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By R. Xie, J. Liu, Y. Zhu, Y. Li

The surface chemistry features of spodumene and feldspar were investigated by XPS, zeta potential measurements and first principle calculation. The results indicated that the zeta potential of feldspar was more negative than that of spodumene. The most possible active sites on spodumene and feldspar were Al sites and O sites. However, the number, type and activity of these sites were different. The flotation behaviour of five new collectors (cationic collector decyloxy-propyl-amine (DPA), anionic collector α-bromododecanoic acid (α-BDDA), N-Dodecyliminodiacetic acid (DIDA), and mixed collector DPA-BDDA and DPA-DIDA) were investigated through micro flotation experiments and analysed based on the surface chemistry features of spodumene and feldspar. The results revealed that cationic collector DPA processed a high collecting capacity for both minerals. The highest recovery of spodumene and feldspar was 91.60% and 95.30% respectively. The anionic collector α-BDDA and DIDA showed poor flotation behaviour. The recovery of spodumene and feldspar when using α-BDDA as collector was less than 5% and when using DIDA as collector was less than 1%. For the mixed collector DPA-BDDA, the recovery of spodumene and feldspar was 82.27% and 32.61% respectively at pH 4.5. For mixed collector DPA-DIDA, the recovery of spodumene and feldspar was 35.69% and 9.08% respectively at pH 5.8. The results indicated that the cationic collector had high collecting capacity, but low selectivity. The collecting capacity of anionic collector for spodumene and feldspar was poor at the same concentration compared with cationic collectors. Mixed collector DPA-BDDA showed good flotation behaviour and selectivity on spodumene. The ―COO- in mixed collector might improve the selectivity. However, too much ―COO- would increase the electrostatic repulsion, which might cause low selectively and poor recovery. Keywords: Spodumene, feldspar, surface chemistry features, mixed collector, flotation

Jan 1, 2020

By S. O. Bada

Coal is a complex mixture of organic and mineral constituents and is the most abundant resource of fossil energy in the world. In recent years, significant research into dry coal beneficiation has gained much attention, primarily due to the need to improve grades and reduce the environmental contaminants in coal without the use of water, and to achieve this in as cost-effective manner as possible, relative to wet beneficiation processes. This paper seeks to review the application of various electrostatic separators with their process principles, to draw comparisons between different dry beneficiation techniques with specific emphasis on the tribo-electrostatic separation method, and finally to report the results of tribo electrostatic separation conducted on various South African coals. Previous research conducted on Indian, European and American coals has indicated that this technique is likely to lead to significant economic benefit through the reduction of ash content, NOx and more specifically Sox by separating out the liberated Fe-S-bearing minerals prior to utilization. The removal of the latter suite of minerals is also likely to significantly reduce or eliminate the emissions of associated trace elements, including mercury and arsenic. The research results reported in this paper indicate that the rotary tribo-electrostatic process has the potential for significant upgrading of high ash pulverized South African coal. The impact of various operational parameters was investigated and key factors established for the optimum recovery of low ash and low sulphur fine coal.

Jan 1, 2010

Exxaro installed their first ultra fines treatment plant at Leeuwpan Coal mine. The plant is now fully operational and results already show that the plant has great potential. The plant was designed and installed by DRA. Several challenges were faced during the installation due to the space constraints in the Leeuwpan plant. Efficiency tests were conducted on both modules after commissioning and showed very promising results. A lower ash product with a higher yield can be produced with the fine coal dense medium cyclones compared to the spirals previously employed.

Jan 1, 2010

Slope stability is a fundamental part of a successful mining operation. It impacts directly on the safety of personnel and the economics of the mine. The Jwaneng Mine in Botswana is planning a push back of 644m depth in the south east wall. Mining will commence in 2010 and be completed in 2024. This will put the mine in the deep pit category. The mine has invested in extensive geotechnical data gathering and design programs that started as far back as 2003 for the south east wall. The south east wail of Jwaneng Mine is characterized by foliation that dips adversely into the mining faces. The orienta1ion of the foliation is variable due to intense tectonic movements that have also caused the occurrence of faults that are sub-vertical. A considerable amount of information on the characteristics of structural patterns and the rock mass has been collected. This paper presents an overview of the feasibility level geotechnical design that is about to be concluded.

Jan 1, 2010

By Thomas V. Fame, William E. Porter

"As geological and mining conditions become more complex, and as overall mining economics become more marginal, short- and long-range decision-making regarding multiple-seam surface mining becomes more difficult. The decision-making problem involves a study of economics, cut-off grades and ratios, equipment capabilities, sequencing and selective mining practices.This paper is concerned primarily with multiple-seam mining of bituminous coal. The research has led to the development of an economic decision-making model for use as a day-to-day tool to aid mine operators and pit geologists to decide what and how to mine.The model is designed as an aid for feasibility decision-making in multiple-scam situations and for situations where selective mining is needed or desired. In effect, a simulation of the feasibility and preliminary mine planning phases has been developed. The model is divided into four separate segments: decision-making, simulated mining, cost calculations and the determination of the discounted cash flow return on investment."

Jan 1, 2014

The February General Meeting of the Branch was held at the St. Helena Club on Wednesday, 19th February, 1969. Present were: Twelve members: Mr J. G. Kirchner (Chairman of the O.F.S. Branch), Messrs J. N. Saunders, N. A. Honnet, L. O. W. Leimer (Committee Members), Messrs R. C. Espley-Jones, J. W. Wilson, A. T. Lewis, A. von Holdt, L. J. Thorne, C. Mostert, V. O. Steed, H. H. Schellhorn. Nine Associate Members: Messrs E. R. Penny, G. T. C. Emere, M. Forster, K. Pearce, R. B. Sutherland, D. E. Couperthwaite,A. H. Edwards, M. D. de Lange, G. ,R. Still. Four Graduates: Messrs M. H. Smith, N. Mayer, T. R. Stromsoe, T. A. Ward. Four Affiliates: Messrs D. S. Robinson, L. D. Hulley, R. B. Smith, R. L. Soll11s.One Student: D. R. Fleming. Twenty-three Visitors. Total present: 53. Apologies were received from Messrs C. R. Netscher, A. Leger and V. C. Barnes. MINUTES OF PREVIOUS GENERAL MEETING The minutes of the General Meeting held on 15th November, 1968 and which were published in the February Journal, were taken as read and their adoption moved by Messrs J. N. Saunders and N. A. Honnet. There were no matters arising from the minutes. GENERAL BUSINESS The Chairman reminded members of the forthcoming visit by the Branch to the Dudfield Works of the Anglo-Alpha Cement Company, to take place on Wednesday 16th April. TALK ON ROCK MECHANICS The Chairman called upon Mr J. W. Wilson to address the meeting on the subject of the practical applications of rock mechanics to mining. Mr Wilson used a slide projector to present his subject in a most interesting and instructive manner which eventually resulted in much useful discussion taking place. The Chairman then called upon Mr A. von Holdt to thank the speaker. CLOSURE After thanking the speakers, the Chairman thanked members and visitors for their attendance and closed the meeting at about 10 p.m., after which refreshments were served.

By W. K. Brinsden

In August 1965, the late Mr Alan Smith, then Mill Superintendent at Gold Mines of Kalgoorlie (GMK), Australia, asked me to investigate the planting of vegetation on the GMK slimes dams in order to ease the dust problem in urban and industrial areas-a problem that is caused largely by dust from these barren slimes dams. My early sources of information were the comprehensive papers in various issues of the Journal of The South African Institute of Mining and Metallurgy. However, the climate of Johannesburg differs from that of Kalgoorlie. The average Johannesburg rainfall, which falls mostly in summer, is 730 mm, and the average maximum summer temperature is 26°C (top 34°C). The winters are cool, the average maximum being 18°C (low -7°C). Kalgoorlie, on the other hand, receives, on average, 257 mm of sporadic rainfall, has hot dry summers with an average maximum of 35°C (top 45°C), and cool winters with an average maximum of 18°C (low -2°C). My obvious choice was to look at established trees growing on the GMK lease. A number of Athel pines were growing vigorously adjacent to the Oroya mining and geology offices and also on a nearby sand dump. The Athel pine (Tamarix aphylla), which is native to North Africa, Asia, and India, was originally introduced into Australia in 1936 by Mr Essington Lewis, then manager of BHP. His cuttings were planted in Whyalla, where some difficulty had been experienced in finding trees and shrubs that would flourish despite the district's low rainfall. In August 1965, cuttings of approximately 20 cm length and 1 cm diameter were taken from the GMK trees, stripped of leaves, and placed in jars of water in the sun. When the cuttings had sprouted both leaves and roots, they were planted in local soil in tins (about 20 cm high and 10 cm in diameter), and watered daily. In October 1965, when the new shoots were about 8 cm long, the trees were transplanted onto a lower flat section¬approximately 30 m wide, 30 m long, and 2 m high-of the Trafalgar slimes dam. No additional soil or fertilizer was used, and the trees were planted in their tins, the bases of which had been removed (the tin would eventually rust away). A few common varieties of non-prickly cactus and two native salt bush (spp Atriplex) were also planted, but did not survive, probably because of the acidity of the slime. During the summer of 1965/1966, Kalgoorlie's rainfall was 88 per cent above the average, and this probably helped the trees to survive. The moisture content was usually about 2,5 per cent from about 10 cm below the surface, and the pH value of the slime (d80 approximately 75 µm) was about 6. The trees were watered twice a week for the first four months and then left untended. By 1974 they had grown to only about 0,7 m, which indicated that their growth in slime was very slow. Other Athel pines were planted on the wall of the dam, but did not survive beyond 1974, probably because of the steep (about 500) slope and the hardness of the walls, which were initially formed by hand-shovelling of the slime as the height of the dam was raised. Five of the six Athel pines planted in 1965, which probably reached maturity (approximately 5 m in height) in 1981-16 years after being planted-have survived. In the early 1980s, waste rock had to be dumped on the dam, but the management of KMA (now KCGM) took care to ensure that the trees were not buried. Trials are being conducted on other tailings dams so that the performance of cuttings taken from the trees on Trafalgar dam can be compared with that of cuttings taken at various sites in Western Australia. It might also be worth while for an attempt to be made to strike cuttings from Trafalgar dam in pots containing different mixtures of soil and slime.

Jan 1, 1991

By S. Mohanta, I. D. Behera, B. Sahoo

"Run-of-mine coal contains particles of different sizes with different specific gravities, and when this coal is crushed, the amount of material present in a particular density class changes. This alters the washability characteristics of the coal, which affects the quantity, quality, and separation efficiency of the gravity-based coal washing process. The degree of difficulty in washing a typical coal at a particular specific gravity depends mostly on the amount of material occurring within ±0.1 specific gravity range, which is known as ‘near-gravity material’ at that particular specific gravity of separation. In this paper, two numerical indices, namely ‘near-gravity material index’ and ‘index of washability’, are used to quantify the distribution of near-gravity material in different density classes and to evaluate the degree of difficulty involved in the washing process. The results of this preliminary investigation indicate the uniform distribution of near-gravity material in all density classes for finer size fractions, whereas for coarser size fractions more near-gravity material is present in the lower density classes, making the washing process more difficult at a lower specific gravity of separation. IntroductionThe prime objective of coal beneficiation is to remove physical impurities as effectively and economically as possible. The beneficiation process includes various operations on the asmined coal to make it more suitable for enduse application without destroying the physical identity of the coal. There are several coal beneficiation processes, but gravity-based separators remain the most efficient unit operation for removing the undesirable gangue material from run-of-mine coal. These separators exploit the difference in density between coal particles and gangue particles to effect a separation. The feed is introduced into an aqueous suspension of ultrafine magnetite with a particular density. The feed particles with a relative density less than that of the suspension (clean coal) float to the top surface of the suspension, whereas particles denser than the suspension density (gangue material) sink to the bottom. When the difference in density between the particle and the aqueous suspension is large, the separation is easy, but when this difference is less the separation becomes much more difficult since the settling velocity of the particles is very low. This lower settling velocity increases the probability that particles that should report to floats report to sinks, and vice versa, hence increasing the amount of misplaced material. Therefore, the degree of difficulty in beneficiating a typical coal at a particular specific gravity depends on the amount of material occurring within ±0.1 specific gravity range. This is known as ‘neargravity’ material, also termed ‘near-dense’ material, at that particular specific gravity of separation."

Jan 1, 2016

By T. Szendrei, S. Tose

The Gurney approach to explosive/inert material interaction was adapted to analyse the face velocity in bench blasting. The model is based on the blasthole diameter, rock and explosive density, burden, spacing, linear charge density, and the Gurney energy constant. It is validated by comparing its predictions with a set of 20 field measurements of face velocities reported by Chiappetta et al. (1983) in an iron ore mine. The Gurney model links the observed large scatter of measured face velocities to the variation of the Gurney energy constant. This in turn is linked to the variability of the gas pressure acting on the burden. These variable pressures are generated when detonation product gases migrate into the extensive and complex fracture network around and between in-row blastholes. The energy efficiency of burden movement can be derived from the model. It is shown that ~7% of the explosive’s chemical energy is available for gas expansion work on the burden; of this quantity, 36% is actually converted to burden kinetic energy. That is, less than 3% of chemical energy is ultimately expended in burden displacement and throw. The model further indicatesnthat the projection of high-velocity (say, 100 m/s) flyrock is possible only when the path of leastnresistance through the burden has an effective density far less than the host rock. An equationnis derived that identifies the combinations of burden and path density that may yield flyrock. These values are specific to a particular baseline blast design.

Jan 30, 2026

By M. Paricheh, M. Rahmanpour

"The cost efficiency and high reliability of semi-mobile or combined in-pit crushing-conveying (IPCC) and truck systems, compared to conventional truck-shovel systems alone, make them more attractive for use in modern mining operations. Semi-mobile systems, which are the most common systems in open-pit mining, combine the advantages of both systems such that fewer trucks are required, operating costs are lowered, and the operation is environmentally sound. One major aspect of utilizing this system is determining the location of the in-pit crusher and the timing of relocations. Facility location models are rarely used in the mining sector, but these models may be used for solving the in-pit crusher location problem. To this end, the main parameters affecting the IPCC location in open pit mines are reviewed and examples given of how they are applied to a dynamic location-relocation problem. Subsequently, the model is implemented for Sungun copper mine in Iran and the number and the exact time of relocations of the IPCC units determined. IntroductionNowadays, compared to the last century, metal prices are more volatile, average and cut-off grades have decreased, and stripping ratios increased. From a mining engineering point of view, many ore deposits with simple access and low capital and operating costs have been exhausted. The remaining deposits are located at depth, with no easy access, which requires high initial capital costs (Osanloo, 2012). Mining at great depths and high tonnages is possible only through open pit mining. Today, more than 80% of open pit mines in the world use a shovel-truck system for loading-hauling operations (Osanloo, 2010).With increasing depth, haulage distances increase and the number of loads per truck decreases. As a result, fuel, tyre, and depreciation costs per ton increase. Owing to these factors, open pit mining at great depth (300 to 1000 m) using shovel-truck systems faces some technical and economic problems. In-pit crushing-conveying (IPCC) systems have been known in the mining industry for many decades. The idea was introduced in 1956 in Germany. Today, the cost efficiency and high reliability of IPCC make it more appealing than conventional shovel-truck operation, especially in longer life projects with lengthy transportation distances and high production rates (Koehler, 2003). Since 1956, different aspects of this system have been reviewed by many researchers. Barua and Lanergan (1985) developed a computer program that compares the tonnage aspects of various conveyor layouts. They believed that to maximize the economic benefit of lower haulage costs associated with in-pit conveying, one must first minimize the cost of the flatter slope, which is expressed in terms of additional stripping or tied-up ore. Dos Santos and Stanisic (1987) evaluated the design of a high-angle conveyor at the Majdanpek copper mine. Then, Sturgul (1987) applied GPSS (general purpose simulation system) to find the best location of an in-pit crusher."

Jan 1, 2017

By Y. Yang, L. Li, X. Liu

Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.

Jan 26, 2023

Professor R. P. Plewman graduated with a B.Sc. in mining engineering from the University of the Witwatersrand in 1943, after which he had two years of military service. Mr P. W. J. van Rensburg attended St Andrew's College in Grahamstown before proceeding to the University of the Witwatersrand, where he obtained a B.Sc. (Eng.) degree cum laude in mining and metal. lurgy at the end of 1942 and was awarded the Chamber of Mines Scholarship and Gold Medal. Dr M. G. Atmore, Deputy Technical Director of the Anglo American Corporation of South Mrica, is also Manpower and Education Adviser to the Chamber of Mines of South Mrica and a Visiting Professor at the Imperial College of Science and Technology, London. Mr D. A. Vi1joen attended Queen's College, Queenstown, and then Rhodes University, where he gained a diploma in chemistry and a B. Comm. degree. Mr B. E. Protheroe, C.Eng., obtained a degree in Physical Metallurgy at University College, Cardiff, and an M.sc. in corrosion science from Swansea University. Mr N. J. Devine holds a B.Sc. in Metallurgical Engineering and a G.DE Mining Engineering, both from the University of the Witwatersrand. Dr Oskar Steffen graduated as a civil engineer at the University of the Witwatersrand in 1961, and obtained his master's degree in 1963.

Jan 1, 1984

By G. Akdogan, S. M. Bradshaw, M. I. Isaacs, P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached in order to remove base metals from a concentrate containing platinum group metals (PGMs). This paper investigates the atmospheric leaching process, in order to develop a better understanding of the leaching behaviour of the base metals; in particular Cu, Fe, Ni, and the PGMs in particular Ru and Ir with key process variables, acid concentration, copper concentration under oxidative leaching conditions. Higher initial acid concentration resulted in a higher copper, iron and nickel extractions, as well as higher leaching rates together with faster Cu, Ru, Ir precipitation occurring. On the other hand, a higher initial copper concentration resulted in more nickel but less iron being extracted. Keywords: PGM, converter matte, leaching, precipitation

Jan 1, 2020

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By M. S. Shishvan, S. Klerkx, J. Sattarvand

The inaccurately drilled blastholes from the planned locations cause changes in the spatial distribution of explosive energy; some areas of the blast may receive a surplus of explosive energy, while others see a reduction. This results in less uniform fragmentation, reduces the efficiency of mining operations and increases costs. Additionally, it can lead to slope stability issues, flyrock, and uneven benches. To mitigate these problems, this study attempts to reduce differences in the explosive energy distribution (EED) through an optimization approach that adjusts the height of explosive columns in blastholes. Two optimization algorithms, the Genetic Algorithm (GA) and Tabu Search (TS), are tested. The latter is preferred for its local search neighbourhood strategy that gives superior computation times. Applications on different blast patterns result in improvements of 0.53–1.54%, or 2.14–3.94% when only the affected blocks are considered.

Sep 1, 2021

By Y. Jeong, K. Kim

Excess water can lead to instability and even failure in tailings storage facilities (TSFs). Simply reducing the amount of water in TSFs could be the best way to ensure the safety of nearby communities. In this case study we investigated the effects of reducing the water content in tailings slurry at a copper-cobalt-zinc mine in Mexico. An environmentally friendly polymer was used as a drag reduction agent (DRA) to offset the increase in solids percentage. The potential effects of the increased solids concentration on the tailings transportation system were also assessed. A series of ‘what if’ studies was conducted to assess whether adding the polymer would allow the solids concentration to be increased without changing the pressure loss in the tailings pipeline. The studies entailed conducting pipe loop tests to investigate these changes under various solids/ polymer concentrations and then constructing a computational fluid dynamics (CFD) simulation model using the test results. The validated model was used to determine the optimal polymer percentages needed to maintain the same pressure loss under baseline (30% solids) conditions, and to assess the potential risks (clogging, increased erosion rates) to the pipelines. The potential water savings were found to be significant, varying from about 1.852 Mm3/a at 35% solids to 3.915 Mm3/a at 45% solids.

Dec 13, 2023

By C. Musingwini, A. S. Nhleko, P. M. Muke

Open-pit mine planning includes the determination of a long-term open-pit mine production scheduling (OMPS) plan. The OMPS plan is generally a three-dimensional (3D) block extraction sequence that seeks to maximise the net present value (NPV) of future cash flows, while complying with technical and operational constraints. The OMPS problem is computationally complex because it involves the analysis of large datasets, while simultaneously incorporating both multiple hard and soft constraints. The OMPS problem has been solved using deterministic or exact approaches, heuristic, and metaheuristic models. When compared to heuristic and metaheuristic models, deterministic approaches tend to take much longer to solve the OMPS problem when the number of constraints increases. Therefore, this paper presents a metaheuristic model which utilises a genetic algorithm (GA) framework to solve the OMPS problem. The GA-based model was applied to the Newman1 and Zuck Small mining instances, which are publicly available from the online MineLib database. The NPVs for the OMPS plan generated using the GA-based model for the two case studies were compared to the best-known published MineLib solutions obtained using the TopoSort heuristic model at the time of this study. For the Newman1 instance the equivalent annual NPVs were approximately US$6.6 million for the GA-based solution and US$5.1 million for the TopoSort solution. For the Zuck Small mining instance, the equivalent annual NPVs were approximately US$99.8 million for the GA-based solution and US$102.5 mil for the TopoSort solution. These results show that the GA-based model produced comparable solutions to some of the best-known solutions, thus, indicating strong potential application of GA-based models to solve OMPS problems.

Sep 1, 2021

By B. P. Watson, D. P. Roberts, R. A. Lamos

The Upper Group 2 (UG2) chromitite reef is a shallow-dipping stratiform tabular orebody in the South African Bushveld Complex, which strikes for hundreds of kilometres. Mining is extensive, with depths ranging from close-to-surface to 2 500 m. Pillars are widely used to support the open stopes and bords. Little work has been done in the past to determine the strength of pillars on the UG2 Reef and design was done using formulae developed for other hard-rock mines. This has led to oversized pillars with consequent sterilization of ore. In this paper we describe a back-analysis of stable and failed UG2 pillars on the Bushveld platinum mines, and provides a strength formula for UG2 pillars. The formula may be used cautiously on all Bushveld platinum mines with similar geotechnical, geometrical, and geomechanical conditions to the pillars in the database.

Aug 1, 2021

By A. C. Johnstone

The aim of the study is to determine if pit lakes are a sustainable coal mine closure option in South African. The water balance, chemistry, limnology, and bacterial population of three selected pit lakes were investigated. The lakes are in the three major coal basins of South Africa and are associated with different lithologies and mining methods. The major factors driving the water balance of the pit lakes are direct rainfall, runoff, inflow from old mine workings, and groundwater infiltration, with the major losses being evaporation or discharge onto surface. The study indicated that pit lakes can be designed as ’terminal sinks’ to provide a sustainable mine closure option. The pit lakes sampled have an alkaline pH, and mostly a sodium/calcium sulphate water with total dissolved solids content of less than 3000 mg/l. The phytoplankton and microbiological data indicates that the pit lakes support aquatic life. The study shows that correctly designed pit lakes can be an environmentally sustainable closure option for South Africa’s coal mines. A suggested design manual has been developed to assist mine owners and regulators in developing sustainable coal mine pit lakes as a closure option.

Oct 1, 2021

By H. Zhong, S. Wang, Q. Sun

The flotation performance of 2-(benzylthio)-acetohydroxamic acid (BTHA) to diaspore was first evaluated by micro-flotation tests. The adsorption mechanism was further investigated through adsorption experiments, molecular dynamics simulation, zeta potential and X-ray photoelectron spectroscopy (XPS). The results demonstrated that BTHA had a stronger ability to collect diaspore in comparison with another diaspore collector, benzohydroxamic acid (BHA), especially under the condition of weak alkalinity, the flotation recovery can reach 90%. The more negative interaction energy (ΔE) between BTHA and diaspore from molecular dynamics simulation results revealed that BTHA had an easier adsorption ablity onto diaspore than BHA, which matched with adsorption results. The zeta potential and XPS revealed that Al atoms might bond with -C(=O)NHOH by formation of Al-O bonds. Keywords: Diaspore, flotation; adsorption; 2-(benzylthio)-acetohydroxamic acid

Jan 1, 2020