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By K. Feindel

The distribution of water in operating fuel cells must be carefully managed to optimize the performance, durability, and functionality of the system. For example, the ionic conductivity of polymer electrolyte membranes decreases as membrane hydration is reduced. Flooding at the cathode inhibits mass transport, and it can lead to failure of materials. Build up of liquid water in the gas flow channels of a fuel cell stack will create a non-uniform distribution of pressure drops across the individual cells. We will discuss the application of 1H NMR microscopy to investigate in situ the production and distribution of water throughout an operating H2/O2 polymer electrolyte membrane fuel cell. Polymer electrolyte direct methanol fuel cells posses high theoretical storage capacities as power systems for portable electronic devices. There are, however, two long-standing hurdles to development of practical methanol fuel cell systems. First, the electro oxidation of methanol at the anode of the fuel cell is poisoned by absorbed carbon monoxide, an intermediate in methanol electro oxidation. Second, methanol readily crosses over from the anode to the cathode of the fuel cell. This methanol crossover wastes fuel, and it poisons the electro reduction of oxygen at the cathode. We are investigating use of 2-propanol as an alternative to methanol as a fuel. 2-Propanol is less toxic than methanol, and it is less prone to crossover from the anode to the cathode. More significant, however, is that the electro oxidation of 2-propanol to acetone is faster than the electro oxidation of methanol because it avoids formation of adsorbed carbon monoxide. We will present active catalyst systems for the electro oxidation of 2¬propanol to acetone in fuel cells. We will also present methods to convert the resulting acetone back into 2-propanol, possibly leading towards rechargeable portable fuel cell systems.

Jan 1, 2005

By Anthony Finch

Many mines combine open pit with underground mining, and on many occasions the underground mine is an extension of the open-pit. In these circumstances the decision about where the open-pit stops and the underground starts is crucial and driven by many factors. This paper looks at some of the ways that this cut-over can be calculated and specifically examines the calculation of it using modern mine optimization software. The paper provides a case study which will review various outcomes using these techniques, and demonstrates the influence of various factors on the optimal transition cut-over point. Biographies Mr Finch is a Divisional Manager and a Principal consultant at Snowden Mining Industry Consultants in Vancouver, Canada. At Snowden Mr Finch leads a team of engineers that perform mining engineering studies for projects around the world. Prior to joining Snowden Mr Finch was the Mining Manager at Barrick?s Henty mine in Tasmania Australia. Prior to that Mr Finch has held a variety of roles in both consulting and operations working for various organisations at various levels in the Asia Pacific region. Mr Finch gained a bachelor?s degree in Mining Engineering from the University of Queensland in 1986, and a bachelor?s degree in Economics from the University of Queensland in 1993. His expertise is in mine planning, mine optimisation and mine management. Dr Elkington is a Consultant at Snowden Mining Industry Consultants in Perth, Australia. He is responsible for the design and implementation of Snowden?s proprietary optimization software products. Prior to joining Snowden Dr Elkington completed his PhD in Mine Optimisation at The University of Western Australia, and bachelor?s degrees in Engineering (Hons) and Commerce from The University of Western Australia. He specialises in optimization and trade-off studies, and has consulted on projects across all major commodities and regions.

May 1, 2011

By J. Wild, M. Ounpuu, G. Chevalier

"The requirements for a finer grind at Heath Steele have resulted in the investigation of agitated milling as a cost effective alternative to conventional tumbling ball mills.The grinding unit is a vertically agitated, or stirred ball mill. Grinding occurs as the result of the motion of a single vertical rotor equipped with protruding pins which impart a stirring action to the ball charge. A comparative evaluation of a 30 kW SALA Agitated Mill (SAM), and a 1.5 m x 2.5 m copper-lead regrind ball mill has been conducted at Heath Steele.An overview of agitated milling as it applies to the reduction of sulphide ore will be the primary topic for discussion. Specific parameters including energy efficiency, media consumption, operating costs, and the mechanical aspects of the SAM operation will be presented.Evaluation of the agitated mill has shown that improved grinding performance at much lower work indices than those of the conventional ball mill is possible. Media consumption has proven to be comparable on an average g/kWh basis, but the mechanical availability of the mill has been low.INTRODUCTIONConventional tumbling ball mill grinding has proven to be an energy inefficient process. Energy losses occurring within the ball mill itself can be attributed to particle friction without breakage, kinetic and potential energy losses, plastic and elastic deformation and the production of heat and sound (Lynch, 1977). It can be generally stated that a certain amount of the input energy will be converted to another form as a necessary by-product of particle breakage. Theoretical interpretation of experimental results indicate that the energy required for breaking the ore particles in a ball mill varies between I% and 25% of the total energy input (SME, 1985)."

Jan 1, 1993

By M. Hawker, M. Kreuh

The mining and metallurgy industry is known to be of cyclical nature associated with price volatility. As such, some years are quite lucrative and other years require mining companies to tighten their belts. The field is a mix of junior, mid-tier, and major mining companies. One thing that is common to all of them is the time required and the cost to develop a flowsheet in accordance with best practices. Although a long list of factors can impact flowsheet development, this paper will include the impacts of: experienced metallurgical engineers and laboratories, representative samples for high quality and valuable testwork results, and following engineering development stages. The paper also provides typical time frames to complete selected engineering flowsheet development steps.

Jan 1, 2014

By Robert J. McCarthy

Many technologies have been adopted over the last half century for the haulage of material from open pit mining operations. Some of the technologies utilized include rail, off-highway trucks, conveyors, and slurry pipelines - each having its unique application and benefits. Over time, truck haulage has become the primary means of surface mine material movement, though recently it has been plagued by problems of tire shortages, high diesel fuel costs, labour shortages, and carbon emissions. This paper focuses on In-Pit Crushing and Conveying (IPCC) as a competitor to truck haulage which has the potential to solve many of these problems. An overview of the available technology is presented along with measures required to overcome perceptional if not physical barriers to implementing this technology in modern open pit mines.

May 1, 2011

By Rainer Süss

An investigation was carried out by Mintek to investigate the influence of a range of alloying additions (vanadium, cobalt, zirconium, antimony and germanium) on the formability and hardenability of alloys with gold content >90 wt%. This paper reports on the hardening mechanisms that can be utilised to increase the hardness of gold (>90 wt% Au) by conventional alloying, as well as the hardening effect obtained by alloying with specific elements. Preparation methods for the alloys are described, which include the steps of melting, annealing, quenching, cold working and age hardening. Focus is given specifically on alloys that were developed at Mintek with a gold content >90 wt%, which are not only harder, but exhibit good resistance to tarnishing and corrosion.

Oct 1, 2003

By Farzad Mohammadi, Patrick Littlejohn, David Sanguinetti

Arsenic levels in metal concentrates are increasing as mining companies turn to developing low grade and complex ores. When arsenic bearing minerals are smelted, arsenic deports as gases which must be neutralized by a scrubber system. The resulting scrubber effluent is high in dissolved arsenic and requires treatment before the wastewater can be discharged or re-used. Conventional arsenic removal relies on lime addition followed by calcium arsenate formation and precipitation as hydroxides. As an alternative, arsenic removal with sulphide precipitation is receiving more attention due to potential advantages of the technology. Process streams high in arsenic often contain concentrations of dissolved metals that may be selectively recovered during sulphidization, producing a product that can be reprocessed and reducing waste generation. This paper will review laboratory testing completed for arsenic removal through sulphide addition and precipitation of arsenic (III) sulphide in combination with metals recovery to offset arsenic removal costs.

Jan 1, 2014

By . A. C. Atenas

Control of arsenic in the Potrerillos' Refinery electrolyte has been obtained by withdrawing a bleed stream of circulating electrolyte and ensuring the ratio of [O]/[As] in the cast anodes is maintained between 0.9 and 1.0. In order to achieve this control the anode oxygen must be adjusted, depending on the arsenic level in the cast anodes. It has been necessary to modify the time of the reduction step in the anode furnace refining process. Control of this ratio has permitted electro refining of anodes with high levels of arsenic, up to 3000 ppm, while minimizing the volume of electrolyte that must be removed for impurity control so as not to affect the copper concentration in the electrolyte. However this control strategy is not useful when the arsenic concentration in the cast anode is too high, because it is limited by the maximum oxygen concentration allowable for a good quality anodic. Costs have been reduced in anode furnace refining because it is no longer necessary to use alkaline flux injection to remove the arsenic in cast anodes.

Jan 1, 2007

By Carlos Antônio de Morais, Renata Dias Abreu

The present work describes a study of the separation of terbium and dysprosium from heavy RE concentrate through a solvent extraction circuit in a counter-current system. As the efficiency of the REE extraction by acid extractants rises with the increase of the atomic number of the element, the aim of this work is to extract the elements with higher atomic number maintaining Tb and Dy in the aqueous phase. Thus, terbium was separated first with subsequent separation of dysprosium. The experiments were carried out by using IONQUEST®801 as the extractant and a REE-hydrochloric liquor as feed solution. The optimum operational circuit in terbium separation was comprised of 37 stages: extraction, scrubbing, stripping, and solvent washing. For the dysprosium separation 39 stages were required. Terbium separation over 92% with over 95% purity and a Dy separation over 97% with over 95% purity were obtained.

Jan 1, 2014

By J. Vanderlaan

A proposed method of applying high-speed, non-destructive part scanning technologies to the production process of UO2 (Uranium Dioxide) fuel pellets is presented. The scanning process examines each pellet individually for correct surface roughness and any surface imperfection or defects. Using optical scanning methods, which consist of laser and CCD camera technology, the complete circumferential surface of the pellet is examined to meet the reactor fuel bundle specifications.

Aug 1, 2010

By J. N. Cram

"The comments given are to help allay generally accepted ideas that the handling of arsenic as arsenic-trioxide (As2o3J in and from off gas pyrometallurgical operation fumes is difficult, hazardous and expensive. It need not be any of these things if the basic and rather unique chemic3l and physical properties are understood and taken care and advantage of through present day technologies. These particular characteristics are:-(1) As2o3 sublimes and re-condenses, at a relatively low temperature;(2) As2o3 is, for practical in-plant purposes, insoluble in water at ambient temperatures and quite soluble in water just below the boiling point;(3) residual suspended and dissolved As 2o3 can be removed from water by complete dissolution with very little sulfuric acid, followed by the addition of small amounts of ferrous sulfate and calcium chlorate, with oxidation to the ferric and arsenite state and precipitation of an insoluble ferric calcium arsenate, thereby lowering the As2o3 content of solutions to acceptable levels. Even lower levels of non-toxic forms of arsenic solids and residual As2o3 in the water solutions can be attained by also using phosphate, and lime, along with the above.A background re past arsenic processing methods, present day operations, plus predictions re future trends, and hazards, are outlined."

Jan 1, 1979

By Mori Fresko, Stuart M. Jones Jr

"This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded.A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.INTRODUCTIONThis paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide. The list is maintained by Stuart M. Jones, Jr. (author), and is included in the appendix. This list has been the inspiration for similar papers in the past several SAG Conferences. Updates have been solicited from all major mill manufacturers and most have responded. Information from this list is compiled to illustrate the growth of the AG/SAG mill market and the use by industry and selected geographic areas. It covers the market growth through the end of 2010."

Jan 1, 2012

By Chris M. Healey

"Perhaps the single most significant variable in the evaluation of a mining project is the reserve estimate. Many parameters are considered when estimating reserves, among them geology. This paper examines the link between the quality of a reserve estimate and a good understanding of the geological controls for the deposit. A clear understanding of the geometry is essential to the accurate definition of the shape and size of the deposit. This includes the definition of any structural controls as well as the proper interpretation of the stratigraphy. Further when the distribution of grades is erratic and there is consequently a high nugget effect, there are significant problems in estimating the true grade of the deposit.Two Saskatchewan examples are presented, one with good knowledge of the controls and therefore good estimates of reserves, and the other with a poor understanding of the geology and resultant problems in deriving good estimates. In both cases the reserve estimates at various stages in the project development are compared to actual results from underground work. The first example is the Star Lake Mine where just about all the estimates were within 10070 of the actual on both tonnage and grade. The Laurel Lake deposit is discussed to show how problems in interpreting the geological data make reserve estimation very difficult. Laurel Lake has the additional problem of erratic grade distribution."

Jan 1, 1992

By S. Y. Mostowy, P. W. M. Shibley

"When Texas Gulf Sulphur Company discovered the Kidd Creek ore body in 1964, a crash program began almost immediately for the design and construction of a modern concentrator. It was necessary to mill two distinct ore types; one containing copper and zinc, the other lead, silver and zinc minerals. The final concentrator design was to handle 9,000 tons of ore daily in three circuits. One circuit was to treat copper-zinc and another lead-zinc ore exclusively on a permanent basis. A central circuit was designed with adequate flexibility to treat either of the above ore types in accordance with planned mining schedules. Ecstall Mining Limited, a wholly owned subsidiary, now operates the mine and concentrator complexes for Texas Gulf. The mine is located 15 miles north of Timmins and the concentrator 15 miles to the north-east along Highway 101. The ore is hauled from the mine to the concentrator over a 17-mile railroad. Initial milling operations began in November, 1966.1 - ABSTRACTThis paper deals with bulk reagent handling at the Kidd Creek concentrator. The reagent section at Kidd Creek has operated excellently since milling began in 1966. The bulk handling techniques are satisfactory. They have contributed substantially to good working conditions, economical practices and metallurgical efficiencies. The bulk handling features described should be considered in existing and proposed concentrators."

Jan 1, 1970

"Cobalt refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because certain compounds of both metals carry risks for adverse health endpoints by inhalation exposure, it is critical to understand the aerosol concentrations of specific substances and the metallurgical processes through which they enter the air. Vale Canada has therefore decided to describe the histories of its Ni-related operations and to report industrial hygiene measurements when available. This paper describes electrolytic Co operations carried out at Port Colborne, Ontario (1954–1966), and provides aerosol measurements (1995–2008) for current Co electrowinning operations.RÉSUMÉ L’affinage du cobalt chez Vale Canada (anciennement Inco) a été associé à la production de nickel. Puisque certains composés de ces deux métaux comportent des risques d’effets néfastes pour la santé par exposition à l’inhalation, il est essentiel de comprendre les concentrations en aérosol des substances spécifiques ainsi que les procédés métallurgiques par lesquels ils entrent dans l’air. Vale Canada a donc décidé de décrire les historiques de ses opérations liées au nickel et de divulguer les mesures d’hygiène industrielle lorsqu’elles sont disponibles. Le présent article décrit les opérations électrolytiques effectuées sur le Co à Port Colborne, Ontario (1954–1966), et fournit des mesures de la teneur en aérosol (1995–2008) pour l’extraction électrolytique actuelle du Co."

Jan 1, 2015

By C. W. Eggert

"The idea for this talk came to me last year when I was attending the Canadian Gold Metallurgists Meeting. I talked about it to a friend of mine who is an authority on mineral dressing, particularly the theoretical end of the business. He remarked that this was an excellent technical note, why don't you write it up. This is what I have for presentation this morning. I hope in presenting this type of idea in this way it is in keeping with the tradition of the Canadian Gold Metallurgists which was to function on a not too sophisticated level and where operators could get together and trade ideas in an informal way.My basic thesis is that it should be possible to evaluate screen analyses by the application of the standard statistical probability theory. In any statistical analysis the sample is the first consideration. If we look at existing methods of size evaluation we find it is usually based on the fact that a given particle will pass one square aperature and not another. One system of standardizing how these aperatures will be set up is based on Rittenger' s work with the ratio of hole sizes proportional to the square root of 2. Keeping in mind the limitation we have accepted this as our method of 11 sizing"" in attempting to apply standard statistical methods to screen analysis."

Jan 1, 1968

By Colin E. Dunn

Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By Kadri Dagdelen

Recent trends of the mining project show that there will be more and more mechanized, largescale mining operations with complex process options to make low grade deposits economically feasible to develop. The global optimization of large scale, complex mine operations will become more important for the future mining. To serve the industry?s future needs, the OptiMine® software program is developed based on expertise gained at the Colorado School of Mines (CSM) for more than two decades, by using the special solution methodology based on the Mixed Integer Linear Programming (MILP) technique in the Operations Research (OR). The program has been beta-tested on more than 20 projects as a multi-time period scheduling and cutoff grade optimization tool that handles large scale open pit and underground mining operations involving complex process options, many stockpiles and dumps, blending requirements, and truck hour limitations. In each project, various operational options are evaluated in OptiMine® to develop strategic planning to help defining company?s strategies and directions. This paper demonstrates how the OptiMine® can be used to optimize a large scale, complex production scheduling problem on a case study coming from real world project. The case study describes multi-pit mine production scheduling optimization with pit backfills in such a fashion that acid generating waste rocks are encapsulated to minimize environmental impact.

Oct 1, 2009

By Colin E. Dunn

Abstract-Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By Mark Stephenson, Paul Henharen

"The objective in the mineral processing of primary ores is to liberate and effectively recover each individual economically viable diamond with minimal reduction in its potential value.There are three distinctive phases in diamond processing:Feed PreparationWhere the diamonds are liberated and waste material finer than the economically selected cut-off size is rejected. In this section we will discuss the various techniques utilised worldwide to effect feed preparation.Primary ProcessingWhere the diamonds are recovered into a high grade concentrate suitable for the more expensive and selective final recovery process. In this section we will discuss the development of primary processing from jigs and pans to the more current techniques utilised worldwide.Final RecoveryWhere there is selective rejection of waste particles until only diamonds remain. The diamonds may then be acidised prior to packing and marketing.Within these distinct phases a variety of unit processes have been utilised and this paper will discuss their relative merits, limitations and suitability in respect to the various stages of diamond project development from prospecting through to production.Basic capital and operating costs are compared for the autogenous milling route developed in the CIS and the crushing and scrubbing route utilised in the west."

Jan 1, 1994