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By Hylton R. Brown

Although extensive research has been carried on to determine the factors affecting the explosibility of carbonaceous dusts, as much has been published on coal-dust and grain-dust explosions recent reports of loss of life and property in explosions if metal dusts emphasize the lack of information on the extent of the dust-explosion hazard in plants manufacturing or handling; aluminum, magnesium, or zinc powder, as well as other metal or mineral dusts. Early investigators believed that only the carbonaceous dusts formed explosive mixtures with air, and it was not until near the beginning of the present century that the explosibility of certain metal and mineral dusts was recognized generally. In his book, entitled "Fire and Explosion Risks," published in 1904, Von Schwartz called attention to such hazards. Many vague references to metallic-dust explosions are found in the literature, such as "a severe explosion of aluminum dust occurred in the Middle West several years ago," but very little information seems to be available on the extent of the hazard, the number of explosions, or the amount of loss caused by explosions in pants handling metallic or mineral dusts or powders other than those of a carbonaceous nature. A search of the records of insurance companies, rating bureaus, fire underwriters,and fire-protection associations as well as the files and records of Government agencies has been made to obtain authentic data on explosion losses. To indicate the extent of the hazard a summary of laboratory tests covering the explosibility of certain metal dusts, with brief reference to their uses and Methods of manufacture, and the data compiled from the information available on losses are presented in this publication.

Jan 1, 1941

By W. C. Hudson

"The Miami-West Palm Beach belt of silica sand, which may be suitable for the manufacture of high-grade glass, extends 65 miles northward from the neighborhood of Miami to the vicinity of West Palm Beach, The sand presumably originated in the host rocks constituting the oceanward slope of the Appalachian Mountains and the Piedmont Plateau of Georgia and the Carolinas. The sand now lies in a long, narrow, and probably thin belt that forms a dune-capped terrace marking a previous stage of submergence. The highest dune crests appear to be no more than 30 feet above sea level, and the water table is about 10 or 15 feet below the general level of the terrace.The width of the belt in several places is known to be more than a mile, and the thickness of the clean glass sand sampled ranged from 4 to more than 7 feet. Visual inspection and the meager data indicate the existence of bodies of glass sand large enough to supply foreseeable markets.Analyses of three samples indicate that beneficiation would make the sand suitable for the better grades of ordinary and flint glass.The prospective grade and quantity of sand, an available market in Florida for glassware, and the expectation of postwar expansion of the new industry of glass producing justify more detailed exploratory work and beneficiation testing.U. S. Route No. 1, Old Dixie Highway, the Seaboard Railway, and the Florida East Coast Railway, all substantially parallel and usually within a width of a mile or two, run along parts of the belt or between it and the coast. In addition to many streets and unpaved roads, a paved road crosses the belt at right angles about every 5 miles. Numerous towns are situated within or near the belt. Any area selected for a mining, processing, and manufacturing plant would be near a railroad, a highway, and water and also accessible to public utilities.The subtropical climate, famous for its pleasantly warm winters, would preclude seasonal interruption of plant operations."

Apr 1, 1946

By Roy L. Wilfong

Infrared reference spectra are presented of compounds of importance in lead sulfide flotation research. Included are the spectra of several short chain alkyl xanthates of lead and zinc, the corresponding dixanthogen compounds, and the common oxidation products of lead sulfide and their sodium analogs. The spectra of several frequently used industrial flotation reagent xanthates are also presented. A thorough, well-documented discussion is given of the various corrections made to correct the as recorded absorption band data to near absolute values.

Jan 1, 1974

By Elton L. Litchfield

The Bureau of Mines determined minimum energies for direct initiation of expanding gaseous detonation waves in acetylene-oxygen mixtures. Composition limit ranges for the initiation of detonation with fixed energies have been compared to data in the literature. Assuming that the stored electrical energy is completely converted to thermal energy, the agreement between the energy of primary explosive initiators and the energy of electrical discharge initiators was good. Minimum energies for initiation of detonation in the most sensitive composition (40 percent C20 plus 60 percent 0 2) were: 0.64 joule at an initial pressure of 1/4 atmosphere, 5.0X10-2 joule at 1/2 atmos¬phere, and 3.7X10-3 joule at I atmosphere. Fuel concentrations in mixtures initiated to detonation by 4.9X102 joules ranged from 10 to 65 percent C2H2 at 1/4 atmosphere, 10 to 67 percent C2H2 at 1/2 atmosphere, and 9 to 68 percent C2H2 at 1 atmosphere.

Jan 1, 1967

By David Schlain

This Bureau of Mines report describes a method for electrodepositing titanium diboride from a molten salt bath. Initially, the electrolyte is a mixture of LiBO2, NaB02, Na2 Ti03 , Li2Ti03, and Ti02? The cell is operated at 900° C in a dry, inert atmosphere with consumable anodes of titanium or hot-pressed titanium diboride (TiB2) powder. Agitation of the electrolyte is essential. Current densities may be 6 to 9 amperes per square decimeter (amp/dm2) with titanium anodes and 9 to 30 amp/dm2 with titanium diboride anodes. A current density of 6 amp/dm2 is equivalent to a plating rate of about 35 micrometers per hour. The adherence of the TiB2 deposit varies with the substrate material. It is most adherent on molybdenum and on 4130 steel that has been preplated with copper and nickel, less adherent on nickel, and still less adherent on Inconel and on 4130 steel without the preplate. Cathode and anode reactions are suggested.

Jan 1, 1976

By P. D. Bergman

To assess the efficacy and economics of producing power from coal, four open-cycle magnetohydrodynamic (MHD) processing schemes were selected for study. Each involved a different mode of coal combustion and level of gas cleanliness. The options considered were: (1) coal burned in a slagging combustor; (2) suspension gasification with slag removal prior to combustion; (3) parallel cyclone combustors, one operating fuel rich and the other operating with excess air; and (4) suspension gasification by the hot exhaust gases from the MHO duct with ash removed prior to combustion. Option 1 has the highest ash content in the combustion plasma and as a result would have the greatest operational difficulties associated with it. Options 2 and 4 have the cleanest MHD combustion plasma. For coal priced at $4/ton, the power generating cost of option 4,11.78 mills/Kw-hr, is the highest, with Option 1, at 9.04 mills/kW-hr the lowest. These costs may be compared with a conventional power cost of 9.92 mills/kW-hr for the late seventies. Capital costs of three of the four options were competitive with those of conventional thermal power plants employing stack gas S02 cleanup systems. Option 2 has the most favorable combination of operating characteristics and power cost. It was concluded that a clean, high-temperature working fluid can probably be produced from coal without leading to depressed system efficiencies and exorbitant capital costs.

Jan 1, 1973

By J. R. Ruark

This report presents results of the research and development work and operations performed during stage II of the gas combustion retorting research program conducted by the Colorado School of Mines Research Foundation and six major oil companies at the Bureau of Mines Anvil Points Research Facilities. The experimental program, including retort modification and air-gas distributor development, effects of shale quality and particle-size distribution, and other variables on the process, is discussed. Although operating problems are not fully resolved, it appears that the gas combustion retorting process can be successfully applied to achieve oil yields in excess of 85 percent of Fischer assay at mass shale feed rates of 500 pounds per hour per square foot of cross-sectional bed area, approximately twice the rate previously demonstrated to be reasonably practicable.

Jan 1, 1971

Most laboratory sealant studies were carried out in 2.0 inch I.D. Plexiglas tubes of 9.0 inches height containing 4.0 to 4.5 inches reconstructed soil from an 0-8 or 8-16 inch soil horizon at the Lanse site. (When soil was used from the Kato site, the top soil horizon was approximately 0-4 inches. The 4-8 inch horizon was somewhat comparable to the Lanse 8-16 inch horizon.) A 20 mesh Saran or steel screen was placed over the rubber stopper with a bottom drain to a 100 ml measuring cylinder. In some earlier experiments a 1/2 inch bed of 1/4 inch pea-gravel was then added, but in later experiments this was eliminated as it showed no particular utility. Field soil samples collected by a shovel were stored in sealed containers and sieved through a 4 mesh screen just before use. (Moisture content was typically about 25% for A horizon soil and about 20% for B horizon soil.) The sieved soil minus roots was then added in increments of about 1 1/4 inches. Compaction was effected by dropping a weighted ramrod (1-7/8 inches O.D,) five times from a height of two inches. If about twenty tamps were used or if the soil columns were rapped vigorously while water-logged, compaction was high with no detectable percolation. Freezing such samples would then usually cause very slow percolation, e.g. 1-2 ml/day. Using this as a standard procedure, percolation flows were usually stablized after two to three days to rates of about 100 to 200 ml/hour. Percolate was recycled carefully to minimize disturbance of the soil surface. When percolation flows were about 100 to 200 ml/hour, various additives (sealants) were introduced to the moist column in two to three increments to maintain a slight head. Additive concentrations were usually 2-1/2% with some at 5% in earlier experiments. Typical use of 40 ml of 2-1/2% additive corresponds to 4400 lbs/acre. When no more additive was present as supernatent liquid, water washes of about 15 ml were then used several times followed by special additives as needed. More water washes were then used to maintain a head of about 1/2 inch. Percolate was collected in 100 ml cylinders to measure percolation rates in ml/hr. Turbid percolate was evaporated to determine amount of eluted latex. Percolate was sometimes checked for pH by Pan-pH Indicator Paper9,10 reading in 0.5 units. Surface tension measurements were sometimes made by a DuNouy tensiometer10 in experiments using a surfactant for pretreatment.

Jan 1, 1972

By Roy H. Grau, John C. LaScola

"This Bureau of Mines report contains a tabulation of methane emissions during 1980 for all coal mines located in the United States with emissions greater than 0.1 MMcfd. Listed for each mine are methane emission quantity, location, and coalbed. The report also compares records of 1975 and 1980 and describes relationships between emissions in 1980 and the Bureau's coalbed gas content data on 11 mines.INTRODUCTIONMethane gas is a threat to safety in underground coal mines. Research by Government and industry has led to great gains in reducing methane gas ignitions and explosions. The development of advanced methane control techniques is necessary for the safe operation of more gassy mines and the implementation of rapid mining techniques.As part of this research, the Bureau of Mines has surveyed total methane emission data from underground bituminous coal mines in the United States and tabulated emissions from mines producing over 0.1 MMcfd of methane. This report is an update of similar studies previously described in Information Circulars 8733, 8659, and 8558 (2-4).3The data from 1980 were compiled from Mine Safety and Health Administration (MSHA) records of air quality-quantity inspections made quarterly at each mine. The inspections involve measuring airflow and collecting air samples in the main returns. From these data, an average methane emission is calculated and used to represent the daily mine emission for each quarter. The methane emissions given in this report are the averages of the four 1980 quarters and do not include mine emissions from other sources such as degasification projects. Since a previous Bureau study showed that emissions from mines emitting less than 0.1 MMcfd represented only 2 pct of all emissions, 0.1 MMcfd was chosen as a lower limit for data collection (4)."

Jan 1, 1982

By Tony Keller, Setsuo Maeda

Hand-Arm Vibration Syndrome (HAVS) was identified as early as 1918 in Bedford, Indiana in the U.S. Since then much research work has been done around the world in the areas of medical, epidemiological, engineering and legal aspects of HAVS. In Japan, much of the pioneering work in this field has been performed by Dr. Setsuo Maeda and his staff at the National Institute of Industrial Health (NIIH) in Kawasaki. Most recently, reports of work done by this group and by Dr. Ren Dong1 of NIOSH in the U.S., as well as many other suppliers and Japanese practitioners were presented at the 13th Japan Group Meeting on Human Response to Vibration held in Osaka2 during August 3-5, 2005. [ ]

Jan 6, 2006

By C. F. McCarroll

[Laboratory research and, control in the u?odnction an; utilization of petroleum and its product s have eqLmde& greatly during the past decade, rind much of the routine control and experimental equipment noirr requires the con-stant daily use of liquid nercury. In spite of this greater use, very little consideration has becn given to the hazard that might be occasioned by the toxic vapors of mercury unavoicl.a~l.p spilled or otherwise exposed to the atmosphere during the normcl 2rgced1u.e of ln30r~tor;~r operations. A sfmple visual exami~stion gf' sone of the laborztories reveals the prescnce of a considerable quantity of mercury in the craclcs of floors, on work tebles, ad on and mo7md eql~ipmeilt st.ads. Usually this yercurj ie contaminated with oily and dirt BO th~t it remint; in R finely divided state and a srnarl amount presents a relativell- lag? surface for evaporation. Since mercury shows meas~rable vo!-atility st a tempero.turc as lor^ 2s 8.5O F., mercury vapor will bo present in the atnosphere of anjr laboratory wbr.e mercury is exposed. promiscuously]

Jan 1, 1939

By Leslie H. Sharp, Martin J. Gavin

Those of the oil-shale operators in this country who are sincerely attempting to make a real industry out of oil-shale developments, are anxious to obtain fundamental data on the retorting of oil-shale; particularly as regards the effect of certain variable factors in the process of retorting on the quantity and quality of products yielded from oil shales when they are subjected to destructive distillation. From careful examination of a con siderable number of suggested processes for treating oil shales and the con flicting ideas on which they are designed, it seems probable that accurate information of a fundamental nature is highly essential to the successful establishment of an oil-shale industry in this country. . Accordingly, the United States Bureau of Mines, in cooperation with the State of Colorado, is undertaking to furnish some definite and impartial information of this type through investigations now under way at the University of Colorado, Boulder, Colo. A retort for the distillation of oil from oil shale has been designed and installed, together with the necessary auxiliary equipment for controlling and determining variable factors of distillation, and for recovering and de termining the quantity and quality of the products yielded from the shales. The retort is of such a nature that conditions of retorting can be accurately . and completely controlled, and varied at will. It is not designed as a com mercial retort, but only for research purposes. A testing laboratory with equipment necessary for the examination of the shales, physically and chemic ally, and the products yielded by them, has also been fitted up . The material used in the investigations is oil shale obtained from the DeBeque, Colorado, shale field. It yields on distillation in the Bureau of Mines testing apparatus, about 42 gallons of oil to the ton, and is there fore a fairly representative sample of the shales that probably will be first worked in Colorado. The shale used will be as uniform as possible in character and oil yield and will all be obtained from the same seam at the same point, in order to avoid the introduction of unnecessary variable factors in the tests and to render results strictly comparable •

Jul 1, 1920

By Paul Biggs

This Bureau of Mines report provides information on 138 waterflood projects in Wyoming. Injection was in 25 producing zones and 65 fields. Specific data presented include field location, discovery and development, water supply and injection, oil and water production, estimates of oil in place, and oil recoveries by primary and secondary methods. The 138 projects studied will, if successful, recover about 800 million barrels of secondary oil. Almost all of the injection water is from deep water wells.

Jan 1, 1970

By G. S. Rice

[This paper describes preliminary tests at the Bureau's Experimental Mine to determine, under conditions that may prevail ira bituminous coal-mine heading, how small a quantity of fire damp may bring coal-dust into suspension and ignite to it. The results show that the explosion of as little as 150 cubic feet of an explosive mixture of gas and air containing 9 per cent natural gas may start a disastrous explosion Of coal-dust. This is a very small volume, of gas, to cause such a result. Let us suppose that this amount of exclusive mixture, was at the face of an entry which was 10 feet wide and the face was overcut to a depth of 6 foot and an upper layer of coal 2 1/2 feet thick had been removed, the recess so made would save a volume of 150 cubic feet. Furthermore, only 13 cubic feet of pure methane is needed in this volume to produce this 9 per cent explosive mixture.]

Jan 1, 1930

By J. R. Allsup

In cooperation with the Division of Advanced Automotive Power Systems Development, Environmental Protection Agency, the Bureau of Mines studied a conventional spark-ignition engine as a prime mover for use in a hybrid system. The study involved both steady-state and transient engine operation with ignition timing, air-fuel ratio, exhaust gas recirculation, oxidizing type catalytic converters, engine speed, and power output as variables. Data were obtained from two 1971 model 350-cubic-inch-displacement engines mounted on engine dynamometer stands. When the hybrid engine was operated with an oxidizing catalyst at power output levels required for a 4,000-lb curb weight hybrid vehicle, carbon monoxide and hydrocarbon emissions could be reduced to approximately 2.0 grams and 0.3 gram per brake horsepower-hour, respectively. With exhaust gas recirculation, oxides of nitrogen emission levels could be reduced to approximately 1.2 grams per brake horsepower-hour.

Jan 1, 1974

By F. D. Wang

The Bureau of Mines has developed a computer program for evaluating pit slope stability by the finite element stress analysis and limiting equilibrium method. The program includes the finite element method of stress analysis using triangular elements, finite-element model mesh generation, plotting of the model mesh and stress contours, calculation of a factor of safety along a circular or a plane failure surface, and location of a critical circular failure surface. Instructions for preparation of input data, an example problem, and the program listing are presented.

Jan 1, 1972

By G. S. Rice

This paper describes preliminary tests at the Bureau's Experimental Mine to determine, under conditions that may prevail in a bituminous coal-mine heading, how small a quantity of fire damp may bring coal-dust into suspension and ignite it. The results show that the explosion of as little as 150 cubic feet of an explosive mixture of gas and air containing 9 per cent natural gas may start a disastrous explosion of coal-dust. This is a very small volume, of gas, to cause such a result. Let us suppose that this amount of explosive mixture, as at the face of an entry which was 10 feet wide and the face was overcut to a depth of 6 feet and an upper layer of coal 2.5 feet thick had been removed, the recess so made would have a volume of 150 cubic feet. Furthermore, only 13 cubic feet of pure methane is needed in thin volume to produce this 9 per cent explosive mixture.

Jan 1, 1930

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies for syn¬thetic Cu2S and CuS were measured. This investigation is part of the Bureau of Mines goals to provide thermodynamic data essential to the more efficient processing of copper ores, and thereby minimize the current dislocations in energy, environment, and mineral supply. Heat capacities were measured with an adiabatic calorimeter from 5 to 310 K, and resulted in S°298 = 27.76 for Cu2S(c) and S°298 = 16.05 cal/deg mole for CuS(c). Low-temperature values are tabulated for Cp°, S°, -(G°-Ho°)/T, and H°-Ho°. Enthalpies were measured with a copper block calorimeter from 298.15 to 1,600 K for Cu2S(c,1) and 298.15 to 780 K for CuS(c). The thermal behavior of CuS showed no transitions or other significant anomalies for the low- or high-temperature investigations. Cu2S showed reversible transitions at 376 K with an isothermal heat absorption of 0.865 kcal/mole, 720 K with an isothermal absorption of 0.280 kcal/mole, and approximately 1,400 K (congruent melting point) with a heat of fusion of 3.070 kcal/mole. High-temperature data are tabulated for H°-H°298, Cp°, S°, and -(G°-H°298)/T. Enthalpies are also expressed in equation form. The low¬and high-temperature data were combined with data from the literature to cal¬culate and tabulate ?Hf°, ?Gf°, and log Kf as a function of temperature.

Jan 1, 1978

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 5 Typical Input - Ouput The input data and the printed output for case 8 of the simulations (Section A.4) are shown in the following. The branch, level, node, miner and hoist numbers mentioned in the input and output refer to the corresponding numbers in Figures A-3, A-4 and A -5, The plotted ouput, already shown in Figures A,11 and A-12 is not repeated. The input data shown does not include the following simulation parameters: DTIME = 0, 05 FTIME = 130 JPLT(K) = 1 for K = 1, 2, 3 0 for other K TPLSTR = 0.0 TPLST P = 130

Jan 1, 1976

Provide a means of evaluating the in place structural properties of coal seams and coal measure rocks in advance of mining. Approach Develop a sonic logging probe for use in dry wells, a condition common to shallow wells and semi-arid coal regions. How It Works The Bureaus' sonic probe differs from conventional sonic probes because it does not require fluid in the well to couple sonic vibrations to the drill hole wall. A self-contained hydraulic system forces pistons containing the measurement transducers against the wall and clamps them in position until the sonic waveform information has been recorded. The pistons are then retracted and the probe is raised or lowered in the well as required. In the clamped position, the piezoceramic transmitter emits a sonic pulse which travels along the drill hole wall and is detected at the receivers in the form of compressional (P) and shear (S) wave motion. The receivers are designed to be sensitive to either the (P) wave or (S) wave motion as determined by the operator so that discrimination between the two wave types is improved by comparison of the respective output channels, and the travel time between transmitter and detectors can be accurately determined. Use of two receiver stations eliminates errors in timing of pulse travel because of electronic delays inherent in the probe.

Jan 1, 1981