaction rates, site/mine management options, and effectiveness of treatment. The model provides an example of an effective tool for comprehensive, integrated system evaluation and management.

Jan 1, 2003

By C E. Loo

The cohesive zone has a significant influence on blast furnace operation and performance. The high-temperature behaviour of the reducing ferrous burden determines the properties of the cohesive zone and is studied in a laboratory using a softening and melting test. This paper summarises recent work aimed at better understanding the physico-chemical changes in a ferrous bed during softening and melting. Using a combination of standard, non-standard and quenched tests supported by optical image analysis, this work has highlighted some important differences in behaviour between lump, pellets and sinter as well as between the two lump ores and two acid pellets. As with the two lump ores, one pellet is denser than the other and the denser ore/pellet is also higher in silica.Within the cohesive zone, densification of the ferrous layer leads to reduced permeability and greater pressure drop. From the work presented in this paper, two key mechanisms of ferrous layer densification were identified. Firstly, the formation of fayalite, which melts at low temperatures, can act as a lubricant between particles and lead to densification of the ferrous layer under load. Secondly, reduction to metallic iron is topochemical and fayalite in the outer shell of the particle restricts gas flow to the centre and results in the formation of a wustite core. As temperatures rise, the wustite melts and eventually exudes out of the shell, occupying void spaces between particles and further reducing layer voidage and permeability.This work has shown that density and silica content are two key factors that result in increased densification of the ferrous layer. For porous Australian lump ore, the higher porosity and lower silica reduces the formation of fayalite and limits the formation of the wustite core, ultimately leading to a more permeable bed. The difference between the porous and dense ores was more pronounced with the introduction of prereduction to better simulate blast furnace conditions. This suggests that a porous ore gives significantly better cohesive zone permeability and blast furnace operations than a dense ore.The behaviour of fluxed sinter particles is different in that the silica reacts with lime to form dicalcium silicate. Minimal wustite core forms because relict hematite particles in sinter are only small and reduction occurs uniformly throughout the particle. Even with significant loss of material through prereduction, beds formed from sinter remained comparatively rigid. Studies using a typical blast furnace burden mix of 80 per cent fluxed sinter and 20 per cent porous ore showed that the structures of these beds at softening and melting temperatures are very similar to the sinter-only test. Measurements of bed contraction and pressure drop also confirmed that the introduction of 20 per cent porous ore into a sinter bed did not alter its properties. This is an indication that 20 per cent ore can be easily accommodated by blast furnace burdens.CITATION:Loo, C E, 2015. Important acid ferrous burden properties in the cohesive zone of a blast furnace, in Proceedings Iron Ore 2015, pp 367–376 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By S Sineva, E Jak, M Shevchenko, D Shishin

This study represents a part of comprehensive research aimed at integrating nickel into a thermodynamic database constantly developed at Pyrosearch. The behaviour of Ni in calcium-ferrite slags is considered. An integrated approach combining experimental and thermodynamic modelling methods has been employed to predict phase equilibria in the NiO-CaO-FeO-Fe2O3 system under oxidising conditions and in equilibrium with the metal FeNi phase. The compositions of liquid slags and coexisting solid solutions have been determined through the analysis of equilibrated and quenched samples by electron probe microanalysis technique (EPMA). The research results are presented in the form of liquidus projections on the corresponding phase diagrams, considering both oxidising and reducing conditions. The solubility of Ni in spinel, dicalcium ferrite and calcium oxide as well as solubility of Fe and Ca in Ni monoxide, have been examined under several atmospheric conditions. Additionally, the compositions of the NiO-FeO monoxide in equilibrium with metal phase have been studied. The experimental data not only support the outcomes of thermodynamic modelling but also validate the parameters of the applied thermodynamic models, thus confirming the reliability and accuracy of the integrated approach.

Aug 21, 2024

By J R. Manuel, M J. Peterson

Selected drill core samples from a Ferrobamba-limestone-hosted, magnetite-haematite skarn deposit, located in the Apurimac department of the Andahuaylas-Yauri skarn/porphyry belt of south-eastern Peru, were mineralogically and texturally characterised to gain a preliminary indication of the deposit's potential as an iron ore resource. Optical microscopy, X-ray diffraction (XRD) and scanning electron microscopy/electron probe microanalysis (SEM/EPMA) techniques were utilised to determine the characteristics of magnetite, haematite and/or goethite dominated ore types, including variations in the relative proportions and textural relationships of the ore and gangue minerals. The deportment of elements deleterious to processing performance (eg copper, sulfur and potassium) was determined and the beneficiation potential of the samples was briefly assessed. In drill core sections, the ores are grey to reddish in colour, massive and 'metallic' to dark brown and earthy in character, moderately hard and porous (macro and microporous), with variable gangue infill. Ores often appear weathered, typified by ochreous goethite staining and common minor goethite (except in dense core fragments), occasionally exhibiting a more friable texture with coarse magnetite/martite grains. Silicates and lesser carbonate gangue are visible as blue-green to beige to white scaly and/or shaly surface coatings, and finely particulate infill, often goethite stained. Sulfide-rich ore types also occur in part of the deposit, but are restricted to specific drill holes. Magnetite grain size is relatively coarse, compared with magnetite from typical banded iron formations, whereas discrete silicate gangue is mainly bladed/fibrous and/or layered and micaceous in form. XRD analysis indicates the presence of vermiculite, serpentine, stilpnomelane, chlorite, actinolite and clays. There is a spectrum of ore types representing the gradation from 'fresh' (magnetite-dominated) to oxidised and weathered (martite/goethite-dominated). Martite-dominated samples are generally higher in grade, due to leaching and removal of silicate gangue, resulting in higher macroporosity. Where gangue has been leached out, partial replacement by vitreous goethite and/or hydrohaematite is typical, often preserving the fibrous/layered characteristics of the original silicates.

Jan 1, 2009

By Little T. N, Bettess D

For many mining operations the challenge of equalling World Best Practices has become the key motivator for increasing mine productivities and for lowering total costs. In most instances this will only be achieved if mines optimise their total system rather than minimising specific costs within unit operations. In the past, drilling and blasting have been viewed as a cost to be minimised rather than operations which should have their impacts fully leveraged. Once a hardrock orebody is defined the activity which has the most substantial impact in determining the efficiency of a mining operation is the blasting. The output from a blast affects every downstream operation; only by understanding the extent and interactions can the mine be optimised. Substantial improvements to hardrock mining, quarrying and excavation operations are achievable. Instead of seeking the regular one to three per cent improvements based on reduction of consumables, mine operators would be well advised to go for much bigger targets of ten to 30 per cent by fully leveraging the drill and blast operations.

Jan 1, 1995

By D Monaghan

Pumping water for dewatering and water supply is a major component of electricity consumption at mining operations and hence is a significant contributor of greenhouse gas emissions. Pump systems at a typical mine site can be broadly split between above ground centrifugal pumps (generally used for water transfer) and submersible borehole pumps (generally for dewatering and/or water supply). In contrast to above ground pumps, submersible borehole pumps can be subjected to varying duty points (total pumping head and flow requirements) as a result of changing bore water levels and yields, particularly in mine dewatering bores. Typically, much higher pumping rates are required at the commencement of dewatering to remove groundwater storage and to intercept sufficient groundwater throughflow to achieve target drawdowns. Once target drawdown levels are reached it often only requires much lower pumping rates to maintain target drawdowns. Pumps sized to remove the large initial volumes of stored groundwater often end up too large for the lower flow rate required for æmaintenance pumpingÆ. This often results in pumps operating inefficiently, a problem which can be made worse when pumps are throttled to reduce the pump output to better match the reduced bore yield. Current standard operating practice places little emphasis on the electricity consumed by pumps, with the focus often being on minimising capital expenditure (æIf it ainÆt broke donÆt fix itÆ). Submersible pumps can have extended service lives of ten to 20+ years. However as the capital cost of a pump typically represents only five per cent of the life cycle cost, the vast majority of the life cycle cost is energy usage.Through the implementation of a regular review of the operation of borehole pumps, significant reductions in electricity use and associated greenhouse gas emissions can be achieved without impacting the dewatering schedule. In most cases, the capital cost of replacing pumps is more than offset by savings in operating costs. These potential savings become even more significant when considering proposed future carbon tax levees.This paper presents examples of the opportunities for significant reductions in energy, greenhouse gas emissions and overall costs that can be achieved for a range of dewatering scenarios.

Jan 1, 2009

By Liu Z. C

Evans' theory for chisel shaped picks is well known in the field of rock cutting technology. It has been widely accepted as a good mathematical description of how coal and other rocks break under the action of a simple wedge or chisel. Subsequently, Evans proposed a corresponding theory for pointed shaped picks. Theory along with experimental evidence from the laboratory has consistently shown that chisel picks are more efficient than pointed picks. However despite such evidence, pointed picks continue to be the preferred shape in most practical cutting applications. Evans' theory for pointed picks was developed in an attempt to shed light on this apparent incongruity. The theory although predicting forces of the right order was found to be deficient in several respects. This paper examines Evans' theory for pointed picks and proposes changes to it, which brings the theory much more into line with measured data. The issue of the relative efficiencies of chisel and pointed shaped picks is also examined on a theoretical basis and the apparent incongruity is Resolved.

Jan 1, 1995

By G H. Luttrell

The use of secondary desliming cyclones ahead of froth flotation cells to reject ultrafine (-45 ¦m) particles has become a popular option in the United States for preparing fine coal feeds for froth flotation circuits. In light of this popularity, several experimental studies have been performed at industrial plant sites to develop a better understanding of the impacts of ultrafine desliming on froth cell performance and, ultimately, overall plant performance. These studies included an evaluation of various circuit configurations incorporating different flotation technologies (conventional machines and column cells) as well as different dewatering systems (disc filters, screen-bowl centrifuges, and thermal dryers). The data obtained from these studies indicate that deslime circuits offer several important benefits including lower product ash, reduced product moisture, better froth handling characteristics, and lower capital and operating costs. In addition, case studies conducted as part of this investigation have been used to develop generic guidelines for how deslime circuits may be successfully applied to improve the overall profitability of fine coal flotation circuits for both the metallurgical and steam coal markets.

Jan 1, 2005

By A Turichshev

The synthetic rock mass (SRM) approach for modelling jointed and veined rock has been at the forefront of caving geomechanics research for years. A well-constructed and calibrated SRM model can capture the full rock behaviour at a macroscopic scale. Traditionally, SRM technology employed bonded particle models (BPM) due to their ability to model rock’s response to loading without prior specification of behaviour. The SRM modelling process requires the BPM to simulate intact rock and the subsequent introduction of fractures or veins by changing bonding characteristics between the particles. However, bonded particle materials have difficulty reproducing both the compressive and tensile strengths of intact rock. This and other limitations of BPM have been the driving force in exploring the potential of grain-based (2D) and bonded block (3D) models (BBM).This paper reports on recent work exploring the applicability of both BPMs and BBMs in 3D to the modelling of intact rock. The advantages and limitations of both BPMs and BBMs are addressed based on the results of numerical simulations using the PFC3D and 3DEC distinct element codes. The preliminary results suggest that BBMs are better suited for simulating intact rock behaviour than BPMs. Ongoing work aims to better qualify the applicability of BBMs under different conditions. This has significant implications for our understanding of rock mass behaviour in a caving environment.CITATION:Turichshev, A and Hadjigeorgiou, J, 2016. Simulating intact rock behaviour using bonded particle and bonded block models, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 453–460 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

Compared with modern longwall coal mining systems, automation has not been developed very far in the underground metal minin industry. One of the main reasons for this is that present har rock mining systems do not produce ore with a controlled degre of fragmentation. The often poor fragmentation from the stopescauses large extra costs and precludes material which 1-ends itself to automationThe paper investigates the possibility c technology for automatic loading and trapconveyor belt to a shaft dump pocket. With this concept, it will be necessary to control the maximum fragment size by careful blasting design. The degree of fragmentation will have to be finer than is common to-day. The study shows that the belt conveyor mining con-cept with controlled fragmentation may be economically competitive with conventional cyclic loading and transport, even for an annual production as low as 0.5 mill. tonnes.. Fragmentation design and cost calculations have been based on a combination of the Kuznetsov relationship between blasting parameters and mean frag-ment size, and the Rosin-Rammler formula for fragment size distribution.

Jan 1, 1985

By D W. Airey

Frictional rock bolts are widely used because of their low cost. However, they have a thin wall section that makes them prone to corrosion, and they cannot be relied on to provide long-term ground support. It is difficult to assess the capacity after the bolts have been installed as they can only be pulled out if this has been allowed for during insertion. The questions of how long can the rock bolts function effectively and the effectiveness of various surface coatings, which can have significant cost implications are, investigated in this study.A series of accelerated corrosion tests have been performed on frictional rock bolts. The rock bolts, typically 900 mm long, have been inserted into concrete cylinders produced using a styrofoam insert to create the hole for the bolt insertion. Strata rock bolts with four surface coatings have been tested: uncoated black steel, galvanised, enduro (plastic coated) and coated with a proprietary aluminium/zinc alloy. Tests have been performed on two diameters of bolts. Following insertion of the bolts, the concrete cylinders were placed in a large drum filled with saltwater and current was applied to accelerate the corrosion process. The rock bolts were then extracted at various times after the commencement of corrosion. Comparison of the insertion and extraction resistances shows that corrosion initially increases the bolt resistance and that substantial section loss is required for the bolt resistance to drop significantly.CITATION:Airey, D W, 2014. Laboratory corrosion tests of frictional rock bolts, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 257–262 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By A Bennett, A Peck

BHP has recently constructed a Hot Briquetted Iron Plant at Port Hedland in the Pilbara region of Western Australia. Supply of iron ore fines to the plant is by conveyor from the companyÆs existing Nelson Point stockyards. The conveyor passes under Port Hedland harbour in a concrete segmentally lined tunnel, approximately 1030 m long and with a 5.1 m external diameter. The tunnel was constructed by a Tunnel Boring Machine (TBM) which both excavated the ground and erected the tunnel lining. The tunnel was bored between cut and cover in situ concrete portal structures, the TBM being launched from the Finucane Island side towards Port Hedland town. The alignment required lengthy gradients of 1:6 on either side of the harbourÆs dredged channel, under which the tunnel is bored with a minimum clearance of 8 m.The tunnel is fitted-out with:1800 mm belt conveyor capable of 10 000 tph;walkway along which a specially designed inspection/ maintenance vehicle can run; andtunnel services including power, light, fire detection and suppression communications, water mains for wash down and sumps and pumps for drainage.This paper gives a general overview of the design and construct contract, important aspects of the design and the construction process itself.

Jan 1, 1999

By L B. Sukla, V N. Misra

Microbial desulfurisation of coal has significant advantages over physicochemical desulfurisation processes since the former process selectively removes the inorganic sulfur compounds and heavy metals without significant carbon loss. The purpose of this study was to improve the desulfurisation yield of a coal sample from northeastern coalfields, Assam, India using microbial technique. The coal sample contained 2.13 per cent of total sulfur and 2.59 per cent of ash. Stirred tank reactors of 40 L capacity were operated in batch mode. Initially, the reactor was fed with 40 L of slurry containing ten per cent (w/v) coal, ten per cent (v/v) inoculum of mixed culture of mesophilic acidophiles, native to coal itself and the requisite amounts of constituents for 9K medium without added ferrous sulfate. The percolate of the reactor was then used to seed the medium for the next experiment. The purpose was to obtain a better adapted and more active biomass which would give a better desulfurisation yield for coal. Further studies were conducted in the bioreactor, fed with 40 L of slurry containing ten per cent (w/v) pulp density of coal, ten per cent inoculum (derived from previous studies) and the medium, supplemented with ferrous sulfate. Results showed an increased total desulfurisation yield of 43 per cent in the latter treatment in comparison to the previous one, where the desulfurisation yield was only 23 per cent. The findings also demonstrated the convenience of using inocula derived from coal, where 50 - 60 per cent of pyritic sulfur was removed, while chemical desulfurisation is of little significance with the majority of coal types. The ash content was also reduced to 1.74 per cent as the low pH of the process caused dissolution of a number of common minerals present in the coal.

Jan 1, 2004