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By B. T. McClure

Oxidizing catalytic converters are sometimes used by underground mine operators as an emission control device to reduce odor, hydrocarbon (HC), and carbon monoxide (CO) emissions from diesel equipment. The objectives of this report are to quantitatively assess the effects of catalytic converters on diesel exhaust emissions and to make recommendations for their use. Information in this report is from a literature survey and contract research supported by the Bureau of Mines. Catalytic converters are effective in reducing CO, HC, and odors when the exhaust temperature is high enough so that the converter remains above 250° C. Converter temperature is dependent upon engine duty cycle. Catalytic converters increse sulfate emissions and slightly in- crease oxides of nitrogen (NOx) emissions. If low sulfur fuels are not used, the increase in sulfate and nitrogen dioxide (NO2) emissions can offset any advantages of the catalytic converter as measured by the emissions quality index (EQI). In addition, in vitro bioassays have shown that catalytic converters produce soluble organic compounds, which have increased mutagenic activity with respect to untreated exhaust. Based upon criteria recommended by a joint Canadian-United States research panel, catalytic converters should only be used in special circumstances in underground mines. Vehicles equipped with catalytic converters should operate under moderate to heavy load conditions, and use fuel with a sulfur content less than 0.1 pct.

Jan 1, 1988

By G. S. Scott, G. W. Jones

"INTRODUCTION An important phase of the accident-preventing program of the Bureau Mines is the determination of the explosion hazards of various combustible gases, vapors, and liquids encountered in mining and allied industries and the development of methods of eliminating or mitigating them.Recently, isobutane has become a commercially important raw material in the production of aviation gasoline by the alkylation process. 4/ in which isoparaffins are combined with olefins to give higher molecular weight compounds of branched-chain structure.Because of the anticipated commercial importance of isobutane in industry, it has been deemed necessary to study and determine its general explosion haz¬ards. This report gives its limits of inflammability, minimum ignition temper¬atures, and the amounts of nitrogen and carbon dioxide required to render isobutane-air mixtures noninflammable."

Jun 1, 1947

By Sidney Katell

This Bureau of Mines study estimates capital investment, operating costs, and selling prices for three underground bituminous mines producing coal with annual production ranging from 1.03 to 3.09 million tons. It is assumed that the mines have a 20-year life. Wages and union welfare payments are considered as of November 12, 1973, under the Bituminous Wage Agreement of 1971, and costs for material and equipment are based on 1973 indexes. Initial capital investment ranges from $12,938,200 for the 1.03-million-ton-per-year (MJ.Vl tpy) mine to $31,435,500 for the 3.09 MM tpy mine. Total capital investment ranges from $21,607,200 to $51,982,000 for the same mines. Corresponding selling prices for the coal range from $9.11 to $8.06 per ton, assuming a 12-percent discounted cash flow rate of return after Federal income taxes.

Jan 1, 1974

By John P. Capp

The feasibility of simultaneously burning several paths through a coalbed to develop a multiple path underground gasification system was investigated by the Bureau of Mines during two experiments, Boreholes were drilled through the overburden and into the coal and arranged in a circle approximately 50 feet from a central borehole. In the first experiment, in an area which had previously been hydraulically fractured,5 air was injected at the center borehole. The coal was ignited at the other boreholes and the fire fronts traveled toward the center, counter to the flow of air, to backward burn paths through the coalbed. Two paths were linked during the first 5 days of operation. The outlets of these two paths were throttled and air pressure was increased to maintain the flow of air, but no other linkages were made. Fourteen days after the two linkages these two paths were opened and gasification was carried on for 10 days, but with only moderate success. In an effort to overcome operating difficulties air was injected at the peripheral boreholes, and the gases were drawn off at the center borehole. Reversed flow operations continued for 12 days and two more paths linked. The heating value of the gas generally was higher than 100 British thermal units per standard cubic foot (B.t.u. per std. c.f.). Because only four of seven paths linked, however, the entire system could not be evaluated with respect to product-gas output and recovery of energy.

Jan 1, 1961

By R. Hogg, T. F. Dumm

"A procedure for evaluating the size/specific gravity distribution of ultrafine coal and the distributions of sulfur and ash with respect to particle size and specific gravity is described. The procedure is essentially an extension of the conventional coal washability technique in which special precautions are taken to ensure particle dispersion in the heavy organic liquids, centrifuges are used to obtain adequate separation rates, and micromesh sieves are used for size separation at fine sizes. An example of the application of this technique to the evaluation of the extent of liberation of sulfur and ash in a coal sample ground to 90Z passing 200 mesh (74 um) is described.INTRODUCTIONIn order to determine the potential for deep cleaning of coal by fine grinding to liberate sulfur and ash-forming minerals, it is necessary to obtain data on the distributions of these species by size and specific gravity. In conventional coal processing operations, this information is obtained by means of a standard ""washability"" analysis. Attempts to extend this procedure to ultrafine coal, however, have generally been unsatisfactory and have often led to unreliable and inconsistent results [11. The present authors have described a modified washability procedure in which cumulative specific gravity fractionation is combined with sub-sieve size analysis (by laser diffraction/light scattering) to determine the particle size/specific gravity distribution of ultrafine coal [2]. Unfortunately, because this technique does not involve separation of the individual fractions, only limited information can be obtained on the specific distributions of sulfur and ash.The objective of the work described in this paper was to develop and evaluate a procedure for size and specific gravity fractionation of ultrafine coal and to use conventional analyses for sulfur and ash to determine their relative distribution in the coal. The procedure is essentially a simple extension of the standard washability analysis [3] but incorporating special precautions for treating ultrafine particles.EXPERIMENTAL Material The material used in the development and evaluation of the ultrafine coal fractionation procedure was a medium volatile bituminous coal from the Lower Kittanning seam. A sample of the coal (nominally - 1/4 inch), obtained from the Penn State Coal Data Base, was ground to 90% passing 200 mesh by the following two-stage grinding procedure: About 2 kg of the as-received coal were ground to about 30Z passing 200 mesh in a Model 4-E Quakertown mill (""coffee grinder""). About 1 kg of this product was then ground to about 90Z passing 200 mesh in a Holmes Model 300 Pulverizer."

Jan 1, 1989

By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By E. G. King

Difficulty has been encountered in making thermodynamic calculations of metallurgical reactions involving interoxidic compounds of the ferroalloy elements because of the serious lack of most thermodynamic data for these substances. This Bureau of Mines report (the first of a planned series dealing with entropies of vanadates, tungstates, and molybdates) presents low-temperature heat-capacity data and entropy values at 298.15° K. for three crystalline sodium vanadates--metavanadate (NaV03), orthovanadate (Na3VO4), and pyro-vanadate (Na4V2O7). The results are combined with data for the constituent oxides and elements to obtain entropies of formation of the vanadates. Previous to this report only one vanadate had been studied Similarly, ammonium metavanadate.4/

Jan 1, 1961

By M. E. Volin

The Ladd manganese deposits are in San Joaquin County, Calif., about 13 miles southwest of Tracy. The deposits are confined in two main areas of development, roughly about 1,700 feet apart horizontally, and known as the Ladd mine and Fabian mine, respectively. The deposits occur as interbedded lenses in the white cherts of the Franciscan formation. The ore minerals are bementite, rhodochrosite and psilomelane. As a part of the Bureau of Mines program of investigation and development of domestic mineral deposits, a development program was started. August 24, 1940, and completed on June 24, 1941. The Federal Geological Survey cooperated by mapping the geology and logging the drill cores. The program included road building, trenching, rehabilitating the mine workings, trenching underground excavation, sampling, and core drilling. The following pages mention the location, give a brief history, and note the physical features of +1-.1, district. Mine workings are sketched, the deposit is described and the plan of the project is noted. The work performed by the Bureau of Mines is explained in the concluding pages with a summary of the drill hole logs.

Jan 1, 1949

By A. J. Kraemer

This report on the physical and chemical properties of typical crude oils of California is the eighth in a series which will cover the producing districts of the United States, and is supplementary to Serial 2595 of the Bureau of Mines, which includes discussion of results, summary tables, and selected typical analyses of California crudes. The present report contains additional individual analyses of crude, oils from the fields of Fresno, Kern, Los Angeles, Orange, and Ventura Counties.

Jan 1, 1924

By A. J. Kraemer

This report on the physical and chemical properties of crude oils of California is one of a series on the producing districts of the United States. It includes a short discussion of results, tabulated data, and individual analyses of California crudes. Analyses of crude oils from the fields of Fresno, Kern, Los Angeles, Orange, and Ventura Counties have been published in Serials 25952 and 26083. The analyses reported in this paper corer samples that were obtained subsequent to the publication of Serials 2535 and 2608. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting of samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1927

By R. V. Lundquist, H. Leitch

The solubility characteristics of mono calcium aluminate (CaO A₁₂ 0 ) in water and in NaOH , Na₂ CO₂ , and NaOH - Na₂ CO₂ solutions were measured by determining the changes in Al2O3 concentrations in solution over a period of time at a specified temperature . The monocalcium aluminate was synthesized by sintering its starting components for 72 hours at 1,375 ° C. Distilled water and aqueous solutions of technical grades of NaOH and Na₂ CO₂ were used as solvents . The extraction of alumina from the monocalcium aluminate was dependent on the composition of the solvent and partially dependent on temperature for leaching . About 98 percent extraction of alumina from the aluminate occurred in Na₂ CO3 solutions containing 10 to 12 percent NaOH . Other solution compositions produce lesser extractions .

Jan 1, 1963

By F. W. Wessel

This report summarizes Bureau of Mines laboratory tests of four tungsten¬-bearing materials of various grades, The test work has demonstrated that the dry reaction between sodium carbonate and scheelite is best conducted at 900° C. or a few degrees less. The sodium carbonate requirement, in addition to the stoichiometric equivalent of the scheelite, is in some inverse relationship to the grade of tungsten in the ore. Residence time and particle size exert a definite but minor control on the reaction. Pressure-digestion tests on an impure concentrate indicate the technical feasibility of extraction by this process. INTRDUCTION Over 100 years ago Oxland discovered that tungstic oxide could be removed from wolframite and converted to a soluble form by reacting the mineral with a soluble alkaline salt at elevated temperatures. He patented this discovery, and this patent 4/ since has been the basis for most tungsten extraction. Much literature exists on this process and its modifications, and the characteristics and possibilities of the reaction are quite well defined.

Jan 1, 1956

This paper on. the physical and chemical properties of crude oils from California fields is one of a series of reports on the oil-producing districts of the United States., The paper includes a short discussion of results, tabular data, and individual analyses of eight California crudes. Analyses of other crude oils from California have been published in Reports, of Investigations 2595,3/ 2608,4/ and 28465/. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1931

By NIOSH NIOSH

This work explores application of a double alkaline leach method to extraction of alumina from Oregon ferruginous bauxitic materials. The process recovers a greater proportion of alumina from high-silica ores than is possible by a conventional single-leach method. This recovery is accomplished by calcining the ore, removing reactive silica in a preliminary dilute caustic soda leach, and then applying a second leach to dissolve alumina. Ores containing up to 15 percent Si~) 35 percent AI;:) Os, and 30 percent Os were examined. Under conditions of treatment established by experimentation, more than BO-percent alumina extraction was demonstrated. When and if conditions demand the use of low-grade materials, the double-leach process is capable of providing millions of tons of alumina from Oregon ferruginous bauxite.

Jan 1, 1963

By Byron E. Blair

This report describes procedures for using a high-speed camera to study blasting phenomena. Both quantitative and qualitative information can be obtained, provided that proper interpretations of the projected two-dimensional images are made. Geometrical relationships between object and image displacements are given in terms of horizontal and vertical angles of the camera optic axis with respect to the quarry face. Correction factors are given for obtaining true object displacements from image displacements in the camera film plane. The time of initial rock movement also is considered, and the control-ling factors of camera speed, scale factor, minimum increment of projection measurement, etc., are evaluated in terms of minimum time intervals. The high-speed camera and associated equipment are described, and field measurements and laboratory data analysis techniques are outlined. An analysis of a typical high-speed motion picture is made, and the application of the necessary correction factors is illustrated.

Jan 1, 1960

By Clarence O. Babcock

This Bureau of Mines publication presents guidelines for mining near surface and underground bodies of water. The guidelines were based on information developed under contract in three phases of study, as follows: (1) Collection and documentation of data from worldwide sources; (2) application of existing guidelines, foreign, Federal, and State, to case histories of previous inundations; and (3) development of recommended guidelines for underground coal mining near bodies of water aimed at maximum efficient utilization of underground coal resources consistent with minimizing inundation hazards. While the contract guidelines were for the mining of coal seams, they may also be used for mining any tabular sedimentary mineral deposit. Tables are given for the determination of the size of coal pillars needed; for other bedded deposits, similar tables could be determined based on their strength properties.

Jan 1, 1977

By Frank J. Cservenyak

Curtailment of bauxite importation by enemy activities during World War II focused attention on the necessity of developing domestic deposits of aluminous materials. Large quantities of aluminum ores such as kaolin, siliceous bauxites, high-iron bauxites, anorthosite, and diaspore clays are available but not readily amenable to Bayer processing because of excessive impurities. The Bayer process, which is the only commercial method in use in the United States for producing metallurgical-grade alumina, requires a high Al2O3 bauxite relatively low in SiO2 and Fe2O3. The Bureau of Mines was charged by Congress to investigate processes for the production of alumina from these low-grade ores. One part of the program was an investigation, in the laboratory and pilot plant, of the recovery of alumina by the lime-soda sinter process. Ores comprising kaolin, diasporic clays, anorthosite, and siliceous bauxites have been investigated and studied in the laboratory and pilot plant, and a series 'of reports covering these investigations has been prepared.

Jan 1, 1948

By W. W. Weller

Heat capacities of ferrous molybdate (FeMoO4) and ferrous tungstate (FeWO4) were measured over the temperature range 51° to 298.15° K. Ferrous tungstate has a lambda type heat capacity anomaly at 74° K. The 298.15° K entropies are FeMoO4) 30.9 cal/deg mole and FeW04) 31.5 cal/deg mole.

Jan 1, 1966

By Paul T. Allsman

SCIENTIFIC inquiries concerning phenomena that may influence mining technology were widely publicized during the year. The deep-hole drilling project "Moho," 3 the use of nuclear explosives underground, and the recovery of minerals from the depths of the sea became subjects of scientific and general discussion. The mining industry continued to watch these developments with keen interest: but its more immediate concern was the increasing tempo of competition between mineral commodities, the domestic producers of these commodities, and foreign sources of supply. The competitive situation has intensified the industry's efforts to develop more efficient new mining methods, as well as to improve the efficiency of present practices. The attitude of the industry was well illustrated by rapidly expended use of low-cost ammonium nitrate explosives, the establishment of rigid schedules for equipment maintenance, and close attention to the detailed costs of production. The complexity of planning a new coal mine is aptly illustrated by the editors of Mechanization in the April 1959 Issue, in which they outline the cost of developing a mine and the various problems, factors, and decisions involved.4

Jan 1, 1960

By L. R. Burdick

Sulfur compounds have long been recognized as damaging pollutants of the air. A number of investigations have been made to determine the amount of such compounds existing in the air of various cities; moreover, some study has been given to the conditions affecting the concentrations. This paper summarizes published investigation and includes a bibliography on the subject. The methods of obtaining data have differed to the type of sampling, analysis procedure, hour of sampling, number of locations, and number of determinations made. Sampling methods include both the continuous type, covering a day or a number of days, and what can considered the ?snap? type, covering very short periods. Continuous sampling has, given data representing the average concentration at the location chosen but no information regarding variations from hour to hour, are none that might be said to represent the average for a city. The snap-sampling method, while not giving a true average for any one location or area, has in some instances made available date regarding variations of concentration during different hours of the day and at various locations or zones within the area chosen. Although the sulfur compounds in the air nay include sulfur dioxide, sulfur trioxide, hydrogen sulfide, and organic compounds of sulfur, most investigators report on the basis of sulfur dioxide. This gas unites with moisture to form sulfurous acid.

Jan 1, 1939