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By James E. Rider

"Fractures in mine hoist drumshafts are rare. We know of no previously reported attempts to repair a fractured drumshaft; any feasible method would involve welding and the associated problems of distortion, crack formation and strength.In June 1984, a fracture was discovered in the drumshaft of the production hoist in the Teck Corporation, Lamaque Division Mine at Val d'Or, Quebec. Delivery time on a new shaft would have been at least six months. The shaft was repaired in ten days and the total out -of-service time was four weeks.This paper describes why the shaft failed, how it was repaired, and the special alignment procedures employed during re-installation to minimize stresses in the repaired area.IntroductionThe performance of a mine hoist drumshaft is absolutely critical to mine operation. An inoperable drumshaft means no hoist, which in turn means no production or mine operation.Fractures in mine hoist drumshafts are rare. Previously when they have occurred, no one has seriously considered attempting a repair because of problems involved. Any feasible method would involve welding, which raises several major problems - namely, metallurgical, alignment, and strength.In July 1984 this very situation occurred at the Teck Corporation, Lamaque Division Mine in Val d'Or, Quebec.It was recognized that a new shaft would take at least 6 months' fabrication and delivery time. However, having had some experience at repairing broken shafts in other machines under similarly desperate circumstances, and after due consideration, it was concluded that by applying the correct techniques and engaging the right expertise, it would be possible to perform a repair and have the mine back in operation within a month.Thanks to outstanding efforts by all, the repair was accomplished in ten days and total out-of-service-time was only four weeks. The causes of the failure were determined and the calculated stress levels confirmed by strain gauge measurement during operation.The success of this project was achieved by adhering rigorously to fundamental management and engineering principles."

Jan 1, 1988

Mining companies around the globe have long struggled with the need to ensure that earth moving equipment is designed to be operated and maintained under all site conditions without causing harm to people. Incident and accident data from a range of sources clearly identify mining equipment related issues as major causal factors. One Australian source, the NSW Department of Primary Industries? International Mining Fatality Database Project Report (2008) noted that ?Approximately 77% of mining accidents resulting in a fatality have? involved equipment?. The largest number of fatalities were associated with trucks; the next with LHDs. Many of the technical advances in equipment design over the past few decades have not been matched by advances in the human factors design of mining equipment, resulting in a ?design vacuum? that must be filled prior to commissioning new equipment. This ?design vacuum? is generally filled by local dealers. They retrofit equipment according to customer requirements to mitigate risks that have not been designed out by the Original Equipment Manufacturer (OEM). Mining companies have been frustrated by lost time and additional costs associated with this need to retrofit ex-factory designs. Some companies have attempted to address the problem by negotiating company or site-wide ?solutions? to equipment designs, but this has not simplified or clarified the issue from the point of view of the equipment manufacturers. A number of mining companies operating in Australia first discussed the concept of a joint customer approach to improve the Human Factors design of earth moving equipment at the factory level in 2004. They agreed that a new approach to engaging with OEMs was needed; one that would define the ?Problem?, in other words, the basis of the risks, rather than dictate the ?Solution?. The Earth Moving Equipment Safety Round Table (EMESRT) was formally established in 2006 by six global mining companies to establish a process of engagement between Original Equipment Manufacturers (OEMs) and mining customers.

May 1, 2009

By E. G. Gaylord

THE material improvements which have been made in the practice of exploiting oil and gas reservoirs in the United States during recent years may be attributed largely to: (1) The necessity for drilling deeper wells at costs not much greater than was formerly expended on shallower wells. (2) The necessity for producing oil at a lower cost per barrel. (3) A growing recognition of the importance of the nature of production practice upon ultimate yield of oil and gas. The first two of these factors result, to a large extent, from the fact that a greater proportion of new development has been deeper development, and these wells have been drilled in the face of progressively lower per well allowables. In California, for instance, maximum allowables have declined from 400 barrels per day in March, 1938, to 156 barrels per day in September, 1940, and during this same period some 125 wells were drilled to the deeper 10,000-foot producing horizons discovered during this time. The third item listed above results from our increasing knowledge of the basic factors which influence the amount of recovery we may expect from reservoirs. In addition to the longer-range planning now being undertaken by the more prudent operators, State proration and conservation laws have focused attention upon the importance of methods conducive to obtaining progressively greater quantities of the hydrocarbons in place. In a paper of this length it will be possible to discuss only a few of the recent advances. An effort has been made to select the more important of these and to indicate, where possible, the factors which have made these advances possible.

Jan 1, 1941

By Ros Taplin

Realizing the potential of cutting greenhouse gases (GHGs) associated with mining, a variety of approaches has been proposed for their mitigation. The Clean Development Mechanism (CDM) under the Kyoto Protocol to the UN Framework Convention on Climate Change (UNFCCC) has been a key mechanism to assist in implementation of mitigation measures. The objectives of CDM are not only to assist Annex I countries in meeting their GHG emissions reduction targets with cost-effective reduction but also to achieve sustainable development in non-Annex I countries. However, apart from China, India, Brazil and Mexico, many developing countries are still in the stages of formulation or realizing CDM strategies. Projects associated with methane capture and flaring are the fourth most prevalent type of CDM project internationally. This research primarily has addressed emissions abatement and sustainable development aims and effectiveness of registered CDM projects associated with coal mining in China. The paper reviews 30 currently registered CDM projects in China on the UNFCCC database and six other non- Chinese projects. Systematic evaluation involving content analysis of documentary evidence regarding coal mining CDM projects is presented in relation to firstly, quantitative reduction of GHG emissions and secondly, sustainable development outcomes. The projects have been assessed via a set sustainability criteria. Overall it was found that sustainable development goals are only briefly referred to in Project Design Documents, Letter of Approvals and validation documents. Varying types of sustainability initiatives have been implemented with weak to strong indications of effectiveness. This has implications for the future effectiveness of CDM projects in the mining sector, the proposed new market mechanism under UNFCCC, and for assessment of projects under mechanisms established outside the UNFCCC.

Aug 1, 2013

By M. Phylli Bray

"Mining has the reputation of being a very ""macho"" industry. Recently, wider educational opportunities for women in nontraditional occupations and changes in mine technology have combined to make mining a viable career choice for women also. To benefit from this new resource, the mining industry faces the challenge of developing a different work environment from the one now burdened with sexism. Management supported initiatives are needed to facilitate such a transformation. The same rethinking of gender attitudes might also be extended to mining women in their traditional role as ""wife of"". The assumption that the male worker's wife is an unpaid adjunct is being questioned. It is suggested that women's separate concerns both as helpmate and as part of the mining workforce should be considered when planning for mining into the 21st century.IntroductionI must confess that, during the preparation of this paper, there have been many moments when I questioned my temerity. After all, I am not male, I am not an engineer, and I have never had a position in mine management. But as the wife of a mining engineer and a long-time resident of Northern Ontario mining towns, I do have an interest in the mining industry. This interest has had little to do with the technical and management aspects of the industry. Instead my research has been concerned with the impact the mining industry has on the people involved, particularly women, whether directly as employees or indirectly as wives. As I look toward the 21st century, I believe that the whole question of gender relations in the mining industry is one of the critical management issues smouldering below the surface."

Jan 1, 1995

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016

By G. M. Proudfoot

IN June, 1940, a .Longyear 3420 blast-hole drill rig was purchased by the Hudson Bay Mining and Smelting Company for the purpose of experimental blast-hole drilling. The early work showed that the diamond drill could compete successfully with the Leyners then in use and by January 1st, 1941, the diamond drills were placed on contract. They may be considered to have gone into production at that date. Prior to the introduction of the diamond drill, our bench drilling was clone with Ingersoll-Rand S-70 and S-83 Leyner drills. Holes up to 40 feet were drilled, using coupled 1 1/4-inch round steel. Bits with a gauge of 3 inches were used in starting these holes, with a drop of 1/8-inch gauge for each 2-foot run. The holes normally ended with 1 1/2 or 1 5/8-inch gauge, though bits down to 1 1/8 inches were available for holes longer than normal or for holes drilled in abnormally abrasive ground. This method of drilling was very satisfactory and was a distinct improvement on the three-bench method of drilling used previously (1). During 1937 and 1938, when experienced miners were available, Leyner long-hole drilling was carried on with great efficiency. However, in 1939 and 1940, labour turnover in-creased and experienced long-hole drillers became scarcer. This resulted in a marked decline in the efficiency of the drilling operations, with increased costs and less tonnage drilled per shift. EXPERIMENTAL WORK The initial diamond drilling test work was carried on with a Longyear 3420 air-driven blast-hole drill rig, drilling a 1 3/16-inch hole. Tests indicated that diamond drilling could be successfully adapted to local conditions and that overall costs compared favourably with costs obtained with the Leyner long-hole method. Leyner long holes on stope benches usually bottomed at a larger diameter than the 1 3/16 -inch diamond-drill holes. More powder could therefore be introduced into the Leyner holes than could be placed in the diamond-drill holes. To achieve the same fragmentation, additional footage was required when diamond drilling. Diamond-drill holes of larger diameter were indicated.

Jan 1, 1943

By Scott K. Palm, Neil D. Pearson, Jr. Read

"Uncertainty is an important feature of many investments, but it is especially important for mineral properties. Mine properties often entail large investments and fixed commitments. Managers in the mining industry often view price uncertainty as undesirable, due to the possibility that the price of the mined commodity will fall to a level that prevents the firm from recovering its investment and fixed costs. This paper identifies pitfalls in conventional valuation methods and outlines a new approach to valuation based on option pricing theory and dynamic programming. In the process, it identifies generic strategies for organizing mine production in ways that allow the owner to benefit from the uncertainty in mineral prices. IntroductionRisk is pervasive in the mining industry. The operation and maintenance of a mine may involve high, and unavoidable, fixed costs. A mine owner can only begin to recover these fixed costs if the price of the mined commodity is greater than the incremental cost of production. But the prices of many minerals are extremely volatile. The price volatility of copper has been significantly higher than the price volatility of a typical stock, for example. A mine owner cannot be sure that the price of the mineral product will remain high long enough for the firm to recover its capital and fixed costs.Mine owners are able to minimize their losses during periods when the output price is below the incremental cost of production by temporarily closing operations. During these periods they incur only fixed costs. While shut-downs help minimize losses, the y do not help the firm recover its initial investment. If output prices remain low long enough, the fixed costs and original investment may never be recovered. High fixed costs, therefore, lead to substantial downside risk."

Jan 1, 1986

By Gerhard W. Heinrich, Gerald V. Schroeder, Daniel A. Murphy, Daniel F. Suarez, Jamie B. Beauchamp

"Washwater 'Finger' sprays were installed and tested in the copper/nickel separation circuit at Strathcona Mill to improve flotation capacities and related metallurgical performances. The new spray design features submerged sideways introduction of wash water into the flotation froth through nozzles at the end of vertical pipes which are suspended from a header above the froth. This maximizes the effective cross sectional area of flotation vessels while maintaining effective froth cleaning and a desirably high density of the concentrate slurry. The plant tests gave increases of copper concentrate production rates of 17% to 20% for conventional cells and 16% to 20% in column flotation at target grades of 29% to 30% copper and of less than 0.5% nickel. Basic considerations and concepts of tests and evaluation procedures are described.IntroductionMeeting flotation concentrate grade targets at maximum production rates and recoveries is a challenge all too familiar to operators of base metal ore concentrators. Frothwashing is an option to improve grade/recovery performance by minimizing entrainment of impurities into the concentrate, which is commonly known since the sixties (Kaya & Laplante, 1989). It has been recommended for the flotation of sulphides and industrial minerals alike (Kaya & Laplante, 1989; Miller, 1969; Heinrich, 1989) and has found its ultimate application in flotation columns (Finch & Dobby, 1990). The washwater addition in a flotation column is most evenly distributed over the column's cross-sectional area thus ensuring almost complete displacement of feed water from the froth by a countercurrent washwater flow -provided, a positive bias is maintained. Therefore, flotation columns are ideal for cleaning flotation. However, there is usually less room for boosting the concentrate production capacity by increasing airflow or slurry level then with conventional cells because of the smaller cross-sectional area available."

Jan 1, 1994

By P. K. Kaiser, S. Maloney, S. Yazici

"This paper focusses on the strength or capacity of cable bolts and introduces a new perspective for cable bolt design by demonstrating that mining-induced stress changes may affect cables in a detrimental manner. The concept underlying a novel cable bolt pull-out resistanceor bond capacity model is described and its practical significance is demonstrated by application to a simple two dimensional scenario of a fall-of-ground.A number of practical implications emerging from the application of this model are discussed to provide guidance to ground control personnel jar improving cable bolt support systems in mining applications. These include cable layout optimization, use of cable pre-reinforcements, assessment of embedment length requirements, need for plated cables (or straps), use of bird-caged cables (or buttons), and grout quality issues.IntroductionDuring the last decade, cable bolting has become a standard support technique in mining for handling wide spans, reinforcing are passes, preventing or reducing dilution of ore in marginally stable stopes, and for many other rock support need s.In its infancy, many deficiencies in cable bolt supports resulted from improper installation techniques and, in particular, grout quality control problems and the use of empty breather tubes (Goris, 1990). The development of special grout pumps and fail proof placement procedures (Oliver, 1992; Bourchier and O'Flaherty, 1992) have eliminated many of these early problems. Nevertheless, there are still situations where cables seem to lose their capacity during mining, and in these cases the cables do not provide the expected and needed ground support. In some instances, cables perform extremely well, whereas in others the same support layout and quality of support installation seem to be insufficient, allowing falls-of-ground or progressive cavings to occur."

Jan 1, 1992

By K. D. Watson

"THE Mindamar zinc-lead-copper mine, owned by Mindamar Metals Corporation Limited, is at Stirling in Richmond County, near the south-eastern shore of Cape Breton Island, Nova Scotia (Figure I). It is connected by several roads with the Canadian National railway at Sydney and St. Peters.The deposit is said to have been discovered around 1895 as an outcrop in the bed of Copper brook, but the details are obscure. Not until 1925, when it was optioned by American Cyanamid Company, was it developed underground. Between 1927 and 1938, the 1-nine was operated intermittently by The British Metal Corporation (Canada) Limited, and yielded approximately 200,000 tons of ore averaging about IO per cent zinc, 2 per cent lead, I per cent copper, and small quantities of silver and gold. In December 1950, Dome Exploration (Canada) Limited made an agreement with Mindamar Metaî Corporation Limited, which was exploring the old mine, to assume management and prepare the property for production. Production started in April 1952 with a new mill and a new four-compartment shaft, and between that time and the end of 1954 it has totalled 545,347 tons of ore averaging 5·89 per cent zinc, 1·35 per cent lead, 0·66 per cent copper, 0·032 oz. gold, and 2 151 oz. silver.The Mindamar orebodies are irregular lenses and large veins lying within a wide, almost vertical shear zone of remarkable persistency. The shear zone consists mainly of well-foliated sericite schist derived from siliceous siltstone, and it contains a vast amount of dolomite and magne-site of hydrothermal origin. Most of the ore is extremely fine-grained and some of the high-grade material has a conspicuous thinly layered structure. The metallic minerals, in order of decreasing abundance, are pyrite, sphalerite, chalcopyrite, galena, and tennantite; the gangue minerals, in the same order, are dolomite and magnesite, quartz, sericite, talc, chlorite, barite, albite, and alunite.The geological setting of the deposit is shown in Figure 2. Except along streams and lake shores, almost all of the bedrock is concealed by glacial drift. The group of rocks in which the deposit occurs consists principally of greywacke, siltstone, tuff, brecoia, and Javas, and has been correlated lithologically with the Bourinot group of Middle Cambrian age. A short distance west of the mine, these rocks are in contact along the Stirling fault with conglomerate, arkosic sandstone, and quartzite belonging to the Middle River group of Silurian or Devonian (?) age, which elsewhere in the area overlies the Bourinot group unconformably. The large bodies of granitic rocks in the region, and the large lenticular masses of diorite and quartz diorite associated with them, have been assigned by Weeks (5, pp. 68-69) to the Devonian."

Jan 1, 1949

By Robert D. Brown, Robert B. Parsons

"Careful tax planning and proper attention to the regulations can result in an optimum deduction ""of the 25% federal resource allowance. Introduced in the Income Tax Act in1976, in part to compensate for the disallowance of provincial mining taxes and royalties. the 25% ""resource allowance"" is a permitted deduction in computing taxable income from mining and petroleum. However, the rules relating to the deduction are complex, and the importance of the deduction which can readily exceed 25% of net income- is frequently underestimated. This month, Tax Notes discusses the basic rules of calculating the resource allowance, and suggests some tax planning aspects which may warrant consideration.May 6, 1974 - "" .. . our provinces have adjusted royalties, mining taxes and other arrangements to derive what they perceive to be a fair share for the benefit of their people. However, a provincial resource is also a national resource... I am proposing that revenues derived by provincial governments in respect of production from a… mineral resource should no longer be.\ deductible in computing the income of the operator. .. I am proposing that. .. there be an extra abatement from federal income tax in respect of taxable production income.. .fifteen points in the case of mineral profits. .. "" - The Honourable John N. Turner, Minister of Finance. June 23, 1975-"" '"" to meet, at least in part, the request for some form of deductibility in the tax system for provincial resource levies... to offer more incentive to those who explore and develop in Canada. .. I am now proposing, the extra fifteen point abatement of federal taxes would be withdrawn... at the same time, I am introducing a new resource allowance, which would be an extra deduction from income equal to 250/0 of production income.. ."" - The Honourable John N. Turner, Minister of Finance."

Jan 1, 1980

By Lionel Roberge, Borge J. G. Fredriksson

"Late in 1981, a six-rope friction hoist was installed in the Number 2 shaft at Les Mines Seleine Inc. on the Madeleine Islands in Quebec. This paper deals with the reasoning behind the selection of hoisting equipment from the economical point of view, safety point of view, future needs point of view, etc.After establishing the basic parameters for the hoisting system, features of the most common types of hoists (i.e. single-drum hoist, double-drum hoist, Koepe hoist) are briefly laid out. The reasons for selecting a friction (Koepe) hoist are summarized. However, why go for a six-rope hoist rather than the (in North America) more common four-rope hoist? As the subject hoist is the first six-rope hoist in Canada, this question is studied in more detail, covering initial cost, maintenance cost, etc., as well as practical aspects, such as safety, physical dimensions, etc.In summary, experiences from other multi-rope hoist installations world-wide are presented.BackgroundIn 1980, Seleine Mines Inc. was established as a subsidiary of SOQUEM. The new mining company was to develop and operate a salt mine and associated harbour on the Madeleine Islands in the Gulf of St. Lawrence. The Madeleine Islands form part of the Province of Quebec. The mine has a planned annual output of 1.2 million metric tonnes of salt, with reserves in sight for over 20 years. Mining will be by room and pillar, with an underground primary crusher and treatment plant. From the underground treatment plant, the salt will be transferred via conveyors to a 5.5-metre-diameter circular shaft and hoisted to the surface. Surface transportation to the warehouse will again be via conveyor, and a conveyor will also transport the salt from the warehouse to the point of shiploading."

Jan 1, 1983

By Barton G. Stone

The mining and exploration industries have been using Geostatistics (Matheron, 1963) for the past forty years. It has been extensively incorporated into three dimensional block modeling software whose usage has reflected the growth in the use of personal computers since 1980. Because of the utility of geostatistical models in mining and production planning, much of the modern reserve and resource modeling is done by mining engineers, geostatisticians and geological engineers. Explorationists are initially less concerned with three dimensional models until such time as a deposit has been roughly delineated. However, the concept of regionalized variables in ore deposits deals with the effect of spatial correlations between data points in a three dimensional sample space and should be useful for optimizing the spacing of drill holes to allow maximum bang-for-the-buck in drilling programs. This paper examines three common deposit types (porphyry copper, VMS and intrusive gold) to examine whether geostatistical methods have been used to minimize drilling costs because of better understanding of spatial correlations. The three model types were chosen from publicly available corporate websites of Canadian based Junior Mining Companies. They include the Wolverine polymetallic zinc deposit of Yukon Zinc in Yukon, Canada; the El Morro Deposit in Chile (30 percent ownership by New Gold Mining Company, and the Fort Knox Gold deposit in Alaska and 50 percent ownership by Nova Gold Resources). Typically, individual mining corporations post their technical reports as CNI 43-101 reports on their corporate website as indications of the favorability or progress on their more exciting properties. Data considered for this paper was not collected or generated by the author, but the information was extracted from these publicly available sites and had a variety of authorship.

Oct 1, 2009

By J. Zollinger, J. R. Kennedy, E. Bouzy, B. Rouat, D. Daloz

"Ni-based superalloys have been replaced in the last low pressure stage of jet turbines for aircraft by titanium aluminides. In order to improve the properties of these Ti-Al alloys and extend their usage deeper into aircraft engines grain refinement by inoculation has been investigated. Borides are the most common inoculants for Ti-Al alloys, however they form brittle particles which are detrimental to the final properties of the alloy. Inoculants manufactured from a Ti-Al alloy with refractory metal additions were proposed to alleviate the issues arising from inoculation with brittle particles. An alloy was chosen which had less than 10% lattice mismatch with the alloy of interest (Ti-46Al) to maximize efficiency. Initial experimentation showed a decrease in as-cast grain size by a factor of 2 between the inoculated and non-inoculated samples along with an absence of the brittle particles found with boron inoculations. Investigations into the interaction between the inoculants and the melt were also carried out to better understand the inoculant size distribution and efficiency upon solidification.INTRODUCTIONTitanium aluminum alloys are an interesting material for aerospace applications. Their high temperature oxidation resistance and high specific strength make them particularly promising (Kim & Dimiduk, 1991). Recently, titanium aluminides have replaced nickel based superalloys in the last low pressure stage of the GEnx turbine engine. In order to increase their usefulness in turbines their properties must be improved for high temperature (>800oC) applications. Grain refinement is one method to improve the properties of a material, however current methods of grain refinement of Ti-Al alloys by inoculation have significant drawbacks. A new method of inoculating Ti-Al alloys by using Ti-Al alloys with small refractory metal additions (Nb, Ta) has been developed to avoid the drawbacks of current methods while still being effective grain refiners."

Jan 1, 2016

By Rodney Trevor Jones, Arthur Robert Barnes

Anglovaal Minerals acquired the Nkana slag dump from Zambia Consolidated Copper mines (ZCCM) in 1998 and embarked on an ambitious project to pioneer the recovery of cobalt from slag using DC smelting technology. Anglovaal Research Laboratories performed initial pioneering smelting tests in a 250 kW DC furnace over a 3-year period before engaging Mintek for three piloting campaigns at the 1.5 MW level. Mintek had previously developed a reductive smelting process, patented in 1995, using a DC arc furnace for the recovery of cobalt from slags. The results of the pilot-plant test campaigns were used as the basis for engineering the commercial 40 MW operation installed at Chambishi Metals plc in Zambia in 2001. This paper traces the development of understanding of the metallurgical fundamentals ultimately used to predict furnace performance, reviews some of the extreme technical challenges faced, how solutions were identified and highlights some of the critical issues identified during piloting and how these impacted both positively and negatively on the final commercial operation.

Jan 1, 2011

By Jun Shan

The preparation of poly(N-isopropylacrylamide)-monolayer-protected clusters (PNIPAM-MPC) of gold nanoparticles was carried out in a homogeneous phase using three ways, in which three types of PNIPAM ligands were employed. The first type comprised of PNIPAMs with narrow molar mass distributions, synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and thus, bearing a dithiobenzoate at the chain end. These polymers were used directly to passivate the gold nanoparticles upon the Schiffrin reaction in a one-pot synthesis. The second type of ligands was derived from the first one through hydrazinolysis, and they therefore contained a thiol end group. The third type of ligands was PNIPAMs obtained through conventional radical polymerization, post-modified to contain thiol end groups. The PNIPAM-MPCs were characterized by high-resolution transmission electron microscopy, and by dynamic light scattering. The one-pot synthesis utilizing the ligands of the first type turned out to be a simple and facile method, compared with the other two ways, with which the size of the gold nanoparticles can be easily manipulated mainly by adjusting the molar ratios of PNIPAM / HAuCl4. PNIPAM is a more efficient ligand to stabilize the gold nanoparticles in water and in organic solvents than alkanethiols. The surface density of PNIPAM chains ranged from 1.8 to 3.6 chain/nm2, which is much lower than that typical for alkanethiols. The thickness of a PNIPAM monolayer bound to the gold core is somewhat larger than the size of the random coil of corresponding free PNIPAM in aqueous solution, which suggests that the conformation of a PNIPAM chain bound to the gold core is to extended.

Oct 1, 2003

By N. M. Steven, J. M. Moore, J. L. Kuyper

Mineral exploration and research has led to the identification of four types of tungsten mineralization in the NE-trending, Iargelyensialic, inland branch of the late Proterozoic/early Paleozoic Pan-African Damara Orogen. The mineralization (mainly scheelite) occurs in a terrane (the Central Zone) that is characterized by multiple deformation, greenschist/amphibolite-facies metamorphism and numerous peraluminous S-type granitic and pegrnatitic intrusions. The four major types of scheelite mineralization are (in ascending stratigraphic order of host rock): (1) thin (5 cm to 2 meter) quartz+plagioclase+diopside ± scapolite calc-silicate granofels with fmely disseminated scheelite (scheelite-bearing granofels; SBG) developed as discontinuous intercalations within the calc-silicate rocks of the Khan, Spes Bona, Oberwasser and Kuiseb Formations (Nosib and Swakop Groups); (2) gamet+pyroxene± vesuvianite+scheelite ± fluorite replacement skarns hosted by Okawayo, Karibib and lower Kuiseb Formation marbles in the aureoles of late tectonic, unrnineralized leucogranites; (3) metaturbidite-hosted scheelite- (and possibly wolframite-) bearing tourmalinites, both stratiform and crosscutting, in the Kuiseb Formation located in the 'cleavage fronts' of late tectonic granitoids; (4) scheelite-bearing vesuvianite+quartz+garnet skarnoid rocks (several hundred meters in length) in the calcareous metaturbidites of the upper Kuiseb Formation. These scheelite occurrences were discovered by the follow-up of a large number of tungsten anomalies located during a regional stream sediment sampling program. Detailed mapping, ultra-violet surveys and rock sampling proved to be the most effective surface exploration techniques for locating mineralization; soil sampling and geophysics were of almost no use. The largest, continuous scheelite-bearing skarn of economic interest, Otjua, has a drill-indicated reserve of 250 000 tonnes at 0.53 wt5 WO3 and 8 wt% CaF2•

Jan 1, 1994

By A. Allaire

The Goldex operation of Agnico-Eagle Mines (AEM) commenced operations in the spring of 2008. Following some months of initial operation, the grinding circuit capacity was under-performing according to the original design throughput. BBA Inc. (BBA) was commissioned, in February 2009, to study the different options and recommend the quickest and most cost-effective solution to increase the grinding circuit throughput rate. The mandate was to increase the throughput of the grinding circuit to beyond the original design of 7,000 tpd to 8,000 tpd or greater, while retaining the existing SAG and ball mills. The circuit was modelled using JKSimMet software to evaluate the different options, each with a number of different operating parameters. The option of secondary crushing of the SAG mill feed was retained. Comparison of the different options and simulation outcomes, design of the secondary crushing circuit, operating conditions, and initial adjustments in the design and operating results of the new grinding circuit are discussed in this paper.

Jan 1, 2012

By Mark Sherman

"One of the main functions of a process technology and engineering services provider is to select grinding equipment that will meet the client’s throughput rate target. Prudent risk mitigation strategies would suggest that throughput rate estimates be cross-checked using a variety of techniques.Whilst some comminution circuit designers have estimated specific energy requirements via the manipulation of the Bond specific power equation e.g. Barratt’s Grindpower and OMC’s FSAG approach, other designers have opined that the Bond Indices have no role to play in the calculation of SAG mill specific power. As a result, they have developed their own specific energy estimating methodologies, e.g. SMCC’s Drop Weight based power methodology, SPI, SAGDesign, etc. Each method has its supporters and its critics.The challenge facing the engineering provider is how to nominate an SAG mill based circuit throughput rate estimate when faced with significantly disparate specific energies calculated by the different methodologies. This challenge is exacerbated via the continuing evolution of contemporary circuit configurations such as two stage pebble crushing some of which incorporate HPGR technology as the second stage of pebble crushing.The methodology presented in this paper shows that the Bond Indices are an excellent tool for estimating the specific energy requirements for SAG mills in SAB, SABC and SSS circuits. The method accommodates primary crushed feeds, partial and or fully secondary crushed SAG mill feeds, and emulates the impact of pebble crushing on SAG specific energy. As a result, the new Bond Index based method has provided an additional tool for increasing Fluor’s confidence when predicting SAG mill based circuit throughput rates. Based on this outcome, the author proposes that the decades old conundrum of using Bond Indices to calculate SAG specific energies for SAG mill based circuits has been solved."

Jan 1, 2012