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By C. O. Campbell

THE recognition by C. W. McKee, field engineer for Springer Sturgeon Gold Mines, Limited, in the fall of 1940, of the economic possibilities of a small outcrop of baryres near Pembroke, in Hants county, Nova Scotia, followed by aggressive exploration and development by the Company, has placed Canada for the first time in its history in the position of becoming a major producer of barytes and its products. In past years, production of this mineral in Canada has been unimportant. Thus the coral output from 1885 ro 1933, inclusive, amounted to only 41,027 short tons, following which there was no production until 1939. Deposits in Nova Scotia, and particularly in the Lake Ainslie district, Cape Breton, have been the main source of supply, with a production between 1866 and 1925 of 31,689 tons. Following the examination of the outcrop of baryres near Pembroke by Mr. C. W. McKee in October, 1940, the area surrounding it was trenched, and, as this work gave encouraging results, a diamond drilling programme was commenced. A grid system was laid our and sixteen holes aggregating 2809.3 feet were put down, spaced at 100-foot intervals, the deepest hole being 300 feet. This drilling outlined a body of high-grade baryres over 600 feet long and 200 to 250 feet wide, with an average depth of 120 feet and estimated to contain well over one million tons of ore. The limits of the body were reached on the west, north, and southwest, but the drilling was suspended before the eastern limit was determined. Quarrying operations, and construction of a 100-ton mill, were commenced in February, 1941. The mill was placed in operation on May 29th, and on June 15th, eight months after the initial discovery, the first shipment of 2,500 long rons of milled baryres was made to Trinidad, British West Indies.

Jan 1, 1942

By Carlos Alberto Spier

The Águas Claras and Pico mines are two world-class, iron-ore mines hosted within Lower- Proterozoic banded iron-formations (locally known as itabirites) of the Minas Supergroup located in the Quadrilátero Ferrífero District, Minas Gerais, Brazil. The Águas Claras orebody consists of a 2,500 m long roughly tabular-shaped lens hosted within the dolomitic itabirite of the Cauê Formation. Dolomitic itabirite is the protore of the soft high-grade iron ore, which is the main ore type of the Águas Claras orebody, and represents more than 85% of the 284 Mt mined since 1973. Hematite is the main constituent of the iron ores. It occurs as martite, granular hematite and, locally, as specularite. Magnetite appears subordinately as relicts within martite and hematite crystals. Gangue minerals are very rare. These consist of dolomite, chlorite, talc and apatite and are especially common close to the contact with the protore. This virtual absence of gangue minerals is reflected in the chemistry of ores which are characterized by very high Fe contents (an average of 68.2% Fe). The Pico orebody is a continuous ~3,000 m long body of lenticular shape hosted within quartz itabirite, which is the protore of the soft high- and low-grade ores at the Pico mine. The soft high-grade ores, together with the low-grade ores, called iron-rich itabirite, are the main types of ores at the Pico mine, respectively representing approximately 51 % and 29 % of the reserves within the pit. The iron oxide mineralogy is the same as that of the Águas Claras mine, but in different proportions. Gangue minerals are very rare in the high-grade ores, but are slightly more common in the iron-rich itabirite. Quartz is the dominant gangue mineral, and is found with minor quantities of chlorite. The chemistry of the high-grade ores is characterized by high Fe contents (an average of 67.0 %) and low P, Al2O3, and SiO2 which are concentrated in the fines. Iron rich itabirites average 58.6% Fe and 13.5% SiO2.

May 1, 2003

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By H. P. Pew

THE Pembina oil field is in west-central Alberta, about 88 miles west-southwest of Edmonton. The field, about 35 miles long by T HE Pembina oil field is in west-central Alberta, about 88 miles west-southwest of Edmonton. The field, about 35 miles long by 85 miles wide, is the largest in Canada in areal extent, in the amount of oil in place and in the current producing rate. The discovery well was completed in the middle of 1953. The field has grown until its present area is 369,820 acres. There are 74 working interest owners in the field. Early in the producing history of the Pembina field a committee of operators was formed on a permanent basis. The Pembina Operators' Committee has established a permanent staff, which compiles and distributes pertinent field information on a regular basis to all participants. The Alberta Oil and Gas Conservation Board has dealt with field-wide problems primarily through this committee. Expansion of the field was rapid as shown by the number of wells completed -from 135

Jan 1, 1961

By Jun Deng

The aim of this paper is to study the scientificity and reliability of three coal gas indices used to predict coal fire disasters, namely Graham?s ratio, CO/CO2 ratio, Litton ratio and their different characteristics and service conditions. Data from a programmed temperature experiment were applied to check their veracity and accuracy. Each index performed well in detecting the level of a fire. We conclude that it is better to redefine the definition through experimentation before applying a given index. Integrated analysis of the results can provide reliable reference data for predicting spontaneous combustion of coal.

Aug 1, 2013

By M. Lghoul

Acid mine drainage (AMD) remains one of the major environmental problems for the mining industry particularly for many abandoned mine sites. The production of AMD as is commonly known can significantly affect the surrounding groundwater and surface water of the mine site. With the objective to investigate the impact of the AMD produced at the abandoned Kettara mine site (Morocco), groundwater sampling campaign was performed at this site. The sampled waters were analyzed to determine the hydrogeochemical composition, and then results were analyzed using different studied methods such as multivariate statistical analysis and geochemical modeling techniques. Investigation results show that the hydrochemistry of sampled waters is characterized by the relatively significant enrichment of Ca2+, Mg2+ and SO4 2-. The typical mine waters belong to the (Ca2+ +Mg2+)-SO4 2-type. Seasonal variations in major ion concentrations were partly attributed to dissolution/ precipitation processes. The saturation index (SI) calculation of the representative dissolved minerals in waters show that groundwater samples are undersaturated with respect to most potential sulphated secondary minerals.

Aug 1, 2013

By J. A. Russell

MR. M. W. Boom: I would like to congratulate Mr. Russell on his fine paper. One very good point which has always appealed to me is the smooth working of a steam hoist as compared with electrical. He does not mention the steam hoist at Springhill which has been working there for a good many years. MR. S. R. NEWTON: I have read with a great deal of interest the paper presented by Mr. Russell on the development of haulage engines in the mines of the Dominion Steel & Coal Corporation. He is to be congratulated on having produced a comprehensive article showing, step by step, the various improvements that have been made over the years in the design of such engines. I am quite in accord with Mr. Russell's statement that the positive tooth clutch can have too many teeth, and also that the method of driving a sliding clutch hub of any design should be by means of a hexagon or octagon on the shaft. Where the clutch hub does not of necessity slide on the shaft it can be pressed on and keyed to the shaft in the normal manner. With regard to the 'Cramp' internal-expanding jaw-type clutch, while it is true there are more moving parts than with the clutch consisting of a ring with internal cut teeth and a driver having a fewer number of teeth as .described by Mr. Russell; there are compensating advantages to the internal expanding jaw-type of clutch. The V shaped profile of the teeth permits of engagement of the clutch with very much less 'jockeying' of the drum. This is particularly the case in vertical-lift mine hoists, where it may be necessary to engage and disengage the clutching mechanism at frequent intervals.

Jan 1, 1944

Mining Equipment Challenges Equipment Availability Unplanned downtime Maintenance Costs Secondary damage and catastrophic failures (T282 $750k) Emergency work is 4x the cost of planned work Inspections Troubleshooting time Incorrect repairs (parts, labor, lost production) Equipment Life Mis-operation of equipment

May 1, 2013

By A. G. Lylie

Introduction At the Britannia Mining and Smelting Company's mill, the equivalent of 2,500 to 2,800 pounds of copper sulphate crystals per day is made from copper which is precipitated from the mine-water. This copper sulphate is used in the mill for the recovery of sphalerite by2 flotation. From 1932 until 1936 it was produced by exposing the precipitate to air for thirty days and then dissolving the oxidized copper with dilute sulphuric acid. In 1936, the flotation of sphalerite was discontinued and, when it was resumed in 1947, steps were taken to try to improve the former method. The present paper outlines the way in which this was done, and describes the plant and procedure by which copper sulphate is now being made, and by means of which an appreciable saving is being effected. Aboratory Tests The previous work had established that the precipitate, which consists mainly of metallic copper, must be oxidized before the copper would dissolve in dilute sulphuric acid. Various methods for oxidizing it were tried but in the early laboratory work the only suitable one found was to heat the precipitate to 600°C. and hold it at this temperature for two hours. When this was done, approximately 90 per cent of the copper became soluble in .acid. This percentage was considered satisfactory for practical purposes, but the cost of roasting was prohibitive because only a small amount of roasted precipitate was required each day.

Jan 1, 1951

By D. C. Carter, J. P. Anderle

"Exploration drilling of evaporite sequences in eastern Canada has undergone significant changes in equipment, techniques and philosophy since the early 1970s. The result has been the recovery of full-size cores from properly conditioned and stabilized holes, high quality open hole geophysical logs, and high quality metallurgical samples. The majority of modifications have resulted from the necessity to preserve the integrity of the evaporite deposit, and thus ensure the potential development, combined with the need for cost-effective high quality information. This is particularly evident in the priority placed on the development of non-erosive drilling fluids, casing and cementing procedures. The results are applicable to diamond drilling exploration of evaporite deposits anywhere in the world.IntroductionThe majority of current technical and scientific literature and expertise available on such subjects as drilling fluids or cementing procedures is applicable to large diameter, deep (several thousand metres) oil-field type drilling . The differences between oil-field drilling and wire-line core diamond-drilling are dramatic: large diameter, deep holes drilled with a low rpm tricone bit using large volumes of fluid pumped through a large annulus versus small diameter, shallow (less than 600 m) holes drilled with a high rpm diamond-set core bit using small volumes of fluid pumped through a small annulus. Exploration drilling of evaporite sequences in eastern Canada in the early I970s was conducted using oil-field equipment and techniques to complete holes of moderate (1000 m to 1500 m) depth . The prohibitive cost of these operations has necessitated that subsequent exploration drilling employs modified diamond-drilling equipment and techniques developed as part of a transition away from oilfield methodology. The result has been full size core, recovery approaching 1000/0 and the ability to run open hole geophysical logs; a combination of factors enhancing the collection of high quality information (Carter, I989a)."

Jan 1, 1990

By R. Le Houillier, M. Nagamori, A. J. Plumpton

"Asbestos tailings are a typical serpentine, hydrated magnesium silicate, consisting primarily of antigorite and a few per cent of unrecovered fibrous chrysotile. Serpentine has unique thermal properties in that dehydroxylating calcination at 600 to 700°C can yield an amorphous structure in which most of the magnesia is liberated from the original bond with silica and thereby rendered chemically active. The amount of activated magnesia can be quantified by selective leaching with a weak acid such as acetic acid. Many wet processes have been proposed to extract magnesium values from calcined or natural serpentine by means of various acids and their ammonium salts. However, the only commercial utilization of serpentine today is found in dry processes such as the production of fused magnesium phosphate fertilizer .The present paper reviews the physical chemistry of the dehydroxylation of serpentine and also various wet and dry processes in order to provide a general view regarding the chemical transformation of asbestos tailings.IntroductionAsbestos fibers occur as chrysotile, a serpentine polymorph. More than nine tenths of mined asbestos ores consist of massive non-fibrous serpentine, primarily the polymorph antigorite, which is discarded as tailings after fiber extraction. For many decades, Quebec has been a world leader in the production of asbestos fibers. As a result, colossal tonnages of serpentine have accumulated in the Eastern Townships'!'. Serpentine minerals are found in large deposit s throughout the world, and significant research efforts have been made, particularly in Japan and the USSR, mostly in attempts to extract magnesia or silica values therefrom.The chemical composition of serpentine (chrysotile and antigorite) may be ideally expressed as Mg3Si2Os(OH). which corresponds to 43.7% MgO and 43.3% SiO2. Natural serpentines often contain a few per cent of Ni-bearing magnetite and other impurities, and therefore the contents of MgO and Si02are both about 40% or lower.Serpentine (hydrated magnesium silicate) is virtually insoluble in weak acids. However, when dehydroxylated under controlled conditions, ' it decomposes to an amorphous state in which magnesia and silica are isolated and chemically active. The magnesia so activated is readily soluble in weak acids. This unique characteristic of calcined serpentine, first discovered in 1942,, has since attracted the attention of innumerable researchers, whence many processes have been proposed."

Jan 1, 1980

DOME MINES, Limited, is a gold producer situated in the Porcupine area of Ontario, 500 miles north of Toronto. During the year 1960, '71 4,600 tons of ore were milled, yielding gold bullion valued at $6,025,370. Prior to conversion to natural gas, an average of 3,200 tons of coal was consumed annually, one third of which was obtained from Canadian sources with the remainder coming from the United States. Due to the distances involved, the freight charges increased the pithead cost by as much as ISO per cent. Steam is generated at a central boiler plant and used for timber treatment, plant heating and process steam. Until August, 1960, steam was supplied during the winter months by two water tube coal-fired boilers, each rated at 200 boiler horsepower at 100 per cent output. Steam requirement was as high as 150 per cent of boiler rating in the colder periods. The summer load was

Jan 1, 1962

By Yong-neng Feng, Xiao-ping Chen, Wei Guo

"While the uniaxial compressive strength of rock has been extensively investigated, the relation between the saturation and natural compressive strength is relatively unexplored. This paper studies on 1865 statistical data of Chongqing Rail Transit Line 1 and Line 6, which located in the Middle Jurassic of Shaximiao formation. The research focuses on the relation between the saturation and natural compressive strength. The statistical data are categorized and quantified in order to ascertain the softening properties of sandstone and sandy mudstone. The findings suggest that the saturation compressive strength is significant effected by its natural compressive strength, and an empirical formula is introduced to explain the relation. These findings have implications for researchers and engineer who concerned with Chongqing rail transit construction.INTRODUCTIONIn the engineering construction and surrounding rock classification, the uniaxial compressive strength index (Ministry of Water Conservancy, 1995; Ministry of Railways, 1999) is one of the essential parameters of rock mass. Usually, there are two types of the uniaxial compressive strength index, natural and saturation compressive strength, and the ratio of them is the softening coefficient. Most of the previous studies on rock strength had focused on the influence factors (Liu et al., 2008; Liu et al., 1998; Liu et al., 2013; Wang, 2013; Zhang et al., 2008; Zhang et al., 2010; Zeng & Lin, 2003) with experiment and in-situ tests. But few publications that reports a long and formal research project on the relationship between natural and saturation compressive strength. In order to figure out this issue, this study investigated the distribution of Solidity Classification of Rock Mass and softening coefficient based on the statistical data of Chongqing Rail Transit Line 1 and Line 6. Based on the analysis, an empirical formula was proposed to explain the relationship."

Jan 1, 2015

By L. R. Fyffe, D. R. Lentz, S. H. Mcclenaghan

"Abstract - The Eel River area in the southwestern Miramichi terrane of New Brunswick contains a complete calc-alkaline suite of volcanic rocks that are interlayered with intervals of sedimentary and polylithic fragmental rocks, and are overlain by a thick sedimentary sequence. This package, collectively referred to as the Meductic Group, was deposited in a submerged volcanic arc setting interpreted to be part of the Popelogan arc. Rifting of this arc led to the development of the Tetagouche-Exploits back-arc basin, and formation of volcanogenic massive sulfide deposits in bimodal volcanic rocks of the Bathurst Mining Camp in the northeastern Miramichi Terrane. Unlike the Bathurst Mining Camp, volcanic rocks in the southeastern Miramichi Highlands form a continuous calc-alkaline suite characterized by increasing Zr/TiO2 with increasing SiO2, in part resulting from progressive coupled assimilation and fractional crystallization of nested magma systems. Slumping of semi-consolidated volcanic and sedimentary rocks in topographically unstable areas resulted in numerous slumps and debris flows that are preserved throughout the Eel River area. In the early 1990s, the discovery of a large sulfide clast in a road cut along the Benton road sparked interest in the volcanogenic massive sulfide potential of the Eel River area. Subsequent drilling intersected smaller fragments, one clast of which graded 16.7% Zn, 5.6% Pb, 90 ppm Ag, and 220 ppb Au. The intersection of thin lenses of stratiform sulfides in another drillhole indicates favorable conditions for the preservation of massive sulfides. Their subsequent incorporation into synvolcanic debris flows resulted in the transport and deposition of sulfide clasts from hydrothermal vents to more distal locations. Similar to the Buchans deposits of Newfoundland, tracing these debris flows back to their source would be beneficial from an exploration perspective. Approximately 15 km to the southwest of the Eel River area, gold-bearing base metal sulfide clasts (11.1% Zn, 6.13% Pb, 0.19% Cu, 108 ppm Ag, and 1100 ppb Au) occur within intermediate-composition volcanic rocks at Monument Brook in eastern Maine. Sommaire - Le secteur d’Eel River dans le sud-ouest de la terrane de Miramichi au Nouveau Brunswick contient une séquence complète de roches volcaniques calco-alcalines interstratifiées avec des roches sédimentaires et fragmentaires polylithologiques, sous une épaisse couverture sédimentaire. Cet assemblage constitue le Groupe de Meductic, et a été déposé dans un environnement d’arc insulaire interprété comme une partie de l’arc de Popelogan. Le rifting de cet arc à mené au développement du bassin d’arrière-arc de Tetagouche-Exploits, et à la formation de gisements de sulfures massifs volcanogènes dans les roches volcaniques bimodales du Camp Minier de Bathurst dans le nord-est de la terrane de Miramichi. Contrairement au Camp Minier de Bathurst, les roches volcaniques des hautes terres du sud-est de Miramichi constituent une suite calco-alcaline continue caractérisée par un accroissement du rapport Zr/TiO2 à des valeurs croissantes de SiO2, résultant en partie de l’assimilation progressive et de la cristallisation fractionnée de systèmes magmatiques superposés. L’effondrement de roches volcaniques et sédimentaires semi-consolidées dans des secteurs topographiquement instables est à l’origine des nombreux slumps et coulées de débris qui sont préservés dans le secteur d’Eel River. Au début des années 1990, la découverte d’un large claste de sulfures le long de la route Benton provoqué un intérêt pour le potentiel en gisements de sulfures massifs volcanogènes dans les secteur d’Eel River. Des forages ont par la suite recoupé des fragments plus petits, dont un claste qui a retourné des teneurs de 16.7% Zn, 5.6% Pb, 90 ppm Ag et 220 ppb Au. Le recoupement de minces lentilles de sulfures stratiformes dans un autre forage indique des conditions propices à la préservation des sulfures massifs."

Jan 1, 2006

By F. R. Ploeger, J. H. Crocket

"IntroductionRocks in the Kirkland Lake district form part of the Timiskaming Group, a south-facing homoclinal sequence of wackes, conglomerate, trachytic flows and pyroclastic rocks and syenitic intrusive rocks. Hewitt (1963) indicates that the thickest section, about 5 km, of the Timiskaming Group rocks is attained in Lebel Township. Several writers (Thomson, 1948; Hewitt, 1963; Hyde, 1978; Jensen, 1978; and Downes, 1979) have observed that the Timiskaming Group unconformably overlies the Keewatin volcanics, particularly along the northern contact. Recent work by Downes (1979) in McGarry and McVittie townships to the east of Kirkland Lake has shown that much of what had formerly been classified as Timiskaming actually belongs to an older group of rocks, the Larder Lake Group (Jensen 1978).General GeologyA series of fluviatile, braided-stream sedimentary rocks (Hyde, 1978) form the oldest of the three major rock suites at Kirkland Lake. Conglomerates constitute a large proportion of these sedimentary rocks and typically contain a large percentage of a variety of locally derived alkalic rock clasts as well as the distinctive red jasper iron-formation pebbles (Fig. 1a). The associated wacke units can be massive to finely bedded and are interbedded with the conglomerate. They also contain a large alkalic tuffaceous component.Interbedded with these sedimentary rocks are alkalic extrusive rocks, including tuffs, agglomerates, breccias and flows, which represent episodes of fissure and explosive crater eruption (Cooke and Moorhouse, 1969). The tuffs, although dominantly alkalic in composition, are commonly reworked and contain sedimentary features such as graded bedding, scouring and crossbedding (Fig. 1 b). The trachytic flows are massive to porphyritic and outcrop mainly east of Kirkland Lake in the adjoining townships. Altered leucitic porphyritic flows, locally referred to as red and green spotted trachytes, commonly occur."

Jan 1, 1982

By A. Ojaghi, A. R. Mohammadi

"The Marvast monazite deposit is located 35 kilometres south - southwest of Marvast in Yazd province of Iran. A representative sample weighing approximately 10 tons was prepared to study the amenability of the ore to physical beneficiation. The size fraction of +1000 µm was removed due to low monazite content and the –1000 µm size fraction was concentrated by the gravity-classification-magnetic methods. According to the results of sample characterization, the representative sample contains 220 ppm REO that is contained in monazite. It was concentrated to 41.5% REO by the above mentioned methods. The recovery of REO in the monazite concentrate was 41.5%.INTRODUCTIONRare earth elements are critical metals in many countries (Gupta, 2005; UK Geological Survey, 2011). Increasing application of these metals in hi-tech industries and price fluctuation caused by Chinese production policy has led other countries to focus on their local resources (UK Geological Survey, 2011). In this case, Iran is not an exception.REE mineralization in Iran is mainly located in the central zone. Regarding the exploration data, these deposits are divided into two categories. The first group is iron ore deposits in which the REE are carried by phosphate minerals. The other group is placer deposits where monazite is the major mineral of the deposit. The Marvast placer deposit is one of these types of deposit (Daliran, 1990; Mokhtari, 2008; Torab, &Lehmann, 2007; Alipour, 2014)."

Jan 1, 2016

By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company's plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By Paul Guliov

Coal-bearing Tertiary sediments of the Ravenscrag Formation in southern Saskatchewan host numerous deposits of clinker resulting from in situ coal combustion. Clinker deposits form when sediments of relatively low temperature firing properties overlie coal seams which are undergoing prolonged spontaneous combustion. The resulting fired material is useful for decorative landscaping aggregate, rock gardens, driveways, mud control and others. Predicting the occurrence of clinker deposits requires a knowledge of the spatial distribution of coal seams and the nature ofoverlying sediments. Knowledge ofpaleotopography at the time of coal combustion can assist in locating more highly-fused material which can yield greater block sizes. Coal data bases can be used as a predictive tool by outlining areas where coal is or was at or near surface and therefore may have been susceptible to spontaneous combustion.

Jan 1, 2001

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By S. R. McCutcheon, D. R. Lentz

"Abstract - The 12.1 Mt Brunswick No. 6 Zn-Pb-Cu-Ag massive sulfide deposit (New Brunswick, Canada) lies between two subaqueous felsic volcanic formations near the base of the Middle Ordovician Tetagouche Group. The footwall comprises rhyodacitic pyroclastic rocks (Nepisiguit Falls Formation), whereas the hanging wall comprises a sequence of rhyolitic flows, breccias, and hyaloclastites (Flat Landing Brook Formation), with an age difference of less than 3 m.y. The Brunswick No. 6 deposit is a proximal autochthonous deposit with a well-zoned massive sulfide body and a basal Cu zone that, at depth, develops into a stockwork stringer sulfide (feeder) system. The massive sulfides are capped sharply by a layered magnetite-chert unit that extends regionally beyond the deposit. The deposit has a keel shape (sheath) formed by the F1F2 interference pattern. The heterogeneous ductile deformation and upper greenschist-grade regional metamorphism has transposed many of the epigenetic stockwork structures and alteration within the host sequence. Hydrothermal alteration is much more extensive, both vertically and laterally, in the footwall (a few 100 m) than in the hanging wall (<100 m). Anomalies farther up in the hanging wall sequence seem to be associated with independent alteration systems related to the rhyolite domes. The least-altered footwall units exhibit keratophyric alteration (albite or adularia) and weak Mg enrichment (chlorite). More intense micaceous (sericite and Mg-rich chlorite) alteration occurs around the footwall sequence. The transposed stockwork stringer sulfides are typically composed of Fe-rich chlorite (± sericite, ± silica) with pyrite, pyrrhotite, chalcopyrite, arsenopyrite, and sphalerite. The (Fe2O3T+MgO)/(Na2O+K2O) and base metal alteration indices are the best practical lithogeochemical vectoring tools at this deposit. Sommaire - Le gîte de 12.1 Mt de sulfures massifs de Zn-Pb-Cu-Ag Brunswick No.6 est localisé entre deux formations volcaniques felsiques sous-marines situées près de la base du Groupe de Tetagouche d’âge Ordovicien Moyen. Le mur consiste en roches pyroclastiques rhyodacitiques (Formation de Nepisiguit Falls) tandis que le toit consiste en une séquence de coulées, de brèches et d’hyaloclastites de composition rhyolitique (Formation de Flat Landing Brook); la différence d’âge entre les deux est de moins de 3 m.y. Le gisement Brunswick No. 6 est un gîte autochtone proximal comprenant un corps de sulfures massifs clairement zoné ainsi qu’une zone cuprifère basale qui passe progressivement à un stockwork de filonnets de sulfure en profondeur (feeder). Les sulfures massifs sont abruptement surmontés d’une unité laminaire de chert et de magnétite dont l’extension par delà le gisement est régionale. Le gisement affecte la forme d’une quille (fourreau) résultant d’un patron d’interférence F1F2. Plusieurs des structures épigénétiques du stockwork et des patrons d’altération de l’encaissant ont été transposés par la déformation ductile hétérogène ainsi que par le métamorphisme régional au faciès des schistes verts. L’altération hydrothermale est beaucoup plus importante, tant verticalement qu’horizontalement, dans le mur (quelques 100 m) que dans le toit (<100 m). Les anomalies situées plus haut dans le mur semblent être reliées à des systèmes d’altération indépendants associés aux dômes de rhyolite. Les unités les moins altérées du mur une altération kératophyrique (en albite ou en adulaire) ainsi qu’un faible enrichissement en Mg (chlorite). Une altération en mica (séricite et chlorite magnésienne) plus intense est présente autour de la séquence du mur. Les sulfures du stockwork de filonnets transposés consistent typiquement en chlorite ferrifère (± séricite, ± silice) accompagnée de pyrite, de pyrrhotite, de chalcopyrite, d’arsénopyrite et de sphalérite. L’indice d’altération (Fe2O3T+MgO)/(Na2O+K2O) et l’indice des métaux usuels sont les outils d’exploration les plus appropriés dans ce gisement."

Jan 1, 2006