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By Michael T. G. Brown

Syncrude Canada Ltd. has recently completed construction of its ambitious tar-sand mining and processing facilities at Mildred Lake, Alberta. The Syncrude site is approximately 48 km (30 miles) north of Fort McMurray near the west shore of the Athabasca River. The Syncrude operation involves the open-pit mining of approximately 270,000 tonnes (300,000 tons) of tar sand daily using draglines and a conveyor system. Bitumen is extracted from the tar sand, upgraded to oil-gas and transported to refineries in Edmonton and other locations for final processing . The Beaver Creek Dam forms part of the mining facilities for the Syncrude tar-sand mining operation. Water from Beaver Creek is diverted from the open-pit mine site south to the Athabasca River via Ruth Lake and the Poplar Creek Dam. General site layout is shown on Figure I . Design of the dam was completed by R. M. Hardy and Associates Ltd. of Edmonton, Alberta (now Hardy Associates (1978) Ltd) . Construction was undertaken during the summers of 1974 and 1975 under the direction of Canadian Bechtel Limited, managing contractors for Syncrude Canada Ltd. Total length of the dam is approximately 2.8 km (1.7 miles), with a maximum height in the order of 16 m (50 ft) The Beaver Creek Dam is located in a broad, flat, poorly drained valley. About 50 per cent of the site is covered with treeless peat deposits, which ranged in thickness from in excess of 5 m (15 ft) at the east end of the dam to less than 1 m (3 ft) at the central portion. The peat deposits overlie Pleistocene meltwater sediments on top of clay/clay shales of the Clearwater Formation and the tar sands of the McMurray Formation. The peat deposits and high groundwater levels at the site combine to make the excavation and construction of a conventional rolled clay cutoff impractical. For these reasons, the slurry cutoff trench technique was utilized to produce an efficient and effective seepage cutoff under various sections of the Beaver Creek Dam .

Jan 1, 1979

By A. Farzanegan, D. A. Lowther, A. R. Laplante

"Off-line optimization studies are often necessary to improve the efficiency of grinding circuits. These studies are primarily based on the mathematical modelling of processing units (e.g., ball mills and hydrocyclones) and computer simulations. To complete an optimization task, process engineers must possess skills and knowledge of different subtasks involved in such efforts, e.g., plant audit, laboratory tests, and data analysis. Such know-how can be in part provided by Knowledge-Based Systems (KBSs). One such system, being developed in C Language Integrated Production System (CLIPS), is presented here, with focus on the estimation of ball mill selection functions for the purpose of both diagnostic and simulation, and its use for the optimization of ball size. Some of the interpretation and diagnostic rules will be presented, as well as grinding kinetics and classification data likely to fire them.IntroductionSince the late eighties there has been a growing trend in applying Knowledge-Based Systems (KBSs) to mineral processing [Meech 1990, Bearman and Milne 1992). Table l lists some KBS (often referred to as expert systems) applications that have been used mainly as tools for improving on-line monitoring and control of grinding circuits. However, there has been fewer attempts to add the symbolic processing powers of KBSs to conventional off-line grinding simulators. Figure 1 shows a relatively standard procedure to perform an off-line optimization study [Napier-Munn and Lynch 1992]. In brief, a typical program includes taking representative samples from a number of streams, running laboratory tests on collected samples, estimating model parameters which describe physical processing units (e.g. ball mills and hydrocyclones) validating model predictions and using models for simulation trials. One inevitably needs to be familiar with concepts of process modelling and simulation as well as various computer programs to be able to complete all steps of the study. Much of this ""expertise"" can be captured by KBSs, given their inherent capabilities for symbolic knowledge representation and manipulation."

Jan 1, 1997

"RésuméDans la première partie de cet article on discute Ie mode d'écail age aetueJJement en usage dans des mines souterraines. Par la suite, on presente la problematique d'écaillage à l’aide de barres conventionnelles et on discute les plus recénts développements des outils d'ecaillage portatifs et mécanisés ainsi que les techniques de détection des roches branlantes. Plus tard, on analyse la tâche d'écaillage avec des barres conventionnelles. Dans les chapitres qui suivent on présente un concept d'un outil d'écaillage portatif et mécanisé développe à l'Université Laval, ainsi que les résultats des essais de cet outil, effectués dans quelques mines au Québec. On constate que Ie nouvel outil d'écaillage démontre un potentieJ intéressant tant au niveau de l'effort requis pour effectuer la tâche d'écaillage que de la sécurité des mineurs.On conclut que l’application de cet outil fera un pas important sur Ia voie d'amélioration des conditions de travail dans les exploitations souterraines, tout en assuarnt une qualité accrue de l'écaillage.AbstractThe first part of this paper discusses the type of scaling operations presently in use in underground mines and derma; a scaling factor which is expressed as the:: area necessary to scale to extract one ton of ore. Subsequently, the problems associated with conventional scaling methods are discussed as well as recent developments in mechanized hand-held scaling devices and methods of loose detection. The elements of the scaling process are further analyzed. In subsequent sections of this paper, the conception and design of a mechanized scaling device, developed at Universite Laval is described. The results of field tests conducted in Quebec hard rock mines are presented. The experimental findings show that the mechanized hand-held scaling device shows great potential in improving the productivity and safety of underground mining operations."

Jan 1, 1995

By M. F. Gallerneault, V. Fallah, A. Howells, W. M. T. Gallerneault

"The occurrence of recrystallization in cold-worked aluminum sheet during the brazing process leads to loss of strength, an inhomogeneous grain structure and reduced corrosion resistance. AlMgScZr alloys are known for their extraordinary recrystallization resistance due to the influence of Sc and Zr addition on their microstructure. Here, we investigate the effect of alloy composition (i.e. Mn, Mg, Sc, Zr content), cold-roll reduction and pre-aging treatment on the recrystallization behavior of cold-rolled sheets at brazing temperatures typically used during the manufacture of heat exchanger units. The analysis of recrystallization behavior is carried out through microstructural characterization and the results are compared with the behavior of a commercial, AA3xxx-based heat exchanger alloy.INTRODUCTION Control of recrystallization is of critical importance during brazing, which is a widely-used joining technique for aluminum alloys in aircraft structures (Heinz, 2000) and automotive heat exchangers (Miller, 2000; Marshall, 1993). Due to excessive local heat at brazing temperatures, the cold work texture of aluminum alloys in the cold-rolled sheets may undergo a local recrystallization process (Marshall, 1993). This leads to the formation of an inhomogeneous microstructure and thus anisotropic mechanical properties (Miller, 2000) and low corrosion resistance (Marshall, 1993) across the sheet. X800, a commonly-used Al-Mn alloy series for automotive heat exchangers applications, has been developed specifically for a higher strength as well as an enhanced corrosion resistance as opposed to the traditionally-used AA3003 alloy (Marshall, 1993). X800 alloys, however, exhibit a low recrystallization resistance at normal brazing temperatures, i.e. 590°C. In contrast, Al-Sc-Zr alloys have been shown to exhibit an extraordinary recrystallization resistance at such temperatures (Riddle, 2004) while also being corrosion resistant and possessing a high room-temperature strength (Fuller, 2002). This has been shown to be due to the formation of coherent, nanoscale Al3(ScZr) precipitates that effectively impede grain boundaries while also exhibiting very slow coarsening kinetics at high temperatures (Riddle, 2004; Jones, 2003; Ocenasek, 2001). In this study, we analyze the recrystallization behavior of X800 alloys under brazing conditions through introducing Sc and Zr into the system as well as varying the Mn and Mg content. The effect of processing route is also studied by introducing a pre-aging stabilization treatment as well as varying the cold-roll reduction prior to the final brazing anneal."

Jan 1, 2018

By A. J. Basu

Air quality in underground mining operations can fluctuate significantly during the working day, but until recently the only way to ensure a mine had sufficient air quality was to over-ventilate and, with significant delay in adjusting the volume or direction of the airflow, working conditions were tolerable but rarely ideal. Underground ventilation management systems have been considered to achieve improved energy efficiency since at least 1995 in Canada. However, Mine Ventilation Optimization, (MVO) and integrating it with Ventilation on Demand (VOD) is only becoming more of a reality in the last seven (7) years. A systems approach to MVO takes into account all the elements from the point the power is distributed into the ventilation fans through to the actual quality and quantity of fresh air to the working face. Opportunities exist throughout the system for energy savings but not all of them are cost-effective. Depending on the application, these opportunities can be easily realized by properly sizing, streamlining, maintaining and operating the ventilation system using premium mine proven energy efficient components throughout. Implementation of VOD is a key step in achieving the MVO objective. However, VOD is a concept, and it requires various tools, procedures, and strategies for cost-effective and operationally viable implementations. This paper provides a historical background in the development of VOD and provides a framework for proper and cost effective implementation. In addition, an optimized ventilation system will also allow increased airflow by reducing resistances and shock losses. This turn in would allow production target improvement, which could be an attractive objective compared to energy savings. Mine ventilation is the life support system of an underground mine, and contributes to sustainable development and corporate social responsibility goals assuring health and safety aspects of strategic planning. The proposed framework addresses implementing mine ventilation optimization integrating ventilation on demand as a vehicle for energy, health and safety improvement and overall productivity gains in the mining cycle efficiency while significantly reducing carbon footprint of a mine.

Aug 1, 2013

By Dani J. Alldrick, Alastair J. Sinclair, Colin I. Godwin

"The Stewart mining camp has a long history of precious and base metal mining. The camp is abundantly mineralized, with more than 200 widespread, varied, vein prospects, deposits and orebodies. These show wide variations in the mineralogy of ore, gangue and alteration assemblages, and wide variations in textures and structural settings. This report establishes the timing of the different metallogenic epochs and suggests a specific exploration application for systematic leadisotope analyses.Galena lead isotope ratios from a range of mineral occurrences indicate that all these varied deposits formed during two main mineralizing events. Lead isotope data from the Stewart mining camp do not provide absolute ages for the formation of mineral deposits, but the relative distributions of data are consistent with dates determined in other studies. One ore-forming episode occurred in the Early Jurassic and the other in the Middle Eocene. Both metallogenic epochs were brief, regional-scale phenomena. Some deposits from the younger mineralizing episode were emplacedadjacent to or superimposed on the older deposits.Field and laboratory studies show that the two metallogenic epochs are characterized by different base and precious metal suites: Early Jurassic gold-silver-zinc-lead-copper; and Middle Eocene silver-lead-zinc. Therefore, showings of different ages have different base and precious metal potentials and deserve different exploration emphasis. Lead isotope studies provide a reliable, cost-effective method for evaluating the age and commodity potential of small or recently discovered mineral showings and for setting exploration priorities on properties with several varied mineral occurrences. The determination of the age and metal potential of a prospect at an early stage of exploration may govern the urgency, intensity or even the necessity for further exploration work."

Jan 1, 1993

By D. M. Ward, J. H. Ahrens

"The Fond-du-Lac uranium deposit was delineated primarily by percussion drilling and a small program of diamond drilling. Drillcore samples from three diamond drill holes as well as digitized gamma logs from percussion and diamond drill holes were utilized to define and implement an algorithm for the conversion of gamma-log data to equivalent-grade data. The procedures and detailed analysis for the provision of assay data for uranium reserve estimation are documented.IntroductionThe Fond-du-Lac uranium deposit is on the south shore of Lake Athabasca, approximately 2 km southeast o f Fond-du-Lac , northern Saskatchewan. It is on the northern rim o f the Athabasca sandstone basin.A train of mineralized glacial erratics was discovered in 1967 by Farnok, Limited by means of a helicopter-borne radiometric survey. In 1969, a program of diamond drilling by Famok was successful in locating in-situ mineralization in the Athabasca sandstone at the apex of the mineralized boulder train. Since 1974, exploration and development work have been performed under a joint-venture agreement between Eldorado Nuclear Limited and Famok Limited, with Eldorado acting as operator.From the discovery drill hole to the development of the gamma-log to equivalent-grade con version algorithm, the deposit had been tested by a total of 222 drill holes, 210 of which were percussion holes and 12 of which were diamond drill holes. The holes are generally vertical and collared at 10-metre centres on fences spaced 20 metres apart. The deposit is approximately 390 metres long, 10 to 40 metres wide and up to 45 metres deep, and is generally confined to the Athabasca sandstone. Uranium occurs as pitchblende, coffinite and uraniferou s goethite."

Jan 1, 1983

By S. A. Kenzap

This paper provides an overview and discussion of key aspects of operating risk valuation in underground metal mining systems, with impact on project economics, using stochastic computer modelling in Discounted Cash Flow (DCF) analysis. Mine operating risk classification and assessment for ground, equipment and scheduling aspects are presented with an overview of available risk valuation tools that have been developed in engineering disciplines. The classification is organized by keeping in perspective the mine design needs and constraints, as well as the potential economic impact that operating problems can have on an underground development and production system. These sources of cost, revenue and time delays are tabulated to enable the hierarchization of potentially hazardous unplanned events occurring during the mining project life cycle. In complex technological systems, like the underground mining systems, the decision-making process involve a wide range of uncertainties, and often this is based on subjective and qualitative expert evaluations. Whether a qualitative or quantitative analysis is conducted, it is often the case that the probability of a certain project parameter value needs to be estimated. This requires use of methods and techniques to handle subjective, qualitative measures and to combine them with quantitative stochastic modelling in order to evaluate mine operations-related issues on DCF economic performance measure parameters. Links are established between decision making and the risk-based mine planning process for evaluation of design alternatives, with emphasis on the need of introducing flexibility in mine design. Finally, challenges of risk-based mine planning and design implementations are discussed and the call for an integrated risk-based real options systems valuation (ROV) ?in? projects analysis is made.

Aug 1, 2013

By B. M. Das, D. B. Cross

"In June 1983, the Computer Applications and Process Control Committee (CAPC) of the Canadian Institute of Mining and Metallurgy (CIM) circulated a questionnaire to coal mining, exploration and consulting companies in Canada to determine the industry's level of interest in holding a workshop-style meeting to introduce company personnel to ""state-of-the-art "" computer systems designed to carry out specific technical and management junctions. It was necessary to conduct the survey to determine the specific fields of application and the nature of training which are of most interest.Almost universally, the companies expressed interest in computer workshops and training for applications in the Canadian coal industry. The survey showed that all categories of personnel felt the need for some sort of training. Areas of specific interest identified were: exploration and geology, mine design, reserve calculations, coal mining technology, coal preparation, rock mechanics, ventilation, financial planning, and process simulation. The details of this survey together with an assessment of the significance of computer applications in the Canadian coal industry are presented in this paper."

Jan 1, 1986

By Simon C. Dominy, Patrick R. Stephenson, Alwyn E. Annels

Abstract - The often complex, erratic, and localized nature of gold is a common feature of many vein-style gold deposits. This style of mineralization is often referred to as being nuggety or possessing a high-nugget effect. As a result of these complexities resource estimation is difficult and in general, only Exploration Results can be provided or an Inferred Mineral Resource estimated from surface drilling data alone. Underground development, further drilling, and probably bulk sampling will be required to delineate Indicated and Measured Resources. Tonnages can generally be estimated from diamond drill and development information with a reasonable degree of confidence. Grade is much more difficult to define with confidence because it is commonly highly erratic and discontinuous in nature. The dependency of higher confidence Resource categories on development information may create a Catch 22 situation, with funding for such development often depending on the prior definition of at least Indicated Resources. There are no easy solutions to these challenges posed by high-nugget effect deposits, and it is important when classifying and reporting not to downplay the uncertainties often associated with Mineral Resource and Ore Reserve estimates for such deposits. However, in common with all deposit types, if the principles that underpin the estimation, classification, and reporting procedures are borne in mind and common sense applied, most issues can be satisfactorily resolved. This paper discusses the classification and reporting of Mineral Resources for high-nugget effect gold vein deposits within the framework of the JORC Code (JORC, 1999).

Jan 1, 2001

By H. H. Wang

Construction safety documents regulate significant safety actions and requirements by which construction workers or employees should abide in order to secure them from occupational hazard events. Therefore, facilitating faster identification of applicable safety requirements from the documents has become an important topic in the construction safety domain. To address the need in this regard, tools and techniques have been developed and research efforts have been made. One of the research efforts is to utilize ontology, a knowledge representation and reasoning approach, as the methodology to achieve the goal of identifying applicable safety requirements. In such ontology-based researches, the development and construction of the safety concept ontology is an essential task as the concepts and the relationships between the concepts both representing key safety knowledge need to be carefully identified. In this paper, the author focuses on the safety documents without predefined concept structure and aims to address the concept and relationship identification difficulties. Specifically, the author leverages the Formal Concept Analysis (FCA) methodology, a theory of data analysis that identifies conceptual structures among data sets, to mine and analyze the documents in order to discover safety concept structure and to further assist the development of the concept ontology for the construction safety documents. The author expects the application of FCA to construction safety domain can eventually benefit the ontology-based approaches for identification of applicable safety requirements.

Aug 1, 2013

By Brock Morrison, Bernt Ling

"The Kiruna Electric System is an all electric ramp haulage system developed for underground mining. This electric truck haulage system is currently operating on three continents. This paper will review the technology of the system, existing installations as well as the economical benefits to the mining industry. The system was designed and developed to extend and exploit the economical advantages of ramp haulage. Performance information is provided. IntroductionThe Kiruna Electric System has been the subject of a number of technical papers over the past sever al years. During that period, the content of the presentations has changed from concept and theory to prototype testing to description of installed and operating systems.The intent of this paper is threefold:1. to present a brief review of the technical features of the Kiruna Electric Systems;2. to review the existing installations with performance data; and3. to provide a description of on-going developments within the Kiruna Electric Program during 1991.The Kiruna Electric is a high capacity ramp haulage system for underground mining operations due to an All-Electric Drive System, including two heavy duty electric traction motors. The high capacity of the K1050E results from three factors:• payload - 50 tonne• speed - 18 km/hr to 20 km/hr up a IS0J0 ramp (total resistance)• availability - over 90010 during a 12-month period"

Jan 1, 1991

By T. Takahashi, K. Oyamada, Y. Miyata, T. Isoo

The carbonation reaction of steelmaking slag has been known for many years. However, the size of blocks manufactured from this by-product material has been limited due to the difficulty of achieving a uniform reaction throughout the block. Using newly developed conditions, large porous slag blocks (1.0 x 1.0 x 0.5 m) were produced by car¬bonation of steelmaking slag with the optimum amount of water and supplying CO2 deep into slag powder compacted in molds. The development of these blocks has great poten-tial to solve the problem of slag utilization, for example, by recycling slag in large car¬bonated blocks for artificial fish reefs and seaweed cultivation beds. This paper de¬scribes the carbonation reaction, the new process for producing large slag blocks, and the utilization of blocks in past and recent years.

Jan 1, 2004

By Brian Hart, Stamen Dimov, Aparup Chattopadhyay, Barun K. Gorain

"A novel gold deportment technique has been developed for complex copper-gold and double refractory gold ores using state-of-the-art technology. Characterization of these ores is a challenging task due to low copper and gold grades in ores, presence of both primary and secondary copper sulfide phases and variable proportion of visible and invisible gold in different sulfides and iron oxide phases.Double refractory ores are mainly composed of silicates and carbonates with moderate clay and mica, and minor amounts of sulfides and organic carbonaceous matter. Gold mostly occurs as ""invisible gold"" (sub-microscopic gold) as solid solution or as colloidal-sized particles in different sulfides and other phases. The dominance of invisible gold and presence of highly preg-robbing and finely disseminated carbonaceous matter adversely affects gold recovery in flotation and leach circuits. Characterization of this carbonaceous matter, commonly known as TCM and quantification of gold associated within TCM, along with different sulfide and oxide phases is highly complex and challenging.Studies were initiated on various complex ore deposits and also on samples representing various process streams. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy techniques, namely, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metal content in various species. The relevance of the mineralogy characterization to metallurgy will also be discussed in this paper."

Jan 1, 2016

By C. A. Rowland

"Plant owners and operators, plant designers and grinding mill manufacturers are giving much attention to the design and manufacture of autogenous and semi-autogenous grinding mills, particularly the mills that have large diameters and draw power up to 10,000 hp and greater. Reliable designs giving long operating lives are required in today 's ore processing plants.This paper reviews bench-scale and pilot-plant testing to determine first if the ore is suitable .to be ground by these methods and then reviews the data obtained from pilot-plant testing that is used to select the mills and the grinding circuit. The paper then discusses the use of the pilot-plant results to design the mills. The most important pilot-plant data used for mill design are power and the amount of ball charge to be used. The mill size selected is a combination of these factors. Pilot-plant data not only establish power requirements, but can be used in the selection of the type of drive, variable speed or fixed speed, and the operating procedure to be followed. This leads into the mill control circuit to be used. The total charge in the mill, the type of drive and mill discharge arrangements are needed in the calculation of stresses and bearing loads. Conclusions reached from pilot-plant work are used to obtain data for process design, and autogenous and semiautogenous mill design should be part of any test program incorporating either or both of these grinding methods."

Jan 1, 1981

By R. Ghomashchi

Wear, fatigue and corrosion are the most widely encountered modes of failure in materials used in engineering applications, including aero-gas turbines. Although wear is distinctly classified as adhesive, abrasive, erosive, fretting and so on, there are usually more than one wear mechanism involved in the failure of components in service because there are many systems and materials variables active in materials wear that makes it more difficult to study. This is further complicated by the discrepancies between the results of laboratory tests and field data. The present investigation was set up to examine the wear characteristics of M50 and T1 high-speed steels at both room and elevated temperatures to draw a thorough understanding of the wear behavior of this class of high-speed steels. This article focuses on the mechanical and microstructural characterization of wear for T1 and M50 high-speed steels using a pin-on-disk wear machine.

Jan 1, 2005

By G. Shen, W. R. Tyson

In most fracture toughness test standards, such as ASTM E 1290 and BS 7448, crack-tip opening displacement (CTOD) is measured by using three-point bend (SE(B)) or compact (C(T)) samples with deep cracks. The loading mode and crack depth in these tests sometimes are different from that of pipelines. Pipelines usually have shallow defects and experience tensile loading when the supporting ground moves. As a result, the CTOD measured by these samples is lower than that of pipeline in tension. Recent researches suggest using single-edge-notch tension (SE(T)) samples to measure fracture toughness for pipelines. In the present study, shallow and deep SE(T) samples under fixed grip loading were analyzed by using the finite element technique. An equation to relate the CTOD to the area of the load/plastic crack mouth opening displacement (CMOD) is proposed. With this equation, the CTOD of a SE(T) sample can be evaluated by measuring the area under the load/plastic CMOD curve of a SE(T) sample.

Jan 1, 2005

By T. A. Lazier, C. S. Longley

"Paymaster Consolidated Mines, Limited, owns several groups of claims in various parts of the Porcupine district. The area in which mining has been carried on includes parts of lots 5, 6, and 7, con. 1, Tisdale township, and twelve adjoining claims in Deloro township to the south. Highway No. 67A between South Porcupine and Timmins crosses the property.The discovery of the Dome mine in 1909 caused a rush of prospectors to the district and in a few weeks practically all territory adjacent to the Dome was staked. At that time work was started on the West Dome, West Dome Lake, Apex, and Standard properties. These were consolidated in 1930 to form the present Company. Gold was produced from the West Dome Lake from 1915 to 1930, and from the Standard-Paymaster from 1922 to 1928. The total production of the previous and present companies from 1915 to November 30, 1946, has been 487,170 oz. gold and 149,342 oz. silver from 2,337,554 tons of ore."

Jan 1, 1954

By Min-Yuan Cheng

Landslides not only cause interruption of road traffic but also cause damage to passing by vehicles and injure people in Taiwan. Due to the budget limitation of government, the overall assessments and maintenance of all road slops cannot be fulfilled. Priority of road for maintenance is a crucial task for road maintenance department to identify. The purposes of this research are to develop an assessment method for the landslide risk and to make strategies to maintain or repair the slopes along mountain roads. To aim both needs to take into account the environmental conditions of the slopes, the engineering measures for stabilizing road slopes, the transportation issues, and the human concerns when dealing with the slopes maintenance along the mountain roads. This study firstly establishes the Landslides Damage Risk Evaluation Model (LDREM) to calculate the risk of slope failure, considering the probability of landslides, temporal probability, spatial impact probability, the value of human life, transportation time increased, and travel cost due to detour etc., and then the loss of life and transportation can be calculated. Secondly, based on the value of risk and the risk evaluation, considering the risk acceptance criteria for loss of life could provide assistance for road maintenance department to determine the priority of mountain roads for maintenance.

Aug 1, 2013

By Roger St. C. Smart, Paul Weber, Joan E. Thomas, William M. Skinner, Warwick Stewart, Stuart Miller

For mine sites affected by acid rock drainage (ARD) or with a potential future ARD issue, the prime consideration is not only the classification of different waste rock as potentially acid forming or non acid forming but also the peak acid (and metal) release rates and expected ARD duration during which effective ARD management and acid neutralisation capacity (ANC) are required. Methods for assessment of this ANC (e.g., Sobek tests) are already available but can be unreliable in ARD containing significant proportions of framboidal pyrite or iron carbonates. The measurement of negative ANC values and the release of S to solution showed that significant sulfide oxidation may occur prior to and during testing in samples containing reactive (particularly framboidal) pyrite resulting in serious underestimation of the original ANC. A simple methodology with dissolution in Ar-purged water before ANC testing, removing ferrous salts, and sulfate assay after ANC testing corrects these effects. Results also showed that a significant lag period (up to 432 h) may be needed for complete hydrolysis of Fe associated with the standard Sobek ANC testing of, for instance, siderite. Hence, the ANC of iron carbonates is usually significantly overestimated. By filtering and the addition of H202 until there was no subsequent pH drop (due to Fe hydrolysis reactions), followed by back titration to pH 7.0, the ANC for siderite was similar to the ANC determined after 432 h lag by the Modified Sobek ANC test and to the mineralogical carbonate ANCcarb determined by calculation based on electron probe micro-analysis. A chemical ANC calculation, based on neutralising cations released to solution, has provided a method to quantify the short-term ANC of carbonates and silicates in simple mixed mineral assemblages and waste rock samples. Results showed that silicate ANC can be more important in short-term neutralisation than carbonate ANC in low carbonate samples. In the longer-term, decreasing sulfate and metal loads with increasing pH values suggests that eventually sulfide acidity generation rates will match the longer-term inherent acid neutralisation rates of the sample derived from silicates. A kinetic ANC measurement for silicates, after steady state dissolution is reached, that indicates the number of hydrogen ions neutralised/m2/yr has been developed. These values can be used in estimates of the net acid production profile from wastes with low (and decreasing) pyrite content after the short-term ANC is exhausted.

Jan 1, 2004