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By John Porritt, Alain Dorval

"TioMin Resources Inc. is evaluating the feasibility of exploiting the heavy mineral sands deposit at Natashquan on the north shore of the Gulf of St-Lawrence, Quebec. TioMin holds the exploration rights to 180 square kilometres, on which 1.6 billion tonnes of sands grading approximately 6% heavy minerals were outlined. The heavy minerals of value include magnetite, ilmenite/hematite, garnet, and zircon. An important part of this evaluation is the development and testing of a mineral separation flowsheet. Under a comprehensive mandate from TioMin, the Centre de recherches minerales (CRM) provided technical assistance to build and operate an on site primary concentrator pilot plant. This plant produced a 93 tonne concentrate, providing over 60 % heavy minerals. This concentrate was shipped to the CRM pilot plant in Quebec City. It was used for further flowsheet testing and for preparation of products and concentrates of heavy minerals with regard to marketing possibilities. This paper presents the flowsheet developed to produce these concentrates.IntroductionIn late 1992, an 11 tonne bulk sample of sand was collected from within the mineralized zone of the Natashquan deposit. This sample was processed over conventional spirals and wet tables at the pilot plant facilities of the Centre de recherches minerales (CRM) in Quebec City. A primary concentrate was produced, from which several 20 kg samples were forwarded to five research laboratories in North America and in Australia. Their tasks were to determine the mineralogical composition of this concentrate and the potential for recovery of marketable minerals from the heavy mineral sands. Satisfactory results obtained from this approach encouraged TioMin to proceed with a more detailed pilot plant program."

Jan 1, 1995

By C. Gu

Flow field design is critical for PEM fuel cells. The flow field design can affect reactant distribution to the catalyst surface, water management, thermal management and current collection. Therefore, it has tremendous impacts on the fuel cell performance and durability as well as reliability and operational flexibility. In this paper, an optical method is used to study the reactant distribution in the flow field channels of two commonly used flow field designs, straight channel design and serpentine channel design. Images of the flow patterns are shown followed by discussions of the flow patterns.

Jan 1, 2005

By Mohammadreza Jalali

Alberta contains over 400 billion barrels of viscous crude oil in fractured carbonates but there is no viable extraction technology as yet. Petroleum geomechanics has become a vital part of the assessment of such hydrocarbon reserves, especially for naturally fractured cases, which are particularly challenging in terms of accurate recovery prediction because of joint fabric complexity and lithological heterogeneity. As a result of interconnected fractures, transport properties of fractures (mostly permeability issues rather than thermal effects) are affected by production and injection activities that change the pore pressures, temperatures, saturations, and effective stresses. Enhanced oil recovery methods involving massive amounts of fluid injection (hot or cold) at high pressure (pinj) may be used to mobilize and produce the oil; therefore, deeper understanding of the fractured systems is desirable. Pressure and temperature variations in a fractured reservoir change the in situ stresses in the reservoir and surrounding rocks; this affects fracture apertures, radically changing the bulk flow properties because flux rate is highly sensitive to aperture. Hence, coupled pressure, temperature and effective stress changes must be considered for fractured reservoirs under a thermo-hydro-mechanical (THM) coupling approach.A hybrid FDM/DDM coupled method is presented to couple pore pressure and stress around a fracture in an impermeable matrix block. Deformation and stresses are calculated in each time step and then fracture permeability, which is the most sensitive petrophysical parameter in fractured reservoirs, is updated based on the fracture aperture variation. This model is then verified with UDEC (Universal Distinct Element Code) which uses a discrete approach to cope with fractured rock mass behavior.

Jun 1, 2012

By L. I. Kiss, S. Perron, D. Toulouse, S. Poncsák, A. Perron

Bubbles play an important role in many industrial processes. In a Hall-Heroult cell, used for aluminum production, bubbles contribute to induce flow in the cell. The induced flow is important for the thermal balance of the cell as well as for the distribution and dissolution of the alumina. The existence of the bubble layer does not have advantages only. It increases the voltage of the cell and causes deformation along the cryolite-molten aluminum interface. The role of the anode inclination in the behaviour of the bubble layer as well as in the hydrodynamics of the bath is not clearly understood. In this work, the effect of the anode inclination angle on the bubble driven flow is studied in an industrial scale air-water model. The inclination angle is varied up to 5° from the horizontal. The instantaneous flow field is captured by Particle Image Velocimetry (PIV) system. The mean velocity fields were calculated by ensembleaveraging the instantaneous velocity fields measured at different time. The existence of the counter-flow in the interpolar space and the vortex in the side channel has been confirmed. Furthermore it has been observed that the effect of anode slope on the velocity field is weak.

Jan 1, 2006

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By Kai Zhang, Aijun Huang, Jeremy H. Rao, Xinhua Wu, Paul Rometsch

"As one of the most typical additive manufacturing (AM) technologies, selective laser melting (SLM) removes many of the shape restrictions that limit materials design, thereby allowing computationally optimised and high performance structures to be directly produced and tested. Due to the high reflectivity and lower absorptivity of Al alloy A357 powder during high temperature laser melting, one of the issues SLM might bring is the surface roughness and defects present on the parts. In this regard, this study investigates the surface roughness – fatigue property relationship for a heat-treated aluminium alloy A357 after SLM. Via the adjustment of SLM parameters, an ultrafine microstructure can be obtained due to the fast solidification rate. Therefore, comparable or even better mechanical properties can be achieved with respect to traditional A357 casting counterparts. Meanwhile, the surface roughness conditions of the SLMed Al alloy are also influenced by various processing parameters, raw powder properties, and sample building methods. For selective laser melted Al alloy A357 specimens, a dense part with a smoother surface would be expected to correspond with a good fatigue performance.INTRODUCTION Additive Manufacturing (AM), also known as 3D printing, is a process in which a complex part is fabricated layer by layer from a digital design package (Martin et al., 2017). AM has the potential to conserve raw materials, reduce the energy consumption, part cost, and fabrication time. Furthermore, as a typical additive manufacturing (AM) process, selective laser melting (SLM) was originally developed from selective laser sintering (SLS) based on higher quality lasers (Rao, Zhang, Fang, Chen, Wu, & Davies, 2017b). Different from conventional casting consuming valuable time and energy, SLM is now used as a cost effective method for the manufacturing of metals, such as Al-Si alloys, to produce almost full density parts using fine metallic powder and high power laser beam (Tang & Pistorius, 2017)."

Jan 1, 2018

By Navid Bahrani

The grain-based model (GBM) has resolved the difficulty of matching both the directtension (sc) and unconfined-compressive (st strengths of typical brittle rock by providing a synthetic material that mimics deformable, breakable polygonal grains cemented along their adjoining sides with deformable, breakable interfaces modeled as smooth-joint contacts. In this paper, a GBM utilizing a parallel-bonded base material is calibrated to match both st and sc of Lac du Bonnet granite and then used to simulate a Brazilian test. The Brazilian strength (sB) is slightly overestimated and the failure mode includes ductile post-peak response that is not representative of what occurs in laboratory Brazilian tests. By reducing the grain tensile strength, grain failure occurs during the Brazilian test and a more realistic failure mode that includes brittle post-peak response is obtained. However, the unconfinedcompressive strength of the modified material is too low. Sensitivity analysis on the grain and grainboundary strength properties demonstrates that the grain tensile strength controls the sB/sc ratio. Because the grain strength is controlled by the parallel-bond properties and the lowest achievable st/sc ratio in a parallel-bonded material is ~0.25, it is concluded thatsc, st and sB for a typical brittle rock cannot be matched with a GBM that utilizes a parallel-bonded base material.

Jun 1, 2012

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By Y. Kusuda

Since 1981, the Annaka refinery has recovered zinc from zinc leach residues by the Waelz Process. The important considerations of this process are the prevention of the growth of coating accretions in the Waelz kiln and the improvement of the zinc volatilization rate. In this paper, simulation predictions and the results of the industrial operation regarding the prevention of coating accretions in the Waelz kiln and the improvement of the zinc volatilization rate at the Annaka refinery are reported and compared.

Jan 1, 2006

By N. Sarmady, Mei Li, N. C. Parson, W. J. Poole

"The mechanical behaviour of AA6082 is a function of the extrusion conditions and in particular, the quench rate after extrusion. It is well known that precipitation of Mg-Si phases on grain boundaries during quenching can negatively affect the ductility of the alloy. In this study, AA6082 alloys containing 0.5 wt. % Mn and 0.15 wt. % Cr were direct chill (DC) cast, homogenized and then extruded to produce 3 mm x 42 mm strips. The microstructure in the as-extruded strips was unrecrystallized due to the Zener-Smith drag from the Mn/Cr dispersoids. It was shown that a solution treatment of 5 minutes at 560°C did not significantly affecting the as-extruded microstructure but if the as-extruded strip was cold rolled prior to heating, recrystallization occurred concurrently with the solution treatment. As such, 3 initial microstructures were produced, i.e. unrecrystallized and recrystallized with a grain size of 9 and 40 µm. After the solution treatment, controlled cooling experiments were conducted using the Gleeble 3500 thermomechanical simulator with cooling rates of 10, 25, 80°C/s as well as water quenched. The mechanical properties (e.g. yield stress, fracture stress and fracture strain) were determined from tensile tests for the different combinations of initial microstructure and cooling rate. The relationship between the quench rate and precipitation of Mg-Si phases on grain boundaries was examined by FEG-SEM. It was found that the yield stress decreased as the cooling rate decreased and that there was complex relationship between the fracture properties and the microstructure.INTRODUCTION As the automotive industry strives to reduce fuel consumption and CO2 emissions with the goal of reducing the environmental impact, there is a need for lighter vehicles. As a result, aluminum alloys are gaining popularity to replace steel parts as structural components. An exemplar of this is the Ford F-150 pickup truck which has an aluminum body and is ˜750 pounds lighter than the previous steel version of the vehicle. The structure includes a mix of aluminum sheet, extrusions and cast alloys. The current research is concerned with the performance of aluminum extrusions in applications such as side rails, crash tubes and other structural parts. These components experience a combination of bending, stretching and folding both during the forming of the part and in service, e.g. crash of a vehicle. There is a need to have detailed information on the influence of processing on final material performance, in particular the cooling rate after extrusion."

Jan 1, 2018

By Y. Obara, A. Sato

"Limestone is one of the most important mineral resources, and in Japan it is only one mineral which can be fully supplied by the domestic product. Generally limestone mines in Japan located at mountainous regions, and the combination between bench-cut method and the carry-out system using vertical shaft is widely used in the domestic mines. During mining operations, the occurrence of the blockage in the vertical shafts is very serious problem. Once the blockage in the shafts is occurred, a lot of works and dangerous procedures are necessary to solve the problems. It is thought that blockage is influenced by the cohesion and friction coefficient due to clay minerals thrown into the vertical shafts, however, the quantitative and precise reason is not revealed yet.In this study, the process of blockage occurrence was simulated by 2-Dimensional Discrete Element Method (DEM). In the 2D-DEM analysis, discontinuous circular particles are generated, and the individual movement of each particle is calculated by forward difference method. In the analysis, several typical ore distributions are applied, and the DEM analysis was conducted under the various combinations of cohesion and friction coefficient. From analytical results, it was found that the friction coefficient strongly influences to the occurrence of blockage and there were a threshold values which blockage does not occur. Several kinds of shaft shape were also simulated towards different ore size distributions, and those influences to the blockage occurrence were also discussed."

Jan 1, 2015

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By H. A. Pearse

Introduction This paper may be regarded as another instalment of the story of the Britannia milling operation. From time to time in the past, articles (1) have been prepared by various members of the staff, giving details of crushing, grinding, and flotation treatment for the normal Britannia ore. It is not, therefore, the purpose of the present paper further to discuss what may be termed the standard milling operation, but rather to describe a flotation practice which has been evolved directly as a result of the general depression. The normal Britannia ore mixture contains chalcopyrite and pyrite as the main sulphide minerals, together with minor gold and silver values. The standard milling practice, evolved during several years of experimentation, provided for bulk flotation of the two sulphides after primary grinding to only approximately 35-mesh, followed by regrinding of the bulk concentrate, with subsequent separation of the chalcopyrite and pyrite to make a marketable concentrate of each mineral. However, in the face of a constantly increasing surplus of copper on the world markets and a steadily falling price during 1930 and 1931, it was obviously undesirable to continue producing large quantities of this metal at a loss. On the other hand, Company officials were very reluctant to add to unemployment by closing down entirely, provided operations could be continued without excessive losses. Fortunately, the existence was known of a fair sized body of ore, quite low in copper and relatively high in zinc content, with also a very considerably higher gold value than that prevailing in other sections of the mine.

Jan 1, 1934

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By J. G. Speight

Laboratory studies indicate that autogenous heating of low-rank coal can be prevented by a prior treatment which involves immersing the coal for short (5-15 min.) periods in an inert liquid at temperatures between ~ 350° and 400°C. Such "carbonization" effectively reduces the accessible pore volume of the coal to levels at which heat generation through subsequent sorption of moisture and oxygen is too slow to cause significant temperature rises in a stockpile. In addition, this treatment also irreversibly removes most of the moisture held in the raw coal and raises its calorific value by as much as 10-12%.

Jan 1, 1973

By A. Zarei-Hanzaki, O. Golmahalleh, S. M. H. Hosseini, H. Azizi-Alizamini

The main importance of acicular ferrite microstructures arises from their desired combination of mechanical properties in comparison with the bainite and ferrite-pearlite microstructures. Several factors affect the microstructural transition from bainite microstructure into the acicular ferrite one. As is well established any factor corrupting the prior austenitc grain boundaries nucleation potential, such as the thin layer of allotriomorph ferrite and the austenitc deformation inhomogenities may promote the acicular ferrite formation instead of bainite. Accordingly, this study deals with the effects of the aforementioned features on the acicular ferrite formation in low carbon microalloyed steel. The results indicate that the formation of strain-induced ferrite at the prior austenite grain boundaries accompanied by deformation inhomogenities in the austenite grains change the effectiveness of allotriomorph ferrite on acicular ferrite formation from active to inert one.

Jan 1, 2004

By B. D. Thompson

Many mines adopt necessarily conservative backfilling strategies due to a lack of understanding of their backfill behaviour. In the past five years, extensive instrumentation campaigns have focused on measuring in-situ cemented paste backfill behaviour. These tests have resulted in optimised backfilling efficiency through elimination or reduction of cure periods where; i) controls on backfill behaviour are understood, and ii) barricade pressures are demonstrated to be within a safe range using routine monitoring as a required QA/QC procedure. Recently, this work has been extended to consider hydraulic backfill operations. Two stopes have been instrumented at Vale?s Coleman and Garson Ramp mines. The instrumentation and deployment methods are discussed, and representative total earth pressure, pore pressure, and temperature data are presented. In one case, pressures in the stope are relatively low as drainage causes strength gain in the fill and so pressures are arched. In a second example, again, drainage causes strength gain in the fill, but increasing temperatures correlate with pressure increases even during downtimes in filling. These pressure increases are thought to be caused by thermal expansion of the backfill in confined locations. Generally, the instrumentation approach has proven successful in measuring hydraulic backfill behaviour and offers good potential for incorporation into a procedure to safely maximise backfilling efficiency through routine barricade pressure monitoring, when combined with safeguards to ensure adequate fill drainage.

Aug 1, 2013

By S. Onuki, T. Ando, M. Tejima, R. Enomoto, Y. Okada

"Al–Si–Cu–Mg die casting alloys are widely used in the automotive industry, and recent advancements in high pressure die casting technology enable heat treating products to achieve desirable properties. However, CO2emissions associated with die-casting production lines should be reduced to address the global warming issue. In this study, the relation between the microstructures and thermal stability of precipitates formed during isothermal aging at 423, 485, and 558 K of Al-11.0 mass%Si-1.8 mass%Cu-0.2 mass% Mg (JIS ADC12) was investigated using Vickers hardness tests and transmission electron microscopy (TEM). The hardness tests and TEM results showed that Si compounds and Al–Cu compounds enhanced the mechanical properties of the alloy and that the predominant compound affecting the mechanical properties differed between specimens treated at 423 K and those treated at 558 K. Moreover, additional aging at 423–458 K resulted in a material with a Vickers hardness higher than that of the isothermally single-aged material. Differential scanning calorimetry, differential elemental analysis, and selected-area diffraction analysis using TEM suggested that the combination of Al–Cu compounds precipitated at low aging temperatures and Si compounds precipitated during preliminary aging increased the mechanical strength, resulting in a maximum hardness of 130 HV.INTRODUCTIONAl–Si–Cu–Mg die casting alloys have well-balanced mechanical properties, machinability, and cast ability. These alloys are therefore widely used in the automotive industry because of their superior characteristics, accounting for>90% of the aluminum used in die casting production. As a substitute for iron-based materials, these alloys have contributed to the development of lightweight vehicles.Dong et al. (2014) reported that the heat treatment of die casting materials is effective for changing their dimensions under high temperatures as a result of the precipitation of solid-solution elements. Recent advancements in high pressure die casting technology have led to the application of heat treatments of Al–Si–Cu–Mg alloy products to reduce fuel consumption and satisfy customer needs. Although attempts to reduce CO2emissions have focused on fuel consumption in cars and fuel efficiency regulations have become increasingly strict in recent years, CO2discharged from production lines should also be reduced without adversely affecting the properties of the product. Heat treatments for artificial aging after solution treatment (T6 treatment) and after casting (T5 treatment) are CO2discharge sources, which together with a holding furnace account for >80 % of the CO2discharged during the casting process."

Jan 1, 2018

By A. Zangooi, J. A. Finch

Flotation is a separation process based on the collection of particles on the surface of bubbles. Flotation machines disperse air into bubbles using a variety of techniques. The characteristics of the bubble population are strongly affected by the selection of frother type and concentration. As metallurgical results depend on the bubble distribution, the measurement of frother concentration is vital to understand and control performance. A previously developed colorimetric technique was refined to work with low solubility frothers and to increase daily analysis rate. Field-testing demonstrated that the method is robust, reliable and accurate. As well as relating frother concentration to gas dispersion measurements, the results can be used to answer operational questions including: how well a frother dissolves, how reliable and stable frother delivery is, how evenly frother is distributed down a bank, and whether frother distributes between the pulp and froth zones. Some of these points are illustrated from plant experiences. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By Jr. Wilkinson

Suncor Energy currently mines approximately nine hundred thousand tonnes of ore and waste per day at its open pit operations in the Athabasca Oilsands near Fort McMurray, Alberta. Modeling these deposits for planning purposes is particularly challenging given the characteristics associated with the deposit - stratigraphic deposition coupled with gradational grade distribution. The identification of ore and waste is a combination of bitumen cutoff grade, minimum mining thickness and separable waste thickness subject to criteria established by provincial regulatory agencies. Suncor along with Mincom Inc. have collaborated on this project to derive a methodology, automated by computer software, to streamline the ore and waste identification process. This paper explains the methodology and programs created to identify ore and waste in use at Suncor Energy and how this identification is used to categorize reserves and to generate mine design surfaces.

Apr 1, 2005