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By T. Suzuki

Acid leach liquors from spent lithium-ion batteries employing lithium cobalt dioxide (LiCoO2) as a cathode active material contain valuable metals such as cobalt and lithium, as well as common metals such as aluminum and copper. The objective of this study was to develop a hydrometallurgical process providing a high selectively between aluminum, cobalt, copper, and lithium from hydrochloric acid solutions. Batch experiment results showed that selective hydroxide precipitation approach was not suitable because a significant amount of cobalt and lithium was co-precipitated with aluminum and copper hydroxides. In contrast, batch experiments and the subsequent data analysis indicated that the sequence of solvent extraction circuits using PC-88A, Acorga M5640, and tri-n-octylamine (TOA) extractants effectively separates four metals of interest. In the first circuit of the proposed process, copper was selectively extracted by Acorga M5640 at the pH 1.0-2.0. Aluminum, cobalt, and lithium remain in the aqueous phase. In the second circuit, aluminium is selectively extracted by PC-88A at pH 2.0-2.5. For the separation of remaining cobalt and lithium, Acorga M5640 provided higher separation efficiency compared to PC-88A single extractant and PC-88A/TOA mixed extractant. However, the stripping efficiency of cobalt from the Acorga M5640 organic phase was found to be low (less than 10 %). Therefore, PC-88A/TOA mixed extractant rather than Acorga M5640 is an advisable choice for the separation of cobalt and lithium. Keywords: spent lithium-ion secondary batteries, solvent extraction, lithium, cobalt

Sep 1, 2012

By A. Oberrauner

Electrostatic separation is a dry separation technique usable for many applications in the mining- and recycling industries. At the Chair of Mineral Processing intensified research has been done on this topic during the last years. One challenge was to measure the triboelectric charging of fine mineral particles in a triboelectric charging device consisting of an electrically insulated polyethylene rotor/stator assembly. These tests, performed on monomineralic samples, were accomplished in a climate chamber. It was shown that charging of minerals not only depends on rotor speed, feed rate and atmospheric circumstances but also on the properties of the applied electrostatic field. Tests on pure calcite in contact with the polyethylene rotor/stator system resulted in specific triboelectric charges up to +10 nC/g at low relative humidity. With more water present in the surrounding atmosphere, these charging values decreased significantly. However, at higher relative humidity, triboelectric charge values could be maintained after an electrostatic field of positive polarity was applied. Similarly, charging behavior was found with other hydrophilic minerals. The idea behind all these tests was to find the largest charging difference between minerals occurring together in a deposit and to be able to charge them oppositely, assuming that this means good sort ability in an electrostatic separator. The results gained from these investigations are shown. After having obtained many results on charging pure minerals, it became interesting to test the applicability of the charging tendencies on electrostatic separation of fines <100 µm. In order to do so, a separator for fine polymineralic powders was developed, constructed and combined with the triboelectric charging device, all being set up in a climate chamber. This new so-called coax-separator is presented along with first test-results.

Sep 1, 2012

By Shankar Narasimhan

Data Reconciliation is a technique that has been developed more than fifty years ago and has been refined over the past few decades and is now being deployed routinely in several process industries such as refining, petrochemicals, mineral processing and hydro-metallurgy. The main aim of data reconciliation is to obtain accurate estimates of all process variables and parameters using plant measurements that are invariably corrupted by random errors and may also contain biases and other gross errors. These reconciled estimates are subsequently used either in offline exercises such as simulation, retrofitting, and de-bottlenecking or in online optimization and control applications. In this presentation, a brief history of data reconciliation, its assumptions, and uses are reviewed. New developments in this area are highlighted such as robust data reconciliation to handle model uncertainties, and reconciliation using identified models derived purely from operating data. Several case studies in the mineral processing industries reported in the literature are also highlighted to indicate the potential benefits of this technique.

Sep 1, 2012

By C. Eswaraiah

A drop weight tester (DWT) is designed and fabricated for the purpose of analyzing single particle impact breakage characteristics of different ores. The test results were evaluated through the breakage distributions of different size fractions at five different input energy levels. The breakage parameter, t10 (Narayanan, 1986) is used to represent the degree of size reduction, which is assumed to be representative of the breakage product size distribution obtained from single particle breakage. Representation of breakage distribution with this method consist one more breakage dependent parameter (a). To evaluate the impact breakage characteristic of different ores, a mathematical relationship was established to analyze the dependency of breakage parameters, t10 and a on specific input energy (EIS) or fracture energy (Tavares et al, 1998, Fandrich, 1998), specimen size (?) and Bond?s operating work index (WI0). Mathematical results developed gives adequate model for all ball mill modeling. It can be concluded that the drop weight test method is a useful and practical way of evaluating the impact strengths of various ores and results of which can be used in modeling mills.

Sep 1, 2012

By Ben Murphy, Alejandro Yanez, Tatu Miettinen

"Flotation using large volume cells has grown in importance during recent years, particularly given the increasing demand for minerals whilst ore grades are decreasing. Outotec introduced the TankCell® e300 in 2007 to enable concentrator plants to process these higher tonnages. From the beginning, TankCell® e300s with FloatForce® mixing mechanisms have demonstrated good metallurgical performance with decreased operating costs and high availability. This paper deals with specific engineering challenges that need to be considered when installing these units rather than giving examples of performance. Today there are over 100 TankCell® e300s operational worldwide. As more of these units are installed new technical challenges are encountered and solutions developed to maximize their productivity. Lessons have been learnt by operators, engineering companies and the cell manufacturers on how best to design and layout these cells in modern concentrators to ensure smooth transition from design to installation to operation. This paper presents information on important design considerations and learning that has been obtained through the design, installation and commissioning of the TankCell e300 around the world. Areas pertaining to cells layout such as feed and discharge arrangements along with items of metallurgical concern such as sampling, reagent addition and the potential benefits of installing a variable speed drive on the motor will be covered in depth."

Jan 1, 2014

By D. Kosior

Influence of frothers (a-terpineol and n-octanol) concentration on kinetics of a three phase contact (TPC) formation by a bubble colliding with a hydrophobic surface (Teflon) of different roughness was studied using a high-speed camera (1040 frames per second). It was found that the Teflon surface roughness and the frother concentration strongly affected time of the TPC formation (tTPC) and time of drainage (tD) of the liquid film separating the colliding bubble from the solid surfaces. With increasing Teflon surface roughness, from ca 1 to 80 µm, the time of the TPC formation was shortened by over the order of magnitude, from ca 100 to a few milliseconds only. At low a-terpineol and n-octanol concentrations, thetTPC values were shorter than in distilled water due to lowering the bubble velocity in the frother presence and diminished bouncing of the colliding bubble. However, at high frothers concentrations the tTPC values were prolonged, despite that the bubble velocity was similar. The prolongation of the tTPC at high frother concentrations indicates that air (micro- and/or nano-bubbles) was present at the Teflon surfaces of different roughness. The mechanism of the tTPCprolongation at high frother dosage is described.

Sep 1, 2012

By E. Lee

Cone crushers are widely used within the mining and aggregate industries for the size reduction of minerals, ores, and rock materials. In mining applications for example, the product from cone crushers is often fed to HPGRs or directly to mills in the subsequent grinding circuit. An improved cone crusher performance can therefore result in an overall improved and more efficient comminution process. The objective of this paper is to systematically study a number of different ways of applying compressive crushing. By mathematically modelling these different crushing concepts and then theoretically optimizing crushing sequences accordingly, each concept can be studied and evaluated. In addition, aspects concerning whether or not the results are mechanically or practically achievable are considered. This study thus explores the advantages and disadvantages of different crushing concepts. In this paper, four different theoretical crushing concepts are presented and studied. The results show that in terms of interparticle crushing, optimal crushing sequences with varying compression ratios can be replaced by easier implemented series of constant compressions without significant deterioration. It is also shown that that considerably better performance is obtained for crushing sequences with both breakage modes. The subsequent comparison between such concepts indicates that different approaches can achieve the same results, and that the different concepts are comparable. It is further concluded that interparticle crushing should be kept to a minimum if fines generation or energy consumption is to be minimized, and that each of the studied concepts presents different challenges for implementation. Keywords: compressive crushing, cone crusher, optimization, modeling, crushing concept

Sep 1, 2012

In this study, the effect of different regrinding conditions on the depression of fine pyrite at the cleaner stage was investigated. The regrinding condition was manipulated by different grinding media (stainless steel and mild steel). It was found that, after regrinding with mild steel grinding media, the flotation recovery of pyrite is much lower than with stainless steel grinding media, and it is more difficult to restore by adding more collector. This means, regrinding with mild steel grinding media may depress the pyrite flotation more strongly. The copper activation of pyrite during regrinding was also studied. It was found, that the mild steel grinding media is more beneficial to copper activation than stainless steel media. Additionally, the analysis of pyrite recovery based on the particle size indicated, that the fine particles are more susceptible to different grinding environments than intermediate and coarse particles and therefore are more easily depressed with a much lower flotation recovery.

Sep 1, 2012

By H. Z. Kuyumcu

Coking of coal blends using high volatile coals with poor coking abilities to produce a high quality coke for blast furnace application can be achieved by compacting the coal blend prior to the carbonization process. Here densification up to a relative material density of 80 %, i.e. a compact density around 1100 kg/m3, has proven to be advantageous. Coal is compacted by stamping, if the so-called stamp charging process applied. Compacting of the coal by pressing is practised in case of the cokemaking with so-called heat-recovery ovens. Stamped and pressed coal cakes require over the cake volume uniform high density and mechanical stability. Besides the aspects of the coal selection, the efficiency of the process is mainly determined by the operating parameters compacting time and compacting energy for coal cake making. At the Department for Mechanical Process Engineering & Solids Processing of the Technical University Berlin the two sub-processes of densification and strengthening during stamping and during pressing are theoretically and experimentally investigated using specially developed lab-scale compacting test units and a strength test device. Describing cake density in terms of coal properties for a given coal and measured compacting energy input then leads to a compacting equation with the so-called Stampability as the integral model parameter for the stamping process. For the pressing process the cake density can be calculated with the measured compacting pressure and the Compressibility factor, respectively. Investigations were carried out to provide evidence of a significant influence of coal type, coal surface moisture, coal granulometric and mechanical properties on the densification process. The overall objective of the work is to establish a comprehensive mathematical model on the compacting behavior of large coal bulk quantities and the optimization of the compacting processes by stamping and by pressing. Keywords: coal compacting, agglomeration, stamping, pressing, cokemaking

Sep 1, 2012

By T. Wang

A new kind of mixed chelate collector was prepared in order to separate gangue (mainly quartz) and iron minerals efficiently during room temperature. The collector was was composed of two chelate collectors DES and DA. Floatation tests were carried out under 28?C with mixed magnetic concentrates of Donganshan sintering plant, and optimal test conditions were obtained, in which a direct floatation was undertaken and then a close circuit reverse floatation tests ( one roughing, one cleaning, and two scavenging), and a result of Fe grade of siderite concentrate 36.49%, Fe recovery of siderite concentrate 10.65%, Fe grade of final concentrate 66.27%, Fe recovery of final concentrate 78.25%, and Fe grade of tailing 16.22% was gained. Fourier Transform Infrared (FTIR) Spectra and Zeta potential of siderite and quartz adsorbed the DES and DA collectors before and after were measured in order to analyze the reaction between the collector and minerals. Furthermore, Molecule electronegativity of DES and DA was calculated by Electronegativity Proportionality Principle (EPP). Results showed that DES molecules have five active adsorbing sites and their molecule electronegativity was stronger while DA molecules have three active adsorbing sites, which all make the mixed collector has efficiently collecting performance. Zeta potential results of Quartz and siderite showed that at pH 11.5 both kinds of particles charged negative and at this pH value the mixed collector were mainly anionic collectors which indicate that electrostatic adsorption does not exist at this situation. FTIR results showed that characteristic peaks of the mixed collector changed before and after adsorption with the minerals, which means that there exists chemical adsorption or hydrogen bonding.

Jan 1, 2014

By Vincent C. Smith, Agit Singh, Bernard Muller

The control of minerals processing plants is by no means trivial. In order to address some of the difficulties, it was decided to develop and test a model predictive controller (MPC) for a milling circuit. A milling simulator was written to test the MPC controller. Due to the large number of tuning parameters in a controller of this type, an optimising algorithm was written that automatically tunes the controller. Good, robust control was obtained when the controller was tuned using this algorithm. The controller was tested for various scenarios that are often encountered in the minerals processing industry. When problems were encountered, the MPC algorithm was specially adapted to accommodate for these difficulties. Control was further improved by using feedforward control as well as quadratic programming. The movement of the manipulated variables was reduced by using a region of uncertainty that allows the controlled variable to vary within a specified region around the setpoint. Integrators were handled by adapting the algorithm slightly and adding an optional integral error portion in the MPC controller. The performance of the enhanced MPC controller was compared to PI controllers on both the simulator and a commercial plant. The MPC controller showed faster responses with less interaction in both cases.

Jan 1, 2003

Spent automobile catalyst is an important secondary resource of PGMs (platinum group metals) and the recovery is significant. Various methods of recovery technology have been reported and applied in practical production, including pyro- and hydrometallurgical processes. Since the grade of PGMs in the catalysts is so low, approximately 0.5 wt. %, the present recycling technologies require high energy-consumption, it is of great significance to enrich the PGMs with some energy saving physical separation methods as a pretreatment. Automobile catalyst is usually composed of cordierite phase as a substrate and alumina phase, with PGMs, which covers the cordierite phase. We adopted the quenching pretreatment, one method of thermal shock, to generate micro-cracks between the two phases and separate the alumina phase from cordierite. Quenching was carried out by heating the catalysts in an electric furnace of different temperatures followed by rapid soaking into cold water. It was found that the phase boundary between alumina and cordierite was broken in the quenching and selective separation (detachment) of alumina from the cordierite could be achieved in the following surface grinding. The effect of quenching was checked by microscopic observation, hardness measurement, and chemical analysis. This paper figures out the stress formula of the quenching process, which is largely connected with layer thickness and temperature gradient by using an FEM (Finite Element Method) simulation and clarifies the mechanism of crack generation in the quenching process. Keywords: automobile catalyst, PGM, quenching process, FEM

Sep 1, 2012

By J. Drzymala

Ores and raw materials are subjected to mineral processing operations to increase the content of their useful components. Upgrading of these materials can proceed with different selectivity and therefore, there is a need to know and monitor the separation results of the process. The separation results can be evaluated using tables and graphs called upgrading curves. The course of lines in the upgrading curves is usually complex and depends on the graph type and process parameters. The Halbich grade vs. recovery plot is frequently used because is practical and it indicates several characteristic features of separation results. Separations by means of flotation of several different shale, dolomite and sandstone copper ores were performed along with determination of their mineral composition, copper content, liberation degree, and the maximum theoretical copper content in the first concentrate. These data, plotted as the Halbich upgrading curves, allowed to find other characteristic points such as practical maximum copper content in the first concentrate, maximum curvature coexisting with the liberation degree, maximum recovery of ore valuable components, and the slope the recovery-grade line at high recoveries as a measure of liberation. Correlations between theoretical and practical maximum copper contents in the first concentrate as well liberation degree and maximum curvature were also presented. They show that the ore type significantly influences the shape of the Halbich curve and its characteristic points.

Sep 1, 2012

By S. Makni

Flotation is a complex process in which many mechanisms come into interaction. In this paper, an approach to model these mechanisms in order to predict size-by-size flotation performances is presented. The estimation of the collection efficiency of particles takes into account the serial sub-processes of particle-bubble collision, attachment and detachment. The model was applied to an industrial plant and yielded satisfactory results whereby the actual flotation performances could be correctly predicted. Furthermore, the flotation model allowed investigating the possibility of improving flotation performances by a split flotation feed in comparison to the actual single-stage process.

Sep 1, 2012

By Avishan Atrafi

Frothing behavior of surfactants originate from their preferential adsorption at the gas-solution interface. Different surfactants may demonstrate different adsorption behaviors depending on their molecular structure and surface activity. The quantity and rate of adsorption of surfactants at the gas- solution interface in flotation systems will certainly affect kinetics of reaction and fractionation of surfactant between bulk and foam phase and subsequently their frothing characteristics. In this paper, the frothing characteristics of sodium oleate which is the main constituent of fatty acids used in flotation systems is explained. The adsorption behavior of sodium oleate is then compared to a typical non-ionic frother (Methyl Isobutyl Carbinol, MIBC) in terms of different adsorption behavior at the gas-solution interface. Since long chain fatty acids are weak electrolytes, their behavior is a strong function of pH. Also semi soluble salts including apatite contain considerable amounts of ions like calcium in their lattice, so the effect of presence of ions on the frothing behavior of fatty acids requires an investigation. A mass balance on the surfactant transferred to the foam was solved to estimate the bubble surface area flux in foam, which explained how the adsorbed surfactant at gas-solution interface controls the bubble surface area flux at foam. Since sodium oleate adsorption at foam takes place gradually, frother concentration as a function of time was monitored by the total organic carbon measurement (TOC) to compare the surfactant uptake rate at different concentrations, pH and ionic strength. The surfactant concentration adsorbed within foam together with the value of adsorption density from the Gibbs adsorption, leads to the calculation of the surface area flux and prediction of average bubble size in the foam at a specific time frame. This value was compared at different concentrations of sodium oleate. Dynamic surface tension measurements were accompanied to explain the adsorption behavior, though finally equilibrium surface tension turns out to better explain the foamability characteristics. Keywords: flotation collectors, flotation froths, foams, fatty acids, adsorption behavior

Sep 1, 2012

By K. C. Corin

It is well known that the grinding circuit plays a crucial role in flotation. The effect of pulp chemistry during grinding is often overlooked. It is believed that the surface properties of the minerals can be adjusted during flotation rather than during grinding. However, recent development in surface analysis techniques (TOF-SIMS, XPS, and AES etc.) have proven that the hydrophilic iron hydroxides formed at the mineral surface during grinding make it difficult for collector adsorption, which may result in poor grades and recoveries of the valuable minerals. This study investigated the effect of the pulp chemistry conditions during milling and the subsequent effects on flotation performance of an Nkomati ore. The results have shown that there was approximately 10 % increase in Ni recovery, when the ore was ground at a dissolved oxygen (DO) concentration of 0 ppm (DO-0) in comparison to no gas control during the grinding stage. However, when the pH was changed from 9 to 11, no gas control resulted in a 20 % decrease in the Ni recovery compared to only 5 % decrease in the Ni recovery at DO-0. A noteworthy observation is that controlling a combination of DO and pH during grinding is of critical importance for better floatability and selectivity for such a system. It also became clear from this study that the presence of oxygen is critical to the consumption of xanthate, which is consistent with the general literature. It has been established that grinding at lower DO levels/redox potentials (Eh) in the presence of xanthate significantly improves the flotation performance of the valuable minerals.

Sep 1, 2012

By M. Alvarez-Silva

The control of the amount of chromite reporting to the concentrate during the flotation of UG2 ore is of critical importance since its presence affects the downstream smelting process. It is generally reported that the main mechanism responsible for chromite recovery is through entrainment. This is reflected in analyzing the solids and water recoveries. These in turn are strongly dependent on the froth phase. In the present investigation a laboratory scale column flotation cell was used to investigate the role of the froth phase in the flotation of UG2 ore. Such a device is superior to a standard batch cell since it operates at steady state in open circuit and also allows for a greater degree of flexibility in terms of froth heights. The mass of solids and water recovered in the concentrate as well as chromite (Cr2O3) recovery by size class was determined as a function of froth height, superficial gas velocity and depressant dosage. The results showed that depressants had little effect on chromite recovery but increased the grade due to the depression of gangue minerals. A 60cm froth height always resulted in slightly lower solids, water and chromite recovery than for 30cm. Typically only 20-25 % of solids reaching the pulp-froth interface reached the launder. The relationship between solids and water recovery for a wide range of conditions indicated that chromite is mostly recovered by entrainment. Keywords: UG2 ore, column flotation cell

Sep 1, 2012

By N. D. Dementieva

Based on lab and pilot-plant tests to recover gold, silver and lead of a Russian deposit, a collective and flotation concentration flow sheet with lead and sulfide concentrates was proposed. The type of the deposit is gold-sulfide-quartz-bearing. The recovery of gold, silver, and lead to a lead concentrate was 47.4%, 68.1% and 70.7%, respectively. The grade of gold and silver grade was 170 g/t and 372 g/t, respectively. The mass percent of lead, zinc and arsenic mass percent was 41.7%, 0.34% and 0.63%, respectively. The recovery of gold and silver recovery to a sulfide concentrate was 50.1% and 28.8% at the grade of gold 20.5 g/t and silver 66.2 g/t. Sulfide concentrate with arsenic mass percent ~3% was biooxidised followed by CIL and obtaining metal at the site as well as zinc concentrate from bioleaching solutions with zinc mass percent 45% at its 64% recovery. The total gold and silver recovery using a developed technology with the account of their treatment at a polymetallic plant was 92.2% and 93.7%, respectively.

Sep 1, 2012

By Y. Y. Zhou

This paper introduces the application of CRIMM high-gradient magnetic separator in refinement of feldspar powders as well as the supporting technical outfits needed by the refining process with the high-gradient magnetic separator as main equipment. It could reduce the content of Fe2O3 to 0.03% with a deferrization rate of 85.88% from the feldspar raw ore containing 0.17% Fe2O3by using the above refining technology, producing an ultrapure feldspar product.

Jan 1, 2014

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using sodium dodecyl sulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).In order to investigate the effect of the initial concentration of Fe3+ on As removal, sets of experiments were performed with a concentration of Fe3+ in the proper range of pH (5,0 – 6,0) previously observed in the coprecipitation tests. As removal improves significantly as the concentration of the coprecipitant agent increases from 60 mg.L-1 (77,4%) to 80 mg.L-1 (99,7%). This is probably due to the higher concentration of ferric hydroxide (Fe(OH)3) which provides a larger surface area available for adsorption of As. From the initial coprecipitant concentration of 80 mg.L-1, As removal has shown to be rather high (? 99,7%), with the maximum being (99,9%) by using a Fe3+ concentration of 160 mg.L-1. Therefore, for a maximum As removal, under these test conditions, the optimum concentration of Fe3+ is 160mg.L-1.This paper also shows the effect of the initial concentration of Al3+ on As removal at a suitable range of pH (7,0 – 8,0). A very significant increase on As removal was found to occur as the initial concentration of coprecipitant was increased from 60 mg.L-1 (35,7%) to 80 mg.L-1 (97,7%) and a decrease in As floatability (43,7% - 54,5%) was found to occur from that Al3+ concentration amount. Based upon those results, the optimum Al3+ concentration so as to remove As under these test conditions is 80 mg.L-1."

Jan 1, 2003