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By J. D. Bateman, A. S. Dadson

"The Giant claims are on the west side of Yellowknife bay about 1 ½ miles north of the settlement of Yellowknife. They were staked in 1935 by prospectors in the employ of Burwash Yellowknife Gold Mines, Limited, and were transferred to Giant Yellowknife Gold Mines, Limited, in 1937, on the incorporation of that Company. During the period 1936 to 1940 a number of surface discoveries were investigated by trenching, test pitting, and diamond drilling. A shallow inclined shaft was sunk on the Brock zone, a system of narrow and irregular quartz veins, and some 75 tons of high-grade ore was mined and shipped to the Trail smelter. In 1943 management control was acquired by Frobisher Exploration Company, Limited. An intensive campaign of diamond drilling was commenced in January 1944 and carried on continuously for 2 years. This drilling indicated the presence of substantial gold orebodies lying within well-developed shear zones. Two shafts, 1 ¼ miles apart, were sunk during 1946 and underground development started on two of the orebodies.The claims are underlain largely by rocks of the Yellowknife greenstone belt, which extends from the shore of Great Slave lake along the west side of Yell ow knife bay and northward . The most conspicuous structural features are the steeply dipping late faults. The chief of these is the West Bay, which bisects the greenstone belt at an acute angle and crosses the southern part of the Giant group. At the 'big bend' near the west boundary of the claims there is a remarkably sudden change in the strike of the fault, from about 12° N.W. to about 3° N.E. The apparent horizontal displacement along this fault is of the order of 3 miles, with the east side moved relatively north. There are also a large number of lesser faults with apparent horizontal displacements of a few feet up to l,70J feet for the Townsite fault. Most of these faults trend north to northwest. Surface examination indicates that, at least for most of them, the movement corresponds to that along the West Bay fault, that is, the east side moved relatively north. According to the available evidence, all or most•of the movem:nt along the West Bay fault and along the lesser faults was post-ore. Late diabase dyk:s that cut through ore-bearing shear zones, with chilled margins in contact with the mineralized material, are apparently displaced to the same extent as earlier geological markers. ( see Frontispiece. )"

Jan 1, 1954

By M. Amsden

"Since the computer program is far from complete this must be only a brief progress report on the computerization of flotation metallurgy at the Ecstall concentrator at Timmins.Ecstall is currently treating about 10,000 tons per day of two different ore types. One is a low sulphide copper-zinc ore, the other is a high sulphide lead-zinc-silver ore. The concentrator is divided into three individual grinding and flotation circuits. In effect there are three mills under one roof. Normally there are two circuits on copper-zinc ore and oneone lead-zinc-silver ore. At this point in time one of the copper-zinc circuits is under computerized metallurgy control.The first step in this control is the use of an ARL on-stream x-ray analyzer, coupled with a Honeywell 21 computer which types out assays and recoveries for each individual circuit. Our approach to a computer program was to keep it simple. The program was written to coincide as closely as possible to what an operator would do in the performance of his duties based on the in-formation he was getting from the x-ray analyser read-out. Initially, computer control was put on just the copper circuit of the ""A"" Division, controlling the collector addition at three points in the circuit; primary, secondary, and scavengers. The control was based on recoveries and the grade of the copper concentrate. Targets like 95% recovery and 24% copper concentrate grades that it was felt the circuit could achieve were set to start with. It quickly became apparent that this alone was not enough because if on a certain ore the best recovery that could be made was only 94.9% the computer kept calling for more reagents until the circuit was completely out of control. On another ore it might have been quite possible to get 96% recovery but when the set point of 95% was reached the computer stopped trying for any more. To overcome this problem a very simple optimum seeking program was devised by one of the Ecstall staff and it has worked very satisfactorily since being put into use in July 1970.In the copper float only the two collectors R-208 and the xanthate R-317 are under computer control. The addition of frother and depressant is left to the operator. The flotation cells have automatic level controls which can be adjusted by the operator. pH is controlled automatically through a lime loop-sensor arrangement."

Jan 1, 1971

By R. M. Kalanchey

The application of pressure oxidation processes to copper feed materials has gained increased exposure in recent years and some of these processes have made commercial inroads, although rather limited to date. Among the hydrometallurgical processes with significant commercial potential, Dynatec's copper pressure leaching process has been applied to arsenic-bearing copper materials and has shown, through a number of batch and continuous test programs, that pressure oxidation is a technically feasible option for the recovery of copper with coincident sequestration of arsenic in an environmentally benign residue.

Jan 1, 2007

By D. Kim

Kennecott operates one of the largest and most modern copper refineries in the world at Magna, Utah, USA. The inputs to the refinery are anodes produced at Kennecott Smelter, which has extremely high contents of lead and bismuth. In order to minimize undesired effects in the electrolytic refining process, unwanted impurities, especially bismuth, must be controlled. This paper describes the process development of practicing state-of-the-art quality control and presents the pilot test results of using the MRT Technology for Bi production.

Jan 1, 2007

By Brent Robertson

Failure to meet quality objectives during the execution of any industrial project has lasting negative impacts on facility life cycle performance. Cost overruns, schedule delays, and rework are characteristics of project quality issues that arise during the project. Commissioning and start-up problems, low production, production bottlenecks, breakdowns and the necessity for operational work-arounds are characteristics of project quality issues that appear after project completion. Risks such as production facility downtime, shortened equipment life, and potential HSE violations must be clearly identified and addressed during project planning phases. Appropriate Quality Assurance (QA) and Quality Control (QC) focus must be placed on identified high-risk areas. In order to be effective, quality systems must be flexible, non-confrontational, consistent, and adaptable to projects of any size ? from capital mega-projects to small maintenance projects. All project participants must be aligned in how they are approaching quality and the difference between QA and QC must be clear to everyone on the project. Emphasis must be placed on QA activities to minimize project cost, reduce rework, manage change, and reduce the production facility operational risk. QA is focused on the work processes used to generate the design and confirming that the processes are present and being followed. Issues in the work processes guarantee that the output drawings and specifications will be less than optimal. The identification and monitoring of quality-critical processes provides a focus for QA activities. QC activities are then used to generate proof that the project was implemented correctly and become a key part of the turnover.

Nov 1, 2011

By Alireza Entesari

Removal of metal ions from effluents represents a significant technical challenge. As a consequence several industries, including mining, are faced with issues relating to removal of contaminant cations and anions from solution. This study evaluates three natural mineral materials referred to as basalt, scoria, and calcined shale for treatment of metal contaminated effluents by adsorption. Adsorption tests were conducted to asses the possibility of removing cationic and anionic metal ions from prepared solutions and mine water effluents. Sustainable production of industrial minerals requires that a diverse range of added value products be introduced.

May 1, 2006

By X. Zhong

Thermal shock resistant properties of reaction sintered bauxite-based ß -Sialon bonded corundum have been investigated, and the results are compared with those of Al2O3 based counterpart. It is found they all have very good thermal shock resistance. Their residual strength ratios after one thermal shock cycle at ? T=1200°C and A T=1350°C are 61-73% and 53-65% respectively. TSR parameters are calculated based on thermal expansion, modulus of elasticity, and fracture toughness determined. The reasons for improved TSR of these composite materials are discussed.

Jan 1, 2004

By I. Cifuentes

Chemical and physical characterization of copper electrodeposits obtained on mesh and plate cathodes in conventional and reactive electrodialysis lab-scale cells have been carried out. The effect of Fe, Mn, Cl and guar on electrodeposit composition and morphology were determined by means of metallographies, scanning electron microscopy (SEM), atomic force microscopy (AFM), inductively coupled plasma mass spectrometry (ICP-MS) and Auger electron spectroscopy (AES). Each impurity influenced the deposit morphology in a different way (e. g. grain size, surface roughness). AFM proved to be a very effective tool for quantifiying and classifiying surface quality.

Jan 1, 2007

By Michael Schindler

Uranyl mineral dissolution appears to be complex, affected by factors such as solution pH and the presence of various cations in solution, and sometimes involving formation of secondary surface precipitates. Such secondary precipitates potentially could armor the underlying uranyl mineral surfaces from further dissolution. A detailed understanding on the formation of secondary precipitate is therefore essential for predictive modeling of radionuclide fate and transport in the subsurface. Several types of secondary precipitates on the surface of uranyl minerals were examined using Atomic Force Microscopy, Scanning Electron Microscopy, and, Xray Photoelectron Spectroscopy.

Aug 1, 2010

By R. H. Keyes Duval

"The one point left off the table was pumping costs, i.e. the cost of pumping to the cyclones.At East Malartic 5 x 5 S R L pumps that had been used to pump the classifier overflow were used to pump the rod and ball mill discharges to the cyclones. Maintenance costs on the pumps rose from $105 in 6 months to $1000 per month. The pumps had to be operated at 1150 rpm and impellers lasted only 5 to 6 days. These pumps were replaced by 6 x 6 S R. L. pumps operating at 825 rpm, but at this speed the coarser sands settled and plugged the pipe lines and the speed was increased to 925 rpm. The maintenance cost is now $100 per m::rnth which is 0 003 cents per ton milled. The impellers now last 1 month and the casing linings 6 months.Density meters are often used on cyclone overflows and sometimes on the cyclone feed. Haliburton weighted tube density meters are used in some plants. They are cheaper than the radioactive density controller, $2500 as compared to $ 6000The angle of the discharge spray from the apex can be used to judge the quality of perform1nce of a cyclone.For ordinary metallurgical applications the inside slope of the cyclone is not too important but for fine separation steeper slopes are used.The cyclone is a versatile tool and will handle considerable variations in feed tonnage - probably up to 15%. Above this variation the number of cyclones used has to be increased or decreased or the tonnage fed to them has to be adjusted"

Jan 1, 1965

By W. M. Lupton

"Internal grinding mill entries are routinely done by mill personnel during scheduled maintenance periods. Reasons for entry include mill liner life profiles, liner inspcections and replacement and grinding media investigations. These entries require employees to adhere to safety regulations and policies including special permitting, testing, procedure-following practices and the wearing of proper personal protective equipment.A realized semi-autogenous mill entry safety hazard is the unpredicted breakage and occasional shattering of large diameter grinding media while personnel are inside. This was a concern to both media user and supflier. American Barrick's Holt McDermott Mine has improved mi l operational procedures and the media manufacturer has assisted by their developments to essentially eliminate this problem.This paper presents the improvements instituted; and the author's wish to communicate this potential hazard to other large diameter SAG ball users or potential users.INTRODUCTIONAmerican Barrick' s Holt McDermott mine is situated on Highway 101, some 70 kilometers northeast of Kirkland Lake, Ontario, 120 km east of Timmins and 90 km northwest of Rouyn Noranda, Quebec. The mine draws 160 employees from these surrounding areas to extract and process the underground ore, and recover near 60,000 ounces of gold per year. The mill department is completing it's fifth year of operation this spring.The company and the employees are proud of the safety improvements realized over the short history of the mine. Post accident/incident reviews and pro-active safety awareness programs have substantially reduced the mine's accident frequency and severity to date.One of the mill department's objectives is to provide a safe working environment for mill personnel, which includes the interior of the grinding mills."

Jan 1, 1993

Recently, renewed interest in the recovery of uranium from leach solutions has necessitated a re-examination of the hydrometallurgy methods used for uranium in the 1960?s to 1970?s. A synthesizing overview of the lessons learned in those decades together with examination of recent developments in this area is warranted. This paper considers uranium recovery chemistry from acid and alkali leach solutions using solvent extraction and resin ion exchange, and provides information on circuit selection and configuration, equipment selection and design, as well as operational considerations. The unique thermodynamics of uranium solvent extraction are also presented and discussed.

Aug 1, 2010

By J. Koike

Mg alloys for structural application have attracted much attention. However, high process cost and poor mechanical reliability are major concerns upon expanding the application to a wider area. In order to break through these barriers, better ductility is desired at lower temperature. Plastic anisotropy and peculiar twin formation appear to play key roles in the deformation and fracture mechanisms of Mg alloys. In the paper, dislocation slip and twin formation are reviewed. The effects of crystallographic texture and grain size are discussed. The results suggest that a good control of microstructure and texture can improve ductility and mechanical reliability of Mg alloys.

Jan 1, 2006

By D. J. Sapsford

This paper details results from laboratory simulation of an innovative underground bioleaching process. The underground reactors are periodic flushed with recycled leachate to remove uranium that accumulates within the reactor water. This leaching cycle has been recreated within the laboratory. This study examines the influence of varying cycle protocol on uranium leaching. Protocol variants examined include variation of flushing frequency, flush volume, leachate recycle, nutrient solution (NPK) addition to reactors and Fe(III) sulphate addition to reactors. The presented data highlight the dramatic improvements in uranium recovery that might be achievable by varying the operating protocol for the actual underground reactors.

Aug 1, 2010

By I. Zhitomirsky, X. Pang

The outstanding thermal and chemical stability, excellent mechanical properties and biocompatibility of zirconia have made this material an important candidate for fabrication of advanced protective coatings on metals, graphite, carbon fibers and biomedical implants. Nanostructured polymer-ceramic composite films containing zirconia were synthesized on metallic substrates by combining cathodic electrosynthesis of inorganic particles with electrophoretic deposition of cationic polyelectrolytes. Thick crack-free oxide and composite coatings were obtained using this newly developed technique. The deposits were studied by thermogravimetric analysis, X-ray diffraction analysis, scanning electron microscopy and atomic force microscopy. The mechanisms of deposition are discussed.

Jan 1, 2004

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004

By W. L. Stuewe

For the purpose of this paper I shall, in order to limit myself, define the words 'Maintenance' and 'Equipment' as follows: Maintenance shall mean the 'care of or 'the sustaining of equipment in as nearly perfect condition as possible. Equipment shall mean any item of a mechanical nature entering into the production of coal; it will be seen that unless one limits the use of this word it could take in administration as well as operative equipment, and include metal mines, mills and smelters, and manufacturing plants. In any industry the first consideration is the proper operation of all units entering into the production of the article manufactured or produced. I wish to quote here what a man, well known internationally in financial circles, told his operators at the time a large expansion programme was under consideration. His exact words were: "I do not care how much it is going to cost. What I want to know is how much it is going to cost to operate and maintain. It is the continuous drain for repairs that costs us the most money." The truth of this statement has been proved time and again, and many companies have found the cost of maintenance to be the balance between profit and loss-so much so that, in two instances with which the writer is familiar, the mechanical equipment was practically replaced throughout. I bring this point out here to emphasize the value and necessity of keeping abreast of the times, and obtaining maximum efficiency with the minimum outlay. Time is indeed money where delays occur due to defective or poorly kept equipment, and it is absolutely necessary to prevent machinery from becoming defective or inefficient.

Jan 1, 1930

Ni and samaria-doped ceria (Ni-SDC) cermet are desirable materials for making a solid oxide fuel cell anode working at intermediate temperature (800°C or lower) due to its good ionic/electronic conductivity at the reduced operating temperature. An advantage of the use of a Ni-SDC anode is the enlargement of the effective reaction zone in the interfacial area between the anode and the electrolyte. As a result of the mixed ionic/electronic conductivity of the anode, the electrode reaction rate is enhanced. Investigations into the properties of the ceria-based anode reveal that the performance of the anode is closely related to its microstructures, which are dependent on the composition and fabrication conditions of the ceramics. In this paper, a method for quantitative characterization and correlation of Ni-SDC cermet microstructures to the performance of an anode is investigated. A series of Ni-SDC anode samples are prepared by screen-printing (SP) and spin-coating (SC) techniques, and different microstructures of the samples are obtained through controlling the SP or SC conditions and the sintering temperature. Individual phases (Ni, SDC and pore) in the tri-phase boundary (TPB) microstructures in the electrode are differentiated and segmented from each other in optical and SEM images based on the differences in refractivity and atomic contrasts among the phases. The geometric properties of the segmented phases are characterized using image analysis methods, so that a quantitative skeleton illustrating the TPB microstructures of the Ni-SDC electrode is obtained. Statistical analysis of the distribution of the three phases in the TPB microstructures is performed and the relationship of the microstructures with the optimum electrode is interpreted in terms of the microstructure analysis data.

Jan 1, 2005

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005